3D Printing Info

Filament comparison

PEKK vs TPU-CF

Compare printing settings, strength, heat resistance, dated prices and sources.

PEKK guideCarbon-fibre TPU guide

2 selected · all documented properties

Open these two in the interactive comparisonMore PEKK comparisonsMore TPU-CF comparisons
PEKK vs TPU-CF — documented properties and sources
PropertyPEKKHIGHTEMPCarbon-fibre TPUFLEX
Market snapshot
Listing priceUSD/kg; dated snapshots$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings$107.05/kg median; $107.05–$107.05/kg across 1 dated product listings
Identity & Market
Base polymer / chemistryPolyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[1][2]Carbon-fibre reinforced thermoplastic polyurethane at the hard end of the range[3]
Densityg/cm³1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[2][1]1.22 (Extrudr FLEX HARD CF, ISO 2781)[3]
Typical priceUSD/kg1 kg-equivalent spools cluster near 550[4][5][6]107 for the only retail listing found (Extrudr 0.5 kg coil, incl. VAT)[7]
Price range across brandsUSD/kg333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[4][5][6][8][9]One listing only: EUR 49.56 incl. VAT per 0.5 kg coil, direct from Extrudr; no reseller or second brand found[7]
Market availability1–5Niche, a handful of specialist brands[4][5][6]Niche, a handful of specialist brands — Extrudr's FLEX HARD CF is the only carbon-filled flexible with a published datasheet found here[3]
Spool sizes & diameters1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[4][5][2]1.75 mm; 0.5 and 2 kg coils[7]
Typical applicationsAerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[1][2]Stiffened flexible parts — damping mounts and semi-rigid brackets[3]
Printing Parameters
Nozzle temperature°CNot documented230–260 (Extrudr FLEX HARD CF)[3]
Bed temperature°C140 (3DXTech CarbonX PEKK-A CF15)[1]50–90 (Extrudr FLEX HARD CF)[3]
Enclosure / chamber requirement1–5Actively heated chamber required[10][11]Open frame is fine[3]
Bed surface & adhesion aidNot documentedPEI sheet or painter's tape; Polymaker warns TPU can over-stick and advises a glue stick as a release agent[12][13]
Maximum volumetric flow (mm³/s; see test conditions)mm³/sNot documented1.6–8 at the 20–100 mm/s Extrudr specifies on a 0.4 mm nozzle at 0.2 mm layer[3]
Overall printing difficulty1–5Expert / industrial hardware only[10][11]Advanced — enclosure, hardware upgrades, tuning; hardened nozzle needed[3]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[1][2]Hardened steel required — Extrudr marks FLEX HARD CF as needing a hardened nozzle where its unfilled FLEX grades do not[3]
Abrasiveness1–5Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[1][2]Highly abrasive — standard CF composite[3]
Nozzle clog risk1–5Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[14]High — jams from moisture, heat creep or particles; a flexible base plus chopped carbon fibre, which Prusa lists as a higher nozzle-clogging risk, and Extrudr requires a hardened nozzle[15][3][12]
Hotend requirementNot documentedNo special hot-end required, but a direct-drive extruder is (Simplify3D)[12]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Not documentedModerate[16]
Drying temperature & timeNot documented60 °C for 6 h (Extrudr FLEX HARD CF)[3]
Symptoms when wetNot documentedBubbling and popping at the nozzle, stringing and a rough surface[16]
Effect of moisture on strengthNo dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[14]Polymaker groups TPU with the highly hygroscopic materials; no dry-versus-conditioned figures are published[16]
Storage requirementNot documentedSealed with desiccant; often kept in a dryer during the print[16]
Mechanical Properties
Tensile strength (XY)MPa86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]Not documented
Young's modulusMPa2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]35 (Extrudr FLEX HARD CF, ISO 527-2/5A/500)[3]
Elongation at break%6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[2][1]380 ultimate elongation (Extrudr FLEX HARD CF, ISO 527-2/5A/500), against 490 for the unfilled FLEX HARD[3]
Flexural strengthMPa136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]Not documented
Flexural modulusMPa3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]Not documented
Other impact dataIzod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[2]Not documented
Layer adhesion / Z tensileMPa50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[2][17]Not documented
Brittleness1–5Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[2][1]Very ductile — bends far before failing[3]
Hardness (scale-specific)Shore A / Shore D / RockwellNot documented70 Shore D (Extrudr FLEX HARD CF, ISO 868), against 58 Shore D for the unfilled FLEX HARD[3]
Creep resistance / sustained load1–5Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[2]Below average — no CF-grade creep test; the grade is 70 Shore D where a 95A TPU bar crept from 74.5 to 82.7 mm over 5 days at 1.25 kg[3][18]
Fatigue / repeated-flex resistance1–5Not documentedGood — 380 % ultimate elongation and a damping application set (Extrudr cites longboard wheels), below the unfilled grades[3]
Elasticity / flexibility1–5Rigid[1]Semi-flexible[3]
Z strength as % of XY%56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[2][17]Not documented
Wear resistance & frictionNot documentedAbrasion 26 mm³ (Extrudr FLEX HARD CF, ISO 4649-A) — the same as the unfilled FLEX HARD[3]
Thermal Properties
HDT at 0.45 MPa°C158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[2][1]Not documented
HDT at 1.8 MPa°C156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[2]Not documented
Glass transition (Tg)°C156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[2][1]-24 (Extrudr FLEX HARD CF)[3]
Melting point / Vicat°C300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[2][1]Vicat A 140 (Extrudr FLEX HARD CF, ISO 306)[3]
Thermal expansion (CTE)µm/m·K36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[2][17]Not documented
Environment & Chemical
UV resistance1–5Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[2]Good — years with some colour shift; Polymaker lists UV exposure among the conditions TPU withstands[13]
Chemical resistanceNot documentedWithstands industrial solvents and UV exposure (Polymaker)[13]
Food contactNot documentedNot food safe without specific certification (Polymaker)[13]
Biodegradability / compostabilityNot documentedNot biodegradable[13]
RecyclabilityNot documentedNot accepted in household plastic collection[13]
Electrical & ESD propertiesUnfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[2][1][17]Not documented
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[19]Low hazard — minimal VOC and particle emission; TPU was not among the nine filaments in the chamber study[19]
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[19]Open a window / occasional ventilation[19]
Dust & fibre handling hazardCarbon fibre is bound in the matrix; sanding dust should not be inhaled[1]Carbon fibre is bound in the matrix; sanding dust should not be inhaled[3]
Post-Processing
Sanding & machiningNot documentedDifficult to sand or smooth; Polymaker limits post-processing to trimming or tumbling[13]
Gluing & solvent weldingNot documentedCyanoacrylate bonds TPU; no common solvent welds it[13]
Vapour / chemical smoothingNot documentedNo practical vapour smoothing[13]
Support material pairingNot documentedPolymaker warns TPU supports are often very difficult to remove[13]
Dimensional accuracy & detailNot documentedTear strength 165 kN/m (Extrudr FLEX HARD CF, ISO 34-1B)[3]
Solvents & Solubility
Soluble inConcentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[20][21]DMF, DMSO, NMP and THF dissolve the TPU matrix and leave the fibre; ketones are partial solvents. Laboratory reagents.[22]
Softened or crazed byConcentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[20]Toluene and benzene swell it up to +50 % by weight at 23 °C; esters swell it severely; ethanol and IPA soften it.[22]
Solvent welding & smoothing agentNone — no solvent softens a polyaryletherketone.[20]None practical — the true solvents (DMF, THF, NMP) are laboratory reagents and leave the joint swollen and weak.[22]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  2. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  3. Extrudr Product Catalogue (DURAPRO PA12 data block) Extrudr · 2025-03 · tds
  4. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  5. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  6. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  7. Extrudr TPU FLEX Hard CF — product page (1.75 mm, 0.5 and 2 kg coils, price) Extrudr (FD3D GmbH) · 2026-08 · vendor
  8. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  9. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  10. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  11. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  12. Flexible (TPE/TPU) — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  13. TPU — material basics Polymaker Wiki · 2026-08 · doc
  14. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  15. Composite materials filled with carbon, kevlar or glass Prusa Knowledge Base · 2026-08 · doc
  16. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  17. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  18. BambuLab TPU 95A HF vs Qidi TPU 95A HF — results spreadsheet My Tech Fun (Igor Gaspar) · 2024-02 · test
  19. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  20. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  21. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
  22. Elastollan — Chemical properties: swelling and chemical resistance BASF · 2026-08 · tds