3D Printing Info

Filament comparison

PEKK vs rPLA

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PEKK vs rPLA — documented properties and sources
PropertyPEKKHIGHTEMPRecycled PLA (rPLA)PLA
Market snapshot
Listing priceUSD/kg; dated snapshots$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings$20.79/kg median; $16.05–$40.64/kg across 8 dated product listings
Identity & Market
Base polymer / chemistryPolyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[1][2]PLA regranulated from post-industrial PLA manufacturing waste; post-consumer feedstock is rare[3][4][5]
Densityg/cm³1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[2][1]1.24 (ISO 1183)[3]
Typical priceUSD/kg1 kg-equivalent spools cluster near 550[6][7][8]1 kg spools run 20–22[9][10][11]
Price range across brandsUSD/kg333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[6][7][8][12][13]16–41 across brands; Fiberlogy refill 16, Filamentive 750 g 41[14][15]
Market availability1–5Niche, a handful of specialist brands[6][7][8]Available from several mainstream brands[4][5][11]
Spool sizes & diameters1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[6][7][2]1.75 and 2.85 mm; 0.75, 0.85 and 1 kg spools plus spool-less refills[16][14][4]
Typical applicationsAerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[1][2]General-purpose printing where the feedstock's recycled content matters more than an exact colour match[4][5]
Diameter tolerance± mmNot documented±0.03 guaranteed by Prusa Research today; the 2021 datasheet specified ±0.05, against ±0.02 for virgin Prusament PLA[4][3][17]
Printing Parameters
Nozzle temperature°CNot documented210 ± 10 (Prusament); 200 ± 15 (Filamentive)[3][5]
Bed temperature°C140 (3DXTech CarbonX PEKK-A CF15)[1]40–60 (Prusament); up to 60 (Filamentive)[3][5]
Enclosure / chamber requirement1–5Actively heated chamber required[18][19]Open frame is fine[3][20]
Part cooling fanNot documented100 %[3]
Warping tendency1–5Not documentedNone — brim not generally needed[3]
Bed-adhesion difficulty1–5Not documentedSticks to anything[21]
Overall printing difficulty1–5Expert / industrial hardware only[18][19]Beginner — prints on any machine out of the box[3][20]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[1][2]Brass fine indefinitely[20]
Abrasiveness1–5Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[1][2]Non-abrasive[22][20]
Nozzle clog risk1–5Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[23]Very low[20]
Heat-creep / jam sensitivity1–5Not documentedModerate — good heatbreak cooling needed; PLA softens below 60 °C[24]
Hotend requirementNot documentedNo special hot-end required[21]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Not documentedModerate — 0.3 % after both 24 h and 7 days at 28 °C / 37 % RH (Prusa Polymers method), against 0.19 % in 7 days for virgin Prusament PLA[3][17]
Equilibrium moisture content at ~50 % RH%Not documented0.3 after 24 h and 7 days at 28 °C / 37 % RH (Prusa Polymers method)[3]
Symptoms when wetNot documentedBubbling and popping at the nozzle, stringing, rough surface and weak layers[25]
Effect of moisture on strengthNo dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[23]Polymaker rates PLA low-sensitivity — the loss shows as poor layer adhesion and brittle layers rather than a published strength figure[25]
Storage requirementNot documentedSealed with desiccant below 20 % RH; shelf life at ambient is long[26][21]
Mechanical Properties
Tensile strength (XY)MPa86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]49 printed horizontal and 55 printed vertical XZ (ISO 527-1, yield); virgin Prusament PLA gives 51 and 59 by the same method[3][17]
Young's modulusMPa2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]2100 printed horizontal, 2300 printed vertical XZ (ISO 527-1); virgin Prusament PLA 2300 and 2400[3][17]
Elongation at break%6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[2][1]3.1 at yield printed horizontal (ISO 527-1); virgin Prusament PLA 2.9[3][17]
Flexural strengthMPa136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]82 printed horizontal, 87 printed vertical XZ (ISO 178); virgin Prusament PLA 83 and 99[3][17]
Flexural modulusMPa3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]3100 printed horizontal (ISO 178) — the same as virgin Prusament PLA[3][17]
Other impact dataIzod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[2]Charpy unnotched 14.0 printed horizontal (ISO 179-1); virgin Prusament PLA 13[3][17]
Layer adhesion / Z tensileMPa50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[2][27]21 ± 2 (Prusa Polymers interlayer adhesion test); virgin Prusament PLA 17 ± 3 by the same test[3][17]
Brittleness1–5Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[2][1]Brittle — snaps with little warning[24][22]
Hardness (scale-specific)Shore A / Shore D / RockwellNot documented80 Shore D (Prusa Polymers in-house method); virgin Prusament PLA 81[3][17]
Creep resistance / sustained load1–5Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[2]Poor — no recycled-PLA creep data published; virgin PLA sagged from 12 to 18.7–20.3 mm over 5 days at 1.25 kg[28][29]
Fatigue / repeated-flex resistance1–5Not documentedPoor — no grade-specific S-N curve; plain printed PLA ran 38 000–49 000 cycles at 30 % of tensile strength (R = 0.2)[30][24]
Elasticity / flexibility1–5Rigid[1]Rigid[22]
Z strength as % of XY%56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[2][27]Not documented
Thermal Properties
HDT at 0.45 MPa°C158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[2][1]55 (ISO 75, 0.45 MPa) — the same as virgin Prusament PLA[3][17]
HDT at 1.8 MPa°C156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[2]53 (ISO 75, 1.8 MPa); virgin Prusament PLA 55[3][17]
Glass transition (Tg)°C156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[2][1]Not documented
Melting point / Vicat°C300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[2][1]Not documented
Continuous service temperature°CNot documented55 (Filamentive states heat resistance up to 55 °C)[5]
Thermal expansion (CTE)µm/m·K36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[2][27]96–99 for plain printed PLA (fibre Bragg grating, 25–50 °C); no grade-specific measurement published[31]
Flammability / UL 94Not documentedFlammable; no UL 94 rating published by the major brands[26][32]
Environment & Chemical
UV resistance1–5Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[2]Degrades within weeks outdoors[24][33]
Chemical resistanceNot documentedGood against weak acids, oils and grease; poor against strong acids and alkalis; dissolved by chloroform, THF and hot benzene[32][24]
Water / humidity resistance in service1–5Not documentedGood — insoluble in water[26]
Food contactNot documentedFilamentive certifies its rPLA to EN 71-3 and lists it food safe; printed layer grooves still harbour bacteria[5][24]
Biodegradability / compostabilityNot documentedIndustrially compostable only — needs sustained 55 °C; not home compostable[5]
RecyclabilityNot documentedThe feedstock itself; Filamentive uses 50 % post-industrial content and runs a PLA take-back scheme[5][15]
Electrical & ESD propertiesUnfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[2][1][27]Not documented
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[34]Low hazard — minimal VOC and particle emission[34]
Hazardous species emittedNot documentedPrusament rPLA Corn Pigment uses organic waste pigments such as red algae, which give a noticeable scent while printing[4]
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[34]None needed in a normal room[34]
Dust & fibre handling hazardCarbon fibre is bound in the matrix; sanding dust should not be inhaled[1]Not documented
Post-Processing
Sanding & machiningNot documentedWet sanding — dry sanding heats the surface by friction and smears it[33][24]
Gluing & solvent weldingNot documentedSuperglue for most joints; acetone works on some grades depending on additives and colour[4]
Vapour / chemical smoothingNot documentedNo practical vapour smoothing — only chloroform, hot benzene or THF, which are laboratory-only[24]
Solvents & Solubility
Soluble inConcentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[35][36]Chloroform: 10 % w/v in 2–4 h at 23 °C, every grade and morphology; THF and DMF only at 65 °C. Laboratory reagents.[37]
Softened or crazed byConcentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[35]Acetone, ethyl acetate and toluene plasticise it but dissolve <1 % even at 65 °C; submersion in acetone crazes and destroys parts.[37][38]
Solvent welding & smoothing agentNone — no solvent softens a polyaryletherketone.[35]Chloroform vapour smooths and welds PLA at the cost of tensile strength; acetone does not smooth it at all.[39][38]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  2. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  3. Prusament PLA Recycled Technical Datasheet v1.0 Prusa Polymers · 2021-12 · tds
  4. Prusament rPLA Corn Pigment 1kg — product page Prusa Research · 2026-08 · vendor
  5. Filamentive PLA (recycled) — product page Filamentive · 2026-08 · vendor
  6. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  7. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  8. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  9. 3D-Fuel ReFuel Recycled PLA 1kg 3D-Fuel · 2026-08 · vendor
  10. Proto-pasta Black Recycled PLA 1kg Proto-pasta · 2026-08 · vendor
  11. Formfutura ReForm rPLA (White) 1kg Filament2Print · 2026-08 · vendor
  12. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  13. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  14. Fiberlogy rPLA Refill Anthracite 850 g 3DJake International · 2026-08 · vendor
  15. Filamentive PLA (rPLA) 750 g CREATE Education · 2026-08 · vendor
  16. Kimya PLA-R 750 g Crea3D · 2026-08 · vendor
  17. Prusament PLA Technical Datasheet v1.1 Prusa Polymers · 2022-02 · tds
  18. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  19. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  20. Filament Material Guide Prusa Knowledge Base · 2026-08 · doc
  21. PLA — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  22. Prusament PLA — material page Prusa Polymers · 2026-08 · doc
  23. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  24. PLA — material guide Prusa Knowledge Base · 2026-08 · doc
  25. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  26. Bambu Filament Technical Data Sheet V3.0 — PLA Basic Bambu Lab · 2026-08 · tds
  27. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  28. BambuLab PLA Basic vs PLA Tough vs PLA-CF — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  29. PolyTerra PLA vs PLA+ — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  30. Mechanical Properties of Additively Manufactured Polymeric Materials — PLA and PETG — For Biomechanical Applications Polymers 16(13):1868 · 2024-06 · paper
  31. Characterization of Thermal Expansion Coefficient of 3D Printing Polymeric Materials Using Fiber Bragg Grating Sensors Materials 17(18):4668 · 2024-09 · paper
  32. PolyLite PLA Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
  33. Prusament PLA Technical Data Sheet v1.0 Prusa Polymers · 2018-09 · tds
  34. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  35. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  36. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
  37. Solubility Study of Ingeo Biopolymer Grades in Common Organic Solvents (NWPD003) NatureWorks · 2019-10 · tds
  38. Improve your 3D prints with chemical smoothing Prusa Research · 2026-08 · doc
  39. Effect of vapour smoothing in trichloromethane on 3D printed PLA — surface, mechanical and chemical structure Pitale, Keche & Chopra, Engineering Research Express 6(4) 045579 · 2024-12 · paper