Filament comparison
POM vs PPS
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | POM (acetal)ENGINEERING | PPSHIGHTEMP |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | Not documented | $116.97/kg median; $84.00–$200.00/kg across 3 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Polyoxymethylene, normally the copolymer POM-C. Apium's filament grade is POM-C with antistatic additives; no unfilled POM filament was found on sale[1][2] | Polyphenylene sulfide — a semi-crystalline high-temperature polymer[3][4] |
| Densityg/cm³ | 1.41 (extruded POM-C stock)[1] | 1.28 (ISO 1183, 3DXTech) and 1.33 (ISO 1183, Spectrum PPS AM230)[3][5] |
| Typical priceUSD/kg | Not documented | 1 kg-equivalent spools span 84–200; the middle of the market is about 117[6][7][8] |
| Price range across brandsUSD/kg | Not documented | 84-200 across brands and diameters; IEMAI 3D 84 at 1 kg, Spectrum PPS AM230 117 at 750 g, 3DXTech ThermaX PPS 140 at 2.85 mm and 200 at 1.75 mm[6][7][8] |
| Market availability1–5 | Special order, 1-2 makers worldwide — Apium sells a POM-C ESD filament through its own shop and states its printers are the only ones able to process POM-C; no POM filament appears in the 3DJAKE or igo3d product sitemaps, at MatterHackers or at Printed Solid[2][9][10][11] | Niche, a handful of specialist brands[6][7] |
| Spool sizes & diameters | Not documented | 1.75 and 2.85 mm; 500 g and 750 g spools[6][7] |
| Typical applications | Gears, bushings, bearings, conveyor and food-machinery parts; Apium markets its POM-C ESD grade for semiconductor insulators, aerospace fasteners and sliding parts[1][2] | Chemical-plant and under-bonnet parts needing solvent resistance above 200 °C[4] |
| Printing Parameters | ||
| Nozzle temperature°C | Not documented | 335-345 (3DXTech printed-specimen conditions); 300-330 (Spectrum)[3][5] |
| Bed temperature°C | Not documented | 110-130 (3DXTech); 100-120 (Spectrum)[3][5] |
| Enclosure / chamber requirement1–5 | Not documented | Actively heated chamber required[12][13] |
| Recommended chamber temperature°C | Not documented | 60-80 actively heated (Spectrum PPS AM230)[5] |
| Bed surface & adhesion aid | Not documented | Adhesive required — Spectrum specifies Magigoo Pro HT[5] |
| Overall printing difficulty1–5 | Not documented | Expert / industrial hardware only[12][13] |
| Extruder requirement | Apium states that the adaptive heating system on its industrial machines is what makes POM-C printable, and that no other 3D printer can process it[2] | Not documented |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Not documented | Brass fine indefinitely for unfilled grades, but brass softens near these nozzle temperatures — hardened or plated hot ends are the norm[12] |
| Abrasiveness1–5 | Not documented | Non-abrasive when unfilled[3] |
| Nozzle clog risk1–5 | Not documented | Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 110 °C pre-dry before every print[14] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Low (0.1-0.3 %) — extruded POM-C stock takes up 0.18 % in 24 h and 0.80 % at saturation (ASTM D570)[1] | Negligible (<0.1 % EMC) — Polymaker states minimal water absorption at 0.05 %[4] |
| Equilibrium moisture content at ~50 % RH% | Not documented | 0.01 in 24 h on extruded stock (ASTM D570) — effectively non-absorbing[15] |
| Drying temperature & time | Not documented | At least 3 h at 90 °C in hot dry air if the filament has taken up moisture (Spectrum)[5] |
| Effect of moisture on strength | Not documented | Little to measure — equilibrium uptake is 0.05 %; 3DXTech still specifies a 110 °C, 4 h pre-dry before printing[4][14] |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 66.9 at break and 64.1 at yield (extruded POM-C stock, ASTM D638; converted from 9700 and 9300 psi)[1] | 50 at break (printed XY, ISO 527, 3DXTech); 65 at break injection-moulded (ISO 527, Spectrum); 94 at yield on extruded stock (ASTM D638)[3][5][15] |
| Young's modulusMPa | 2275 (extruded POM-C stock, ASTM D638; converted from 330,000 psi)[1] | 2650 (printed XY, ISO 527, 3DXTech); 3650 injection-moulded (ISO 527, Spectrum); 5769 on extruded stock (ASTM D638)[3][5][15] |
| Elongation at break% | 40 at break and 9 at yield (extruded POM-C stock, ASTM D638)[1] | 18 at break (printed XY, ISO 527, 3DXTech) against 2.0 injection-moulded (Spectrum) and 2.5 on extruded stock — the suppliers disagree by nearly an order of magnitude[3][5][15] |
| Flexural strengthMPa | 89.6 (extruded POM-C stock, ASTM D790; converted from 13,000 psi)[1] | 52 (printed XY, ISO 178, 3DXTech); 141 on extruded stock (ASTM D790)[3][15] |
| Flexural modulusMPa | 2758 (extruded POM-C stock, ASTM D790; converted from 400,000 psi)[1] | 2540 (printed XY, ISO 178)[3] |
| Charpy impact, notchedkJ/m² | Not documented | 1.3 notched injection-moulded (ISO 179-1eA, Spectrum); unnotched 18[5] |
| Other impact data | Izod 53 J/m on extruded POM-C stock, converted from 1.0 ft-lb/in[1] | Izod notched 33 J/m on extruded PPS stock, converted from 0.62 ft-lb/in (ASTM D256)[15] |
| Brittleness1–5 | Tough — absorbs impact, yields before breaking; extruded stock elongates 40 % before failing. No printed figure is published[1] | Moderate[3] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Rockwell 86 (and R120) — the source names only the R scale on extruded POM-C stock (ASTM D785)[1] | Rockwell 105 (and R124) on extruded PPS stock (ASTM D785)[15] |
| Creep resistance / sustained load1–5 | Not documented | Excellent — holds load for years. Ensinger lists high creep resistance as a headline property of extruded PPS stock, and Spectrum states that rigidity, strength and creep resistance are unchanged under continuous load at high temperature[15][5] |
| Elasticity / flexibility1–5 | Not documented | Rigid[3] |
| Wear resistance & friction | Wear factor 65e-10 in3*min/(ft*lb*h) and a dynamic coefficient of friction of 0.21 at 40 psi and 50 fpm (ASTM D3702, extruded stock) — the properties that make acetal the default gear and bushing plastic; Apium lists good sliding properties as the reason for its grade[1][2] | Not documented |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 158 (extruded POM-C stock, ASTM D648 at 66 psi; converted from 316 °F)[1] | 90 (printed XY, ISO 75 at 0.45 MPa, 3DXTech); 129 injection-moulded (ISO 75, Spectrum); 204 on extruded stock (ASTM D648 at 66 psi)[3][5][15] |
| HDT at 1.8 MPa°C | 110 (extruded POM-C stock, ASTM D648 at 264 psi; converted from 230 °F)[1] | 107 injection-moulded (ISO 75 at 1.81 MPa, Spectrum); 104 on extruded stock (ASTM D648 at 264 psi)[5][15] |
| Melting point / Vicat°C | 165 melting (extruded POM-C stock; converted from 329 °F)[1] | 283 melting (ISO 11357, 3DXTech) and 280 on extruded stock; Vicat softening 236 at 50 N injection-moulded (ISO 306, Spectrum)[3][5][15] |
| Continuous service temperature°C | 91 long term and 141 intermittent (extruded POM-C stock; converted from 195 °F and 285 °F)[1] | 170 long-term service on extruded PPS stock, converted from 338 °F[15] |
| Thermal expansion (CTE)µm/m·K | 84.6 (extruded POM-C stock, ASTM D696; source states 4.7e-5 in/in/°F)[1] | 59.4 (extruded PPS stock, 22-60 °C, ASTM D696; source states 3.3e-5 in/in/°F)[15] |
| Flammability / UL 94 | UL 94 HB on extruded POM-C stock[1] | UL 94 V-0 at 1.5 mm, rated on the base resin[3] |
| Environment & Chemical | ||
| Chemical resistance | Good chemical resistance, particularly to bases; Apium lists resistance to bases as a headline property[1][2] | Outstanding — PPS resists essentially all solvents below 200 °C[4] |
| Water / humidity resistance in service1–5 | Good — minor absorption; 0.80 % water at saturation (ASTM D570, extruded stock)[1] | Excellent — essentially unaffected; extruded stock takes up 0.01 % water in 24 h[15] |
| Electrical & ESD properties | Volume resistance 1e14 ohm-cm, dielectric strength 500 V/mil and dielectric constant 3.7 at 60 Hz on extruded stock (ASTM D257, D149, D150); Apium's filament grade adds antistatic agents[1][2] | Not documented |
| Health & Safety | ||
| Fume toxicity1–5 | Not documented | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[16] |
| Ventilation / filtration requirement1–5 | Not documented | Ventilated room or enclosure recommended[16] |
| Post-Processing | ||
| Sanding & machining | Easy to machine — Ensinger lists machinability as a headline property of POM-C stock[1] | Not documented |
| Solvents & Solubility | ||
| Soluble in | Hexafluoroisopropanol dissolves it at room temperature; NMP and DMF only when hot. Laboratory reagents.[17] | None — PPS does not dissolve in any known solvent below 200 °C.[18][19] |
| Softened or crazed by | Acids, oxidants, halogens and hot concentrated zinc chloride attack it; alcohols, ketones and esters do not.[17][19] | Nothing at 23 °C; Ensinger rates it only conditionally resistant to benzene, dichloromethane, toluene and pyridine.[19] |
| Solvent welding & smoothing agent | None — no solvent softens POM below its melting point, which is why it is bolted or heat-welded rather than glued.[17] | None — no solvent welds or smooths PPS.[18] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- TECAFORM AH natural (POM-C) — stock shape properties Ensinger · 2026-08 · tds
- POM-C ESD 3D printing — material page Apium 3D Technologies · 2026-08 · doc
- ThermaX PPS Technical Data Sheet v3 3DXTech · 2026-08 · tds
- PPS — material basics Polymaker Wiki · 2026-08 · doc
- Spectrum PPS AM230 Technical Data Sheet Spectrum Filaments · 2022-04 · tds
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- Spectrum PPS AM230 Natural, 1.75 mm / 750 g 3DJAKE · 2026-08 · vendor
- IEMAI 3D PPS 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- 3DJAKE product catalogue 3DJAKE · 2026-08 · vendor
- igo3d product sitemap (17452 product URLs) igo3d · 2026-08 · vendor
- Printed Solid product catalogue Printed Solid · 2026-08 · vendor
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- THERMAX PPS — product page (print recommendations) 3DXTech · 2026-08 · doc
- TECATRON natural (PPS) — stock shape properties Ensinger · 2026-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Resistance of Ultramid, Ultraform and Ultradur to chemicals (TI-KTU/AS-28 e) BASF · 2000-10 · tds
- PPS (Polyphenylene sulfide) — Knowledge Base Prusa Research · 2026-08 · doc
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds