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High-temperature polymers · Material guide

PPSU

Tg 230 °C, the highest glass transition here, and repeatedly steam-autoclavable — the usual choice for sterilisable tooling when PEEK is too expensive. Stratasys and 3DXTech agree on 55 MPa…

4 product listings4 brands
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At a glance

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Tg 230 °C, the highest glass transition here, and repeatedly steam-autoclavable — the usual choice for sterilisable tooling when PEEK is too expensive. Stratasys and 3DXTech agree on 55 MPa printed tensile to within rounding.

Applications

PPSU is used in reusable instrument trays, sterilization cases and instrument handles because selected grades retain toughness through repeated hot-water, steam and disinfectant exposure. Syensqo also describes injection-molded hot-water plumbing components that replace brass: resistance to corrosion and hot chlorinated water, combined with low creep under load, supports durable fittings. Beverage-equipment fittings and sight windows are other listed uses.

Repeated hot cleaning is a central reason to choose PPSU over PSU, but the service cycle and formulation still matter. Aircraft-interior R-7000 compounds and hydrogen-system HYRA grades target different requirements from a general-purpose PPSU resin. FDM requires demanding chamber and drying conditions, and some printed grades are far less ductile than stock. Qualifying a printed fitting or reusable device therefore includes its actual cleaning cycles, joints, impact loads and end-use requirements.

  • Injection-molded hot-water plumbing components ↗

    Injection molding · Selected Radel PPSU and Acudel modified PPSU resins; not an FDM pressure qualification · Manufacturer-listed applications

    Syensqo describes PPSU and modified PPSU replacing brass in hot-water systems, with tight molding tolerances, resistance to chlorinated water and low creep under sustained warm loads.

Sources
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Representative catalog values. Check the exact grade and its linked conditions before using a setting.

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Nozzle temperature (°C)

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Full value & sources

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04

Drying

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Full value & sources

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Properties & source data

39 documented fields

Open a topic to explore the complete data. Each value keeps its original conditions, units and dated sources.

Material & market7 fields
PPSU — Identity & Market
Property and unitPublished value and conditionsSources and dates
Base polymer / chemistryPolyphenylsulfone — an amorphous high-temperature sulfone polymer
1 source
Density (g/cm³)1.28 (ISO 1183, 3DXTech; ASTM D792, Stratasys PPSF)
2 sources
Typical price (USD/kg)1 kg-equivalent spools span 223–733; the middle of the market is about 425
4 sources
Price range across brands (USD/kg)223-733 across brands; IEMAI 3D 223 at 1 kg, 3DXTech ThermaX PPSU 250 at 500 g, 3D4Makers 425 at 750 g, Kimya PPSU-S 733 at 500 g
4 sources
Market availability (1–5)Niche, a handful of specialist brands
3 sources
Spool sizes & diameters1.75 and 2.85 mm; 200 g to 750 g spools
3 sources
Typical applicationsSteam-sterilisable medical and dental tooling, and aircraft interior parts
1 source
Print settings4 fields
PPSU — Printing Parameters
Property and unitPublished value and conditionsSources and dates
Bed temperature (°C)130–150 (3DXTech)
1 source
Enclosure / chamber requirement (1–5)Actively heated chamber required
2 sources
Warping tendency (1–5)Severe — heated chamber needed
1 source
Overall printing difficulty (1–5)Expert / industrial hardware only
2 sources
Nozzle wear & reliability3 fields
PPSU — Hardware Wear & Reliability
Property and unitPublished value and conditionsSources and dates
Nozzle hardness required (1–4)Brass fine indefinitely for unfilled grades, but brass softens near these nozzle temperatures — hardened or plated hot ends are the norm
1 source
Abrasiveness (1–5)Non-abrasive when unfilled
1 source
Nozzle clog risk (1–5)Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print
1 source
Moisture & drying2 fields
PPSU — Moisture Behaviour
Property and unitPublished value and conditionsSources and dates
Equilibrium moisture content at ~50 % RH (%)0.37 in 24 h and 1.1 at saturation on extruded stock (ASTM D570)
1 source
Effect of moisture on strengthNo dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures
1 source
Strength & mechanical properties10 fields
PPSU — Mechanical Properties
Property and unitPublished value and conditionsSources and dates
Tensile strength (XY) (MPa)55 (printed XY, ISO 527, 3DXTech) and 55 (printed on side long edge, ASTM D638, Stratasys PPSF); 79 at yield on extruded stock
3 sources
Young's modulus (MPa)2100 (printed, ASTM D638, Stratasys PPSF) and 2310 (printed XY, ISO 527, 3DXTech); 2344 on extruded stock
3 sources
Elongation at break (%)3 (printed, ISO 527 and ASTM D638) against 60 on extruded stock — printing costs PPSU almost all of its ductility
3 sources
Flexural strength (MPa)110 (printed, ISO 178 and ASTM D790, 3DXTech and Stratasys PPSF agree); 91 on extruded stock
3 sources
Flexural modulus (MPa)2200 (printed, ASTM D790, Stratasys PPSF) and 2215 (printed XY, ISO 178, 3DXTech)
2 sources
Other impact dataIzod notched 58.7 J/m and unnotched 165.5 J/m (printed, ASTM D256 Method A, Stratasys PPSF); 160 J/m notched on extruded stock
2 sources
Brittleness (1–5)Brittle — snaps with little warning
1 source
Hardness (scale-specific) (Shore A / Shore D / Rockwell)Rockwell M86 on printed PPSF (ASTM D785, Stratasys); M96 on extruded PPSU stock (and an unlabelled 123)
2 sources
Creep resistance / sustained load (1–5)Good. Printed PPSF holds 189 °C heat deflection at 1.8 MPa (ASTM D648) and extruded stock is rated 149 °C long-term service, but Ensinger does not claim the creep resistance it claims for PSU and PPS
2 sources
Elasticity / flexibility (1–5)Rigid
1 source
Heat & temperature6 fields
PPSU — Thermal Properties
Property and unitPublished value and conditionsSources and dates
HDT at 0.45 MPa (°C)190 (printed XY, ISO 75 at 0.45 MPa, 3DXTech)
1 source
HDT at 1.8 MPa (°C)189 (printed, ASTM D648 at 264 psi, Stratasys PPSF); 207 on extruded stock, converted from 405 °F
2 sources
Glass transition (Tg) (°C)230 (DSC) — the highest glass transition in the dataset
1 source
Continuous service temperature (°C)149 long-term service on extruded PPSU stock, converted from 300 °F
1 source
Thermal expansion (CTE) (µm/m·K)55.0 (printed PPSF, ASTM D696; source states 5.5e-5 mm/mm/°C) and 55.8 on extruded stock (ASTM D696, from 3.1e-5 in/in/°F)
2 sources
Flammability / UL 94UL 94 V-0 at 1.5 mm, rated on the base resin
1 source
Weather & chemical resistance2 fields
PPSU — Environment & Chemical
Property and unitPublished value and conditionsSources and dates
Chemical resistanceWithstands repeated steam autoclaving, the usual reason to choose PPSU over PSU; Stratasys also lists PPSF as passing 24 h stress-crack exposure to antifreeze, petrol, motor oil, power-steering, transmission and washer fluid at 23 °C and 100 °C
2 sources
Electrical & ESD propertiesVolume resistivity 5e13 to 1.5e14 ohm-cm and dielectric strength 80-290 V/mil on printed PPSF (ASTM D257, D149)
1 source
Health & safety2 fields
PPSU — Health & Safety
Property and unitPublished value and conditionsSources and dates
Fume toxicity (1–5)Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered
1 source
Ventilation / filtration requirement (1–5)Ventilated room or enclosure recommended
1 source
Solvents & solubility3 fields
PPSU — Solvents & Solubility
Property and unitPublished value and conditionsSources and dates
Soluble inDichloromethane dissolves it at 23 °C at every stress level; acetone solvates and softens unstressed PPSU (Solvay ESCR).
1 source
Softened or crazed byMEK ruptures stressed parts and toluene crazes them above 13.8 MPa; glass-filled grades survive where unfilled craze.
1 source
Solvent welding & smoothing agentDichloromethane cements PPSU and NMP softens residual resin; both are laboratory reagents, not workshop stock.
1 source
How to read these values

Values describe representative grades, not every spool. Manufacturer datasheets and independent tests retain their source labels and dates. Printed orientation, test method, conditioning and formulation can change results. Unknown values are —. A listed use is not a certification. Shore A, Shore D and Rockwell hardness are separate scales.

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Product listings and datasheets

4 listings

Historical USD/kg snapshots. Read each listing’s sale/from qualifiers, spool mass, source date, shipping and tax notes. Product figures are separate from the material summary.

Browse 4 products from 4 brands
IEMAI 3DPPSU223.00 USD/kg

$223.00 / 1 kg spool, store.iemai3d.com, Aug 2026

One of the few high-temperature data sheets that reports printed XY against ZX specimens rather than resin figures.

Open product listing ↗
IEMAI 3D PPSU — product-specific figures
Density (g/cm³)1.209 printed part density (ISO 1183-1)
Tensile strength (XY) (MPa)65.1 printed XY against 51.6 printed ZX (ISO 527, dried specimens)
Young's modulus (MPa)2037 printed XY and 2036 ZX (ISO 527, dried specimens)
Elongation at break (%)6.5 printed XY against 3.2 ZX at break (ISO 527)
Flexural strength (MPa)92.6 printed XY and 96.5 ZX (ISO 178)
Charpy impact, notched (kJ/m²)13.8 notched Charpy printed XY against 5.5 ZX (ISO 179-2)
Other impact dataUnnotched Charpy 200.7 kJ/m² printed XY against 22.6 ZX; notched Izod 12.0 against 5.5 (ISO 179-2, ISO 180)
Layer adhesion / Z tensile (MPa)51.6 printed ZX (ISO 527, dried)
Z strength as % of XY (%)79 (printed ZX against XY tensile, ISO 527)
HDT at 0.45 MPa (°C)218 (ISO 75-2 at 0.45 MPa)
HDT at 1.8 MPa (°C)212 (ISO 75-2 at 1.8 MPa)
Glass transition (Tg) (°C)220 (ISO 11357-2)
Thermal expansion (CTE) (µm/m·K)55 (ISO 11359-2)
Flammability / UL 94Passes FAR 25.853(a) 12 s and 60 s vertical burn at 1.59 and 6.35 mm
3DXTechThermaX PPSU250.00 USD/kg

$125.00 / 500 g spool = $250.00/kg, 3dxtech.com product catalogue, Aug 2026

Handle thermax-ppsu-1.

Open product listing ↗
3DXTech ThermaX PPSU — product-specific figures
Density (g/cm³)1.28 (ISO 1183)
Nozzle temperature (°C)390–410 (TDS printed-specimen condition)
Bed temperature (°C)130–150 (TDS printed-specimen condition)
Tensile strength (XY) (MPa)55 (printed XY, ISO 527)
Young's modulus (MPa)2310 (printed XY, ISO 527)
Elongation at break (%)3 (printed XY, ISO 527)
Flexural strength (MPa)110 (printed XY, ISO 178)
Flexural modulus (MPa)2215 (printed XY, ISO 178)
HDT at 0.45 MPa (°C)190 (ISO 75, 0.45 MPa)
Glass transition (Tg) (°C)230 (DSC)
Flammability / UL 94UL 94 V-0 at 1.5 mm (base resin)
3D4MakersPPSU Filament424.80 USD/kg

EUR 295.00 / 750 g spool = $424.80/kg at 1.08 USD/EUR, 3d4makers.com catalogue, Aug 2026

The 3D4Makers table lists '2340 MPa' under Tensile Stress; that is a modulus figure mislabelled, so no tensile strength is recorded here.

Open product listing ↗
3D4Makers PPSU Filament — product-specific figures
Density (g/cm³)1.29 (ASTM D792)
Diameter tolerance (± mm)0.05 at 1.75 mm; 0.10 at 2.85 mm, 99 % roundness
Nozzle temperature (°C)390–410
Bed temperature (°C)120–220
Bed surface & adhesion aidMagigoo HT on glass or a PEI sheet
Drying temperature & time120 °C for 2–4 h
Flexural modulus (MPa)2410 (ASTM D790)
Other impact dataIzod notched 690 J/m (ASTM D256); tensile impact 399 kJ/m² (ASTM D1822)
KimyaPPSU-S732.56 USD/kg

EUR 339.15 incl. 19 % VAT / 500 g spool = EUR 678.30/kg = $732.56/kg at 1.08 USD/EUR, igo3d.com, Aug 2026

Kimya prints its test specimens XY at 15–30 mm/s.

Open product listing ↗
Kimya PPSU-S — product-specific figures
Density (g/cm³)1.29 (ASTM D792)
Diameter tolerance (± mm)0.1 at 1.75 mm
Nozzle temperature (°C)360–400
Bed temperature (°C)140
Equilibrium moisture content at ~50 % RH (%)0.37 water absorption in 24 h (ASTM D250)
Tensile strength (XY) (MPa)69.6 (printed XY, ASTM D638)
Young's modulus (MPa)2340 (printed XY, ASTM D638)
Elongation at break (%)60–120 at break, 7.2 at yield (printed XY, ASTM D638)
Flexural strength (MPa)91 (printed XY, ASTM D790)
Flexural modulus (MPa)2410 (printed XY, ASTM D790)
Other impact dataTensile impact 399 kJ/m² (printed XY, ASTM D1822)
HDT at 1.8 MPa (°C)207 (ASTM D648, 1.8 MPa)
Glass transition (Tg) (°C)220 (ASTM E1356)
Continuous service temperature (°C)180 maximum use temperature
Food contactApproved to EU 10/2011 for all colours
Electrical & ESD propertiesVolume resistivity 9.0×10^15 Ω·cm (ASTM D257); dielectric constant 3.44 (ASTM D150)

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