Filament comparison
PEKK vs PSU
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | PEKKHIGHTEMP | PSUHIGHTEMP |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $525.00/kg median; $332.50–$771.12/kg across 6 dated product listings | $168.00/kg median; $168.00–$168.00/kg across 1 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Polyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[1][2] | Polysulfone — the lowest-temperature and cheapest of the sulfone family[3] |
| Densityg/cm³ | 1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[2][1] | 1.24 (ISO 1183)[3] |
| Typical priceUSD/kg | 1 kg-equivalent spools cluster near 550[4][5][6] | 1 kg-equivalent spools cluster near 250[4] |
| Price range across brandsUSD/kg | 333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[4][5][6][7][8] | 168-250 across formats; 250 g spool $42 (168/kg), 500 g $125 (250/kg) — 3DXTech is the only filament supplier found[4] |
| Market availability1–5 | Niche, a handful of specialist brands[4][5][6] | Special order, 1–2 makers worldwide[4] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[4][5][2] | 1.75 mm; 250 g and 500 g spools[4] |
| Typical applications | Aerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[1][2] | Transparent high-temperature housings, medical trays and hot-water fittings[3] |
| Printing Parameters | ||
| Bed temperature°C | 140 (3DXTech CarbonX PEKK-A CF15)[1] | 120–140 (3DXTech)[3] |
| Enclosure / chamber requirement1–5 | Actively heated chamber required[9][10] | Actively heated chamber required[9][10] |
| Overall printing difficulty1–5 | Expert / industrial hardware only[9][10] | Expert / industrial hardware only[9][10] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[1][2] | Brass fine indefinitely for unfilled grades, but brass softens near these nozzle temperatures — hardened or plated hot ends are the norm[9] |
| Abrasiveness1–5 | Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[1][2] | Non-abrasive when unfilled[3] |
| Nozzle clog risk1–5 | Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[11] | Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[12] |
| Moisture Behaviour | ||
| Equilibrium moisture content at ~50 % RH% | Not documented | 0.30 in 24 h on extruded stock (ASTM D570)[13] |
| Effect of moisture on strength | No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[11] | No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[12] |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1] | 52 (printed XY, ISO 527, 3DXTech); 81 at break on extruded stock (ASTM D638)[3][13] |
| Young's modulusMPa | 2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1] | 2100 (printed XY, ISO 527)[3] |
| Elongation at break% | 6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[2][1] | 8 (printed XY, ISO 527) against 50 on extruded stock — nearly three times PPSU's printed 3 %[3][14][13] |
| Flexural strengthMPa | 136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1] | 87 (printed XY, ISO 178)[3] |
| Flexural modulusMPa | 3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1] | 2050 (printed XY, ISO 178)[3] |
| Other impact data | Izod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[2] | Izod notched 69 J/m on extruded PSU stock, converted from 1.3 ft-lb/in (ASTM D256)[13] |
| Layer adhesion / Z tensileMPa | 50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[2][15] | Not documented |
| Brittleness1–5 | Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[2][1] | Moderate[3] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Not documented | Rockwell M120 on extruded PSU stock (ASTM D785)[13] |
| Creep resistance / sustained load1–5 | Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[2] | Good. Ensinger lists high creep resistance as a headline property of extruded PSU stock, which is rated to 173 °C heat deflection at 1.8 MPa[13] |
| Elasticity / flexibility1–5 | Rigid[1] | Rigid[3] |
| Z strength as % of XY% | 56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[2][15] | Not documented |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[2][1] | 172 (printed XY, ISO 75 at 0.45 MPa, 3DXTech); 181 on extruded stock, converted from 358 °F at 66 psi[3][13] |
| HDT at 1.8 MPa°C | 156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[2] | 174 on extruded PSU stock, converted from 345 °F at 264 psi (ASTM D648)[13] |
| Glass transition (Tg)°C | 156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[2][1] | 187 (DSC, 3DXTech) and 185 on extruded stock (ASTM D3418), against 230 for PPSU[3][14][13] |
| Melting point / Vicat°C | 300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[2][1] | Not documented |
| Continuous service temperature°C | Not documented | 141 long-term service on extruded PSU stock, converted from 285 °F[13] |
| Thermal expansion (CTE)µm/m·K | 36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[2][15] | 55.8 (extruded PSU stock, ASTM D696; source states 3.1e-5 in/in/°F)[13] |
| Flammability / UL 94 | Not documented | UL 94 V-0 on extruded PSU stock[13] |
| Environment & Chemical | ||
| UV resistance1–5 | Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[2] | Not documented |
| Electrical & ESD properties | Unfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[2][1][15] | Surface resistance above 10¹³ ohm/sq — an insulator (IEC 60093)[3] |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[16] | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[16] |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[16] | Ventilated room or enclosure recommended[16] |
| Dust & fibre handling hazard | Carbon fibre is bound in the matrix; sanding dust should not be inhaled[1] | Not documented |
| Solvents & Solubility | ||
| Soluble in | Concentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[17][18] | Chlorinated hydrocarbons — dichloromethane, chloroform — dissolve polysulfone; ketones and esters attack it as well.[19][17] |
| Softened or crazed by | Concentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[17] | Acetone, MEK, ethyl acetate, benzene and toluene craze or stress-crack it; methanol and isopropanol only marginally.[17][19] |
| Solvent welding & smoothing agent | None — no solvent softens a polyaryletherketone.[17] | Dichloromethane cement welds PSU and NMP softens residual resin. Both are laboratory reagents.[19] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
- Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
- ThermaX PSU Technical Data Sheet v3 3DXTech · 2026-08 · tds
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
- Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
- Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
- IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
- THERMAX PSU — product page (print recommendations) 3DXTech · 2026-08 · doc
- TECASON S natural (PSU) — stock shape properties Ensinger · 2026-08 · tds
- ThermaX PPSU Technical Data Sheet v3 3DXTech · 2026-08 · tds
- Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
- The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
- Radel PPSU, Veradel PESU, Acudel modified PPSU Design Guide — environmental stress cracking tables Solvay Specialty Polymers · 2026-08 · tds