Filament comparison
PEEK-CF vs PPS
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | Fibre-reinforced PEEKHIGHTEMP | PPSHIGHTEMP |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $597.50/kg median; $448.00–$695.00/kg across 5 dated product listings | $116.97/kg median; $84.00–$200.00/kg across 3 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Short-fibre reinforced PEEK. 3DXTech's CarbonX grade is nominally 10 wt% carbon and its FibreX grade 20 wt% glass; LEHVOSS Luvocom 3F PEEK CF 9676 is 15 wt% carbon; Ensinger's machining stock runs to 30 wt% carbon[1][2][3][4] | Polyphenylene sulfide — a semi-crystalline high-temperature polymer[5][6] |
| Densityg/cm³ | 1.39 (ISO 1183)[1] | 1.28 (ISO 1183, 3DXTech) and 1.33 (ISO 1183, Spectrum PPS AM230)[5][7] |
| Typical priceUSD/kg | 1 kg-equivalent spools span 448–972; the middle of the market is about 598[2][3][8] | 1 kg-equivalent spools span 84–200; the middle of the market is about 117[2][9][10] |
| Price range across brandsUSD/kg | 448-972 across formats and filler types; IEMAI 3D CF-PEEK and GF-PEEK 448 at 1 kg, 3DXTech CarbonX PEEK+CF10 598 at 2 kg and FibreX PEEK+GF20 695 at 1 kg, Luvocom 3F PEEK CF 9676 648 at 2 kg[2][3][8][11] | 84-200 across brands and diameters; IEMAI 3D 84 at 1 kg, Spectrum PPS AM230 117 at 750 g, 3DXTech ThermaX PPS 140 at 2.85 mm and 200 at 1.75 mm[2][9][10] |
| Market availability1–5 | Niche, a handful of specialist brands[2][3] | Niche, a handful of specialist brands[2][9] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 200 g to 2 kg spools[2][3] | 1.75 and 2.85 mm; 500 g and 750 g spools[2][9] |
| Typical applications | Stiff aerospace and oil-and-gas parts where PEEK alone is not rigid enough[1] | Chemical-plant and under-bonnet parts needing solvent resistance above 200 °C[6] |
| Printing Parameters | ||
| Nozzle temperature°C | Not documented | 335-345 (3DXTech printed-specimen conditions); 300-330 (Spectrum)[5][7] |
| Bed temperature°C | Not documented | 110-130 (3DXTech); 100-120 (Spectrum)[5][7] |
| Enclosure / chamber requirement1–5 | Actively heated chamber required[12][13] | Actively heated chamber required[12][13] |
| Recommended chamber temperature°C | Not documented | 60-80 actively heated (Spectrum PPS AM230)[7] |
| Bed surface & adhesion aid | Not documented | Adhesive required — Spectrum specifies Magigoo Pro HT[7] |
| Warping tendency1–5 | Moderate — needs adhesion aid or draught shield; the fibre cuts PEEK's crystallisation shrinkage[1] | Not documented |
| Overall printing difficulty1–5 | Expert / industrial hardware only[12][13] | Expert / industrial hardware only[12][13] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Hardened steel required[1] | Brass fine indefinitely for unfilled grades, but brass softens near these nozzle temperatures — hardened or plated hot ends are the norm[12] |
| Abrasiveness1–5 | Highly abrasive — standard CF composite[1] | Non-abrasive when unfilled[5] |
| Nozzle clog risk1–5 | High — jams from moisture, heat creep or particles; 3DXTech adds a hardened 0.4 mm minimum nozzle and 0.25 mm layers to the mandatory 120 °C pre-dry[14][15] | Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 110 °C pre-dry before every print[16] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Not documented | Negligible (<0.1 % EMC) — Polymaker states minimal water absorption at 0.05 %[6] |
| Equilibrium moisture content at ~50 % RH% | 0.06 in 24 h on extruded CF30 stock (ASTM D570)[4] | 0.01 in 24 h on extruded stock (ASTM D570) — effectively non-absorbing[17] |
| Drying temperature & time | Not documented | At least 3 h at 90 °C in hot dry air if the filament has taken up moisture (Spectrum)[7] |
| Effect of moisture on strength | No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[14] | Little to measure — equilibrium uptake is 0.05 %; 3DXTech still specifies a 110 °C, 4 h pre-dry before printing[6][16] |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 105 at break (printed XY, ISO 527, CF10); 121 at yield on extruded CF30 stock (ASTM D638)[1][4] | 50 at break (printed XY, ISO 527, 3DXTech); 65 at break injection-moulded (ISO 527, Spectrum); 94 at yield on extruded stock (ASTM D638)[5][7][17] |
| Young's modulusMPa | 8100 (printed XY, ISO 527, CF10) — more than double unfilled PEEK; 6343 on extruded CF30 stock (ASTM D638)[1][4] | 2650 (printed XY, ISO 527, 3DXTech); 3650 injection-moulded (ISO 527, Spectrum); 5769 on extruded stock (ASTM D638)[5][7][17] |
| Elongation at break% | 3 at break (printed XY, ISO 527), against 28 for unfilled PEEK[1][18] | 18 at break (printed XY, ISO 527, 3DXTech) against 2.0 injection-moulded (Spectrum) and 2.5 on extruded stock — the suppliers disagree by nearly an order of magnitude[5][7][17] |
| Flexural strengthMPa | 136 (printed XY, ISO 178, CF10); 193 on extruded CF30 stock (ASTM D790)[1][4] | 52 (printed XY, ISO 178, 3DXTech); 141 on extruded stock (ASTM D790)[5][17] |
| Flexural modulusMPa | 8300 (printed XY, ISO 178, CF10); 7171 on extruded CF30 stock (ASTM D790)[1][4] | 2540 (printed XY, ISO 178)[5] |
| Charpy impact, notchedkJ/m² | Not documented | 1.3 notched injection-moulded (ISO 179-1eA, Spectrum); unnotched 18[7] |
| Other impact data | Izod notched 61.9 J/m on extruded CF30 stock, converted from 1.16 ft-lb/in (ASTM D256)[4] | Izod notched 33 J/m on extruded PPS stock, converted from 0.62 ft-lb/in (ASTM D256)[17] |
| Brittleness1–5 | Brittle — snaps with little warning; elongation falls from 28 % to 3 %[1][18] | Moderate[5] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Rockwell M107 on extruded PEEK-CF30 stock (ASTM D785), against M100 unfilled[4][19] | Rockwell 105 (and R124) on extruded PPS stock (ASTM D785)[17] |
| Creep resistance / sustained load1–5 | Excellent — holds load for years. Ensinger rates carbon-fibre PEEK stock as very highly creep resistant and specifies 260 °C continuous service[4] | Excellent — holds load for years. Ensinger lists high creep resistance as a headline property of extruded PPS stock, and Spectrum states that rigidity, strength and creep resistance are unchanged under continuous load at high temperature[17][7] |
| Fatigue / repeated-flex resistance1–5 | Good. Victrex rates PEEK for long-term fatigue as well as creep; the fibre cuts elongation at break from 28 % to 3 %, which limits repeated large-strain flexing[20][1][18] | Not documented |
| Elasticity / flexibility1–5 | Rigid[1] | Rigid[5] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 265 (printed XY, ISO 75 at 0.45 MPa, CarbonX PEEK+CF10) against 140 for unfilled PEEK[1][18] | 90 (printed XY, ISO 75 at 0.45 MPa, 3DXTech); 129 injection-moulded (ISO 75, Spectrum); 204 on extruded stock (ASTM D648 at 66 psi)[5][7][17] |
| HDT at 1.8 MPa°C | 316 on extruded CF30 stock, converted from 600 °F at 264 psi (ASTM D648)[4] | 107 injection-moulded (ISO 75 at 1.81 MPa, Spectrum); 104 on extruded stock (ASTM D648 at 264 psi)[7][17] |
| Glass transition (Tg)°C | 143 (DSC, CarbonX PEEK+CF10) — the fibre does not move the glass transition[1] | Not documented |
| Melting point / Vicat°C | 334 melting on extruded CF30 stock, converted from 633 °F[4] | 283 melting (ISO 11357, 3DXTech) and 280 on extruded stock; Vicat softening 236 at 50 N injection-moulded (ISO 306, Spectrum)[5][7][17] |
| Continuous service temperature°C | 260 long-term on extruded CF30 stock, converted from 500 °F; 300 short term[4] | 170 long-term service on extruded PPS stock, converted from 338 °F[17] |
| Thermal expansion (CTE)µm/m·K | 14.4 (extruded PEEK-CF30 stock, ASTM D696; source states 0.80e-5 in/in/°F) — about a third of unfilled PEEK[4][19] | 59.4 (extruded PPS stock, 22-60 °C, ASTM D696; source states 3.3e-5 in/in/°F)[17] |
| Flammability / UL 94 | UL 94 V-0 on the base resin; Ensinger lists extruded PEEK-CF30 stock as inherently flame resistant[18][4] | UL 94 V-0 at 1.5 mm, rated on the base resin[5] |
| Environment & Chemical | ||
| Chemical resistance | Not documented | Outstanding — PPS resists essentially all solvents below 200 °C[6] |
| Water / humidity resistance in service1–5 | Not documented | Excellent — essentially unaffected; extruded stock takes up 0.01 % water in 24 h[17] |
| Electrical & ESD properties | Surface resistance above 10⁹ ohm/sq — not static-dissipative (ASTM D257)[1] | Not documented |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[21] | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[21] |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[21] | Ventilated room or enclosure recommended[21] |
| Dust & fibre handling hazard | Carbon fibre is bound in the matrix; sanding dust should not be inhaled[1] | Not documented |
| Solvents & Solubility | ||
| Soluble in | 95–98 wt% sulphuric acid dissolves the matrix at 40–70 °C and leaves the fibre. Nothing else touches PEEK.[22][23] | None — PPS does not dissolve in any known solvent below 200 °C.[24][23] |
| Softened or crazed by | Concentrated nitric, hydrofluoric, hydrobromic and hydriodic acids attack it; DCM, DMSO and THF swell thin-walled sections.[25][23] | Nothing at 23 °C; Ensinger rates it only conditionally resistant to benzene, dichloromethane, toluene and pyridine.[23] |
| Solvent welding & smoothing agent | None — no solvent softens PEEK, so parts are joined thermally or mechanically, never chemically.[25][23] | None — no solvent welds or smooths PPS.[24] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- CarbonX Carbon Fiber PEEK Technical Data Sheet v3 3DXTech · 2026-08 · tds
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
- TECAPEEK CF30 black (PEEK-CF30) — stock shape properties Ensinger · 2026-08 · tds
- ThermaX PPS Technical Data Sheet v3 3DXTech · 2026-08 · tds
- PPS — material basics Polymaker Wiki · 2026-08 · doc
- Spectrum PPS AM230 Technical Data Sheet Spectrum Filaments · 2022-04 · tds
- IEMAI 3D CF-PEEK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- Spectrum PPS AM230 Natural, 1.75 mm / 750 g 3DJAKE · 2026-08 · vendor
- IEMAI 3D PPS 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- IEMAI 3D GF-PEEK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- CARBONX PEEK+CF10 — product page (print recommendations) 3DXTech · 2026-08 · doc
- Composite materials filled with carbon, kevlar or glass Prusa Knowledge Base · 2026-08 · doc
- THERMAX PPS — product page (print recommendations) 3DXTech · 2026-08 · doc
- TECATRON natural (PPS) — stock shape properties Ensinger · 2026-08 · tds
- ThermaX PEEK Technical Data Sheet v3 3DXTech · 2026-08 · tds
- TECAPEEK natural (PEEK) — stock shape properties Ensinger · 2026-08 · tds
- PEEK polymers — product overview Victrex · 2026-08 · doc
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
- PPS (Polyphenylene sulfide) — Knowledge Base Prusa Research · 2026-08 · doc
- What solvents are not compatible with PEEK? — fluidics technical FAQ IDEX Health & Science · 2026-08 · doc