Filament comparison
PEKK vs TPU 98A
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | PEKKHIGHTEMP | TPU 98A / hard TPUFLEX |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $525.00/kg median; $332.50–$771.12/kg across 6 dated product listings | $94.99/kg median; $34.99–$149.99/kg across 3 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Polyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[1][2] | Hard thermoplastic polyurethane at 98 Shore A to about 60 Shore D — the rigid end of the TPU range[3][4] |
| Densityg/cm³ | 1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[2][1] | 1.23 (Fillamentum Flexfill 98A); 1.2 (Extrudr FLEX HARD, ISO 2781)[3][4] |
| Typical priceUSD/kg | 1 kg-equivalent spools cluster near 550[5][6][7] | 1 kg spools cluster near 150[8] |
| Price range across brandsUSD/kg | 333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[5][6][7][9][10] | 95–150 across brands; Proto-pasta Clear Rigid TPU 95, Push Plastic TPU 100A 150[11][8] |
| Market availability1–5 | Niche, a handful of specialist brands[5][6][7] | Available from several mainstream brands[8][11][4] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[5][6][2] | 1.75 and 2.85 mm; 0.5, 0.75 and 1 kg spools[11][8] |
| Typical applications | Aerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[1][2] | Drive belts, wheels, snap-fits and bumpers that need to flex but hold shape under load[3] |
| Printing Parameters | ||
| Nozzle temperature°C | Not documented | 230–260 (Extrudr FLEX HARD)[4] |
| Bed temperature°C | 140 (3DXTech CarbonX PEKK-A CF15)[1] | 50–90 (Extrudr FLEX HARD)[4] |
| Enclosure / chamber requirement1–5 | Actively heated chamber required[12][13] | Open frame is fine[4] |
| Part cooling fan | Not documented | 0–30 % (Extrudr FLEX HARD)[4] |
| Bed surface & adhesion aid | Not documented | PEI sheet or painter's tape; Polymaker warns TPU can over-stick and advises a glue stick as a release agent[14][15] |
| Maximum volumetric flow (mm³/s; see test conditions)mm³/s | Not documented | 4.6 (Extrudr FLEX HARD, stated max volumetric speed on a 0.4 mm nozzle)[4] |
| Warping tendency1–5 | Not documented | None[4] |
| Overall printing difficulty1–5 | Expert / industrial hardware only[12][13] | Easy — minor profile tuning; at this hardness the filament pushes like a rigid material[4] |
| Extruder requirement | Not documented | Bowden viable at this hardness — Extrudr rates FLEX HARD to 100 mm/s where its soft grades cap lower[4] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[1][2] | Brass fine indefinitely[4] |
| Abrasiveness1–5 | Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[1][2] | Non-abrasive[4] |
| Nozzle clog risk1–5 | Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[16] | Low[17] |
| Heat-creep / jam sensitivity1–5 | Not documented | Moderate — good heatbreak cooling needed[15] |
| Hotend requirement | Not documented | No special hot-end required, but a direct-drive extruder is (Simplify3D)[14] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Not documented | Moderate — the TPU family absorbs readily; Extrudr specifies a 12 h dry at 60 °C for FLEX HARD[4][17] |
| Drying temperature & time | Not documented | 60 °C for 12 h (Extrudr FLEX HARD)[4] |
| Symptoms when wet | Not documented | Bubbling and popping at the nozzle, stringing and a rough surface[17] |
| Effect of moisture on strength | No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[16] | Polymaker groups TPU with the highly hygroscopic materials; no dry-versus-conditioned figures are published[17] |
| Storage requirement | Not documented | Sealed with desiccant; often kept in a dryer during the print[17] |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1] | 53.7 at break (Fillamentum Flexfill 98A, DIN 53504)[3] |
| Young's modulusMPa | 2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1] | Not documented |
| Elongation at break% | 6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[2][1] | 318 at break (Fillamentum Flexfill 98A, DIN 53504); Extrudr FLEX HARD 490 (ISO 527-2)[3][4] |
| Flexural strengthMPa | 136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1] | Not documented |
| Flexural modulusMPa | 3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1] | Not documented |
| Other impact data | Izod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[2] | Not documented |
| Layer adhesion / Z tensileMPa | 50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[2][18] | Not documented |
| Brittleness1–5 | Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[2][1] | Very ductile — bends far before failing[3] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Not documented | 98 Shore A and 60 Shore D (Fillamentum, ISO 7619-1); Extrudr FLEX HARD 58 Shore D (ISO 868)[3][4] |
| Creep resistance / sustained load1–5 | Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[2] | Poor — no 98A creep test; a printed 95A TPU bar crept from 74.5 to 82.7 mm over 5 days at 1.25 kg[19] |
| Fatigue / repeated-flex resistance1–5 | Not documented | Excellent — living hinges viable[15] |
| Elasticity / flexibility1–5 | Rigid[1] | Semi-flexible[3][4] |
| Z strength as % of XY% | 56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[2][18] | Not documented |
| Wear resistance & friction | Not documented | Abrasion 23 mm³ (Fillamentum, ISO 4649 method A) and 26 mm³ (Extrudr FLEX HARD, ISO 4649-A) — the best abrasion figures in the group[3][4] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[2][1] | Not documented |
| HDT at 1.8 MPa°C | 156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[2] | Not documented |
| Glass transition (Tg)°C | 156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[2][1] | Not documented |
| Melting point / Vicat°C | 300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[2][1] | 190–210 melting (Extrudr FLEX HARD, ISO 3146-C); Vicat A 140 (ISO 306)[4] |
| Thermal expansion (CTE)µm/m·K | 36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[2][18] | Not documented |
| Environment & Chemical | ||
| UV resistance1–5 | Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[2] | Good — years with some colour shift; Polymaker lists UV exposure among the conditions TPU withstands[15] |
| Chemical resistance | Not documented | Withstands industrial solvents and UV exposure (Polymaker)[15] |
| Food contact | Not documented | Not food safe without specific certification (Polymaker)[15] |
| Biodegradability / compostability | Not documented | Not biodegradable[15] |
| Recyclability | Not documented | Not accepted in household plastic collection[15] |
| Electrical & ESD properties | Unfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[2][1][18] | Not documented |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[20] | Low hazard — minimal VOC and particle emission; TPU was not among the nine filaments in the chamber study[20] |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[20] | Open a window / occasional ventilation[20] |
| Dust & fibre handling hazard | Carbon fibre is bound in the matrix; sanding dust should not be inhaled[1] | Not documented |
| Post-Processing | ||
| Sanding & machining | Not documented | Difficult to sand or smooth; Polymaker limits post-processing to trimming or tumbling[15] |
| Gluing & solvent welding | Not documented | Cyanoacrylate bonds TPU; no common solvent welds it[15] |
| Vapour / chemical smoothing | Not documented | No practical vapour smoothing[15] |
| Support material pairing | Not documented | Polymaker warns TPU supports are often very difficult to remove[15] |
| Dimensional accuracy & detail | Not documented | Tear strength 170 kN/m (Fillamentum, ISO 34-1) and 175 kN/m (Extrudr FLEX HARD, ISO 34-1B)[3][4] |
| Solvents & Solubility | ||
| Soluble in | Concentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[21][22] | DMF, DMSO, NMP and THF dissolve TPU; acetone, MEK and cyclohexanone are partial solvents. All laboratory reagents.[23] |
| Softened or crazed by | Concentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[21] | Toluene and benzene swell it up to +50 % by weight at 23 °C; esters swell it severely; ethanol and IPA soften it.[23] |
| Solvent welding & smoothing agent | None — no solvent softens a polyaryletherketone.[21] | None practical — the true solvents (DMF, THF, NMP) are laboratory reagents and leave the joint swollen and weak.[23] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
- Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
- Flexfill TPU 98A Technical Data Sheet Fillamentum · 2019-08 · tds
- Extrudr Product Catalogue (DURAPRO PA12 data block) Extrudr · 2025-03 · tds
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
- Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
- Push Plastic product catalogue Push Plastic · 2026-08 · vendor
- Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
- IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- Proto-pasta product catalogue Proto-pasta · 2026-08 · vendor
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- Flexible (TPE/TPU) — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- TPU — material basics Polymaker Wiki · 2026-08 · doc
- THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
- BambuLab TPU 95A HF vs Qidi TPU 95A HF — results spreadsheet My Tech Fun (Igor Gaspar) · 2024-02 · test
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
- The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
- Elastollan — Chemical properties: swelling and chemical resistance BASF · 2026-08 · tds