3D Printing Info

Filament comparison

PEKK vs PPA-CF

Compare printing settings, strength, heat resistance, dated prices and sources.

PEKK guidePPA-CF (carbon-fibre polyphthalamide) guide

2 selected · all documented properties

Open these two in the interactive comparisonMore PEKK comparisonsMore PPA-CF comparisons
PEKK vs PPA-CF — documented properties and sources
PropertyPEKKHIGHTEMPPPA-CF (carbon-fibre polyphthalamide)PA
Market snapshot
Listing priceUSD/kg; dated snapshots$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings$84.99/kg median; $21.99–$266.67/kg across 7 dated product listings
Identity & Market
Base polymer / chemistryPolyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[1][2]Polyphthalamide — semi-aromatic nylon — with 10–15 wt% chopped carbon fibre; Bambu Lab lists the composition as semi-aromatic nylon plus carbon fibre, Raise3D and Siraya Tech state 15 wt%, Flashforge 10 %[3][4][5][6]
Densityg/cm³1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[2][1]1.15 (Raise3D) to 1.25 (Bambu Lab and IEMAI 3D), ISO 1183; Flashforge 1.21–1.23[3][4][5][7]
Typical priceUSD/kg1 kg-equivalent spools cluster near 550[8][9][10]1 kg-equivalent spools span 22–267; the middle of the market is about 85[11][12][13][14][15][16]
Price range across brandsUSD/kg333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[8][9][10][17][18]22–267 across brands; CHCKX 22 on Amazon, IEMAI 3D 51, Siraya Tech 57 and 85, Bambu Lab 200 at 750 g, Raise3D 209, 3DXTech CarbonX HTN+CF 267 at 750 g[11][12][13][19][14][15][16]
Market availability1–5Niche, a handful of specialist brands[8][9][10]Available from several mainstream brands[11][12][13][14][15]
Spool sizes & diameters1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[8][9][2]1.75 mm; 750 g, 1 kg, 2 kg and 2.5 kg spools[3][13][15]
Typical applicationsAerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[1][2]Under-bonnet automotive brackets, jigs and end-use parts that must stay stiff above the 100 °C working ceiling of PA6-CF[4][5]
Diameter tolerance± mmNot documented0.05 (Bambu Lab and Siraya Tech, 1.75 mm)[3][6]
Printing Parameters
Nozzle temperature°CNot documented280–310 (Bambu Lab and CHCKX); 280–320 (Siraya Tech)[3][6][16]
Bed temperature°C140 (3DXTech CarbonX PEKK-A CF15)[1]100–120 (Bambu Lab and CHCKX); Siraya Tech runs cooler at 70–90[3][6][16]
Enclosure / chamber requirement1–5Actively heated chamber required[20][21]Enclosure required (passive) — Bambu Lab specifies a 50–80 °C chamber and Siraya Tech requires an enclosure, while Flashforge states its LUVOCOM-based grade prints on machines with no heated chamber[3][5][13]
Recommended chamber temperature°CNot documented50–80 (Bambu Lab); specimens were printed at a 52 °C chamber and Bambu Lab notes 70–80 °C raises Z properties[3]
Part cooling fanNot documentedBambu Lab turns the part fan on; Siraya Tech runs it off[3][6]
Bed surface & adhesion aidNot documentedSmooth or textured PEI plate with a glue stick, or a PVP glue coating[3][6]
Maximum volumetric flow (mm³/s; see test conditions)mm³/sNot documented8–12 mm³/s at 300–320 °C (Siraya Tech)[6]
Overall printing difficulty1–5Expert / industrial hardware only[20][21]Advanced — enclosure, hardware upgrades, tuning; a 320 °C hot end and a hardened nozzle are the entry requirements[3][6]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[1][2]Hardened steel required — Siraya Tech and CHCKX specify hardened steel or better, Raise3D warns brass wears quickly[4][6][16]
Abrasiveness1–5Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[1][2]Highly abrasive — standard CF/GF composites and glow fills[4][6]
Nozzle clog risk1–5Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[22]Moderate — needs dry filament and a clean nozzle; Siraya Tech states nozzles below 0.4 mm will clog[6][13]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Not documentedHigh (0.8–2 %) — 1.30 % saturated at 25 °C / 55 % RH for Bambu Lab and IEMAI 3D against 2.35 % for the same makers' PA6-CF, which is the whole reason to pay for PPA[3][7][23]
Equilibrium moisture content at ~50 % RH%Not documented1.30 saturated at 25 °C / 55 % RH (Bambu Lab and IEMAI 3D) against 2.35 for their PA6-CF; Siraya Tech 1.37 and 1.09 by ISO 62, Raise3D 0.6 by ISO 62 Method 1, Flashforge below 0.1 at 23 °C / 24 h[3][4][5][6][24][7][23]
Drying temperature & timeNot documented100–140 °C for 8–12 h (Bambu Lab, hotter is better within that range); Siraya Tech 100 °C for 4–6 h; Raise3D 80–100 °C for 6–12 h[3][4][6]
Effect of moisture on strengthNo dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[22]Not documented
Storage requirementNot documentedSealed below 20 % RH with desiccant (Bambu Lab); Raise3D keeps the spool in a dry box throughout the print[3][4]
Mechanical Properties
Tensile strength (XY)MPa86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]95–168 (printed XY, ISO 527): Siraya Tech 95, Flashforge 108–112, Siraya Tech Core 112, Raise3D 122 conditioned and annealed, Bambu Lab and IEMAI 3D 168[3][4][5][6][24][7]
Young's modulusMPa2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]7100–11800 (printed XY): Flashforge 7100–8000, Raise3D and Siraya Tech 7800, Siraya Tech Core 9300, Bambu Lab and IEMAI 3D 11800[3][4][5][6][24][7]
Elongation at break%6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[2][1]1.9–5 at break (printed XY): Raise3D 1.9, Siraya Tech 2, Siraya Tech Core 2.25, Bambu Lab and IEMAI 3D 3.2, Flashforge 3.5–5[3][4][5][6][24][7]
Flexural strengthMPa136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]145–221 (printed XY, ISO 178): Siraya Tech 145, Siraya Tech Core 178, Raise3D 190, Bambu Lab and IEMAI 3D 208, Flashforge 210–221[3][4][5][6][24][7]
Flexural modulusMPa3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]6500–9860 (printed XY, ISO 178): Flashforge 6500–7000, Siraya Tech 6800, Raise3D 8510, Siraya Tech Core 8700, Bambu Lab and IEMAI 3D 9860[3][4][5][6][24][7]
Charpy impact, notchedkJ/m²Not documented6.5 notched Charpy XY (Bambu Lab and IEMAI 3D, ISO 179); Raise3D 7.8 and Siraya Tech 11 by ISO 179 without stating notched[3][4][6][7]
Other impact dataIzod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[2]Bambu Lab and IEMAI 3D unnotched Charpy 41.7 kJ/m² XY against 4.3 in Z; Flashforge Izod 9–11 kJ/m² XY against 2.5–3 in Z[3][5][7]
Layer adhesion / Z tensileMPa50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[2][25]57 printed Z (Bambu Lab and IEMAI 3D, ISO 527); Raise3D measures 30.2 by a custom mono-layer method[3][4][7]
Brittleness1–5Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[2][1]Brittle — snaps with little warning; 2–3 % elongation at break is typical[3][4][6]
Creep resistance / sustained load1–5Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[2]Good — Flashforge cites outstanding creep resistance at high temperature and Raise3D high creep resistance, both against other nylons[4][5]
Elasticity / flexibility1–5Rigid[1]Rigid[3]
Z strength as % of XY%56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[2][25]34 (Bambu Lab and IEMAI 3D, Z against XY tensile, ISO 527)[3][7]
Thermal Properties
HDT at 0.45 MPa°C158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[2][1]188–227 (ISO 75 at 0.45 MPa): Raise3D 188, Flashforge 220, Bambu Lab and IEMAI 3D 227; Siraya Tech reaches 192–199 only after annealing, 84.5–97 unannealed[3][4][5][6][24][7]
HDT at 1.8 MPa°C156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[2]113–196 (ISO 75 at 1.8 MPa): Raise3D 113, Bambu Lab and IEMAI 3D 196; Siraya Tech reaches 119–126 only after annealing, 82.5–84 unannealed[3][4][6][24][7]
Glass transition (Tg)°C156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[2][1]80 (Siraya Tech, ASTM D3418) to 85 (Bambu Lab and IEMAI 3D, DSC)[3][6][7]
Melting point / Vicat°C300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[2][1]Melting point 231 (Raise3D) to 258 (Bambu Lab and IEMAI 3D); Vicat softening 230–238 (ISO 306)[3][4][6][24][7]
Continuous service temperature°CNot documented120 (Flashforge, IEC 60216, LUVOCOM PPA-CF)[5]
Annealing responseNot documentedBambu Lab anneals at 120–140 °C for 6–12 h; Raise3D at 80–100 °C for 8 h and warns of up to 0.5 % Z shrinkage. On Siraya Tech's grades annealing lifts HDT at 0.45 MPa from 84.5 to 192 °C while notched Charpy falls from 11 to 6.3 kJ/m²[3][4][6]
Thermal expansion (CTE)µm/m·K36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[2][25]Not documented
Flammability / UL 94Not documentedFlammable; Bambu Lab lists water, carbon oxides and nitrogen oxides as combustion products. No UL 94 rating is published for the filament grades surveyed[3]
Environment & Chemical
UV resistance1–5Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[2]Not documented
Chemical resistanceNot documentedBetter than general nylon against weak acids, weak alkalis, most organic solvents and most oils and greases (Bambu Lab); not resistant to strong acids or strong alkalis[3]
Water / humidity resistance in service1–5Not documentedGood — minor absorption; 1.3 % saturated moisture is roughly half what PA6-CF takes up[3][23]
Electrical & ESD propertiesUnfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[2][1][25]Flashforge's data sheet gives a surface resistance of 10³ Ω or below (IEC 60093) for its LUVOCOM-based PPA-CF — the carbon loading makes it conductive rather than merely dissipative[5]
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[26]Not documented
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[26]Not documented
Dust & fibre handling hazardCarbon fibre is bound in the matrix; sanding dust should not be inhaled[1]Chopped carbon fibre; dry sanding and cutting release respirable fibre-laden dust[27]
Post-Processing
Support material pairingNot documentedBambu Lab pairs it with Support for PA/PET; Raise3D warns that PPA-CF used as its own support bonds permanently to the model once it takes up moisture, so supports must come off before annealing[3][4]
Solvents & Solubility
Soluble inConcentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[28][29]Formic acid, phenol, m-cresol and hexafluoroisopropanol dissolve the matrix at 23 °C, leaving the fibre; laboratory reagents.[30]
Softened or crazed byConcentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[28]Zinc chloride solutions stress-crack the nylon matrix, alcoholic calcium chloride dissolves it, mineral acids attack it.[30]
Solvent welding & smoothing agentNone — no solvent softens a polyaryletherketone.[28]None — nylon's only solvents (formic acid, phenol, HFIP) degrade the part, and the fibre blocks surface flow anyway.[30]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  2. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  3. Bambu Filament Technical Data Sheet V1.0 — PPA-CF Bambu Lab · 2026-08 · tds
  4. Raise3D Industrial PPA CF Technical Data Sheet V2.0 Raise3D · 2022-04 · tds
  5. Flashforge PPA-CF Filament Technical Data Sheet (LUVOCOM PPA-CF, 10 % carbon fibre) Flashforge · 2026-08 · tds
  6. Siraya Tech Fibreheart PPA-CF Technical Data Sheet Siraya Tech · 2026-08 · tds
  7. IEMAI 3D CF-PPA Technical Data Sheet IEMAI 3D · 2025-04 · tds
  8. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  9. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  10. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  11. PPA-CF — Bambu Lab US Store Bambu Lab · 2026-08 · vendor
  12. Raise3D Industrial PPA CF Filament 1.75 mm (1 kg) — product listing MatterHackers · 2026-08 · vendor
  13. Fibreheart PPA-CF Filament — product page Siraya Tech · 2026-08 · vendor
  14. IEMAI 3D CF-PPA 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  15. CARBONX HTN+CF — product page 3DXTech · 2026-08 · vendor
  16. CHCKX PPA-CF 3D Printing Filament Matte Black 1 kg 1.75 mm 10 % Carbon Fiber — Amazon listing Amazon.com · 2026-08 · vendor
  17. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  18. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  19. Siraya Tech Fibreheart PPA-CF Core Filament — product page Siraya Tech · 2026-08 · vendor
  20. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  21. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  22. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  23. Bambu Filament Technical Data Sheet V3.0 — PA6-CF Bambu Lab · 2026-08 · tds
  24. Siraya Tech Fibreheart PPA-CF Core Technical Data Sheet Siraya Tech · 2026-08 · tds
  25. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  26. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  27. PET-CF / PPA-CF / PPS-CF / PA6-CF carbon fibre filament usage guide Bambu Lab Wiki · 2026-08 · doc
  28. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  29. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
  30. Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds