Filament comparison
PEEK-CF vs PMMA
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | Fibre-reinforced PEEKHIGHTEMP | PMMA (acrylic)ENGINEERING |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $597.50/kg median; $448.00–$695.00/kg across 5 dated product listings | $49.99/kg median; $49.99–$49.99/kg across 1 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Short-fibre reinforced PEEK. 3DXTech's CarbonX grade is nominally 10 wt% carbon and its FibreX grade 20 wt% glass; LEHVOSS Luvocom 3F PEEK CF 9676 is 15 wt% carbon; Ensinger's machining stock runs to 30 wt% carbon[1][2][3][4] | Poly(methyl methacrylate) — acrylic, sold for 3D printing as a transparent glass substitute[5] |
| Densityg/cm³ | 1.39 (ISO 1183)[1] | Not documented |
| Typical priceUSD/kg | 1 kg-equivalent spools span 448–972; the middle of the market is about 598[2][3][6] | 1 kg spools cluster near 50[7] |
| Price range across brandsUSD/kg | 448-972 across formats and filler types; IEMAI 3D CF-PEEK and GF-PEEK 448 at 1 kg, 3DXTech CarbonX PEEK+CF10 598 at 2 kg and FibreX PEEK+GF20 695 at 1 kg, Luvocom 3F PEEK CF 9676 648 at 2 kg[2][3][6][8] | 50 at Push Plastic's 1 kg listing; 3 kg spools run the same per kilogram[7] |
| Market availability1–5 | Niche, a handful of specialist brands[2][3] | Special order, 1–2 makers worldwide[7] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 200 g to 2 kg spools[2][3] | 1.75 and 2.85 mm; 1 and 3 kg spools[7] |
| Typical applications | Stiff aerospace and oil-and-gas parts where PEEK alone is not rigid enough[1] | Transparent covers and light guides where PC's yellowing or cost rules it out[5] |
| Printing Parameters | ||
| Enclosure / chamber requirement1–5 | Actively heated chamber required[9][10] | Not documented |
| Warping tendency1–5 | Moderate — needs adhesion aid or draught shield; the fibre cuts PEEK's crystallisation shrinkage[1] | Not documented |
| Overall printing difficulty1–5 | Expert / industrial hardware only[9][10] | Not documented |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Hardened steel required[1] | Not documented |
| Abrasiveness1–5 | Highly abrasive — standard CF composite[1] | Not documented |
| Nozzle clog risk1–5 | High — jams from moisture, heat creep or particles; 3DXTech adds a hardened 0.4 mm minimum nozzle and 0.25 mm layers to the mandatory 120 °C pre-dry[11][12] | Not documented |
| Moisture Behaviour | ||
| Equilibrium moisture content at ~50 % RH% | 0.06 in 24 h on extruded CF30 stock (ASTM D570)[4] | Not documented |
| Effect of moisture on strength | No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[11] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 105 at break (printed XY, ISO 527, CF10); 121 at yield on extruded CF30 stock (ASTM D638)[1][4] | Not documented |
| Young's modulusMPa | 8100 (printed XY, ISO 527, CF10) — more than double unfilled PEEK; 6343 on extruded CF30 stock (ASTM D638)[1][4] | Not documented |
| Elongation at break% | 3 at break (printed XY, ISO 527), against 28 for unfilled PEEK[1][13] | Not documented |
| Flexural strengthMPa | 136 (printed XY, ISO 178, CF10); 193 on extruded CF30 stock (ASTM D790)[1][4] | Not documented |
| Flexural modulusMPa | 8300 (printed XY, ISO 178, CF10); 7171 on extruded CF30 stock (ASTM D790)[1][4] | Not documented |
| Other impact data | Izod notched 61.9 J/m on extruded CF30 stock, converted from 1.16 ft-lb/in (ASTM D256)[4] | Not documented |
| Brittleness1–5 | Brittle — snaps with little warning; elongation falls from 28 % to 3 %[1][13] | Not documented |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Rockwell M107 on extruded PEEK-CF30 stock (ASTM D785), against M100 unfilled[4][14] | Not documented |
| Creep resistance / sustained load1–5 | Excellent — holds load for years. Ensinger rates carbon-fibre PEEK stock as very highly creep resistant and specifies 260 °C continuous service[4] | Not documented |
| Fatigue / repeated-flex resistance1–5 | Good. Victrex rates PEEK for long-term fatigue as well as creep; the fibre cuts elongation at break from 28 % to 3 %, which limits repeated large-strain flexing[15][1][13] | Not documented |
| Elasticity / flexibility1–5 | Rigid[1] | Not documented |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 265 (printed XY, ISO 75 at 0.45 MPa, CarbonX PEEK+CF10) against 140 for unfilled PEEK[1][13] | Not documented |
| HDT at 1.8 MPa°C | 316 on extruded CF30 stock, converted from 600 °F at 264 psi (ASTM D648)[4] | Not documented |
| Glass transition (Tg)°C | 143 (DSC, CarbonX PEEK+CF10) — the fibre does not move the glass transition[1] | Not documented |
| Melting point / Vicat°C | 334 melting on extruded CF30 stock, converted from 633 °F[4] | Not documented |
| Continuous service temperature°C | 260 long-term on extruded CF30 stock, converted from 500 °F; 300 short term[4] | Not documented |
| Thermal expansion (CTE)µm/m·K | 14.4 (extruded PEEK-CF30 stock, ASTM D696; source states 0.80e-5 in/in/°F) — about a third of unfilled PEEK[4][14] | Not documented |
| Flammability / UL 94 | UL 94 V-0 on the base resin; Ensinger lists extruded PEEK-CF30 stock as inherently flame resistant[13][4] | Not documented |
| Environment & Chemical | ||
| Electrical & ESD properties | Surface resistance above 10⁹ ohm/sq — not static-dissipative (ASTM D257)[1] | Not documented |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[16] | Not documented |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[16] | Not documented |
| Dust & fibre handling hazard | Carbon fibre is bound in the matrix; sanding dust should not be inhaled[1] | Not documented |
| Solvents & Solubility | ||
| Soluble in | 95–98 wt% sulphuric acid dissolves the matrix at 40–70 °C and leaves the fibre. Nothing else touches PEEK.[17][18] | Acetone, MEK, ethyl and butyl acetate, THF, chloroform and carbon tetrachloride dissolve it; the last two are laboratory reagents.[19] |
| Softened or crazed by | Concentrated nitric, hydrofluoric, hydrobromic and hydriodic acids attack it; DCM, DMSO and THF swell thin-walled sections.[20][18] | Alcohols, aliphatic hydrocarbons, oils and phthalate plasticisers craze it, and the threshold falls as stress rises.[19] |
| Solvent welding & smoothing agent | None — no solvent softens PEEK, so parts are joined thermally or mechanically, never chemically.[20][18] | Dichloromethane acrylic cement (IPS Weld-On 3): 2–5 min soak, 17.2 MPa lap shear at one week. Controlled carcinogen.[21] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- CarbonX Carbon Fiber PEEK Technical Data Sheet v3 3DXTech · 2026-08 · tds
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
- TECAPEEK CF30 black (PEEK-CF30) — stock shape properties Ensinger · 2026-08 · tds
- PMMA Filament 1.75mm 1kg — product page Push Plastic · 2026-08 · vendor
- IEMAI 3D CF-PEEK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- Push Plastic product catalogue Push Plastic · 2026-08 · vendor
- IEMAI 3D GF-PEEK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- CARBONX PEEK+CF10 — product page (print recommendations) 3DXTech · 2026-08 · doc
- Composite materials filled with carbon, kevlar or glass Prusa Knowledge Base · 2026-08 · doc
- ThermaX PEEK Technical Data Sheet v3 3DXTech · 2026-08 · tds
- TECAPEEK natural (PEEK) — stock shape properties Ensinger · 2026-08 · tds
- PEEK polymers — product overview Victrex · 2026-08 · doc
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
- Chemical resistance of PMMA products Mitsubishi Chemical (Acrypet) · 2026-08 · tds
- What solvents are not compatible with PEEK? — fluidics technical FAQ IDEX Health & Science · 2026-08 · doc
- Weld-On 3 Acrylic Plastic Cement — technical data sheet (shipped as dichloromethane) IPS Corporation · 2002-07 · tds