3D Printing Info

Filament comparison

PEKK vs PLA HS

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PEKK vs PLA HS — documented properties and sources
PropertyPEKKHIGHTEMPHigh-Speed PLAPLA
Market snapshot
Listing priceUSD/kg; dated snapshots$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings$19.99/kg median; $11.49–$32.99/kg across 10 dated product listings
Identity & Market
Base polymer / chemistryPolyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[1][2]PLA with rheology and crystallisation tuned for high volumetric flow; melt index 15.4 g/10 min vs 7–11 for standard PLA[3][4]
Densityg/cm³1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[2][1]1.23 (ISO 1183, at 21.5 °C)[3]
Typical priceUSD/kg1 kg-equivalent spools cluster near 550[5][6][7]Mainstream 1 kg spools cluster near 20[8][9][10]
Price range across brandsUSD/kg333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[5][6][7][11][12]11–33 across brands; budget house brands 11–18, Prusament 33[13][14][15]
Market availability1–5Niche, a handful of specialist brands[5][6][7]Stocked by most mainstream brands[16][10][17]
Spool sizes & diameters1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[5][6][2]1.75 mm; 1 kg spools[8][10]
Typical applicationsAerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[1][2]Large or repetitive prints on printers that can sustain high flow[18][16]
Diameter tolerance± mmNot documented±0.03 (Bambu Lab PLA Basic, rated to 258 mm/s)[19]
Printing Parameters
Nozzle temperature°CNot documented210–230 for high-speed work; 190–210 at classic speeds[3][16]
Bed temperature°C140 (3DXTech CarbonX PEKK-A CF15)[1]30–60 (Polymaker); 35–45 (Bambu Lab)[3][20]
Enclosure / chamber requirement1–5Actively heated chamber required[21][22]Open frame is fine[3]
Part cooling fanNot documentedFan on[3]
Maximum volumetric flow (mm³/s; see test conditions)mm³/sNot documented≈24 at 300 mm/s with a 0.4 mm nozzle and 0.2 mm layer; 30 % more flow than regular PLA at the same temperature[3][16][18][23]
Warping tendency1–5Not documentedNone[3]
Bed-adhesion difficulty1–5Not documentedSticks to anything[24]
Overall printing difficulty1–5Expert / industrial hardware only[21][22]Easy — minor profile tuning; needs a printer that can actually reach the flow rate[16][3]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[1][2]Brass fine indefinitely[25]
Abrasiveness1–5Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[1][2]Non-abrasive[26][25]
Nozzle clog risk1–5Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[27]Very low[25]
Heat-creep / jam sensitivity1–5Not documentedModerate — good heatbreak cooling needed; PLA softens below 60 °C[28]
Hotend requirementNot documentedNo special hot-end required[24]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Not documentedModerate — 0.40 % equilibrium at 23 °C / 70 % RH[3]
Equilibrium moisture content at ~50 % RH%Not documented0.40 equilibrium at 23 °C / 70 % RH (Polymaker PolySonic)[3]
Drying temperature & timeNot documented55 °C for 6 h; 50 °C for 8 h (Bambu Lab)[3][20]
Symptoms when wetNot documentedBubbling and popping at the nozzle, stringing, rough surface and weak layers[29]
Effect of moisture on strengthNo dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[27]Polymaker rates PLA low-sensitivity — the loss shows as poor layer adhesion and brittle layers rather than a published strength figure[29]
Storage requirementNot documentedSealed with desiccant below 20 % RH; shelf life at ambient is long[20][24]
Mechanical Properties
Tensile strength (XY)MPa86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]43.9 at 300 mm/s and 46.0 at 46.7 mm/s (printed XY, ISO 527); 58.6 on My Tech Fun bars for Creality Hyper PLA[3][30]
Young's modulusMPa2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]2650 at 300 mm/s, 2878 at classic speed (printed XY, ISO 527)[3]
Elongation at break%6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[2][1]15.1 at 300 mm/s, 21.5 at classic speed (printed XY, ISO 527)[3]
Flexural strengthMPa136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]71.4 at 300 mm/s, 76.5 at classic speed (printed XY, ISO 178)[3]
Flexural modulusMPa3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]2798 at 300 mm/s, 2868 at classic speed (printed XY, ISO 178)[3]
Charpy impact, notchedkJ/m²Not documented5.0 at 300 mm/s, 6.1 at classic speed (printed XY, ISO 179, notched)[3]
Other impact dataIzod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[2]Printing at 300 mm/s instead of 46.7 mm/s costs 4.6 % tensile strength and 18 % notched Charpy[3]
Layer adhesion / Z tensileMPa50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[2][31]32.4 at 300 mm/s, 37.3 at classic speed (printed Z, ISO 527); 35.3 for Creality Hyper PLA vs 23.0 for average PLA on identical bars[3][30]
Brittleness1–5Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[2][1]Moderate[3]
Hardness (scale-specific)Shore A / Shore D / RockwellNot documented78.7 Shore D measured on printed bars for Sunlu PLA Meta (My Tech Fun), against 75.3 for the same maker's plain PLA[32]
Creep resistance / sustained load1–5Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[2]Poor — 12 mm bar sagged to 17.7 mm over 6 days at 1.25 kg[30]
Fatigue / repeated-flex resistance1–5Not documentedPoor — no grade-specific S-N curve; plain printed PLA ran 38 000–49 000 cycles at 30 % of tensile strength (R = 0.2)[33][28]
Elasticity / flexibility1–5Rigid[1]Rigid[3]
Z strength as % of XY%56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[2][31]74 at 300 mm/s, 81 at classic speed (printed)[3]
Thermal Properties
HDT at 0.45 MPa°C158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[2][1]53 (ISO 75, 0.45 MPa)[3]
HDT at 1.8 MPa°C156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[2]52 (ISO 75, 1.8 MPa)[3]
Glass transition (Tg)°C156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[2][1]59 (DSC)[3]
Melting point / Vicat°C300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[2][1]164 peak melt (DSC); crystallisation 96 °C, Vicat 61 °C[3]
Continuous service temperature°CNot documented53 — loaded bars begin to move at this temperature[30]
Thermal expansion (CTE)µm/m·K36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[2][31]96–99 for plain printed PLA (fibre Bragg grating, 25–50 °C); no grade-specific measurement published[34]
Flammability / UL 94Not documentedFlammable; no UL 94 rating published by the major brands[20][4]
Environment & Chemical
UV resistance1–5Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[2]Degrades within weeks outdoors[28][35]
Chemical resistanceNot documentedGood against weak acids, oils and grease; poor against strong acids and alkalis[3]
Water / humidity resistance in service1–5Not documentedGood — insoluble in water[20]
Food contactNot documentedBase resin is food-contact grade, but printed layer grooves harbour bacteria; Prusa advises against food use[28]
Biodegradability / compostabilityNot documentedIndustrially compostable only — needs sustained 55 °C; not home compostable[36][28]
RecyclabilityNot documentedMechanically recyclable; not accepted in household plastic collection[36]
Electrical & ESD propertiesUnfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[2][1][31]Not documented
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[37]Low hazard — minimal VOC and particle emission[37]
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[37]None needed in a normal room[37]
Dust & fibre handling hazardCarbon fibre is bound in the matrix; sanding dust should not be inhaled[1]Not documented
Post-Processing
Sanding & machiningNot documentedWet sanding — dry sanding heats the surface by friction and smears it[35][28]
Gluing & solvent weldingNot documentedCyanoacrylate for most joints; some grades partially dissolve and bond with acetone[28][38]
Vapour / chemical smoothingNot documentedNo practical vapour smoothing — only chloroform, hot benzene or THF, which are laboratory-only[28]
Support material pairingNot documentedPolySupport and PolyDissolve S1 (Polymaker)[3]
Solvents & Solubility
Soluble inConcentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[39][40]Chloroform: 10 % w/v in 2–4 h at 23 °C, every grade and morphology; THF and DMF only at 65 °C. Laboratory reagents.[41]
Softened or crazed byConcentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[39]Acetone, ethyl acetate and toluene plasticise it but dissolve <1 % even at 65 °C; submersion in acetone crazes and destroys parts.[41][42]
Solvent welding & smoothing agentNone — no solvent softens a polyaryletherketone.[39]Chloroform vapour smooths and welds PLA at the cost of tensile strength; acetone does not smooth it at all.[43][42]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  2. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  3. PolySonic PLA Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
  4. PolyLite PLA Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
  5. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  6. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  7. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  8. PolySonic PLA 1.75mm/1kg — product page Polymaker Shop · 2026-08 · vendor
  9. Overture High Speed PLA 1.75mm Overture3D · 2026-08 · vendor
  10. High Speed PLA filament collection Anycubic Official Store · 2026-08 · vendor
  11. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  12. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  13. PLA Meta filament collection Sunlu Official Store · 2026-08 · vendor
  14. QIDI PLA Rapido 1.75mm 1kg 3D Printers Depot · 2026-08 · vendor
  15. Prusament PLA Prusa Pro Green 1kg (NFC) Prusa Research · 2026-08 · vendor
  16. PolySonic PLA — product page Polymaker · 2026-08 · vendor
  17. Creality PLA filament collection Creality Official Store · 2026-08 · vendor
  18. Polymaker Launches New High-Speed 3D Printing Filament — PolySonic PLA & PLA Pro Polymaker · 2023-11 · doc
  19. PLA Basic — product page Bambu Lab US Store · 2026-08 · vendor
  20. Bambu Filament Technical Data Sheet V3.0 — PLA Basic Bambu Lab · 2026-08 · tds
  21. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  22. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  23. Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
  24. PLA — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  25. Filament Material Guide Prusa Knowledge Base · 2026-08 · doc
  26. Prusament PLA — material page Prusa Polymers · 2026-08 · doc
  27. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  28. PLA — material guide Prusa Knowledge Base · 2026-08 · doc
  29. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  30. Creality Hyper PLA filament review — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  31. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  32. Carbon Fiber PLA vs META-PLA vs PLA+ vs PLA by Sunlu — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  33. Mechanical Properties of Additively Manufactured Polymeric Materials — PLA and PETG — For Biomechanical Applications Polymers 16(13):1868 · 2024-06 · paper
  34. Characterization of Thermal Expansion Coefficient of 3D Printing Polymeric Materials Using Fiber Bragg Grating Sensors Materials 17(18):4668 · 2024-09 · paper
  35. Prusament PLA Technical Data Sheet v1.0 Prusa Polymers · 2018-09 · tds
  36. Filamentive PLA (recycled) — product page Filamentive · 2026-08 · vendor
  37. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  38. Prusament rPLA Corn Pigment 1kg — product page Prusa Research · 2026-08 · vendor
  39. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  40. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
  41. Solubility Study of Ingeo Biopolymer Grades in Common Organic Solvents (NWPD003) NatureWorks · 2019-10 · tds
  42. Improve your 3D prints with chemical smoothing Prusa Research · 2026-08 · doc
  43. Effect of vapour smoothing in trichloromethane on 3D printed PLA — surface, mechanical and chemical structure Pitale, Keche & Chopra, Engineering Research Express 6(4) 045579 · 2024-12 · paper