3D Printing Info

Filament comparison

PC-FR vs PEKK

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PC-FR vs PEKK — documented properties and sources
PropertyFlame-retardant PC (PC-FR)PCPEKKHIGHTEMP
Market snapshot
Listing priceUSD/kg; dated snapshots$87.50/kg median; $54.99–$224.00/kg across 4 dated product listings$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings
Identity & Market
Base polymer / chemistryFlame-retardant polycarbonate. Polymaker builds its grade on Covestro's Makrolon family and rates it UL 94 V-0[1][2]Polyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[3][4]
Densityg/cm³1.18 (Bambu Lab) and 1.2 (Polymaker), ISO 1183[2][1]1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[4][3]
Typical priceUSD/kg1 kg-equivalent spools span 55–224; the two mainstream 1 kg grades are 55 and the industrial grades 120–224[2][5]1 kg-equivalent spools cluster near 550[6][7][8]
Price range across brandsUSD/kg55–224 across brands; Bambu Lab and Polymaker 55, 3DXTech FR PC/ABS 120, 3DXLABS FR-PC 224[2][5][6]333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[6][7][8][9][10]
Market availability1–5Available from several mainstream brands[2][5][6]Niche, a handful of specialist brands[6][7][8]
Spool sizes & diameters1.75 mm; 0.75 and 1 kg spools[5][6][2]1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[6][7][4]
Typical applicationsElectrical enclosures, transport interiors and battery housings that must meet a flammability rating[1][2]Aerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[3][4]
Diameter tolerance± mm±0.03 (Bambu Lab PC FR)[2]Not documented
Printing Parameters
Nozzle temperature°C260–280 (Bambu Lab); 250–270 (Polymaker)[2][1]Not documented
Bed temperature°C90–110 (Bambu Lab); 90–105 (Polymaker)[2][1]140 (3DXTech CarbonX PEKK-A CF15)[3]
Enclosure / chamber requirement1–5Enclosure required (passive) — Bambu Lab specifies a 45–60 °C chamber, Polymaker 70–100 °C[2][1]Actively heated chamber required[11][12]
Recommended chamber temperature°C45–60 (Bambu Lab); 70–100 (Polymaker)[2][1]Not documented
Part cooling fan0–60 % (Bambu Lab)[2]Not documented
Bed surface & adhesion aidSmooth or textured PEI plate (Bambu Lab)[2]Not documented
Maximum volumetric flow (mm³/s; see test conditions)mm³/s24 at Bambu Lab's 300 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[2][13]Not documented
Warping tendency1–5Severe — heated chamber needed[1][14]Not documented
Bed-adhesion difficulty1–5Needs a specific surface plus adhesive[15][16]Not documented
Stringing / oozing tendency1–5Moderate — retraction tuning needed; Polymaker flags stringing as a common PC problem[16]Not documented
Overall printing difficulty1–5Advanced — enclosure, hardware upgrades, tuning[2][14]Expert / industrial hardware only[11][12]
Hardware Wear & Reliability
Nozzle hardness required1–4Brass fine indefinitely[14]Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[3][4]
Abrasiveness1–5Non-abrasive[1]Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[3][4]
Nozzle clog risk1–5Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a 6 h pre-dry at 80 °C[17]Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[18]
Heat-creep / jam sensitivity1–5Slightly sensitive[15]Not documented
Hotend requirementAll-metal hot end required (Simplify3D)[15]Not documented
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Low (0.1–0.3 %) — 0.12 % saturated at 25 °C / 55 % RH (Bambu Lab), half that of unfilled Bambu Lab PC[2][19]Not documented
Equilibrium moisture content at ~50 % RH%0.12 saturated at 25 °C / 55 % RH (Bambu Lab)[2]Not documented
Drying temperature & time75 °C for 6 h (Polymaker)[1]Not documented
Symptoms when wetBubbling and popping at the nozzle, stringing and a rough surface[20]Not documented
Effect of moisture on strengthNo dry-versus-conditioned figures are published. Polymaker calls PC highly hygroscopic and requires a 70–80 °C dry for 6–8 h; run wet, the loss shows as surface defects and poor layer adhesion[16][20]No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[18]
Storage requirementAirtight containers with desiccant to prevent reabsorption[16]Not documented
Mechanical Properties
Tensile strength (XY)MPa60 ± 4 (Bambu Lab) and 67 ± 4.5 (Polymaker) printed XY, ISO 527[2][1]86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[4][3]
Young's modulusMPa1670 ± 40 (Bambu Lab) and 2634 ± 182 (Polymaker) printed XY, ISO 527[2][1]2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[4][3]
Elongation at break%2.4 ± 0.3 (Bambu Lab) and 3.49 ± 0.7 (Polymaker) at break, printed XY, ISO 527 — the retardant roughly halves unfilled PC's elongation[2][1][21]6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[4][3]
Flexural strengthMPa96.6 ± 1.3 printed XY, ISO 178 (Polymaker)[1]136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[4][3]
Flexural modulusMPa2518 ± 53 printed XY, ISO 178 (Polymaker)[1]3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[4][3]
Charpy impact, notchedkJ/m²11.7 ± 1.6 printed XY, ISO 179, notched (Polymaker)[1]Not documented
Other impact dataNotched Charpy 7.5 ± 1.6 kJ/m² at −30 °C printed XY (Polymaker, ISO 179-1/1eA)[1]Izod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[4]
Layer adhesion / Z tensileMPa21 ± 3 (Bambu Lab) and 46 ± 4.8 (Polymaker) printed Z, ISO 527[2][1]50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[4][22]
Brittleness1–5Moderate[2][1]Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[4][3]
Hardness (scale-specific)Shore A / Shore D / RockwellRockwell 70 (118) — the source does not name the scales and Shore D 79 on extruded unfilled PC stock (ASTM D785, D2240); no figure is published for a flame-retardant filament[23]Not documented
Creep resistance / sustained load1–5Good. Moulded unfilled PC sustained 41 MPa tensile creep at room temperature without breaking, but the retardant package drops the glass transition to 115 °C in Polymaker's grade, so the unfilled rating is not carried over in full[24][1]Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[4]
Elasticity / flexibility1–5Rigid[1]Rigid[3]
Z strength as % of XY%35 (Bambu Lab) to 69 (Polymaker), printed[2][1]56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[4][22]
Thermal Properties
HDT at 0.45 MPa°C110 (Polymaker) and 113 (Bambu Lab), ISO 75 at 0.45 MPa[1][2]158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[4][3]
HDT at 1.8 MPa°C107 (Polymaker) and 108 (Bambu Lab), ISO 75 at 1.8 MPa[1][2]156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[4]
Glass transition (Tg)°C115 (Polymaker) and 145 (Bambu Lab), DSC[1][2]156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[4][3]
Melting point / Vicat°CAmorphous — no melting point; Vicat 114 (Bambu Lab, ISO 306)[2]300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[4][3]
Continuous service temperature°C113 — Prusa publishes this as the temperature resistance of Prusament PC Blend[25]Not documented
Thermal expansion (CTE)µm/m·K68.4 on extruded unfilled PC stock (ASTM D696; source states 3.8e-5 in/in/°F); no figure is published for a flame-retardant grade[23]36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[4][22]
Flammability / UL 94UL 94 V-0 (Polymaker PolyMax PC-FR); 3DXTech rates its FR PC/ABS V-0 at 1.5 mm on the base resin[1][26]Not documented
Environment & Chemical
UV resistance1–5Degrades within weeks outdoors unless stabilised[16]Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[4]
Chemical resistanceWithstands oils, solvents and fuels; Polymaker rates it good against weak acids[16]Not documented
Food contactBisphenol-A polycarbonate is not offered as food-contact filament[16]Not documented
Biodegradability / compostabilityNot biodegradable[16]Not documented
RecyclabilityMechanically recyclable but not accepted in household plastic collection[16]Not documented
Electrical & ESD propertiesNot documentedUnfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[4][3][22]
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised[27]Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[27]
Ultrafine-particle emission rateparticles/min≈4 × 10¹⁰ median — the highest ultrafine-particle rate of the nine filaments in the chamber study, above every ABS tested[27]Not documented
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[27][14]Ventilated room or enclosure recommended[27]
Dust & fibre handling hazardNot documentedCarbon fibre is bound in the matrix; sanding dust should not be inhaled[3]
Post-Processing
Sanding & machiningSands and machines well; the toughness means it cuts rather than chips[15]Not documented
Gluing & solvent weldingCyanoacrylate; dichloromethane solvent-welds PC but is a laboratory reagent[15]Not documented
Vapour / chemical smoothingNo practical vapour smoothing[15]Not documented
Support material pairingPrints its own supports; 3DXTech sells a dedicated PC break-away support[15]Not documented
Solvents & Solubility
Soluble inDichloromethane, chloroform, DMF and dioxane dissolve it outright (Covestro, 6 days at 23 °C). Laboratory reagents.[28]Concentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[29][30]
Softened or crazed byMethanol, butyl acetate, ether, 1 % NaOH and phthalate plasticisers stress-crack it; acetone, MEK and xylene swell it.[28]Concentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[29]
Solvent welding & smoothing agentDichloromethane cement welds PC — 16.5 MPa lap shear at one week (IPS Weld-On 3). A controlled carcinogen.[31]None — no solvent softens a polyaryletherketone.[29]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. PolyMax PC-FR Technical Data Sheet V5.5 Polymaker · 2024-11 · tds
  2. Bambu Filament Technical Data Sheet V1.0 — PC FR Bambu Lab · 2026-08 · tds
  3. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  4. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  5. Polymaker product catalogue Polymaker · 2026-08 · vendor
  6. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  7. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  8. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  9. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  10. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  11. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  12. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  13. Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
  14. ABS / ASA / PC Usage Guide Bambu Lab Wiki · 2026-08 · doc
  15. Polycarbonate — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  16. PC — material basics Polymaker Wiki · 2026-08 · doc
  17. 3DXTech Firewire FR-PC/ABS product page 3DXTech · 2026-08 · vendor
  18. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  19. Bambu Filament Technical Data Sheet V2.0 — PC Bambu Lab · 2026-08 · tds
  20. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  21. PolyLite PC Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
  22. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  23. TECANAT natural (PC) — stock shape properties Ensinger · 2026-08 · tds
  24. Experimental data for creep and dynamic mechanical properties of polycarbonate and polycarbonate/ABS Data in Brief 42:108264 · 2022-06 · paper
  25. Prusament PC Blend Technical Datasheet v1.1 Prusa Polymers · 2022-02 · tds
  26. Firewire Flame Retardant PC/ABS Technical Data Sheet Rev 3.0 3DXTech · 2026-08 · tds
  27. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  28. Makrolon — The chemical resistance (Makrolon 2800, 6 days at 23 °C and 50 °C) Covestro · 2016-12 · tds
  29. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  30. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
  31. Weld-On 3 Acrylic Plastic Cement — technical data sheet (shipped as dichloromethane) IPS Corporation · 2002-07 · tds