Filament comparison
PA blend vs PLA-GF
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | PA6/66 copolymer blendsPA | Glass-fibre PLA (PLA-GF)PLA |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $65.62/kg median; $62.00–$113.33/kg across 4 dated product listings | $44.99/kg median; $29.99–$59.99/kg across 2 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | PA6/66 copolymer — a nylon alloy that lowers the melting point and improves printability against straight PA6[1][2] | PLA filled with chopped glass fibre — 12 wt% (Polymaker HT-PLA-GF), 15–20 wt% (eSUN PLA-GF). Bambu Lab PLA Galaxy uses glass microspheres, not fibre, and is not equivalent[3][4][5] |
| Densityg/cm³ | 1.12 (ISO 1183, Polymaker CoPA)[1] | 1.31 (eSUN) to 1.337 (Polymaker), ISO 1183 / GB/T 1033[3][4] |
| Typical priceUSD/kg | 1 kg-equivalent spools cluster near 65[6][7][8] | 1 kg spools cluster near 30[9][10] |
| Price range across brandsUSD/kg | 62–113 across brands; add:north Adura 62, PrimaCreator NylonPower PA6/66 65 at 500 g, Polymaker CoPA 67, 3DXTech AmideX Nylon 6-66 113[6][11][7][8] | 30–60 across brands; Polymaker 30, Proto-pasta 60[9][10] |
| Market availability1–5 | Available from several mainstream brands[6][11] | Niche, a handful of specialist brands[9][10][4] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 0.5, 0.75 and 1 kg spools[6][11][7][8] | 1.75 mm; 0.5 and 1 kg spools[10][6] |
| Typical applications | General-purpose nylon parts and, unusually, CoPA can support itself if the support is removed before it absorbs moisture[1] | Stiff brackets and fixtures; the Polymaker grade is aimed at parts annealed for heat resistance[3] |
| Printing Parameters | ||
| Nozzle temperature°C | 250–270 (Polymaker CoPA)[1] | 210–230 (Polymaker HT-PLA-GF)[3] |
| Bed temperature°C | 25–50 (Polymaker CoPA)[1] | 25–60 (Polymaker HT-PLA-GF)[3] |
| Enclosure / chamber requirement1–5 | Enclosure required (passive) — Polymaker specifies a chamber at ambient temperature[1] | Open frame is fine[3] |
| Part cooling fan | Not documented | Fan on — eSUN specifies 100 %[4] |
| Maximum volumetric flow (mm³/s; see test conditions)mm³/s | 16 at Polymaker's 200 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[1][12] | 28 at Polymaker's stated 350 mm/s on a 0.4 mm nozzle at 0.2 mm layer; eSUN prints its specimens at 60 mm/s[3][4][12] |
| Shrinkage% | Not documented | 0.05 in X-Y and Z, 0.10 diagonal (Polymaker HT-PLA-GF)[3] |
| Overall printing difficulty1–5 | Advanced — enclosure, hardware upgrades, tuning; must be kept below 20 % RH throughout[1][13] | Intermediate — dry filament and a tuned profile; hardened nozzle mandatory[3] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Brass fine indefinitely for unfilled grades[14] | Hardened steel required[3] |
| Abrasiveness1–5 | Non-abrasive when unfilled[14] | Highly abrasive — standard GF composite[3] |
| Nozzle clog risk1–5 | Very high — frequent jams without careful setup[15][13] | Moderate — needs dry filament and a clean nozzle; Prusa lists higher risk of nozzle clogging for glass-filled composites[16] |
| Hotend requirement | Not documented | Hardened steel or ruby nozzle; Polymaker's own slicer preset sets a minimum nozzle hardness of 40 HRC[3] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Very high (>2 %) — Polymaker's own wet-state specimens reached 6.16 % moisture content after 48 h immersion at 60 °C[1][13] | Moderate — the PLA matrix takes up 0.40–0.51 % saturated; no glass-filled grade publishes its own figure[17][18] |
| Drying temperature & time | 100 °C for 8 h (Polymaker CoPA)[1] | 60 °C for 6 h (Polymaker HT-PLA-GF)[3] |
| Symptoms when wet | Popping and cracking during extrusion, then hard-to-diagnose defects[15] | Not documented |
| Effect of moisture on strength | Measured dry against wet on printed specimens at 6.16 % moisture (Polymaker CoPA): tensile 78.0 → 34.3 MPa, Young's modulus 2703 → 724 MPa, flexural strength 109.8 → 22.6 MPa, while notched Charpy rises 6.9 → 27.7 kJ/m² and elongation 12.7 → 13.2 %[1][15] | Polymaker rates PLA low-sensitivity and publishes no dry-versus-conditioned figures for this grade; absorbed water flashes to steam and shows as bubbling and poor layer adhesion[13] |
| Storage requirement | Polymaker states CoPA must always be stored and used below 20 % relative humidity[1] | Not documented |
| Hydrolysis at melt temperature | Polymaker requires a 100 °C dry for 8 h and storage below 20 % RH; no molecular-weight loss figure is published, and the published wet data is conditioning rather than melt hydrolysis[1][19] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 78.0 ± 0.7 printed XY dry and 34.3 ± 2.5 wet, ISO 527 (Polymaker CoPA)[1] | 50.1 as printed and 50.2 annealed, printed XY, ISO 527 (Polymaker); eSUN quotes 59.3 by GB/T 1040[3][4] |
| Young's modulusMPa | 2703 ± 259 printed XY dry and 724 ± 61 wet, ISO 527 (Polymaker CoPA)[1] | 3794 as printed, 4207 annealed, printed XY, ISO 527 (Polymaker)[3] |
| Elongation at break% | 12.7 ± 2.1 printed XY dry and 13.2 ± 2.3 wet, ISO 527 (Polymaker CoPA)[1] | 2.77 as printed, 2.3 annealed, printed XY, ISO 527 (Polymaker); eSUN quotes 7.99[3][4] |
| Flexural strengthMPa | 109.8 ± 1.3 printed XY dry and 22.6 ± 0.5 wet, ISO 178 (Polymaker CoPA)[1] | 86.4 printed XY, ISO 178 (Polymaker)[3] |
| Flexural modulusMPa | 2510 ± 25 printed XY dry and 636 ± 11 wet, ISO 178 (Polymaker CoPA)[1] | 3685 printed XY, ISO 178 (Polymaker); eSUN quotes 4415 flexural modulus by GB/T 9341[3][4] |
| Charpy impact, notchedkJ/m² | 6.9 ± 1.4 printed XY dry and 27.7 ± 1.2 wet, ISO 179 notched (Polymaker CoPA) — impact quadruples when conditioned[1] | 5.31 ± 0.46 as printed and 4.92 ± 0.50 annealed (printed XY, ISO 179, notched); Z 4.28 ± 0.18[3] |
| Other impact data | Not documented | Izod 10.16 kJ/m² (eSUN, GB/T 1843)[4] |
| Layer adhesion / Z tensileMPa | 45.8 ± 1.5 printed Z dry, falling to 13.7 ± 1.2 wet, ISO 527 (Polymaker CoPA)[1] | 23.7 as printed, 22.5 annealed, printed Z, ISO 527 (Polymaker)[3] |
| Brittleness1–5 | Tough — absorbs impact, yields before breaking[1] | Very brittle — elongation at break 2.77 % in XY and 0.85 % in Z[3] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Shore D 86 and Rockwell 85 (108) — the source does not name the scales on extruded unfilled PA66 stock (ASTM D2240, D785)[20] | Not documented |
| Creep resistance / sustained load1–5 | Not documented | Poor — no GF-grade creep test; plain printed PLA sagged from 12 to 16.2–21.8 mm over 5 days at 1.25 kg[21][22][23] |
| Fatigue / repeated-flex resistance1–5 | Excellent — living hinges viable[14] | Poor — no grade-specific S-N curve; plain printed PLA ran 38 000–49 000 cycles at 30 % of tensile strength and elongation at break falls to 2.77 % in XY and 0.85 % in Z[24][3] |
| Elasticity / flexibility1–5 | Semi-flexible[15] | Rigid[3] |
| Z strength as % of XY% | 59 dry (45.8 Z against 78.0 XY) and 40 wet, printed[1] | 47 as printed (23.7 Z against 50.1 XY), printed[3] |
| Wear resistance & friction | Not documented | eSUN describes high wear resistance and positions the grade for wear parts[4] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 111 (ISO 75, 0.45 MPa, Polymaker CoPA)[1] | 75.5 as printed, 114.7 after annealing (ISO 75, 0.45 MPa) — the point of the material[3] |
| HDT at 1.8 MPa°C | 70 (ISO 75, 1.8 MPa, Polymaker CoPA)[1] | 59.7 as printed, 84 after annealing (ISO 75, 1.8 MPa)[3] |
| Glass transition (Tg)°C | 66 (DSC, Polymaker CoPA)[1] | 59.8 (DSC)[3] |
| Melting point / Vicat°C | 189 melting (DSC); Vicat 180, crystallisation 148, decomposition 370 (Polymaker CoPA)[1] | 174.9 peak melt (DSC); Vicat 148.9 as printed, 148.3 annealed[3] |
| Annealing response | 80 °C for 6 h (Polymaker CoPA)[1] | Annealing lifts HDT at 0.45 MPa from 75.5 to 114.7 °C and modulus from 3794 to 4207 MPa[3] |
| Thermal expansion (CTE)µm/m·K | 81.0 on extruded unfilled PA66 stock (ASTM D696; source states 4.5e-5 in/in/°F) — the same chemistry as a PA6/66 copolymer[20] | Not documented |
| Environment & Chemical | ||
| UV resistance1–5 | Not documented | Degrades within weeks outdoors[25] |
| Water / humidity resistance in service1–5 | Absorbs water, properties shift — 6.16 % uptake cost 56 % of tensile strength and 73 % of modulus[1] | Not documented |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised[26] | Low hazard — minimal VOC and particle emission[26] |
| VOC emission rateµg/min | Up to 180 caprolactam, the dominant VOC from nylon; total VOC reached nearly 200 µg/min, the highest of the nine filaments tested[26] | Not documented |
| Ultrafine-particle emission rateparticles/min | ≈2 × 10⁸ median — low for ultrafine particles despite the highest VOC mass of any filament tested[26] | Not documented |
| Hazardous species emitted | Caprolactam, at up to 180 µg/min from nylon filament — the largest single-VOC emission rate measured in the study[26] | Not documented |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[26] | None needed in a normal room[26] |
| Dust & fibre handling hazard | Not documented | Glass fibre is bound in the matrix; avoid inhaling sanding dust[27] |
| Post-Processing | ||
| Support material pairing | CoPA can support itself, but Polymaker warns the support bonds permanently if it absorbs moisture before removal[1] | Not documented |
| Dimensional accuracy & detail | Not documented | Near-zero shrinkage — 0.05 % in X-Y and Z (Polymaker)[3] |
| Solvents & Solubility | ||
| Soluble in | Dissolved at 23 °C by formic acid above ~50 %, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — laboratory reagents.[28] | Chloroform dissolves the PLA matrix (10 % w/v, 2–4 h at 23 °C) and leaves the filler as loose sludge; laboratory reagent.[29] |
| Softened or crazed by | Zinc chloride solutions stress-crack it — 10 % marginal, 37 % not resistant; alcoholic calcium chloride dissolves it.[28] | Acetone, ethyl acetate and toluene plasticise the matrix but dissolve <1 % even at 65 °C; acetone submersion crazes parts.[29][30] |
| Solvent welding & smoothing agent | None — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[28] | Chloroform vapour attacks only the resin fraction, so the filler is left standing proud; no workshop-safe agent exists.[31][30] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
- AmideX Nylon 6-66 — product page 3DXTech · 2026-08 · vendor
- Polymaker HT-PLA-GF Technical Data Sheet V1.1 Polymaker · 2026-08 · tds
- eSUN ePLA-GF Technical Data Sheet V1.0 (Nov 2023) eSUN (copy hosted on 3d.nice-cdn.com) · 2023-11 · tds
- Bambu Filament Technical Data Sheet V1.0 — PLA Galaxy Bambu Lab · 2026-08 · tds
- Polymaker product catalogue Polymaker · 2026-08 · vendor
- add:north Adura product page add:north · 2026-08 · vendor
- PrimaCreator SELECT NylonPower PA6/66 product page PrimaCreator · 2026-08 · vendor
- Polymaker HT-PLA-GF — product page Polymaker Shop · 2026-08 · vendor
- Proto-pasta product catalogue Proto-pasta · 2026-08 · vendor
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
- Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
- Composite materials filled with carbon, kevlar or glass Prusa Knowledge Base · 2026-08 · doc
- Bambu Filament Technical Data Sheet V3.0 — PLA Basic Bambu Lab · 2026-08 · tds
- PolyLite PLA Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
- PolyMide CoPA — Technical Data Sheet page Polymaker Wiki · 2026-08 · tds
- TECAMID 66 natural (PA66) — stock shape properties Ensinger · 2026-08 · tds
- BambuLab PLA Basic vs PLA Tough vs PLA-CF — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
- Polymaker PLA Pro vs PLA-CF — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
- Carbon Fiber PLA vs META-PLA vs PLA+ vs PLA by Sunlu — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
- Mechanical Properties of Additively Manufactured Polymeric Materials — PLA and PETG — For Biomechanical Applications Polymers 16(13):1868 · 2024-06 · paper
- PLA — material guide Prusa Knowledge Base · 2026-08 · doc
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- StoneFil safety data sheet Formfutura · 2026-08 · msds
- Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
- Solubility Study of Ingeo Biopolymer Grades in Common Organic Solvents (NWPD003) NatureWorks · 2019-10 · tds
- Improve your 3D prints with chemical smoothing Prusa Research · 2026-08 · doc
- Effect of vapour smoothing in trichloromethane on 3D printed PLA — surface, mechanical and chemical structure Pitale, Keche & Chopra, Engineering Research Express 6(4) 045579 · 2024-12 · paper