Filament comparison
PEKK vs PLA
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | PEKKHIGHTEMP | PLA (standard)PLA |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $525.00/kg median; $332.50–$771.12/kg across 6 dated product listings | $19.74/kg median; $9.99–$32.99/kg across 24 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Polyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[1][2] | Poly(lactic acid), a thermoplastic aliphatic polyester from fermented plant starch[3][4] |
| Densityg/cm³ | 1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[2][1] | 1.17–1.24 (ISO 1183)[3][5][4] |
| Typical priceUSD/kg | 1 kg-equivalent spools cluster near 550[6][7][8] | Mainstream 1 kg spools cluster near 20[9][10][11] |
| Price range across brandsUSD/kg | 333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[6][7][8][12][13] | 10–33 across brands; budget house brands 10–14, premium European 26–33[14][15][16][17] |
| Market availability1–5 | Niche, a handful of specialist brands[6][7][8] | Ubiquitous, every brand and retailer[18][19] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[6][7][2] | 1.75 and 2.85 mm; 0.75, 0.85, 1 and 1.1 kg spools plus spool-less refills[9][20][21][16][22] |
| Typical applications | Aerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[1][2] | Concept models, functional prototypes, low-wear toys, jigs used at room temperature[23] |
| Diameter tolerance± mm | Not documented | ±0.02 (Prusament) to ±0.03 (Bambu Lab, Prusa Research standard)[3][9][24] |
| Printing Parameters | ||
| Nozzle temperature°C | Not documented | 190–230; Prusament specifies 210 ± 10[3][5][4] |
| Bed temperature°C | 140 (3DXTech CarbonX PEKK-A CF15)[1] | 25–60; Prusament 40–60, Bambu Lab 35–45[3][5][4] |
| Enclosure / chamber requirement1–5 | Actively heated chamber required[25][26] | Open frame is fine[5][18] |
| Part cooling fan | Not documented | 100 % from the second layer; reduce on the first one or two layers for bed adhesion[3][19] |
| Bed surface & adhesion aid | Not documented | Smooth or textured PEI, glass or painter's tape; glue stick only where release is a problem[5][27][19] |
| Maximum volumetric flow (mm³/s; see test conditions)mm³/s | Not documented | 12–20 (PrusaSlicer max volumetric speed guidance for PLA)[28] |
| Warping tendency1–5 | Not documented | None[29][18] |
| Bed-adhesion difficulty1–5 | Not documented | Sticks to anything — glue only needed on smooth PEI[5][4][19] |
| Stringing / oozing tendency1–5 | Not documented | Slight — 1–3 mm retraction handles it; oozing rises with nozzle temperature[5][19][30] |
| Overall printing difficulty1–5 | Expert / industrial hardware only[25][26] | Beginner — prints on any machine out of the box[18][19] |
| Extruder requirement | Not documented | Any extruder; Bowden and direct drive both fine, no hardware upgrades[18] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[1][2] | Brass fine indefinitely[18] |
| Abrasiveness1–5 | Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[1][2] | Non-abrasive[29][18] |
| Nozzle clog risk1–5 | Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[31] | Very low[18][19] |
| Heat-creep / jam sensitivity1–5 | Not documented | Moderate — good heatbreak cooling needed; softens below 60 °C so it deforms in a warm cold zone[27][32] |
| Hotend requirement | Not documented | Any standard hotend; PTFE-lined is fine at PLA temperatures[18] |
| Other hardware wear | Not documented | None — brass nozzles and standard drive gears are unaffected[29][18] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Not documented | Moderate — 0.40–0.51 % saturated at 23–25 °C and 55–70 % RH[4][5][33] |
| Equilibrium moisture content at ~50 % RH% | Not documented | 0.43 saturated at 25 °C / 55 % RH (Bambu Lab); 0.51 equilibrium (Polymaker)[4][5] |
| Drying temperature & time | Not documented | 50–55 °C for 6–8 h in a forced-air dryer; 45 °C for 12 h in the Bambu Lab AMS HT[5][4][32] |
| Symptoms when wet | Not documented | Bubbling and popping at the nozzle, stringing, rough surface and weak layers[34] |
| Effect of moisture on strength | No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[31] | Polymaker rates PLA low-sensitivity — it absorbs moisture slowly and the loss shows as poor layer adhesion and brittle layers rather than a published strength figure[34] |
| Storage requirement | Not documented | Sealed with desiccant below 20 % RH; shelf life at ambient is long[4][19] |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1] | 35–52 (printed XY, ISO 527); 55 mean across 16 brands and 53 for the reference PLA in a later run, both on 4×4 mm printed bars[3][5][4][35][36] |
| Young's modulusMPa | 2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1] | 2300–3427 (printed XY, ISO 527)[3][5][4] |
| Elongation at break% | 6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[2][1] | 6.3–12.2 (printed XY, ISO 527); Prusament quotes 2.9 at yield[5][4][3] |
| Flexural strengthMPa | 136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1] | 76–87 (printed XY, ISO 178); Fiberlogy quotes 81 by ASTM D790[3][5][4][37] |
| Flexural modulusMPa | 3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1] | 2750–3230 (printed XY, ISO 178); Fiberlogy quotes 3800 by ASTM D790[3][5][4][37] |
| Charpy impact, notchedkJ/m² | Not documented | 3.3–7.9 (printed XY, ISO 179, notched)[5][4] |
| Other impact data | Izod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[2] | Charpy unnotched, printed: 13–14 (Prusament, ISO 179-1), 26.6 (Bambu Lab PLA Basic)[3][4] |
| Layer adhesion / Z tensileMPa | 50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[2][38] | 17–31 (Prusa interlayer test and printed Z tensile); 23 mean on My Tech Fun 4×4 mm bars[3][4][36] |
| Brittleness1–5 | Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[2][1] | Brittle — snaps with little warning[27][29] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Not documented | 81 Shore D (Prusa Polymers in-house method); 75.3 Shore D measured on printed bars (My Tech Fun, Sunlu PLA)[3][39] |
| Creep resistance / sustained load1–5 | Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[2] | Poor — deforms under load at room temperature; 12 mm bar sagged to 20.3 mm over 5 days at 1.25 kg[40][41] |
| Fatigue / repeated-flex resistance1–5 | Not documented | Poor — 38 000–49 000 cycles at 30 % of tensile strength, against 79 000–193 000 for PETG (printed, R = 0.2, 7 Hz)[42][27] |
| Elasticity / flexibility1–5 | Rigid[1] | Rigid[29] |
| Z strength as % of XY% | 56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[2][38] | 77–89 on TDS specimens; ≈44 on My Tech Fun 4×4 mm bars[5][4][36] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[2][1] | 55–60 (ISO 75, 0.45 MPa)[3][5][4] |
| HDT at 1.8 MPa°C | 156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[2] | 54–58 (ISO 75, 1.8 MPa)[3][5][4] |
| Glass transition (Tg)°C | 156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[2][1] | 55–61 (DSC)[3][5][4] |
| Melting point / Vicat°C | 300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[2][1] | 145–160 peak melt (Prusament, ISO 11357); 150 and 160 by DSC (PolyLite, Bambu Lab); Vicat 57–63 (ISO 306)[23][5][4] |
| Continuous service temperature°C | Not documented | 50–55 — loaded bars begin to move at this temperature[29][36] |
| Annealing response | Not documented | Bambu Lab conditions specimens at 55 °C for 8 h; annealing at 50–60 °C for 6–12 h raises crystallinity but can warp parts[4][43] |
| Thermal expansion (CTE)µm/m·K | 36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[2][38] | 96 ± 5 at 0° and 99 ± 5 at 90° raster (printed PLA, fibre Bragg grating, 25–50 °C)[44] |
| Flammability / UL 94 | Not documented | Flammable; no UL 94 rating published by the major brands[4][5] |
| Environment & Chemical | ||
| UV resistance1–5 | Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[2] | Degrades within weeks outdoors[27][23] |
| Outdoor durability | Not documented | Not suitable for long-term outdoor use — UV embrittlement plus softening above 55 °C in direct sun[23][27] |
| Chemical resistance | Not documented | Good against weak acids, oils and grease; poor against strong acids and alkalis; dissolved by chloroform, THF and hot benzene[5][27] |
| Water / humidity resistance in service1–5 | Not documented | Good — insoluble in water, absorbs 0.4–0.5 % at equilibrium[4][45] |
| Food contact | Not documented | Base resin is food-contact grade and EN 71-3 certified by some brands, but printed layer grooves harbour bacteria; Prusa advises against food use[27][45] |
| Biodegradability / compostability | Not documented | Industrially compostable only — needs sustained 55 °C and specific microbial conditions; not home compostable[45][27][4] |
| Recyclability | Not documented | Mechanically recyclable; not accepted in household plastic collection, so brand take-back schemes are the practical route[45] |
| Electrical & ESD properties | Unfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[2][1][38] | Not documented |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[46] | Low hazard — minimal VOC and particle emission[46] |
| VOC emission rateµg/min | Not documented | 4–5 lactide, the dominant VOC (chamber study, three printers)[46] |
| Ultrafine-particle emission rateparticles/min | Not documented | ≈1 × 10⁸ median across three printers; only laywood ≈8 × 10⁷ and laybrick ≈6 × 10⁷ were lower[46] |
| Hazardous species emitted | Not documented | Lactide (3,6-dimethyl-1,4-dioxane-2,5-dione) dominates; no styrene or caprolactam as a leading species[46] |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[46] | None needed in a normal room[46] |
| Dust & fibre handling hazard | Carbon fibre is bound in the matrix; sanding dust should not be inhaled[1] | Not documented |
| Post-Processing | ||
| Sanding & machining | Not documented | Wet sanding — dry sanding heats the surface by friction and smears it[23][27] |
| Gluing & solvent welding | Not documented | Cyanoacrylate for most joints; some grades partially dissolve and bond with acetone, depending on additives and colour[27][24] |
| Vapour / chemical smoothing | Not documented | No practical vapour smoothing — only chloroform, hot benzene or THF, which are laboratory-only[27] |
| Support material pairing | Not documented | PolySupport and PolyDissolve S1 (Polymaker); Support for PLA (Bambu Lab)[5][4] |
| Dimensional accuracy & detail | Not documented | Good — low shrinkage and features under 0.2 mm resolve; 55° overhangs and 30 mm bridges[29][4][19] |
| Solvents & Solubility | ||
| Soluble in | Concentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[47][48] | Chloroform: 10 % w/v in 2–4 h at 23 °C, every grade and morphology; THF and DMF only at 65 °C. Laboratory reagents.[49] |
| Softened or crazed by | Concentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[47] | Acetone, ethyl acetate and toluene plasticise it but dissolve <1 % even at 65 °C; submersion in acetone crazes and destroys parts.[49][50] |
| Solvent welding & smoothing agent | None — no solvent softens a polyaryletherketone.[47] | Chloroform vapour smooths and welds PLA at the cost of tensile strength; acetone does not smooth it at all.[51][50] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
- Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
- Prusament PLA Technical Datasheet v1.1 Prusa Polymers · 2022-02 · tds
- Bambu Filament Technical Data Sheet V3.0 — PLA Basic Bambu Lab · 2026-08 · tds
- PolyLite PLA Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
- Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
- PLA Basic — product page Bambu Lab US Store · 2026-08 · vendor
- MH Build Series PLA Filament White 1.75mm 1kg MatterHackers · 2026-08 · vendor
- 3DJAKE ecoPLA Black 1.75mm 1000g 3DJake International · 2026-08 · vendor
- Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
- IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- JAYO PLA Classic 1.1KG 1.75mm JAYO Official Store · 2026-08 · vendor
- ELEGOO PLA Filament 1.75mm Colored 1KG Elegoo US Official Store · 2026-08 · vendor
- Fillamentum PLA Extrafill Natural 1kg Fillamentum USA · 2026-08 · vendor
- Prusament PLA Jet Black 1kg (NFC) Prusa Research · 2026-08 · vendor
- Filament Material Guide Prusa Knowledge Base · 2026-08 · doc
- PLA — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- Fiberlogy rPLA Refill Anthracite 850 g 3DJake International · 2026-08 · vendor
- JAYO Silk PLA+ 1.75mm 1.1kg JAYO Official Store · 2026-08 · vendor
- ColorFabb PLA/PHA 750g 3D Universe · 2026-08 · vendor
- Prusament PLA Technical Data Sheet v1.0 Prusa Polymers · 2018-09 · tds
- Prusament rPLA Corn Pigment 1kg — product page Prusa Research · 2026-08 · vendor
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- PLA — material guide Prusa Knowledge Base · 2026-08 · doc
- Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
- Prusament PLA — material page Prusa Polymers · 2026-08 · doc
- PLA — material basics Polymaker Wiki · 2026-08 · doc
- THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
- Filament Drying Recommendations Bambu Lab Wiki · 2026-08 · doc
- PolySonic PLA Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- 16 PLA brand comparison test — results spreadsheet My Tech Fun (Igor Gaspar) · 2022-10 · test
- Creality Hyper PLA filament review — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
- Easy PLA — product and technical data Fiberlogy · 2026-08 · tds
- Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
- Carbon Fiber PLA vs META-PLA vs PLA+ vs PLA by Sunlu — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
- BambuLab PLA Basic vs PLA Tough vs PLA-CF — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
- PolyTerra PLA vs PLA+ — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
- Mechanical Properties of Additively Manufactured Polymeric Materials — PLA and PETG — For Biomechanical Applications Polymers 16(13):1868 · 2024-06 · paper
- Bambu Filament Technical Data Sheet V3.0 — PLA Matte Bambu Lab · 2026-08 · tds
- Characterization of Thermal Expansion Coefficient of 3D Printing Polymeric Materials Using Fiber Bragg Grating Sensors Materials 17(18):4668 · 2024-09 · paper
- Filamentive PLA (recycled) — product page Filamentive · 2026-08 · vendor
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
- The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
- Solubility Study of Ingeo Biopolymer Grades in Common Organic Solvents (NWPD003) NatureWorks · 2019-10 · tds
- Improve your 3D prints with chemical smoothing Prusa Research · 2026-08 · doc
- Effect of vapour smoothing in trichloromethane on 3D printed PLA — surface, mechanical and chemical structure Pitale, Keche & Chopra, Engineering Research Express 6(4) 045579 · 2024-12 · paper