3D Printing Info

Filament comparison

PLA+ vs PPA

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PLA+ vs PPA — documented properties and sources
PropertyPLA+ / Tough PLAPLAPPA (polyphthalamide)PA
Market snapshot
Listing priceUSD/kg; dated snapshots$16.49/kg median; $10.45–$39.99/kg across 10 dated product listings$45.49/kg median; $45.49–$45.49/kg across 1 dated product listings
Identity & Market
Base polymer / chemistryPLA compounded with impact modifiers; suppliers publish the base as polylactic acid only[1][2]Polyphthalamide — a semi-aromatic polyamide in which aromatic diacid units replace part of the aliphatic backbone; Raise3D and Bambu Lab both label it high-temperature nylon[3][4]
Densityg/cm³1.17–1.24 (Polymaker); 1.21 (Bambu Lab, ISO 1183)[1][2]1.21 (ISO 1183, Siraya Tech Fibreheart PPA)[5]
Typical priceUSD/kgMainstream 1 kg spools cluster near 16[6][7]One 1 kg listing on the market, at 45[8]
Price range across brandsUSD/kg10–40 across brands; budget house brands 10–17, Sakata 3D HR-870 26, Polymaker and Fiberlogy 36–40[9][7][10][11][12]45 for the only unfilled PPA filament found — Siraya Tech Fibreheart PPA at 1 kg; every other PPA in retail is carbon- or glass-filled[8]
Market availability1–5Stocked by most mainstream brands[9][6][7][10][11]Special order, 1–2 makers worldwide — Siraya Tech is the only brand found selling unfilled PPA filament[8]
Spool sizes & diameters1.75 and 2.85 mm; 0.75, 0.85, 1 and 1.1 kg spools[10][11][9]1.75 mm, 1 kg[8]
Typical applicationsFunctional parts and enclosures that need impact tolerance but not heat resistance[1][2]Gears, bearings and tooling that must hold load above the reach of PA6 or PA12, and parts exposed to fuels and industrial chemicals[5]
Diameter tolerance± mm±0.03 (Bambu Lab)[13]Not documented
Printing Parameters
Nozzle temperature°C190–230 (Polymaker); Bambu Lab Tough+ needs 220–250[1][2]280–300 (Siraya Tech)[5]
Bed temperature°C25–60 (Polymaker); 35–65 (Bambu Lab Tough+)[1][2]70–80 (Siraya Tech)[5]
Enclosure / chamber requirement1–5Open frame is fine[1][2]Enclosure recommended — Siraya Tech advises an enclosure to hold temperature and limit warping on larger prints[5]
Part cooling fanFan on[1][2]20–60 % (Siraya Tech)[5]
Bed surface & adhesion aidTextured or smooth PEI; Bambu Lab recommends glue stick or liquid glue for Tough+[1][2]PEI sheet with a glue stick, or a PVP glue coating[5]
Warping tendency1–5None[1]Not documented
Bed-adhesion difficulty1–5Sticks to anything[14]Not documented
Stringing / oozing tendency1–5Slight — 1–3 mm retraction handles it[1][14]Not documented
Overall printing difficulty1–5Easy — minor profile tuning; Tough+ wants a hotter nozzle than plain PLA[1][2]Advanced — enclosure, hardware upgrades, tuning; needs a 300 °C-class hot end and a dry spool[5]
Hardware Wear & Reliability
Nozzle hardness required1–4Brass fine indefinitely[15]Brass fine indefinitely — Siraya Tech states a hardened steel nozzle is not needed for the unfilled grade[5]
Abrasiveness1–5Non-abrasive[16][15]Non-abrasive when unfilled[5]
Nozzle clog risk1–5Very low[15]Moderate — needs dry filament and a clean nozzle; Siraya Tech tells users to dry only when moisture symptoms appear, rather than before every print[5]
Heat-creep / jam sensitivity1–5Moderate — good heatbreak cooling needed; softens below 60 °C like plain PLA[17]Not documented
Hotend requirementNo special hot-end required[14]High-quality metal nozzle, 0.4–1.0 mm; hardened steel not required (Siraya Tech)[5]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Low — 0.27 % saturated at 25 °C / 55 % RH[2]High (0.8–2 %) — Siraya Tech publishes 2.59 % by ISO 62 immersion for the unfilled grade; on the equilibrium basis Bambu Lab uses, its 15 % carbon-filled PPA reaches 1.30 % against 2.35 % for the same maker's PA6-CF[5][4][18]
Equilibrium moisture content at ~50 % RH%0.27 saturated at 25 °C / 55 % RH (Bambu Lab Tough+)[2]2.59 by ISO 62 water immersion (Siraya Tech, unfilled) — an immersion figure, not the 25 °C / 55 % RH equilibrium basis the filled grades are quoted on, so the two are not directly comparable[5]
Drying temperature & time55 °C for 6–8 h; 65–75 °C for 12 h on a Bambu Lab X1 heatbed[1][2]80–100 °C for 4–6 h (Siraya Tech)[5]
Symptoms when wetBubbling and popping at the nozzle, stringing, rough surface and weak layers[19]Oozing, bubbles and a rough surface finish (Siraya Tech)[5]
Effect of moisture on strengthPolymaker rates PLA low-sensitivity and publishes no dry-versus-conditioned figures for the modified grades; the loss shows as poor layer adhesion rather than a strength number[19]Siraya Tech publishes dry against saturated for the same grade: tensile 70 → 60 MPa, flexural 114 → 87 MPa, HDT at 1.8 MPa 73.5 → 48.5 °C, while Charpy rises 10 → 14.5 kJ/m²[5][8]
Storage requirementSealed with desiccant below 20 % RH; shelf life at ambient is long[2][14]Dry box below 15 % RH (Siraya Tech)[5]
Mechanical Properties
Tensile strength (XY)MPa35–43 (printed XY, ISO 527); 53 on My Tech Fun 4×4 mm bars for Bambu Lab Tough[1][2][20][21]72 at break (printed, ASTM D638, Siraya Tech); the product page quotes 70 dry and 60 saturated[5][8]
Young's modulusMPa1860–2150 (printed XY, ISO 527) — below plain PLA at 2300–3427[1][2][22][23]3600 (printed, ASTM D638, Siraya Tech)[5]
Elongation at break%5.1–5.7 (printed XY, ISO 527)[1][2]10.5 at break (printed, ASTM D638, Siraya Tech)[5]
Flexural strengthMPa62–65 (printed XY, ISO 178) — below plain PLA at 76–87[1][2][24][23]115 (printed, ISO 178, Siraya Tech); 114 dry against 87 saturated on the product page[5][8]
Flexural modulusMPa2140–2393 (printed XY, ISO 178)[1][2]3350 (printed, ISO 178, Siraya Tech)[5]
Charpy impact, notchedkJ/m²38.9–72.3 (printed XY, ISO 179, notched) — 5–9× plain PLA[1][2]10.1 Charpy (printed, ISO 179, Siraya Tech); the data sheet does not state whether the specimen was notched[5]
Other impact dataCharpy unnotched 80.6 printed XY (Bambu Lab Tough+); CNC Kitchen measured ~20 vs 5 kJ/m² for PolyLite PLA[2][20]Not documented
Layer adhesion / Z tensileMPa20.9–32.4 printed Z (ISO 527); 33.0 on My Tech Fun layer-adhesion bars vs 27.6 for PLA Basic[1][2][21]Not documented
Brittleness1–5Tough — absorbs impact, yields before breaking[1][2][20]Moderate — 10.5 % elongation at break puts it between PA6 and the fibre-filled grades[5]
Hardness (scale-specific)Shore A / Shore D / Rockwell78.8 Shore D measured on printed bars (My Tech Fun), against 75.3 for the same maker's plain PLA[25]Not documented
Creep resistance / sustained load1–5Poor — 12 mm bar sagged to 20.2 mm over 5 days at 1.25 kg, the same as plain PLA[21][26]Good — Raise3D cites high creep resistance as a reason to choose the PPA matrix over other nylons[3]
Fatigue / repeated-flex resistance1–5Below average — impact modifiers raise absorbed energy 5–9×; plain PLA ran 38 000–49 000 cycles at 30 % of tensile strength[27][2][20]Not documented
Elasticity / flexibility1–5Rigid[1]Rigid — 3.6 GPa tensile modulus[5]
Z strength as % of XY%60 (Bambu Lab Tough+) to 78 (PolyMax PLA), printed[1][2]Not documented
Wear resistance & frictionNot documentedSiraya Tech describes the unfilled grade as low-friction and self-lubricating, aimed at gears and bearings[5][8]
Thermal Properties
HDT at 0.45 MPa°C55 (PolyMax) to 61 (Tough+), ISO 75 at 0.45 MPa[1][2]81 dry and 61 saturated (printed, ISO 75 Method B at 0.45 MPa, Siraya Tech)[5]
HDT at 1.8 MPa°C52 (PolyMax) to 58 (Tough+), ISO 75 at 1.8 MPa[1][2]73.5 dry and 48.5 saturated (printed, ISO 75 Method A at 1.8 MPa, Siraya Tech) — unfilled PPA deflects near its Tg; the 190–227 °C figures quoted for PPA are carbon-filled grades[5][4]
Glass transition (Tg)°C61 (DSC)[1][2]80 (ASTM D3418, Siraya Tech)[5]
Melting point / Vicat°C149–151 peak melt (DSC); Vicat 62 (ISO 306)[1][2]231 melting point (ASTM D3418) and 230 Vicat (ISO 306), Siraya Tech[5]
Continuous service temperature°C48–57 — loaded bars begin to move at this temperature: 48 for Polymaker PLA Pro, 50 for Sunlu PLA+, 52 for Bambu Lab Tough, 57 for PolyTerra PLA+[21][28][25][26]Not documented
Annealing responseNot documentedSiraya Tech's product page offers annealing for strength while its own data sheet says annealing is not recommended because the print can warp; on its 15 % carbon-filled PPA, annealing lifts HDT at 1.8 MPa from 82.5 to 119 °C[5][8][29]
Thermal expansion (CTE)µm/m·K96–99 for plain printed PLA (fibre Bragg grating, 25–50 °C); no grade-specific measurement published[30]Not documented
Flammability / UL 94Flammable; no UL 94 rating published by the major brands[2][1]Not documented
Environment & Chemical
UV resistance1–5Degrades within weeks outdoors[17][31]Not documented
Chemical resistanceGood against weak acids, oils and grease; poor against strong acids and alkalis[1][2]Withstands fuels, oils and industrial chemicals; Bambu Lab rates semi-aromatic nylon better than general nylon against weak acids, weak alkalis and most organic solvents[5][4]
Water / humidity resistance in service1–5Not documentedAbsorbs water, properties shift — a saturated specimen loses about 15 % of its tensile strength and 25 °C of heat-deflection temperature[5][8]
Food contactBase resin is food-contact grade, but printed layer grooves harbour bacteria; Prusa advises against food use[17]Not documented
Biodegradability / compostabilityIndustrially compostable only — needs sustained 55 °C; not home compostable[32][17]Not documented
RecyclabilityMechanically recyclable; not accepted in household plastic collection[32]Not documented
Health & Safety
Fume toxicity1–5Low hazard — minimal VOC and particle emission[33]Not documented
Ventilation / filtration requirement1–5None needed in a normal room[33]Not documented
Post-Processing
Sanding & machiningWet sanding — dry sanding heats the surface by friction and smears it[31][17]Not documented
Gluing & solvent weldingCyanoacrylate for most joints; some grades partially dissolve and bond with acetone[17][34]Not documented
Vapour / chemical smoothingNo practical vapour smoothing — only chloroform, hot benzene or THF, which are laboratory-only[17]Not documented
Support material pairingPolySupport and PolyDissolve S1 (Polymaker); Support for PLA (Bambu Lab)[1][2]Compatible with quick-release support materials (Siraya Tech)[5]
Dimensional accuracy & detail55° overhangs and 30 mm bridges (Bambu Lab Tough+)[2]Not documented
Solvents & Solubility
Soluble inChloroform: 10 % w/v in 2–4 h at 23 °C, every grade and morphology; THF and DMF only at 65 °C. Laboratory reagents.[35]Dissolved at 23 °C by formic acid, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — all laboratory reagents.[36]
Softened or crazed byAcetone, ethyl acetate and toluene plasticise it but dissolve <1 % even at 65 °C; submersion in acetone crazes and destroys parts.[35][37]Mineral acids, oxidants, halogens and zinc chloride solutions attack the amide bond; ordinary solvents do not.[36]
Solvent welding & smoothing agentChloroform vapour smooths and welds PLA at the cost of tensile strength; acetone does not smooth it at all.[38][37]None — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[36]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. PolyMax PLA Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
  2. Bambu Filament Technical Data Sheet V3.0 — PLA Tough+ Bambu Lab · 2026-08 · tds
  3. Raise3D Industrial PPA CF Technical Data Sheet V2.0 Raise3D · 2022-04 · tds
  4. Bambu Filament Technical Data Sheet V1.0 — PPA-CF Bambu Lab · 2026-08 · tds
  5. Siraya Tech Fibreheart PPA Technical Data Sheet Siraya Tech · 2026-08 · tds
  6. eSUN PLA+ 1.75mm 1KG eSUN Official Store · 2026-08 · vendor
  7. Overture PLA+ 1.75mm Overture3D · 2026-08 · vendor
  8. Siraya Tech Fibreheart PPA Filament — product page Siraya Tech · 2026-08 · vendor
  9. JAYO PLA+ 1.1KG Reusable Spool 1.75mm JAYO Official Store · 2026-08 · vendor
  10. Polymaker PolyMax PLA 0.75kg Polymaker Shop · 2026-08 · vendor
  11. Fiberlogy Impact PLA 850g 3DJake International · 2026-08 · vendor
  12. PLA HR-870 NATURAL Sakata 3D Filaments · 2026-08 · vendor
  13. PLA Basic — product page Bambu Lab US Store · 2026-08 · vendor
  14. PLA — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  15. Filament Material Guide Prusa Knowledge Base · 2026-08 · doc
  16. Prusament PLA — material page Prusa Polymers · 2026-08 · doc
  17. PLA — material guide Prusa Knowledge Base · 2026-08 · doc
  18. Bambu Filament Technical Data Sheet V3.0 — PA6-CF Bambu Lab · 2026-08 · tds
  19. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  20. The difference of PLA and PLA+ tested! (feat. Polymaker) CNC Kitchen · 2020-08 · test
  21. BambuLab PLA Basic vs PLA Tough vs PLA-CF — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  22. Prusament PLA Technical Datasheet v1.1 Prusa Polymers · 2022-02 · tds
  23. PolyLite PLA Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
  24. Bambu Filament Technical Data Sheet V3.0 — PLA Basic Bambu Lab · 2026-08 · tds
  25. Carbon Fiber PLA vs META-PLA vs PLA+ vs PLA by Sunlu — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  26. PolyTerra PLA vs PLA+ — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  27. Mechanical Properties of Additively Manufactured Polymeric Materials — PLA and PETG — For Biomechanical Applications Polymers 16(13):1868 · 2024-06 · paper
  28. Polymaker PLA Pro vs PLA-CF — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  29. Siraya Tech Fibreheart PPA-CF Technical Data Sheet Siraya Tech · 2026-08 · tds
  30. Characterization of Thermal Expansion Coefficient of 3D Printing Polymeric Materials Using Fiber Bragg Grating Sensors Materials 17(18):4668 · 2024-09 · paper
  31. Prusament PLA Technical Data Sheet v1.0 Prusa Polymers · 2018-09 · tds
  32. Filamentive PLA (recycled) — product page Filamentive · 2026-08 · vendor
  33. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  34. Prusament rPLA Corn Pigment 1kg — product page Prusa Research · 2026-08 · vendor
  35. Solubility Study of Ingeo Biopolymer Grades in Common Organic Solvents (NWPD003) NatureWorks · 2019-10 · tds
  36. Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
  37. Improve your 3D prints with chemical smoothing Prusa Research · 2026-08 · doc
  38. Effect of vapour smoothing in trichloromethane on 3D printed PLA — surface, mechanical and chemical structure Pitale, Keche & Chopra, Engineering Research Express 6(4) 045579 · 2024-12 · paper