Filament comparison
PPS vs TPU 98A
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | PPSHIGHTEMP | TPU 98A / hard TPUFLEX |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $116.97/kg median; $84.00–$200.00/kg across 3 dated product listings | $94.99/kg median; $34.99–$149.99/kg across 3 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Polyphenylene sulfide — a semi-crystalline high-temperature polymer[1][2] | Hard thermoplastic polyurethane at 98 Shore A to about 60 Shore D — the rigid end of the TPU range[3][4] |
| Densityg/cm³ | 1.28 (ISO 1183, 3DXTech) and 1.33 (ISO 1183, Spectrum PPS AM230)[1][5] | 1.23 (Fillamentum Flexfill 98A); 1.2 (Extrudr FLEX HARD, ISO 2781)[3][4] |
| Typical priceUSD/kg | 1 kg-equivalent spools span 84–200; the middle of the market is about 117[6][7][8] | 1 kg spools cluster near 150[9] |
| Price range across brandsUSD/kg | 84-200 across brands and diameters; IEMAI 3D 84 at 1 kg, Spectrum PPS AM230 117 at 750 g, 3DXTech ThermaX PPS 140 at 2.85 mm and 200 at 1.75 mm[6][7][8] | 95–150 across brands; Proto-pasta Clear Rigid TPU 95, Push Plastic TPU 100A 150[10][9] |
| Market availability1–5 | Niche, a handful of specialist brands[6][7] | Available from several mainstream brands[9][10][4] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 500 g and 750 g spools[6][7] | 1.75 and 2.85 mm; 0.5, 0.75 and 1 kg spools[10][9] |
| Typical applications | Chemical-plant and under-bonnet parts needing solvent resistance above 200 °C[2] | Drive belts, wheels, snap-fits and bumpers that need to flex but hold shape under load[3] |
| Printing Parameters | ||
| Nozzle temperature°C | 335-345 (3DXTech printed-specimen conditions); 300-330 (Spectrum)[1][5] | 230–260 (Extrudr FLEX HARD)[4] |
| Bed temperature°C | 110-130 (3DXTech); 100-120 (Spectrum)[1][5] | 50–90 (Extrudr FLEX HARD)[4] |
| Enclosure / chamber requirement1–5 | Actively heated chamber required[11][12] | Open frame is fine[4] |
| Recommended chamber temperature°C | 60-80 actively heated (Spectrum PPS AM230)[5] | Not documented |
| Part cooling fan | Not documented | 0–30 % (Extrudr FLEX HARD)[4] |
| Bed surface & adhesion aid | Adhesive required — Spectrum specifies Magigoo Pro HT[5] | PEI sheet or painter's tape; Polymaker warns TPU can over-stick and advises a glue stick as a release agent[13][14] |
| Maximum volumetric flow (mm³/s; see test conditions)mm³/s | Not documented | 4.6 (Extrudr FLEX HARD, stated max volumetric speed on a 0.4 mm nozzle)[4] |
| Warping tendency1–5 | Not documented | None[4] |
| Overall printing difficulty1–5 | Expert / industrial hardware only[11][12] | Easy — minor profile tuning; at this hardness the filament pushes like a rigid material[4] |
| Extruder requirement | Not documented | Bowden viable at this hardness — Extrudr rates FLEX HARD to 100 mm/s where its soft grades cap lower[4] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Brass fine indefinitely for unfilled grades, but brass softens near these nozzle temperatures — hardened or plated hot ends are the norm[11] | Brass fine indefinitely[4] |
| Abrasiveness1–5 | Non-abrasive when unfilled[1] | Non-abrasive[4] |
| Nozzle clog risk1–5 | Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 110 °C pre-dry before every print[15] | Low[16] |
| Heat-creep / jam sensitivity1–5 | Not documented | Moderate — good heatbreak cooling needed[14] |
| Hotend requirement | Not documented | No special hot-end required, but a direct-drive extruder is (Simplify3D)[13] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Negligible (<0.1 % EMC) — Polymaker states minimal water absorption at 0.05 %[2] | Moderate — the TPU family absorbs readily; Extrudr specifies a 12 h dry at 60 °C for FLEX HARD[4][16] |
| Equilibrium moisture content at ~50 % RH% | 0.01 in 24 h on extruded stock (ASTM D570) — effectively non-absorbing[17] | Not documented |
| Drying temperature & time | At least 3 h at 90 °C in hot dry air if the filament has taken up moisture (Spectrum)[5] | 60 °C for 12 h (Extrudr FLEX HARD)[4] |
| Symptoms when wet | Not documented | Bubbling and popping at the nozzle, stringing and a rough surface[16] |
| Effect of moisture on strength | Little to measure — equilibrium uptake is 0.05 %; 3DXTech still specifies a 110 °C, 4 h pre-dry before printing[2][15] | Polymaker groups TPU with the highly hygroscopic materials; no dry-versus-conditioned figures are published[16] |
| Storage requirement | Not documented | Sealed with desiccant; often kept in a dryer during the print[16] |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 50 at break (printed XY, ISO 527, 3DXTech); 65 at break injection-moulded (ISO 527, Spectrum); 94 at yield on extruded stock (ASTM D638)[1][5][17] | 53.7 at break (Fillamentum Flexfill 98A, DIN 53504)[3] |
| Young's modulusMPa | 2650 (printed XY, ISO 527, 3DXTech); 3650 injection-moulded (ISO 527, Spectrum); 5769 on extruded stock (ASTM D638)[1][5][17] | Not documented |
| Elongation at break% | 18 at break (printed XY, ISO 527, 3DXTech) against 2.0 injection-moulded (Spectrum) and 2.5 on extruded stock — the suppliers disagree by nearly an order of magnitude[1][5][17] | 318 at break (Fillamentum Flexfill 98A, DIN 53504); Extrudr FLEX HARD 490 (ISO 527-2)[3][4] |
| Flexural strengthMPa | 52 (printed XY, ISO 178, 3DXTech); 141 on extruded stock (ASTM D790)[1][17] | Not documented |
| Flexural modulusMPa | 2540 (printed XY, ISO 178)[1] | Not documented |
| Charpy impact, notchedkJ/m² | 1.3 notched injection-moulded (ISO 179-1eA, Spectrum); unnotched 18[5] | Not documented |
| Other impact data | Izod notched 33 J/m on extruded PPS stock, converted from 0.62 ft-lb/in (ASTM D256)[17] | Not documented |
| Brittleness1–5 | Moderate[1] | Very ductile — bends far before failing[3] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Rockwell 105 (and R124) on extruded PPS stock (ASTM D785)[17] | 98 Shore A and 60 Shore D (Fillamentum, ISO 7619-1); Extrudr FLEX HARD 58 Shore D (ISO 868)[3][4] |
| Creep resistance / sustained load1–5 | Excellent — holds load for years. Ensinger lists high creep resistance as a headline property of extruded PPS stock, and Spectrum states that rigidity, strength and creep resistance are unchanged under continuous load at high temperature[17][5] | Poor — no 98A creep test; a printed 95A TPU bar crept from 74.5 to 82.7 mm over 5 days at 1.25 kg[18] |
| Fatigue / repeated-flex resistance1–5 | Not documented | Excellent — living hinges viable[14] |
| Elasticity / flexibility1–5 | Rigid[1] | Semi-flexible[3][4] |
| Wear resistance & friction | Not documented | Abrasion 23 mm³ (Fillamentum, ISO 4649 method A) and 26 mm³ (Extrudr FLEX HARD, ISO 4649-A) — the best abrasion figures in the group[3][4] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 90 (printed XY, ISO 75 at 0.45 MPa, 3DXTech); 129 injection-moulded (ISO 75, Spectrum); 204 on extruded stock (ASTM D648 at 66 psi)[1][5][17] | Not documented |
| HDT at 1.8 MPa°C | 107 injection-moulded (ISO 75 at 1.81 MPa, Spectrum); 104 on extruded stock (ASTM D648 at 264 psi)[5][17] | Not documented |
| Melting point / Vicat°C | 283 melting (ISO 11357, 3DXTech) and 280 on extruded stock; Vicat softening 236 at 50 N injection-moulded (ISO 306, Spectrum)[1][5][17] | 190–210 melting (Extrudr FLEX HARD, ISO 3146-C); Vicat A 140 (ISO 306)[4] |
| Continuous service temperature°C | 170 long-term service on extruded PPS stock, converted from 338 °F[17] | Not documented |
| Thermal expansion (CTE)µm/m·K | 59.4 (extruded PPS stock, 22-60 °C, ASTM D696; source states 3.3e-5 in/in/°F)[17] | Not documented |
| Flammability / UL 94 | UL 94 V-0 at 1.5 mm, rated on the base resin[1] | Not documented |
| Environment & Chemical | ||
| UV resistance1–5 | Not documented | Good — years with some colour shift; Polymaker lists UV exposure among the conditions TPU withstands[14] |
| Chemical resistance | Outstanding — PPS resists essentially all solvents below 200 °C[2] | Withstands industrial solvents and UV exposure (Polymaker)[14] |
| Water / humidity resistance in service1–5 | Excellent — essentially unaffected; extruded stock takes up 0.01 % water in 24 h[17] | Not documented |
| Food contact | Not documented | Not food safe without specific certification (Polymaker)[14] |
| Biodegradability / compostability | Not documented | Not biodegradable[14] |
| Recyclability | Not documented | Not accepted in household plastic collection[14] |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[19] | Low hazard — minimal VOC and particle emission; TPU was not among the nine filaments in the chamber study[19] |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[19] | Open a window / occasional ventilation[19] |
| Post-Processing | ||
| Sanding & machining | Not documented | Difficult to sand or smooth; Polymaker limits post-processing to trimming or tumbling[14] |
| Gluing & solvent welding | Not documented | Cyanoacrylate bonds TPU; no common solvent welds it[14] |
| Vapour / chemical smoothing | Not documented | No practical vapour smoothing[14] |
| Support material pairing | Not documented | Polymaker warns TPU supports are often very difficult to remove[14] |
| Dimensional accuracy & detail | Not documented | Tear strength 170 kN/m (Fillamentum, ISO 34-1) and 175 kN/m (Extrudr FLEX HARD, ISO 34-1B)[3][4] |
| Solvents & Solubility | ||
| Soluble in | None — PPS does not dissolve in any known solvent below 200 °C.[20][21] | DMF, DMSO, NMP and THF dissolve TPU; acetone, MEK and cyclohexanone are partial solvents. All laboratory reagents.[22] |
| Softened or crazed by | Nothing at 23 °C; Ensinger rates it only conditionally resistant to benzene, dichloromethane, toluene and pyridine.[21] | Toluene and benzene swell it up to +50 % by weight at 23 °C; esters swell it severely; ethanol and IPA soften it.[22] |
| Solvent welding & smoothing agent | None — no solvent welds or smooths PPS.[20] | None practical — the true solvents (DMF, THF, NMP) are laboratory reagents and leave the joint swollen and weak.[22] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- ThermaX PPS Technical Data Sheet v3 3DXTech · 2026-08 · tds
- PPS — material basics Polymaker Wiki · 2026-08 · doc
- Flexfill TPU 98A Technical Data Sheet Fillamentum · 2019-08 · tds
- Extrudr Product Catalogue (DURAPRO PA12 data block) Extrudr · 2025-03 · tds
- Spectrum PPS AM230 Technical Data Sheet Spectrum Filaments · 2022-04 · tds
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- Spectrum PPS AM230 Natural, 1.75 mm / 750 g 3DJAKE · 2026-08 · vendor
- IEMAI 3D PPS 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- Push Plastic product catalogue Push Plastic · 2026-08 · vendor
- Proto-pasta product catalogue Proto-pasta · 2026-08 · vendor
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- Flexible (TPE/TPU) — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- TPU — material basics Polymaker Wiki · 2026-08 · doc
- THERMAX PPS — product page (print recommendations) 3DXTech · 2026-08 · doc
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- TECATRON natural (PPS) — stock shape properties Ensinger · 2026-08 · tds
- BambuLab TPU 95A HF vs Qidi TPU 95A HF — results spreadsheet My Tech Fun (Igor Gaspar) · 2024-02 · test
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- PPS (Polyphenylene sulfide) — Knowledge Base Prusa Research · 2026-08 · doc
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
- Elastollan — Chemical properties: swelling and chemical resistance BASF · 2026-08 · tds