3D Printing Info

Filament comparison

PEKK vs POM

Compare printing settings, strength, heat resistance, dated prices and sources.

PEKK guidePOM (acetal) guide

2 selected · all documented properties

Open these two in the interactive comparisonMore PEKK comparisonsMore POM comparisons
PEKK vs POM — documented properties and sources
PropertyPEKKHIGHTEMPPOM (acetal)ENGINEERING
Market snapshot
Listing priceUSD/kg; dated snapshots$525.00/kg median; $332.50–$771.12/kg across 6 dated product listingsNot documented
Identity & Market
Base polymer / chemistryPolyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[1][2]Polyoxymethylene, normally the copolymer POM-C. Apium's filament grade is POM-C with antistatic additives; no unfilled POM filament was found on sale[3][4]
Densityg/cm³1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[2][1]1.41 (extruded POM-C stock)[3]
Typical priceUSD/kg1 kg-equivalent spools cluster near 550[5][6][7]Not documented
Price range across brandsUSD/kg333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[5][6][7][8][9]Not documented
Market availability1–5Niche, a handful of specialist brands[5][6][7]Special order, 1-2 makers worldwide — Apium sells a POM-C ESD filament through its own shop and states its printers are the only ones able to process POM-C; no POM filament appears in the 3DJAKE or igo3d product sitemaps, at MatterHackers or at Printed Solid[4][10][11][12]
Spool sizes & diameters1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[5][6][2]Not documented
Typical applicationsAerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[1][2]Gears, bushings, bearings, conveyor and food-machinery parts; Apium markets its POM-C ESD grade for semiconductor insulators, aerospace fasteners and sliding parts[3][4]
Printing Parameters
Bed temperature°C140 (3DXTech CarbonX PEKK-A CF15)[1]Not documented
Enclosure / chamber requirement1–5Actively heated chamber required[13][14]Not documented
Overall printing difficulty1–5Expert / industrial hardware only[13][14]Not documented
Extruder requirementNot documentedApium states that the adaptive heating system on its industrial machines is what makes POM-C printable, and that no other 3D printer can process it[4]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[1][2]Not documented
Abrasiveness1–5Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[1][2]Not documented
Nozzle clog risk1–5Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[15]Not documented
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Not documentedLow (0.1-0.3 %) — extruded POM-C stock takes up 0.18 % in 24 h and 0.80 % at saturation (ASTM D570)[3]
Effect of moisture on strengthNo dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[15]Not documented
Mechanical Properties
Tensile strength (XY)MPa86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]66.9 at break and 64.1 at yield (extruded POM-C stock, ASTM D638; converted from 9700 and 9300 psi)[3]
Young's modulusMPa2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]2275 (extruded POM-C stock, ASTM D638; converted from 330,000 psi)[3]
Elongation at break%6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[2][1]40 at break and 9 at yield (extruded POM-C stock, ASTM D638)[3]
Flexural strengthMPa136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]89.6 (extruded POM-C stock, ASTM D790; converted from 13,000 psi)[3]
Flexural modulusMPa3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]2758 (extruded POM-C stock, ASTM D790; converted from 400,000 psi)[3]
Other impact dataIzod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[2]Izod 53 J/m on extruded POM-C stock, converted from 1.0 ft-lb/in[3]
Layer adhesion / Z tensileMPa50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[2][16]Not documented
Brittleness1–5Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[2][1]Tough — absorbs impact, yields before breaking; extruded stock elongates 40 % before failing. No printed figure is published[3]
Hardness (scale-specific)Shore A / Shore D / RockwellNot documentedRockwell 86 (and R120) — the source names only the R scale on extruded POM-C stock (ASTM D785)[3]
Creep resistance / sustained load1–5Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[2]Not documented
Elasticity / flexibility1–5Rigid[1]Not documented
Z strength as % of XY%56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[2][16]Not documented
Wear resistance & frictionNot documentedWear factor 65e-10 in3*min/(ft*lb*h) and a dynamic coefficient of friction of 0.21 at 40 psi and 50 fpm (ASTM D3702, extruded stock) — the properties that make acetal the default gear and bushing plastic; Apium lists good sliding properties as the reason for its grade[3][4]
Thermal Properties
HDT at 0.45 MPa°C158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[2][1]158 (extruded POM-C stock, ASTM D648 at 66 psi; converted from 316 °F)[3]
HDT at 1.8 MPa°C156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[2]110 (extruded POM-C stock, ASTM D648 at 264 psi; converted from 230 °F)[3]
Glass transition (Tg)°C156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[2][1]Not documented
Melting point / Vicat°C300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[2][1]165 melting (extruded POM-C stock; converted from 329 °F)[3]
Continuous service temperature°CNot documented91 long term and 141 intermittent (extruded POM-C stock; converted from 195 °F and 285 °F)[3]
Thermal expansion (CTE)µm/m·K36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[2][16]84.6 (extruded POM-C stock, ASTM D696; source states 4.7e-5 in/in/°F)[3]
Flammability / UL 94Not documentedUL 94 HB on extruded POM-C stock[3]
Environment & Chemical
UV resistance1–5Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[2]Not documented
Chemical resistanceNot documentedGood chemical resistance, particularly to bases; Apium lists resistance to bases as a headline property[3][4]
Water / humidity resistance in service1–5Not documentedGood — minor absorption; 0.80 % water at saturation (ASTM D570, extruded stock)[3]
Electrical & ESD propertiesUnfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[2][1][16]Volume resistance 1e14 ohm-cm, dielectric strength 500 V/mil and dielectric constant 3.7 at 60 Hz on extruded stock (ASTM D257, D149, D150); Apium's filament grade adds antistatic agents[3][4]
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[17]Not documented
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[17]Not documented
Dust & fibre handling hazardCarbon fibre is bound in the matrix; sanding dust should not be inhaled[1]Not documented
Post-Processing
Sanding & machiningNot documentedEasy to machine — Ensinger lists machinability as a headline property of POM-C stock[3]
Solvents & Solubility
Soluble inConcentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[18][19]Hexafluoroisopropanol dissolves it at room temperature; NMP and DMF only when hot. Laboratory reagents.[20]
Softened or crazed byConcentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[18]Acids, oxidants, halogens and hot concentrated zinc chloride attack it; alcohols, ketones and esters do not.[20][18]
Solvent welding & smoothing agentNone — no solvent softens a polyaryletherketone.[18]None — no solvent softens POM below its melting point, which is why it is bolted or heat-welded rather than glued.[20]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  2. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  3. TECAFORM AH natural (POM-C) — stock shape properties Ensinger · 2026-08 · tds
  4. POM-C ESD 3D printing — material page Apium 3D Technologies · 2026-08 · doc
  5. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  6. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  7. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  8. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  9. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  10. 3DJAKE product catalogue 3DJAKE · 2026-08 · vendor
  11. igo3d product sitemap (17452 product URLs) igo3d · 2026-08 · vendor
  12. Printed Solid product catalogue Printed Solid · 2026-08 · vendor
  13. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  14. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  15. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  16. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  17. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  18. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  19. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
  20. Resistance of Ultramid, Ultraform and Ultradur to chemicals (TI-KTU/AS-28 e) BASF · 2000-10 · tds