3D Printing Info

Filament comparison

PEKK vs PLA+

Compare printing settings, strength, heat resistance, dated prices and sources.

PEKK guidePLA+ / Tough PLA guide

2 selected · all documented properties

Open these two in the interactive comparisonMore PEKK comparisonsMore PLA+ comparisons
PEKK vs PLA+ — documented properties and sources
PropertyPEKKHIGHTEMPPLA+ / Tough PLAPLA
Market snapshot
Listing priceUSD/kg; dated snapshots$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings$16.49/kg median; $10.45–$39.99/kg across 10 dated product listings
Identity & Market
Base polymer / chemistryPolyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[1][2]PLA compounded with impact modifiers; suppliers publish the base as polylactic acid only[3][4]
Densityg/cm³1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[2][1]1.17–1.24 (Polymaker); 1.21 (Bambu Lab, ISO 1183)[3][4]
Typical priceUSD/kg1 kg-equivalent spools cluster near 550[5][6][7]Mainstream 1 kg spools cluster near 16[8][9]
Price range across brandsUSD/kg333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[5][6][7][10][11]10–40 across brands; budget house brands 10–17, Sakata 3D HR-870 26, Polymaker and Fiberlogy 36–40[12][9][13][14][15]
Market availability1–5Niche, a handful of specialist brands[5][6][7]Stocked by most mainstream brands[12][8][9][13][14]
Spool sizes & diameters1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[5][6][2]1.75 and 2.85 mm; 0.75, 0.85, 1 and 1.1 kg spools[13][14][12]
Typical applicationsAerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[1][2]Functional parts and enclosures that need impact tolerance but not heat resistance[3][4]
Diameter tolerance± mmNot documented±0.03 (Bambu Lab)[16]
Printing Parameters
Nozzle temperature°CNot documented190–230 (Polymaker); Bambu Lab Tough+ needs 220–250[3][4]
Bed temperature°C140 (3DXTech CarbonX PEKK-A CF15)[1]25–60 (Polymaker); 35–65 (Bambu Lab Tough+)[3][4]
Enclosure / chamber requirement1–5Actively heated chamber required[17][18]Open frame is fine[3][4]
Part cooling fanNot documentedFan on[3][4]
Bed surface & adhesion aidNot documentedTextured or smooth PEI; Bambu Lab recommends glue stick or liquid glue for Tough+[3][4]
Warping tendency1–5Not documentedNone[3]
Bed-adhesion difficulty1–5Not documentedSticks to anything[19]
Stringing / oozing tendency1–5Not documentedSlight — 1–3 mm retraction handles it[3][19]
Overall printing difficulty1–5Expert / industrial hardware only[17][18]Easy — minor profile tuning; Tough+ wants a hotter nozzle than plain PLA[3][4]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[1][2]Brass fine indefinitely[20]
Abrasiveness1–5Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[1][2]Non-abrasive[21][20]
Nozzle clog risk1–5Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[22]Very low[20]
Heat-creep / jam sensitivity1–5Not documentedModerate — good heatbreak cooling needed; softens below 60 °C like plain PLA[23]
Hotend requirementNot documentedNo special hot-end required[19]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Not documentedLow — 0.27 % saturated at 25 °C / 55 % RH[4]
Equilibrium moisture content at ~50 % RH%Not documented0.27 saturated at 25 °C / 55 % RH (Bambu Lab Tough+)[4]
Drying temperature & timeNot documented55 °C for 6–8 h; 65–75 °C for 12 h on a Bambu Lab X1 heatbed[3][4]
Symptoms when wetNot documentedBubbling and popping at the nozzle, stringing, rough surface and weak layers[24]
Effect of moisture on strengthNo dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[22]Polymaker rates PLA low-sensitivity and publishes no dry-versus-conditioned figures for the modified grades; the loss shows as poor layer adhesion rather than a strength number[24]
Storage requirementNot documentedSealed with desiccant below 20 % RH; shelf life at ambient is long[4][19]
Mechanical Properties
Tensile strength (XY)MPa86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]35–43 (printed XY, ISO 527); 53 on My Tech Fun 4×4 mm bars for Bambu Lab Tough[3][4][25][26]
Young's modulusMPa2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]1860–2150 (printed XY, ISO 527) — below plain PLA at 2300–3427[3][4][27][28]
Elongation at break%6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[2][1]5.1–5.7 (printed XY, ISO 527)[3][4]
Flexural strengthMPa136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]62–65 (printed XY, ISO 178) — below plain PLA at 76–87[3][4][29][28]
Flexural modulusMPa3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]2140–2393 (printed XY, ISO 178)[3][4]
Charpy impact, notchedkJ/m²Not documented38.9–72.3 (printed XY, ISO 179, notched) — 5–9× plain PLA[3][4]
Other impact dataIzod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[2]Charpy unnotched 80.6 printed XY (Bambu Lab Tough+); CNC Kitchen measured ~20 vs 5 kJ/m² for PolyLite PLA[4][25]
Layer adhesion / Z tensileMPa50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[2][30]20.9–32.4 printed Z (ISO 527); 33.0 on My Tech Fun layer-adhesion bars vs 27.6 for PLA Basic[3][4][26]
Brittleness1–5Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[2][1]Tough — absorbs impact, yields before breaking[3][4][25]
Hardness (scale-specific)Shore A / Shore D / RockwellNot documented78.8 Shore D measured on printed bars (My Tech Fun), against 75.3 for the same maker's plain PLA[31]
Creep resistance / sustained load1–5Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[2]Poor — 12 mm bar sagged to 20.2 mm over 5 days at 1.25 kg, the same as plain PLA[26][32]
Fatigue / repeated-flex resistance1–5Not documentedBelow average — impact modifiers raise absorbed energy 5–9×; plain PLA ran 38 000–49 000 cycles at 30 % of tensile strength[33][4][25]
Elasticity / flexibility1–5Rigid[1]Rigid[3]
Z strength as % of XY%56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[2][30]60 (Bambu Lab Tough+) to 78 (PolyMax PLA), printed[3][4]
Thermal Properties
HDT at 0.45 MPa°C158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[2][1]55 (PolyMax) to 61 (Tough+), ISO 75 at 0.45 MPa[3][4]
HDT at 1.8 MPa°C156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[2]52 (PolyMax) to 58 (Tough+), ISO 75 at 1.8 MPa[3][4]
Glass transition (Tg)°C156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[2][1]61 (DSC)[3][4]
Melting point / Vicat°C300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[2][1]149–151 peak melt (DSC); Vicat 62 (ISO 306)[3][4]
Continuous service temperature°CNot documented48–57 — loaded bars begin to move at this temperature: 48 for Polymaker PLA Pro, 50 for Sunlu PLA+, 52 for Bambu Lab Tough, 57 for PolyTerra PLA+[26][34][31][32]
Thermal expansion (CTE)µm/m·K36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[2][30]96–99 for plain printed PLA (fibre Bragg grating, 25–50 °C); no grade-specific measurement published[35]
Flammability / UL 94Not documentedFlammable; no UL 94 rating published by the major brands[4][3]
Environment & Chemical
UV resistance1–5Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[2]Degrades within weeks outdoors[23][36]
Chemical resistanceNot documentedGood against weak acids, oils and grease; poor against strong acids and alkalis[3][4]
Food contactNot documentedBase resin is food-contact grade, but printed layer grooves harbour bacteria; Prusa advises against food use[23]
Biodegradability / compostabilityNot documentedIndustrially compostable only — needs sustained 55 °C; not home compostable[37][23]
RecyclabilityNot documentedMechanically recyclable; not accepted in household plastic collection[37]
Electrical & ESD propertiesUnfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[2][1][30]Not documented
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[38]Low hazard — minimal VOC and particle emission[38]
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[38]None needed in a normal room[38]
Dust & fibre handling hazardCarbon fibre is bound in the matrix; sanding dust should not be inhaled[1]Not documented
Post-Processing
Sanding & machiningNot documentedWet sanding — dry sanding heats the surface by friction and smears it[36][23]
Gluing & solvent weldingNot documentedCyanoacrylate for most joints; some grades partially dissolve and bond with acetone[23][39]
Vapour / chemical smoothingNot documentedNo practical vapour smoothing — only chloroform, hot benzene or THF, which are laboratory-only[23]
Support material pairingNot documentedPolySupport and PolyDissolve S1 (Polymaker); Support for PLA (Bambu Lab)[3][4]
Dimensional accuracy & detailNot documented55° overhangs and 30 mm bridges (Bambu Lab Tough+)[4]
Solvents & Solubility
Soluble inConcentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[40][41]Chloroform: 10 % w/v in 2–4 h at 23 °C, every grade and morphology; THF and DMF only at 65 °C. Laboratory reagents.[42]
Softened or crazed byConcentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[40]Acetone, ethyl acetate and toluene plasticise it but dissolve <1 % even at 65 °C; submersion in acetone crazes and destroys parts.[42][43]
Solvent welding & smoothing agentNone — no solvent softens a polyaryletherketone.[40]Chloroform vapour smooths and welds PLA at the cost of tensile strength; acetone does not smooth it at all.[44][43]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  2. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  3. PolyMax PLA Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
  4. Bambu Filament Technical Data Sheet V3.0 — PLA Tough+ Bambu Lab · 2026-08 · tds
  5. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  6. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  7. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  8. eSUN PLA+ 1.75mm 1KG eSUN Official Store · 2026-08 · vendor
  9. Overture PLA+ 1.75mm Overture3D · 2026-08 · vendor
  10. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  11. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  12. JAYO PLA+ 1.1KG Reusable Spool 1.75mm JAYO Official Store · 2026-08 · vendor
  13. Polymaker PolyMax PLA 0.75kg Polymaker Shop · 2026-08 · vendor
  14. Fiberlogy Impact PLA 850g 3DJake International · 2026-08 · vendor
  15. PLA HR-870 NATURAL Sakata 3D Filaments · 2026-08 · vendor
  16. PLA Basic — product page Bambu Lab US Store · 2026-08 · vendor
  17. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  18. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  19. PLA — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  20. Filament Material Guide Prusa Knowledge Base · 2026-08 · doc
  21. Prusament PLA — material page Prusa Polymers · 2026-08 · doc
  22. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  23. PLA — material guide Prusa Knowledge Base · 2026-08 · doc
  24. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  25. The difference of PLA and PLA+ tested! (feat. Polymaker) CNC Kitchen · 2020-08 · test
  26. BambuLab PLA Basic vs PLA Tough vs PLA-CF — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  27. Prusament PLA Technical Datasheet v1.1 Prusa Polymers · 2022-02 · tds
  28. PolyLite PLA Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
  29. Bambu Filament Technical Data Sheet V3.0 — PLA Basic Bambu Lab · 2026-08 · tds
  30. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  31. Carbon Fiber PLA vs META-PLA vs PLA+ vs PLA by Sunlu — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  32. PolyTerra PLA vs PLA+ — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  33. Mechanical Properties of Additively Manufactured Polymeric Materials — PLA and PETG — For Biomechanical Applications Polymers 16(13):1868 · 2024-06 · paper
  34. Polymaker PLA Pro vs PLA-CF — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  35. Characterization of Thermal Expansion Coefficient of 3D Printing Polymeric Materials Using Fiber Bragg Grating Sensors Materials 17(18):4668 · 2024-09 · paper
  36. Prusament PLA Technical Data Sheet v1.0 Prusa Polymers · 2018-09 · tds
  37. Filamentive PLA (recycled) — product page Filamentive · 2026-08 · vendor
  38. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  39. Prusament rPLA Corn Pigment 1kg — product page Prusa Research · 2026-08 · vendor
  40. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  41. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
  42. Solubility Study of Ingeo Biopolymer Grades in Common Organic Solvents (NWPD003) NatureWorks · 2019-10 · tds
  43. Improve your 3D prints with chemical smoothing Prusa Research · 2026-08 · doc
  44. Effect of vapour smoothing in trichloromethane on 3D printed PLA — surface, mechanical and chemical structure Pitale, Keche & Chopra, Engineering Research Express 6(4) 045579 · 2024-12 · paper