3D Printing Info

Filament comparison

PEKK vs PPS

Compare printing settings, strength, heat resistance, dated prices and sources.

PEKK guidePPS guide

2 selected · all documented properties

Open these two in the interactive comparisonMore PEKK comparisonsMore PPS comparisons
PEKK vs PPS — documented properties and sources
PropertyPEKKHIGHTEMPPPSHIGHTEMP
Market snapshot
Listing priceUSD/kg; dated snapshots$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings$116.97/kg median; $84.00–$200.00/kg across 3 dated product listings
Identity & Market
Base polymer / chemistryPolyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[1][2]Polyphenylene sulfide — a semi-crystalline high-temperature polymer[3][4]
Densityg/cm³1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[2][1]1.28 (ISO 1183, 3DXTech) and 1.33 (ISO 1183, Spectrum PPS AM230)[3][5]
Typical priceUSD/kg1 kg-equivalent spools cluster near 550[6][7][8]1 kg-equivalent spools span 84–200; the middle of the market is about 117[6][9][10]
Price range across brandsUSD/kg333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[6][7][8][11][12]84-200 across brands and diameters; IEMAI 3D 84 at 1 kg, Spectrum PPS AM230 117 at 750 g, 3DXTech ThermaX PPS 140 at 2.85 mm and 200 at 1.75 mm[6][9][10]
Market availability1–5Niche, a handful of specialist brands[6][7][8]Niche, a handful of specialist brands[6][9]
Spool sizes & diameters1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[6][7][2]1.75 and 2.85 mm; 500 g and 750 g spools[6][9]
Typical applicationsAerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[1][2]Chemical-plant and under-bonnet parts needing solvent resistance above 200 °C[4]
Printing Parameters
Nozzle temperature°CNot documented335-345 (3DXTech printed-specimen conditions); 300-330 (Spectrum)[3][5]
Bed temperature°C140 (3DXTech CarbonX PEKK-A CF15)[1]110-130 (3DXTech); 100-120 (Spectrum)[3][5]
Enclosure / chamber requirement1–5Actively heated chamber required[13][14]Actively heated chamber required[13][14]
Recommended chamber temperature°CNot documented60-80 actively heated (Spectrum PPS AM230)[5]
Bed surface & adhesion aidNot documentedAdhesive required — Spectrum specifies Magigoo Pro HT[5]
Overall printing difficulty1–5Expert / industrial hardware only[13][14]Expert / industrial hardware only[13][14]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[1][2]Brass fine indefinitely for unfilled grades, but brass softens near these nozzle temperatures — hardened or plated hot ends are the norm[13]
Abrasiveness1–5Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[1][2]Non-abrasive when unfilled[3]
Nozzle clog risk1–5Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[15]Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 110 °C pre-dry before every print[16]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Not documentedNegligible (<0.1 % EMC) — Polymaker states minimal water absorption at 0.05 %[4]
Equilibrium moisture content at ~50 % RH%Not documented0.01 in 24 h on extruded stock (ASTM D570) — effectively non-absorbing[17]
Drying temperature & timeNot documentedAt least 3 h at 90 °C in hot dry air if the filament has taken up moisture (Spectrum)[5]
Effect of moisture on strengthNo dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[15]Little to measure — equilibrium uptake is 0.05 %; 3DXTech still specifies a 110 °C, 4 h pre-dry before printing[4][16]
Mechanical Properties
Tensile strength (XY)MPa86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]50 at break (printed XY, ISO 527, 3DXTech); 65 at break injection-moulded (ISO 527, Spectrum); 94 at yield on extruded stock (ASTM D638)[3][5][17]
Young's modulusMPa2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]2650 (printed XY, ISO 527, 3DXTech); 3650 injection-moulded (ISO 527, Spectrum); 5769 on extruded stock (ASTM D638)[3][5][17]
Elongation at break%6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[2][1]18 at break (printed XY, ISO 527, 3DXTech) against 2.0 injection-moulded (Spectrum) and 2.5 on extruded stock — the suppliers disagree by nearly an order of magnitude[3][5][17]
Flexural strengthMPa136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]52 (printed XY, ISO 178, 3DXTech); 141 on extruded stock (ASTM D790)[3][17]
Flexural modulusMPa3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]2540 (printed XY, ISO 178)[3]
Charpy impact, notchedkJ/m²Not documented1.3 notched injection-moulded (ISO 179-1eA, Spectrum); unnotched 18[5]
Other impact dataIzod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[2]Izod notched 33 J/m on extruded PPS stock, converted from 0.62 ft-lb/in (ASTM D256)[17]
Layer adhesion / Z tensileMPa50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[2][18]Not documented
Brittleness1–5Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[2][1]Moderate[3]
Hardness (scale-specific)Shore A / Shore D / RockwellNot documentedRockwell 105 (and R124) on extruded PPS stock (ASTM D785)[17]
Creep resistance / sustained load1–5Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[2]Excellent — holds load for years. Ensinger lists high creep resistance as a headline property of extruded PPS stock, and Spectrum states that rigidity, strength and creep resistance are unchanged under continuous load at high temperature[17][5]
Elasticity / flexibility1–5Rigid[1]Rigid[3]
Z strength as % of XY%56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[2][18]Not documented
Thermal Properties
HDT at 0.45 MPa°C158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[2][1]90 (printed XY, ISO 75 at 0.45 MPa, 3DXTech); 129 injection-moulded (ISO 75, Spectrum); 204 on extruded stock (ASTM D648 at 66 psi)[3][5][17]
HDT at 1.8 MPa°C156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[2]107 injection-moulded (ISO 75 at 1.81 MPa, Spectrum); 104 on extruded stock (ASTM D648 at 264 psi)[5][17]
Glass transition (Tg)°C156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[2][1]Not documented
Melting point / Vicat°C300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[2][1]283 melting (ISO 11357, 3DXTech) and 280 on extruded stock; Vicat softening 236 at 50 N injection-moulded (ISO 306, Spectrum)[3][5][17]
Continuous service temperature°CNot documented170 long-term service on extruded PPS stock, converted from 338 °F[17]
Thermal expansion (CTE)µm/m·K36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[2][18]59.4 (extruded PPS stock, 22-60 °C, ASTM D696; source states 3.3e-5 in/in/°F)[17]
Flammability / UL 94Not documentedUL 94 V-0 at 1.5 mm, rated on the base resin[3]
Environment & Chemical
UV resistance1–5Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[2]Not documented
Chemical resistanceNot documentedOutstanding — PPS resists essentially all solvents below 200 °C[4]
Water / humidity resistance in service1–5Not documentedExcellent — essentially unaffected; extruded stock takes up 0.01 % water in 24 h[17]
Electrical & ESD propertiesUnfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[2][1][18]Not documented
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[19]Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[19]
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[19]Ventilated room or enclosure recommended[19]
Dust & fibre handling hazardCarbon fibre is bound in the matrix; sanding dust should not be inhaled[1]Not documented
Solvents & Solubility
Soluble inConcentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[20][21]None — PPS does not dissolve in any known solvent below 200 °C.[22][20]
Softened or crazed byConcentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[20]Nothing at 23 °C; Ensinger rates it only conditionally resistant to benzene, dichloromethane, toluene and pyridine.[20]
Solvent welding & smoothing agentNone — no solvent softens a polyaryletherketone.[20]None — no solvent welds or smooths PPS.[22]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  2. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  3. ThermaX PPS Technical Data Sheet v3 3DXTech · 2026-08 · tds
  4. PPS — material basics Polymaker Wiki · 2026-08 · doc
  5. Spectrum PPS AM230 Technical Data Sheet Spectrum Filaments · 2022-04 · tds
  6. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  7. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  8. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  9. Spectrum PPS AM230 Natural, 1.75 mm / 750 g 3DJAKE · 2026-08 · vendor
  10. IEMAI 3D PPS 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  11. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  12. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  13. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  14. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  15. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  16. THERMAX PPS — product page (print recommendations) 3DXTech · 2026-08 · doc
  17. TECATRON natural (PPS) — stock shape properties Ensinger · 2026-08 · tds
  18. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  19. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  20. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  21. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
  22. PPS (Polyphenylene sulfide) — Knowledge Base Prusa Research · 2026-08 · doc