Filament comparison
PA blend vs TPU soft
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | PA6/66 copolymer blendsPA | Soft TPU (below 85A)FLEX |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $65.62/kg median; $62.00–$113.33/kg across 4 dated product listings | $114.04/kg median; $109.80–$122.27/kg across 4 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | PA6/66 copolymer — a nylon alloy that lowers the melting point and improves printability against straight PA6[1][2] | Very soft thermoplastic elastomers below 85 Shore A. Fiberlogy's FiberFlex 30D measures 81 Shore A, the softest grade with a published datasheet found here[3] |
| Densityg/cm³ | 1.12 (ISO 1183, Polymaker CoPA)[1] | 1.07 (Fiberlogy FiberFlex 30D, ISO 1183)[3] |
| Typical priceUSD/kg | 1 kg-equivalent spools cluster near 65[4][5][6] | 1 kg-equivalent spools cluster near 115[7][8][9] |
| Price range across brandsUSD/kg | 62–113 across brands; add:north Adura 62, PrimaCreator NylonPower PA6/66 65 at 500 g, Polymaker CoPA 67, 3DXTech AmideX Nylon 6-66 113[4][10][5][6] | 110–122 at 1 kg-equivalent; Recreus 70A 110 and 60A 116 at 500 g, NinjaTek Edge 83A 112, NinjaTek Chinchilla 75A 122; the Recreus 3 kg spools fall to 70–73[7][9][8] |
| Market availability1–5 | Available from several mainstream brands[4][10] | Niche, a handful of specialist brands[3][11][7] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 0.5, 0.75 and 1 kg spools[4][10][5][6] | 1.75, 2.85 and 3 mm; 0.5, 0.85, 1, 2 and 3 kg spools[3][7][12][8] |
| Typical applications | General-purpose nylon parts and, unusually, CoPA can support itself if the support is removed before it absorbs moisture[1] | Highly compliant seals, soft grips and prosthetic liners[3] |
| Printing Parameters | ||
| Nozzle temperature°C | 250–270 (Polymaker CoPA)[1] | Not documented |
| Bed temperature°C | 25–50 (Polymaker CoPA)[1] | 50–70 (Fiberlogy FiberFlex 30D)[3] |
| Enclosure / chamber requirement1–5 | Enclosure required (passive) — Polymaker specifies a chamber at ambient temperature[1] | Open frame is fine[3] |
| Bed surface & adhesion aid | Not documented | PEI sheet or painter's tape; Polymaker warns TPU can over-stick and advises a glue stick as a release agent[13][14] |
| Maximum volumetric flow (mm³/s; see test conditions)mm³/s | 16 at Polymaker's 200 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[1][15] | Not documented |
| Overall printing difficulty1–5 | Advanced — enclosure, hardware upgrades, tuning; must be kept below 20 % RH throughout[1][16] | Expert / industrial hardware only — below 85 Shore A the filament buckles in almost any feed path that is not a short, constrained direct drive[12][14] |
| Extruder requirement | Not documented | Direct drive only, with a constrained filament path; Bowden is not viable at this hardness[12][11] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Brass fine indefinitely for unfilled grades[17] | Brass fine indefinitely[18] |
| Abrasiveness1–5 | Non-abrasive when unfilled[17] | Non-abrasive[18] |
| Nozzle clog risk1–5 | Very high — frequent jams without careful setup[19][16] | High — jams from moisture, heat creep or particles; below 85 Shore A the filament buckles and compresses, and Simplify3D warns that raised feed rates most likely end in a jam[13][14][16] |
| Heat-creep / jam sensitivity1–5 | Not documented | Very high — softens in the cold zone readily[14] |
| Hotend requirement | Not documented | No special hot-end required, but a direct-drive extruder is (Simplify3D)[13] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Very high (>2 %) — Polymaker's own wet-state specimens reached 6.16 % moisture content after 48 h immersion at 60 °C[1][16] | Moderate[16] |
| Drying temperature & time | 100 °C for 8 h (Polymaker CoPA)[1] | Not documented |
| Symptoms when wet | Popping and cracking during extrusion, then hard-to-diagnose defects[19] | Bubbling and popping at the nozzle, stringing and a rough surface[16] |
| Effect of moisture on strength | Measured dry against wet on printed specimens at 6.16 % moisture (Polymaker CoPA): tensile 78.0 → 34.3 MPa, Young's modulus 2703 → 724 MPa, flexural strength 109.8 → 22.6 MPa, while notched Charpy rises 6.9 → 27.7 kJ/m² and elongation 12.7 → 13.2 %[1][19] | Polymaker groups TPU with the highly hygroscopic materials; no dry-versus-conditioned figures are published[16] |
| Storage requirement | Polymaker states CoPA must always be stored and used below 20 % relative humidity[1] | Sealed with desiccant; often kept in a dryer during the print[16] |
| Hydrolysis at melt temperature | Polymaker requires a 100 °C dry for 8 h and storage below 20 % RH; no molecular-weight loss figure is published, and the published wet data is conditioning rather than melt hydrolysis[1][20] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 78.0 ± 0.7 printed XY dry and 34.3 ± 2.5 wet, ISO 527 (Polymaker CoPA)[1] | Not documented |
| Young's modulusMPa | 2703 ± 259 printed XY dry and 724 ± 61 wet, ISO 527 (Polymaker CoPA)[1] | Not documented |
| Elongation at break% | 12.7 ± 2.1 printed XY dry and 13.2 ± 2.3 wet, ISO 527 (Polymaker CoPA)[1] | 870 at break (Fiberlogy FiberFlex 30D, ISO 527) — the highest elongation in the dataset[3] |
| Flexural strengthMPa | 109.8 ± 1.3 printed XY dry and 22.6 ± 0.5 wet, ISO 178 (Polymaker CoPA)[1] | Not documented |
| Flexural modulusMPa | 2510 ± 25 printed XY dry and 636 ± 11 wet, ISO 178 (Polymaker CoPA)[1] | Not documented |
| Charpy impact, notchedkJ/m² | 6.9 ± 1.4 printed XY dry and 27.7 ± 1.2 wet, ISO 179 notched (Polymaker CoPA) — impact quadruples when conditioned[1] | Not documented |
| Layer adhesion / Z tensileMPa | 45.8 ± 1.5 printed Z dry, falling to 13.7 ± 1.2 wet, ISO 527 (Polymaker CoPA)[1] | Not documented |
| Brittleness1–5 | Tough — absorbs impact, yields before breaking[1] | Very ductile — bends far before failing[3] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Shore D 86 and Rockwell 85 (108) — the source does not name the scales on extruded unfilled PA66 stock (ASTM D2240, D785)[21] | 81 Shore A and 30 Shore D (Fiberlogy FiberFlex 30D, ISO 7619)[3] |
| Creep resistance / sustained load1–5 | Not documented | Poor — no creep test at this hardness; a printed 95A TPU bar crept from 74.5 to 82.7 mm over 5 days at 1.25 kg[22] |
| Fatigue / repeated-flex resistance1–5 | Excellent — living hinges viable[17] | Excellent — living hinges viable[14] |
| Elasticity / flexibility1–5 | Semi-flexible[19] | Rubbery / highly elastic[3] |
| Z strength as % of XY% | 59 dry (45.8 Z against 78.0 XY) and 40 wet, printed[1] | Not documented |
| Wear resistance & friction | Not documented | Tear strength 95 kN/m (Fiberlogy FiberFlex 30D, ISO 34-1)[3] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 111 (ISO 75, 0.45 MPa, Polymaker CoPA)[1] | Not documented |
| HDT at 1.8 MPa°C | 70 (ISO 75, 1.8 MPa, Polymaker CoPA)[1] | Not documented |
| Glass transition (Tg)°C | 66 (DSC, Polymaker CoPA)[1] | Not documented |
| Melting point / Vicat°C | 189 melting (DSC); Vicat 180, crystallisation 148, decomposition 370 (Polymaker CoPA)[1] | 170 melting (Fiberlogy FiberFlex 30D, DSC)[3] |
| Annealing response | 80 °C for 6 h (Polymaker CoPA)[1] | Not documented |
| Thermal expansion (CTE)µm/m·K | 81.0 on extruded unfilled PA66 stock (ASTM D696; source states 4.5e-5 in/in/°F) — the same chemistry as a PA6/66 copolymer[21] | Not documented |
| Environment & Chemical | ||
| UV resistance1–5 | Not documented | Good — years with some colour shift; Polymaker lists UV exposure among the conditions TPU withstands[14] |
| Chemical resistance | Not documented | Withstands industrial solvents and UV exposure (Polymaker)[14] |
| Water / humidity resistance in service1–5 | Absorbs water, properties shift — 6.16 % uptake cost 56 % of tensile strength and 73 % of modulus[1] | Not documented |
| Food contact | Not documented | Not food safe without specific certification (Polymaker)[14] |
| Biodegradability / compostability | Not documented | Not biodegradable[14] |
| Recyclability | Not documented | Not accepted in household plastic collection[14] |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised[23] | Low hazard — minimal VOC and particle emission; TPU was not among the nine filaments in the chamber study[23] |
| VOC emission rateµg/min | Up to 180 caprolactam, the dominant VOC from nylon; total VOC reached nearly 200 µg/min, the highest of the nine filaments tested[23] | Not documented |
| Ultrafine-particle emission rateparticles/min | ≈2 × 10⁸ median — low for ultrafine particles despite the highest VOC mass of any filament tested[23] | Not documented |
| Hazardous species emitted | Caprolactam, at up to 180 µg/min from nylon filament — the largest single-VOC emission rate measured in the study[23] | Not documented |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[23] | Open a window / occasional ventilation[23] |
| Post-Processing | ||
| Sanding & machining | Not documented | Difficult to sand or smooth; Polymaker limits post-processing to trimming or tumbling[14] |
| Gluing & solvent welding | Not documented | Cyanoacrylate bonds TPU; no common solvent welds it[14] |
| Vapour / chemical smoothing | Not documented | No practical vapour smoothing[14] |
| Support material pairing | CoPA can support itself, but Polymaker warns the support bonds permanently if it absorbs moisture before removal[1] | Polymaker warns TPU supports are often very difficult to remove[14] |
| Solvents & Solubility | ||
| Soluble in | Dissolved at 23 °C by formic acid above ~50 %, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — laboratory reagents.[24] | DMF, DMSO, NMP and THF dissolve TPU; acetone, MEK and cyclohexanone are partial solvents. All laboratory reagents.[25] |
| Softened or crazed by | Zinc chloride solutions stress-crack it — 10 % marginal, 37 % not resistant; alcoholic calcium chloride dissolves it.[24] | Toluene and benzene swell it up to +50 % by weight at 23 °C; esters swell it severely; ethanol and IPA soften it.[25] |
| Solvent welding & smoothing agent | None — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[24] | None practical — the true solvents (DMF, THF, NMP) are laboratory reagents and leave the joint swollen and weak.[25] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
- AmideX Nylon 6-66 — product page 3DXTech · 2026-08 · vendor
- FiberFlex 30D Technical Data Sheet Fiberlogy · 2026-08 · tds
- Polymaker product catalogue Polymaker · 2026-08 · vendor
- add:north Adura product page add:north · 2026-08 · vendor
- PrimaCreator SELECT NylonPower PA6/66 product page PrimaCreator · 2026-08 · vendor
- Recreus product catalogue Recreus · 2026-08 · vendor
- Chinchilla product page — print guidelines, spool sizes and price NinjaTek · 2026-08 · vendor
- NinjaFlex Edge product page — durometer, print guidelines and price NinjaTek · 2026-08 · vendor
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- Filaflex 82A product page (Shore hardness and elongation) Recreus · 2026-08 · vendor
- NinjaFlex 85A Technical Specifications NinjaTek · 2026-08 · tds
- Flexible (TPE/TPU) — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- TPU — material basics Polymaker Wiki · 2026-08 · doc
- Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
- Extrudr Product Catalogue (DURAPRO PA12 data block) Extrudr · 2025-03 · tds
- Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
- PolyMide CoPA — Technical Data Sheet page Polymaker Wiki · 2026-08 · tds
- TECAMID 66 natural (PA66) — stock shape properties Ensinger · 2026-08 · tds
- BambuLab TPU 95A HF vs Qidi TPU 95A HF — results spreadsheet My Tech Fun (Igor Gaspar) · 2024-02 · test
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
- Elastollan — Chemical properties: swelling and chemical resistance BASF · 2026-08 · tds