3D Printing Info

Filament comparison

PEEK-CF vs PEKK

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PEEK-CF vs PEKK — documented properties and sources
PropertyFibre-reinforced PEEKHIGHTEMPPEKKHIGHTEMP
Market snapshot
Listing priceUSD/kg; dated snapshots$597.50/kg median; $448.00–$695.00/kg across 5 dated product listings$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings
Identity & Market
Base polymer / chemistryShort-fibre reinforced PEEK. 3DXTech's CarbonX grade is nominally 10 wt% carbon and its FibreX grade 20 wt% glass; LEHVOSS Luvocom 3F PEEK CF 9676 is 15 wt% carbon; Ensinger's machining stock runs to 30 wt% carbon[1][2][3][4]Polyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[5][6]
Densityg/cm³1.39 (ISO 1183)[1]1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[6][5]
Typical priceUSD/kg1 kg-equivalent spools span 448–972; the middle of the market is about 598[2][3][7]1 kg-equivalent spools cluster near 550[2][3][8]
Price range across brandsUSD/kg448-972 across formats and filler types; IEMAI 3D CF-PEEK and GF-PEEK 448 at 1 kg, 3DXTech CarbonX PEEK+CF10 598 at 2 kg and FibreX PEEK+GF20 695 at 1 kg, Luvocom 3F PEEK CF 9676 648 at 2 kg[2][3][7][9]333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[2][3][8][10][11]
Market availability1–5Niche, a handful of specialist brands[2][3]Niche, a handful of specialist brands[2][3][8]
Spool sizes & diameters1.75 and 2.85 mm; 200 g to 2 kg spools[2][3]1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[2][3][6]
Typical applicationsStiff aerospace and oil-and-gas parts where PEEK alone is not rigid enough[1]Aerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[5][6]
Printing Parameters
Bed temperature°CNot documented140 (3DXTech CarbonX PEKK-A CF15)[5]
Enclosure / chamber requirement1–5Actively heated chamber required[12][13]Actively heated chamber required[12][13]
Warping tendency1–5Moderate — needs adhesion aid or draught shield; the fibre cuts PEEK's crystallisation shrinkage[1]Not documented
Overall printing difficulty1–5Expert / industrial hardware only[12][13]Expert / industrial hardware only[12][13]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required[1]Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[5][6]
Abrasiveness1–5Highly abrasive — standard CF composite[1]Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[5][6]
Nozzle clog risk1–5High — jams from moisture, heat creep or particles; 3DXTech adds a hardened 0.4 mm minimum nozzle and 0.25 mm layers to the mandatory 120 °C pre-dry[14][15]Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[16]
Moisture Behaviour
Equilibrium moisture content at ~50 % RH%0.06 in 24 h on extruded CF30 stock (ASTM D570)[4]Not documented
Effect of moisture on strengthNo dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[14]No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[16]
Mechanical Properties
Tensile strength (XY)MPa105 at break (printed XY, ISO 527, CF10); 121 at yield on extruded CF30 stock (ASTM D638)[1][4]86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[6][5]
Young's modulusMPa8100 (printed XY, ISO 527, CF10) — more than double unfilled PEEK; 6343 on extruded CF30 stock (ASTM D638)[1][4]2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[6][5]
Elongation at break%3 at break (printed XY, ISO 527), against 28 for unfilled PEEK[1][17]6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[6][5]
Flexural strengthMPa136 (printed XY, ISO 178, CF10); 193 on extruded CF30 stock (ASTM D790)[1][4]136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[6][5]
Flexural modulusMPa8300 (printed XY, ISO 178, CF10); 7171 on extruded CF30 stock (ASTM D790)[1][4]3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[6][5]
Other impact dataIzod notched 61.9 J/m on extruded CF30 stock, converted from 1.16 ft-lb/in (ASTM D256)[4]Izod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[6]
Layer adhesion / Z tensileMPaNot documented50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[6][18]
Brittleness1–5Brittle — snaps with little warning; elongation falls from 28 % to 3 %[1][17]Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[6][5]
Hardness (scale-specific)Shore A / Shore D / RockwellRockwell M107 on extruded PEEK-CF30 stock (ASTM D785), against M100 unfilled[4][19]Not documented
Creep resistance / sustained load1–5Excellent — holds load for years. Ensinger rates carbon-fibre PEEK stock as very highly creep resistant and specifies 260 °C continuous service[4]Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[6]
Fatigue / repeated-flex resistance1–5Good. Victrex rates PEEK for long-term fatigue as well as creep; the fibre cuts elongation at break from 28 % to 3 %, which limits repeated large-strain flexing[20][1][17]Not documented
Elasticity / flexibility1–5Rigid[1]Rigid[5]
Z strength as % of XY%Not documented56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[6][18]
Thermal Properties
HDT at 0.45 MPa°C265 (printed XY, ISO 75 at 0.45 MPa, CarbonX PEEK+CF10) against 140 for unfilled PEEK[1][17]158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[6][5]
HDT at 1.8 MPa°C316 on extruded CF30 stock, converted from 600 °F at 264 psi (ASTM D648)[4]156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[6]
Glass transition (Tg)°C143 (DSC, CarbonX PEEK+CF10) — the fibre does not move the glass transition[1]156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[6][5]
Melting point / Vicat°C334 melting on extruded CF30 stock, converted from 633 °F[4]300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[6][5]
Continuous service temperature°C260 long-term on extruded CF30 stock, converted from 500 °F; 300 short term[4]Not documented
Thermal expansion (CTE)µm/m·K14.4 (extruded PEEK-CF30 stock, ASTM D696; source states 0.80e-5 in/in/°F) — about a third of unfilled PEEK[4][19]36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[6][18]
Flammability / UL 94UL 94 V-0 on the base resin; Ensinger lists extruded PEEK-CF30 stock as inherently flame resistant[17][4]Not documented
Environment & Chemical
UV resistance1–5Not documentedGood — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[6]
Electrical & ESD propertiesSurface resistance above 10⁹ ohm/sq — not static-dissipative (ASTM D257)[1]Unfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[6][5][18]
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[21]Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[21]
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[21]Ventilated room or enclosure recommended[21]
Dust & fibre handling hazardCarbon fibre is bound in the matrix; sanding dust should not be inhaled[1]Carbon fibre is bound in the matrix; sanding dust should not be inhaled[5]
Solvents & Solubility
Soluble in95–98 wt% sulphuric acid dissolves the matrix at 40–70 °C and leaves the fibre. Nothing else touches PEEK.[22][23]Concentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[23][22]
Softened or crazed byConcentrated nitric, hydrofluoric, hydrobromic and hydriodic acids attack it; DCM, DMSO and THF swell thin-walled sections.[24][23]Concentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[23]
Solvent welding & smoothing agentNone — no solvent softens PEEK, so parts are joined thermally or mechanically, never chemically.[24][23]None — no solvent softens a polyaryletherketone.[23]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. CarbonX Carbon Fiber PEEK Technical Data Sheet v3 3DXTech · 2026-08 · tds
  2. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  3. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  4. TECAPEEK CF30 black (PEEK-CF30) — stock shape properties Ensinger · 2026-08 · tds
  5. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  6. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  7. IEMAI 3D CF-PEEK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  8. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  9. IEMAI 3D GF-PEEK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  10. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  11. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  12. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  13. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  14. CARBONX PEEK+CF10 — product page (print recommendations) 3DXTech · 2026-08 · doc
  15. Composite materials filled with carbon, kevlar or glass Prusa Knowledge Base · 2026-08 · doc
  16. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  17. ThermaX PEEK Technical Data Sheet v3 3DXTech · 2026-08 · tds
  18. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  19. TECAPEEK natural (PEEK) — stock shape properties Ensinger · 2026-08 · tds
  20. PEEK polymers — product overview Victrex · 2026-08 · doc
  21. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  22. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
  23. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  24. What solvents are not compatible with PEEK? — fluidics technical FAQ IDEX Health & Science · 2026-08 · doc