3D Printing Info

Filament comparison

PEKK vs PPA

Compare printing settings, strength, heat resistance, dated prices and sources.

PEKK guidePPA (polyphthalamide) guide

2 selected · all documented properties

Open these two in the interactive comparisonMore PEKK comparisonsMore PPA comparisons
PEKK vs PPA — documented properties and sources
PropertyPEKKHIGHTEMPPPA (polyphthalamide)PA
Market snapshot
Listing priceUSD/kg; dated snapshots$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings$45.49/kg median; $45.49–$45.49/kg across 1 dated product listings
Identity & Market
Base polymer / chemistryPolyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[1][2]Polyphthalamide — a semi-aromatic polyamide in which aromatic diacid units replace part of the aliphatic backbone; Raise3D and Bambu Lab both label it high-temperature nylon[3][4]
Densityg/cm³1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[2][1]1.21 (ISO 1183, Siraya Tech Fibreheart PPA)[5]
Typical priceUSD/kg1 kg-equivalent spools cluster near 550[6][7][8]One 1 kg listing on the market, at 45[9]
Price range across brandsUSD/kg333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[6][7][8][10][11]45 for the only unfilled PPA filament found — Siraya Tech Fibreheart PPA at 1 kg; every other PPA in retail is carbon- or glass-filled[9]
Market availability1–5Niche, a handful of specialist brands[6][7][8]Special order, 1–2 makers worldwide — Siraya Tech is the only brand found selling unfilled PPA filament[9]
Spool sizes & diameters1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[6][7][2]1.75 mm, 1 kg[9]
Typical applicationsAerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[1][2]Gears, bearings and tooling that must hold load above the reach of PA6 or PA12, and parts exposed to fuels and industrial chemicals[5]
Printing Parameters
Nozzle temperature°CNot documented280–300 (Siraya Tech)[5]
Bed temperature°C140 (3DXTech CarbonX PEKK-A CF15)[1]70–80 (Siraya Tech)[5]
Enclosure / chamber requirement1–5Actively heated chamber required[12][13]Enclosure recommended — Siraya Tech advises an enclosure to hold temperature and limit warping on larger prints[5]
Part cooling fanNot documented20–60 % (Siraya Tech)[5]
Bed surface & adhesion aidNot documentedPEI sheet with a glue stick, or a PVP glue coating[5]
Overall printing difficulty1–5Expert / industrial hardware only[12][13]Advanced — enclosure, hardware upgrades, tuning; needs a 300 °C-class hot end and a dry spool[5]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[1][2]Brass fine indefinitely — Siraya Tech states a hardened steel nozzle is not needed for the unfilled grade[5]
Abrasiveness1–5Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[1][2]Non-abrasive when unfilled[5]
Nozzle clog risk1–5Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[14]Moderate — needs dry filament and a clean nozzle; Siraya Tech tells users to dry only when moisture symptoms appear, rather than before every print[5]
Hotend requirementNot documentedHigh-quality metal nozzle, 0.4–1.0 mm; hardened steel not required (Siraya Tech)[5]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Not documentedHigh (0.8–2 %) — Siraya Tech publishes 2.59 % by ISO 62 immersion for the unfilled grade; on the equilibrium basis Bambu Lab uses, its 15 % carbon-filled PPA reaches 1.30 % against 2.35 % for the same maker's PA6-CF[5][4][15]
Equilibrium moisture content at ~50 % RH%Not documented2.59 by ISO 62 water immersion (Siraya Tech, unfilled) — an immersion figure, not the 25 °C / 55 % RH equilibrium basis the filled grades are quoted on, so the two are not directly comparable[5]
Drying temperature & timeNot documented80–100 °C for 4–6 h (Siraya Tech)[5]
Symptoms when wetNot documentedOozing, bubbles and a rough surface finish (Siraya Tech)[5]
Effect of moisture on strengthNo dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[14]Siraya Tech publishes dry against saturated for the same grade: tensile 70 → 60 MPa, flexural 114 → 87 MPa, HDT at 1.8 MPa 73.5 → 48.5 °C, while Charpy rises 10 → 14.5 kJ/m²[5][9]
Storage requirementNot documentedDry box below 15 % RH (Siraya Tech)[5]
Mechanical Properties
Tensile strength (XY)MPa86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]72 at break (printed, ASTM D638, Siraya Tech); the product page quotes 70 dry and 60 saturated[5][9]
Young's modulusMPa2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]3600 (printed, ASTM D638, Siraya Tech)[5]
Elongation at break%6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[2][1]10.5 at break (printed, ASTM D638, Siraya Tech)[5]
Flexural strengthMPa136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]115 (printed, ISO 178, Siraya Tech); 114 dry against 87 saturated on the product page[5][9]
Flexural modulusMPa3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]3350 (printed, ISO 178, Siraya Tech)[5]
Charpy impact, notchedkJ/m²Not documented10.1 Charpy (printed, ISO 179, Siraya Tech); the data sheet does not state whether the specimen was notched[5]
Other impact dataIzod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[2]Not documented
Layer adhesion / Z tensileMPa50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[2][16]Not documented
Brittleness1–5Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[2][1]Moderate — 10.5 % elongation at break puts it between PA6 and the fibre-filled grades[5]
Creep resistance / sustained load1–5Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[2]Good — Raise3D cites high creep resistance as a reason to choose the PPA matrix over other nylons[3]
Elasticity / flexibility1–5Rigid[1]Rigid — 3.6 GPa tensile modulus[5]
Z strength as % of XY%56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[2][16]Not documented
Wear resistance & frictionNot documentedSiraya Tech describes the unfilled grade as low-friction and self-lubricating, aimed at gears and bearings[5][9]
Thermal Properties
HDT at 0.45 MPa°C158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[2][1]81 dry and 61 saturated (printed, ISO 75 Method B at 0.45 MPa, Siraya Tech)[5]
HDT at 1.8 MPa°C156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[2]73.5 dry and 48.5 saturated (printed, ISO 75 Method A at 1.8 MPa, Siraya Tech) — unfilled PPA deflects near its Tg; the 190–227 °C figures quoted for PPA are carbon-filled grades[5][4]
Glass transition (Tg)°C156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[2][1]80 (ASTM D3418, Siraya Tech)[5]
Melting point / Vicat°C300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[2][1]231 melting point (ASTM D3418) and 230 Vicat (ISO 306), Siraya Tech[5]
Annealing responseNot documentedSiraya Tech's product page offers annealing for strength while its own data sheet says annealing is not recommended because the print can warp; on its 15 % carbon-filled PPA, annealing lifts HDT at 1.8 MPa from 82.5 to 119 °C[5][9][17]
Thermal expansion (CTE)µm/m·K36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[2][16]Not documented
Environment & Chemical
UV resistance1–5Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[2]Not documented
Chemical resistanceNot documentedWithstands fuels, oils and industrial chemicals; Bambu Lab rates semi-aromatic nylon better than general nylon against weak acids, weak alkalis and most organic solvents[5][4]
Water / humidity resistance in service1–5Not documentedAbsorbs water, properties shift — a saturated specimen loses about 15 % of its tensile strength and 25 °C of heat-deflection temperature[5][9]
Electrical & ESD propertiesUnfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[2][1][16]Not documented
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[18]Not documented
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[18]Not documented
Dust & fibre handling hazardCarbon fibre is bound in the matrix; sanding dust should not be inhaled[1]Not documented
Post-Processing
Support material pairingNot documentedCompatible with quick-release support materials (Siraya Tech)[5]
Solvents & Solubility
Soluble inConcentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[19][20]Dissolved at 23 °C by formic acid, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — all laboratory reagents.[21]
Softened or crazed byConcentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[19]Mineral acids, oxidants, halogens and zinc chloride solutions attack the amide bond; ordinary solvents do not.[21]
Solvent welding & smoothing agentNone — no solvent softens a polyaryletherketone.[19]None — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[21]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  2. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  3. Raise3D Industrial PPA CF Technical Data Sheet V2.0 Raise3D · 2022-04 · tds
  4. Bambu Filament Technical Data Sheet V1.0 — PPA-CF Bambu Lab · 2026-08 · tds
  5. Siraya Tech Fibreheart PPA Technical Data Sheet Siraya Tech · 2026-08 · tds
  6. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  7. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  8. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  9. Siraya Tech Fibreheart PPA Filament — product page Siraya Tech · 2026-08 · vendor
  10. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  11. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  12. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  13. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  14. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  15. Bambu Filament Technical Data Sheet V3.0 — PA6-CF Bambu Lab · 2026-08 · tds
  16. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  17. Siraya Tech Fibreheart PPA-CF Technical Data Sheet Siraya Tech · 2026-08 · tds
  18. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  19. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  20. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
  21. Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds