3D Printing InfoFilament comparison
PPA vs PPSU
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | PPA (polyphthalamide)PA | PPSUHIGHTEMP |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $45.49/kg median; $45.49–$45.49/kg across 1 dated product listings | $337.40/kg median; $223.00–$732.56/kg across 4 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Polyphthalamide — a semi-aromatic polyamide in which aromatic diacid units replace part of the aliphatic backbone; Raise3D and Bambu Lab both label it high-temperature nylon[1][2] | Polyphenylsulfone — an amorphous high-temperature sulfone polymer[3] |
| Densityg/cm³ | 1.21 (ISO 1183, Siraya Tech Fibreheart PPA)[4] | 1.28 (ISO 1183, 3DXTech; ASTM D792, Stratasys PPSF)[3][5] |
| Typical priceUSD/kg | One 1 kg listing on the market, at 45[6] | 1 kg-equivalent spools span 223–733; the middle of the market is about 425[7][8][9][10] |
| Price range across brandsUSD/kg | 45 for the only unfilled PPA filament found — Siraya Tech Fibreheart PPA at 1 kg; every other PPA in retail is carbon- or glass-filled[6] | 223-733 across brands; IEMAI 3D 223 at 1 kg, 3DXTech ThermaX PPSU 250 at 500 g, 3D4Makers 425 at 750 g, Kimya PPSU-S 733 at 500 g[7][8][9][10] |
| Market availability1–5 | Special order, 1–2 makers worldwide — Siraya Tech is the only brand found selling unfilled PPA filament[6] | Niche, a handful of specialist brands[7][8][9] |
| Spool sizes & diameters | 1.75 mm, 1 kg[6] | 1.75 and 2.85 mm; 200 g to 750 g spools[7][8][9] |
| Typical applications | Gears, bearings and tooling that must hold load above the reach of PA6 or PA12, and parts exposed to fuels and industrial chemicals[4] | Steam-sterilisable medical and dental tooling, and aircraft interior parts[3] |
| Printing Parameters | ||
| Nozzle temperature°C | 280–300 (Siraya Tech)[4] | Not documented |
| Bed temperature°C | 70–80 (Siraya Tech)[4] | 130–150 (3DXTech)[3] |
| Enclosure / chamber requirement1–5 | Enclosure recommended — Siraya Tech advises an enclosure to hold temperature and limit warping on larger prints[4] | Actively heated chamber required[11][12] |
| Part cooling fan | 20–60 % (Siraya Tech)[4] | Not documented |
| Bed surface & adhesion aid | PEI sheet with a glue stick, or a PVP glue coating[4] | Not documented |
| Warping tendency1–5 | Not documented | Severe — heated chamber needed[11] |
| Overall printing difficulty1–5 | Advanced — enclosure, hardware upgrades, tuning; needs a 300 °C-class hot end and a dry spool[4] | Expert / industrial hardware only[11][12] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Brass fine indefinitely — Siraya Tech states a hardened steel nozzle is not needed for the unfilled grade[4] | Brass fine indefinitely for unfilled grades, but brass softens near these nozzle temperatures — hardened or plated hot ends are the norm[11] |
| Abrasiveness1–5 | Non-abrasive when unfilled[4] | Non-abrasive when unfilled[3] |
| Nozzle clog risk1–5 | Moderate — needs dry filament and a clean nozzle; Siraya Tech tells users to dry only when moisture symptoms appear, rather than before every print[4] | Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[13] |
| Hotend requirement | High-quality metal nozzle, 0.4–1.0 mm; hardened steel not required (Siraya Tech)[4] | Not documented |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | High (0.8–2 %) — Siraya Tech publishes 2.59 % by ISO 62 immersion for the unfilled grade; on the equilibrium basis Bambu Lab uses, its 15 % carbon-filled PPA reaches 1.30 % against 2.35 % for the same maker's PA6-CF[4][2][14] | Not documented |
| Equilibrium moisture content at ~50 % RH% | 2.59 by ISO 62 water immersion (Siraya Tech, unfilled) — an immersion figure, not the 25 °C / 55 % RH equilibrium basis the filled grades are quoted on, so the two are not directly comparable[4] | 0.37 in 24 h and 1.1 at saturation on extruded stock (ASTM D570)[15] |
| Drying temperature & time | 80–100 °C for 4–6 h (Siraya Tech)[4] | Not documented |
| Symptoms when wet | Oozing, bubbles and a rough surface finish (Siraya Tech)[4] | Not documented |
| Effect of moisture on strength | Siraya Tech publishes dry against saturated for the same grade: tensile 70 → 60 MPa, flexural 114 → 87 MPa, HDT at 1.8 MPa 73.5 → 48.5 °C, while Charpy rises 10 → 14.5 kJ/m²[4][6] | No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[13] |
| Storage requirement | Dry box below 15 % RH (Siraya Tech)[4] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 72 at break (printed, ASTM D638, Siraya Tech); the product page quotes 70 dry and 60 saturated[4][6] | 55 (printed XY, ISO 527, 3DXTech) and 55 (printed on side long edge, ASTM D638, Stratasys PPSF); 79 at yield on extruded stock[3][5][15] |
| Young's modulusMPa | 3600 (printed, ASTM D638, Siraya Tech)[4] | 2100 (printed, ASTM D638, Stratasys PPSF) and 2310 (printed XY, ISO 527, 3DXTech); 2344 on extruded stock[3][5][15] |
| Elongation at break% | 10.5 at break (printed, ASTM D638, Siraya Tech)[4] | 3 (printed, ISO 527 and ASTM D638) against 60 on extruded stock — printing costs PPSU almost all of its ductility[3][5][15] |
| Flexural strengthMPa | 115 (printed, ISO 178, Siraya Tech); 114 dry against 87 saturated on the product page[4][6] | 110 (printed, ISO 178 and ASTM D790, 3DXTech and Stratasys PPSF agree); 91 on extruded stock[3][5][15] |
| Flexural modulusMPa | 3350 (printed, ISO 178, Siraya Tech)[4] | 2200 (printed, ASTM D790, Stratasys PPSF) and 2215 (printed XY, ISO 178, 3DXTech)[3][5] |
| Charpy impact, notchedkJ/m² | 10.1 Charpy (printed, ISO 179, Siraya Tech); the data sheet does not state whether the specimen was notched[4] | Not documented |
| Other impact data | Not documented | Izod notched 58.7 J/m and unnotched 165.5 J/m (printed, ASTM D256 Method A, Stratasys PPSF); 160 J/m notched on extruded stock[5][15] |
| Brittleness1–5 | Moderate — 10.5 % elongation at break puts it between PA6 and the fibre-filled grades[4] | Brittle — snaps with little warning[3] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Not documented | Rockwell M86 on printed PPSF (ASTM D785, Stratasys); M96 on extruded PPSU stock (and an unlabelled 123)[5][15] |
| Creep resistance / sustained load1–5 | Good — Raise3D cites high creep resistance as a reason to choose the PPA matrix over other nylons[1] | Good. Printed PPSF holds 189 °C heat deflection at 1.8 MPa (ASTM D648) and extruded stock is rated 149 °C long-term service, but Ensinger does not claim the creep resistance it claims for PSU and PPS[5][15] |
| Elasticity / flexibility1–5 | Rigid — 3.6 GPa tensile modulus[4] | Rigid[3] |
| Wear resistance & friction | Siraya Tech describes the unfilled grade as low-friction and self-lubricating, aimed at gears and bearings[4][6] | Not documented |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 81 dry and 61 saturated (printed, ISO 75 Method B at 0.45 MPa, Siraya Tech)[4] | 190 (printed XY, ISO 75 at 0.45 MPa, 3DXTech)[3] |
| HDT at 1.8 MPa°C | 73.5 dry and 48.5 saturated (printed, ISO 75 Method A at 1.8 MPa, Siraya Tech) — unfilled PPA deflects near its Tg; the 190–227 °C figures quoted for PPA are carbon-filled grades[4][2] | 189 (printed, ASTM D648 at 264 psi, Stratasys PPSF); 207 on extruded stock, converted from 405 °F[5][15] |
| Glass transition (Tg)°C | 80 (ASTM D3418, Siraya Tech)[4] | 230 (DSC) — the highest glass transition in the dataset[3] |
| Melting point / Vicat°C | 231 melting point (ASTM D3418) and 230 Vicat (ISO 306), Siraya Tech[4] | Not documented |
| Continuous service temperature°C | Not documented | 149 long-term service on extruded PPSU stock, converted from 300 °F[15] |
| Annealing response | Siraya Tech's product page offers annealing for strength while its own data sheet says annealing is not recommended because the print can warp; on its 15 % carbon-filled PPA, annealing lifts HDT at 1.8 MPa from 82.5 to 119 °C[4][6][16] | Not documented |
| Thermal expansion (CTE)µm/m·K | Not documented | 55.0 (printed PPSF, ASTM D696; source states 5.5e-5 mm/mm/°C) and 55.8 on extruded stock (ASTM D696, from 3.1e-5 in/in/°F)[5][15] |
| Flammability / UL 94 | Not documented | UL 94 V-0 at 1.5 mm, rated on the base resin[3] |
| Environment & Chemical | ||
| Chemical resistance | Withstands fuels, oils and industrial chemicals; Bambu Lab rates semi-aromatic nylon better than general nylon against weak acids, weak alkalis and most organic solvents[4][2] | Withstands repeated steam autoclaving, the usual reason to choose PPSU over PSU; Stratasys also lists PPSF as passing 24 h stress-crack exposure to antifreeze, petrol, motor oil, power-steering, transmission and washer fluid at 23 °C and 100 °C[3][5] |
| Water / humidity resistance in service1–5 | Absorbs water, properties shift — a saturated specimen loses about 15 % of its tensile strength and 25 °C of heat-deflection temperature[4][6] | Not documented |
| Electrical & ESD properties | Not documented | Volume resistivity 5e13 to 1.5e14 ohm-cm and dielectric strength 80-290 V/mil on printed PPSF (ASTM D257, D149)[5] |
| Health & Safety | ||
| Fume toxicity1–5 | Not documented | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[17] |
| Ventilation / filtration requirement1–5 | Not documented | Ventilated room or enclosure recommended[17] |
| Post-Processing | ||
| Support material pairing | Compatible with quick-release support materials (Siraya Tech)[4] | Not documented |
| Solvents & Solubility | ||
| Soluble in | Dissolved at 23 °C by formic acid, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — all laboratory reagents.[18] | Dichloromethane dissolves it at 23 °C at every stress level; acetone solvates and softens unstressed PPSU (Solvay ESCR).[19] |
| Softened or crazed by | Mineral acids, oxidants, halogens and zinc chloride solutions attack the amide bond; ordinary solvents do not.[18] | MEK ruptures stressed parts and toluene crazes them above 13.8 MPa; glass-filled grades survive where unfilled craze.[19] |
| Solvent welding & smoothing agent | None — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[18] | Dichloromethane cements PPSU and NMP softens residual resin; both are laboratory reagents, not workshop stock.[19] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- Raise3D Industrial PPA CF Technical Data Sheet V2.0 Raise3D · 2022-04 · tds
- Bambu Filament Technical Data Sheet V1.0 — PPA-CF Bambu Lab · 2026-08 · tds
- ThermaX PPSU Technical Data Sheet v3 3DXTech · 2026-08 · tds
- Siraya Tech Fibreheart PPA Technical Data Sheet Siraya Tech · 2026-08 · tds
- PPSF (polyphenylsulfone) — FDM Data Sheet Stratasys · 2018-06 · tds
- Siraya Tech Fibreheart PPA Filament — product page Siraya Tech · 2026-08 · vendor
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- Kimya PPSU-S Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
- 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
- IEMAI 3D PPSU 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- THERMAX PPSU — product page (print recommendations) 3DXTech · 2026-08 · doc
- Bambu Filament Technical Data Sheet V3.0 — PA6-CF Bambu Lab · 2026-08 · tds
- TECASON P black (PPSU) — stock shape properties Ensinger · 2026-08 · tds
- Siraya Tech Fibreheart PPA-CF Technical Data Sheet Siraya Tech · 2026-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
- Radel PPSU, Veradel PESU, Acudel modified PPSU Design Guide — environmental stress cracking tables Solvay Specialty Polymers · 2026-08 · tds