3D Printing Info

Filament comparison

PEKK vs PLA

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PEKK vs PLA — documented properties and sources
PropertyPEKKHIGHTEMPPLA (standard)PLA
Market snapshot
Listing priceUSD/kg; dated snapshots$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings$19.74/kg median; $9.99–$32.99/kg across 24 dated product listings
Identity & Market
Base polymer / chemistryPolyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[1][2]Poly(lactic acid), a thermoplastic aliphatic polyester from fermented plant starch[3][4]
Densityg/cm³1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[2][1]1.17–1.24 (ISO 1183)[3][5][4]
Typical priceUSD/kg1 kg-equivalent spools cluster near 550[6][7][8]Mainstream 1 kg spools cluster near 20[9][10][11]
Price range across brandsUSD/kg333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[6][7][8][12][13]10–33 across brands; budget house brands 10–14, premium European 26–33[14][15][16][17]
Market availability1–5Niche, a handful of specialist brands[6][7][8]Ubiquitous, every brand and retailer[18][19]
Spool sizes & diameters1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[6][7][2]1.75 and 2.85 mm; 0.75, 0.85, 1 and 1.1 kg spools plus spool-less refills[9][20][21][16][22]
Typical applicationsAerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[1][2]Concept models, functional prototypes, low-wear toys, jigs used at room temperature[23]
Diameter tolerance± mmNot documented±0.02 (Prusament) to ±0.03 (Bambu Lab, Prusa Research standard)[3][9][24]
Printing Parameters
Nozzle temperature°CNot documented190–230; Prusament specifies 210 ± 10[3][5][4]
Bed temperature°C140 (3DXTech CarbonX PEKK-A CF15)[1]25–60; Prusament 40–60, Bambu Lab 35–45[3][5][4]
Enclosure / chamber requirement1–5Actively heated chamber required[25][26]Open frame is fine[5][18]
Part cooling fanNot documented100 % from the second layer; reduce on the first one or two layers for bed adhesion[3][19]
Bed surface & adhesion aidNot documentedSmooth or textured PEI, glass or painter's tape; glue stick only where release is a problem[5][27][19]
Maximum volumetric flow (mm³/s; see test conditions)mm³/sNot documented12–20 (PrusaSlicer max volumetric speed guidance for PLA)[28]
Warping tendency1–5Not documentedNone[29][18]
Bed-adhesion difficulty1–5Not documentedSticks to anything — glue only needed on smooth PEI[5][4][19]
Stringing / oozing tendency1–5Not documentedSlight — 1–3 mm retraction handles it; oozing rises with nozzle temperature[5][19][30]
Overall printing difficulty1–5Expert / industrial hardware only[25][26]Beginner — prints on any machine out of the box[18][19]
Extruder requirementNot documentedAny extruder; Bowden and direct drive both fine, no hardware upgrades[18]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[1][2]Brass fine indefinitely[18]
Abrasiveness1–5Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[1][2]Non-abrasive[29][18]
Nozzle clog risk1–5Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[31]Very low[18][19]
Heat-creep / jam sensitivity1–5Not documentedModerate — good heatbreak cooling needed; softens below 60 °C so it deforms in a warm cold zone[27][32]
Hotend requirementNot documentedAny standard hotend; PTFE-lined is fine at PLA temperatures[18]
Other hardware wearNot documentedNone — brass nozzles and standard drive gears are unaffected[29][18]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Not documentedModerate — 0.40–0.51 % saturated at 23–25 °C and 55–70 % RH[4][5][33]
Equilibrium moisture content at ~50 % RH%Not documented0.43 saturated at 25 °C / 55 % RH (Bambu Lab); 0.51 equilibrium (Polymaker)[4][5]
Drying temperature & timeNot documented50–55 °C for 6–8 h in a forced-air dryer; 45 °C for 12 h in the Bambu Lab AMS HT[5][4][32]
Symptoms when wetNot documentedBubbling and popping at the nozzle, stringing, rough surface and weak layers[34]
Effect of moisture on strengthNo dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[31]Polymaker rates PLA low-sensitivity — it absorbs moisture slowly and the loss shows as poor layer adhesion and brittle layers rather than a published strength figure[34]
Storage requirementNot documentedSealed with desiccant below 20 % RH; shelf life at ambient is long[4][19]
Mechanical Properties
Tensile strength (XY)MPa86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]35–52 (printed XY, ISO 527); 55 mean across 16 brands and 53 for the reference PLA in a later run, both on 4×4 mm printed bars[3][5][4][35][36]
Young's modulusMPa2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]2300–3427 (printed XY, ISO 527)[3][5][4]
Elongation at break%6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[2][1]6.3–12.2 (printed XY, ISO 527); Prusament quotes 2.9 at yield[5][4][3]
Flexural strengthMPa136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]76–87 (printed XY, ISO 178); Fiberlogy quotes 81 by ASTM D790[3][5][4][37]
Flexural modulusMPa3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]2750–3230 (printed XY, ISO 178); Fiberlogy quotes 3800 by ASTM D790[3][5][4][37]
Charpy impact, notchedkJ/m²Not documented3.3–7.9 (printed XY, ISO 179, notched)[5][4]
Other impact dataIzod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[2]Charpy unnotched, printed: 13–14 (Prusament, ISO 179-1), 26.6 (Bambu Lab PLA Basic)[3][4]
Layer adhesion / Z tensileMPa50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[2][38]17–31 (Prusa interlayer test and printed Z tensile); 23 mean on My Tech Fun 4×4 mm bars[3][4][36]
Brittleness1–5Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[2][1]Brittle — snaps with little warning[27][29]
Hardness (scale-specific)Shore A / Shore D / RockwellNot documented81 Shore D (Prusa Polymers in-house method); 75.3 Shore D measured on printed bars (My Tech Fun, Sunlu PLA)[3][39]
Creep resistance / sustained load1–5Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[2]Poor — deforms under load at room temperature; 12 mm bar sagged to 20.3 mm over 5 days at 1.25 kg[40][41]
Fatigue / repeated-flex resistance1–5Not documentedPoor — 38 000–49 000 cycles at 30 % of tensile strength, against 79 000–193 000 for PETG (printed, R = 0.2, 7 Hz)[42][27]
Elasticity / flexibility1–5Rigid[1]Rigid[29]
Z strength as % of XY%56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[2][38]77–89 on TDS specimens; ≈44 on My Tech Fun 4×4 mm bars[5][4][36]
Thermal Properties
HDT at 0.45 MPa°C158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[2][1]55–60 (ISO 75, 0.45 MPa)[3][5][4]
HDT at 1.8 MPa°C156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[2]54–58 (ISO 75, 1.8 MPa)[3][5][4]
Glass transition (Tg)°C156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[2][1]55–61 (DSC)[3][5][4]
Melting point / Vicat°C300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[2][1]145–160 peak melt (Prusament, ISO 11357); 150 and 160 by DSC (PolyLite, Bambu Lab); Vicat 57–63 (ISO 306)[23][5][4]
Continuous service temperature°CNot documented50–55 — loaded bars begin to move at this temperature[29][36]
Annealing responseNot documentedBambu Lab conditions specimens at 55 °C for 8 h; annealing at 50–60 °C for 6–12 h raises crystallinity but can warp parts[4][43]
Thermal expansion (CTE)µm/m·K36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[2][38]96 ± 5 at 0° and 99 ± 5 at 90° raster (printed PLA, fibre Bragg grating, 25–50 °C)[44]
Flammability / UL 94Not documentedFlammable; no UL 94 rating published by the major brands[4][5]
Environment & Chemical
UV resistance1–5Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[2]Degrades within weeks outdoors[27][23]
Outdoor durabilityNot documentedNot suitable for long-term outdoor use — UV embrittlement plus softening above 55 °C in direct sun[23][27]
Chemical resistanceNot documentedGood against weak acids, oils and grease; poor against strong acids and alkalis; dissolved by chloroform, THF and hot benzene[5][27]
Water / humidity resistance in service1–5Not documentedGood — insoluble in water, absorbs 0.4–0.5 % at equilibrium[4][45]
Food contactNot documentedBase resin is food-contact grade and EN 71-3 certified by some brands, but printed layer grooves harbour bacteria; Prusa advises against food use[27][45]
Biodegradability / compostabilityNot documentedIndustrially compostable only — needs sustained 55 °C and specific microbial conditions; not home compostable[45][27][4]
RecyclabilityNot documentedMechanically recyclable; not accepted in household plastic collection, so brand take-back schemes are the practical route[45]
Electrical & ESD propertiesUnfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[2][1][38]Not documented
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[46]Low hazard — minimal VOC and particle emission[46]
VOC emission rateµg/minNot documented4–5 lactide, the dominant VOC (chamber study, three printers)[46]
Ultrafine-particle emission rateparticles/minNot documented≈1 × 10⁸ median across three printers; only laywood ≈8 × 10⁷ and laybrick ≈6 × 10⁷ were lower[46]
Hazardous species emittedNot documentedLactide (3,6-dimethyl-1,4-dioxane-2,5-dione) dominates; no styrene or caprolactam as a leading species[46]
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[46]None needed in a normal room[46]
Dust & fibre handling hazardCarbon fibre is bound in the matrix; sanding dust should not be inhaled[1]Not documented
Post-Processing
Sanding & machiningNot documentedWet sanding — dry sanding heats the surface by friction and smears it[23][27]
Gluing & solvent weldingNot documentedCyanoacrylate for most joints; some grades partially dissolve and bond with acetone, depending on additives and colour[27][24]
Vapour / chemical smoothingNot documentedNo practical vapour smoothing — only chloroform, hot benzene or THF, which are laboratory-only[27]
Support material pairingNot documentedPolySupport and PolyDissolve S1 (Polymaker); Support for PLA (Bambu Lab)[5][4]
Dimensional accuracy & detailNot documentedGood — low shrinkage and features under 0.2 mm resolve; 55° overhangs and 30 mm bridges[29][4][19]
Solvents & Solubility
Soluble inConcentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[47][48]Chloroform: 10 % w/v in 2–4 h at 23 °C, every grade and morphology; THF and DMF only at 65 °C. Laboratory reagents.[49]
Softened or crazed byConcentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[47]Acetone, ethyl acetate and toluene plasticise it but dissolve <1 % even at 65 °C; submersion in acetone crazes and destroys parts.[49][50]
Solvent welding & smoothing agentNone — no solvent softens a polyaryletherketone.[47]Chloroform vapour smooths and welds PLA at the cost of tensile strength; acetone does not smooth it at all.[51][50]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  2. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  3. Prusament PLA Technical Datasheet v1.1 Prusa Polymers · 2022-02 · tds
  4. Bambu Filament Technical Data Sheet V3.0 — PLA Basic Bambu Lab · 2026-08 · tds
  5. PolyLite PLA Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
  6. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  7. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  8. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  9. PLA Basic — product page Bambu Lab US Store · 2026-08 · vendor
  10. MH Build Series PLA Filament White 1.75mm 1kg MatterHackers · 2026-08 · vendor
  11. 3DJAKE ecoPLA Black 1.75mm 1000g 3DJake International · 2026-08 · vendor
  12. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  13. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  14. JAYO PLA Classic 1.1KG 1.75mm JAYO Official Store · 2026-08 · vendor
  15. ELEGOO PLA Filament 1.75mm Colored 1KG Elegoo US Official Store · 2026-08 · vendor
  16. Fillamentum PLA Extrafill Natural 1kg Fillamentum USA · 2026-08 · vendor
  17. Prusament PLA Jet Black 1kg (NFC) Prusa Research · 2026-08 · vendor
  18. Filament Material Guide Prusa Knowledge Base · 2026-08 · doc
  19. PLA — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  20. Fiberlogy rPLA Refill Anthracite 850 g 3DJake International · 2026-08 · vendor
  21. JAYO Silk PLA+ 1.75mm 1.1kg JAYO Official Store · 2026-08 · vendor
  22. ColorFabb PLA/PHA 750g 3D Universe · 2026-08 · vendor
  23. Prusament PLA Technical Data Sheet v1.0 Prusa Polymers · 2018-09 · tds
  24. Prusament rPLA Corn Pigment 1kg — product page Prusa Research · 2026-08 · vendor
  25. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  26. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  27. PLA — material guide Prusa Knowledge Base · 2026-08 · doc
  28. Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
  29. Prusament PLA — material page Prusa Polymers · 2026-08 · doc
  30. PLA — material basics Polymaker Wiki · 2026-08 · doc
  31. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  32. Filament Drying Recommendations Bambu Lab Wiki · 2026-08 · doc
  33. PolySonic PLA Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
  34. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  35. 16 PLA brand comparison test — results spreadsheet My Tech Fun (Igor Gaspar) · 2022-10 · test
  36. Creality Hyper PLA filament review — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  37. Easy PLA — product and technical data Fiberlogy · 2026-08 · tds
  38. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  39. Carbon Fiber PLA vs META-PLA vs PLA+ vs PLA by Sunlu — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  40. BambuLab PLA Basic vs PLA Tough vs PLA-CF — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  41. PolyTerra PLA vs PLA+ — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  42. Mechanical Properties of Additively Manufactured Polymeric Materials — PLA and PETG — For Biomechanical Applications Polymers 16(13):1868 · 2024-06 · paper
  43. Bambu Filament Technical Data Sheet V3.0 — PLA Matte Bambu Lab · 2026-08 · tds
  44. Characterization of Thermal Expansion Coefficient of 3D Printing Polymeric Materials Using Fiber Bragg Grating Sensors Materials 17(18):4668 · 2024-09 · paper
  45. Filamentive PLA (recycled) — product page Filamentive · 2026-08 · vendor
  46. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  47. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  48. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
  49. Solubility Study of Ingeo Biopolymer Grades in Common Organic Solvents (NWPD003) NatureWorks · 2019-10 · tds
  50. Improve your 3D prints with chemical smoothing Prusa Research · 2026-08 · doc
  51. Effect of vapour smoothing in trichloromethane on 3D printed PLA — surface, mechanical and chemical structure Pitale, Keche & Chopra, Engineering Research Express 6(4) 045579 · 2024-12 · paper