3D Printing Info

Filament comparison

PA blend vs PLA-GF

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PA blend vs PLA-GF — documented properties and sources
PropertyPA6/66 copolymer blendsPAGlass-fibre PLA (PLA-GF)PLA
Market snapshot
Listing priceUSD/kg; dated snapshots$65.62/kg median; $62.00–$113.33/kg across 4 dated product listings$44.99/kg median; $29.99–$59.99/kg across 2 dated product listings
Identity & Market
Base polymer / chemistryPA6/66 copolymer — a nylon alloy that lowers the melting point and improves printability against straight PA6[1][2]PLA filled with chopped glass fibre — 12 wt% (Polymaker HT-PLA-GF), 15–20 wt% (eSUN PLA-GF). Bambu Lab PLA Galaxy uses glass microspheres, not fibre, and is not equivalent[3][4][5]
Densityg/cm³1.12 (ISO 1183, Polymaker CoPA)[1]1.31 (eSUN) to 1.337 (Polymaker), ISO 1183 / GB/T 1033[3][4]
Typical priceUSD/kg1 kg-equivalent spools cluster near 65[6][7][8]1 kg spools cluster near 30[9][10]
Price range across brandsUSD/kg62–113 across brands; add:north Adura 62, PrimaCreator NylonPower PA6/66 65 at 500 g, Polymaker CoPA 67, 3DXTech AmideX Nylon 6-66 113[6][11][7][8]30–60 across brands; Polymaker 30, Proto-pasta 60[9][10]
Market availability1–5Available from several mainstream brands[6][11]Niche, a handful of specialist brands[9][10][4]
Spool sizes & diameters1.75 and 2.85 mm; 0.5, 0.75 and 1 kg spools[6][11][7][8]1.75 mm; 0.5 and 1 kg spools[10][6]
Typical applicationsGeneral-purpose nylon parts and, unusually, CoPA can support itself if the support is removed before it absorbs moisture[1]Stiff brackets and fixtures; the Polymaker grade is aimed at parts annealed for heat resistance[3]
Printing Parameters
Nozzle temperature°C250–270 (Polymaker CoPA)[1]210–230 (Polymaker HT-PLA-GF)[3]
Bed temperature°C25–50 (Polymaker CoPA)[1]25–60 (Polymaker HT-PLA-GF)[3]
Enclosure / chamber requirement1–5Enclosure required (passive) — Polymaker specifies a chamber at ambient temperature[1]Open frame is fine[3]
Part cooling fanNot documentedFan on — eSUN specifies 100 %[4]
Maximum volumetric flow (mm³/s; see test conditions)mm³/s16 at Polymaker's 200 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[1][12]28 at Polymaker's stated 350 mm/s on a 0.4 mm nozzle at 0.2 mm layer; eSUN prints its specimens at 60 mm/s[3][4][12]
Shrinkage%Not documented0.05 in X-Y and Z, 0.10 diagonal (Polymaker HT-PLA-GF)[3]
Overall printing difficulty1–5Advanced — enclosure, hardware upgrades, tuning; must be kept below 20 % RH throughout[1][13]Intermediate — dry filament and a tuned profile; hardened nozzle mandatory[3]
Hardware Wear & Reliability
Nozzle hardness required1–4Brass fine indefinitely for unfilled grades[14]Hardened steel required[3]
Abrasiveness1–5Non-abrasive when unfilled[14]Highly abrasive — standard GF composite[3]
Nozzle clog risk1–5Very high — frequent jams without careful setup[15][13]Moderate — needs dry filament and a clean nozzle; Prusa lists higher risk of nozzle clogging for glass-filled composites[16]
Hotend requirementNot documentedHardened steel or ruby nozzle; Polymaker's own slicer preset sets a minimum nozzle hardness of 40 HRC[3]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Very high (>2 %) — Polymaker's own wet-state specimens reached 6.16 % moisture content after 48 h immersion at 60 °C[1][13]Moderate — the PLA matrix takes up 0.40–0.51 % saturated; no glass-filled grade publishes its own figure[17][18]
Drying temperature & time100 °C for 8 h (Polymaker CoPA)[1]60 °C for 6 h (Polymaker HT-PLA-GF)[3]
Symptoms when wetPopping and cracking during extrusion, then hard-to-diagnose defects[15]Not documented
Effect of moisture on strengthMeasured dry against wet on printed specimens at 6.16 % moisture (Polymaker CoPA): tensile 78.0 → 34.3 MPa, Young's modulus 2703 → 724 MPa, flexural strength 109.8 → 22.6 MPa, while notched Charpy rises 6.9 → 27.7 kJ/m² and elongation 12.7 → 13.2 %[1][15]Polymaker rates PLA low-sensitivity and publishes no dry-versus-conditioned figures for this grade; absorbed water flashes to steam and shows as bubbling and poor layer adhesion[13]
Storage requirementPolymaker states CoPA must always be stored and used below 20 % relative humidity[1]Not documented
Hydrolysis at melt temperaturePolymaker requires a 100 °C dry for 8 h and storage below 20 % RH; no molecular-weight loss figure is published, and the published wet data is conditioning rather than melt hydrolysis[1][19]Not documented
Mechanical Properties
Tensile strength (XY)MPa78.0 ± 0.7 printed XY dry and 34.3 ± 2.5 wet, ISO 527 (Polymaker CoPA)[1]50.1 as printed and 50.2 annealed, printed XY, ISO 527 (Polymaker); eSUN quotes 59.3 by GB/T 1040[3][4]
Young's modulusMPa2703 ± 259 printed XY dry and 724 ± 61 wet, ISO 527 (Polymaker CoPA)[1]3794 as printed, 4207 annealed, printed XY, ISO 527 (Polymaker)[3]
Elongation at break%12.7 ± 2.1 printed XY dry and 13.2 ± 2.3 wet, ISO 527 (Polymaker CoPA)[1]2.77 as printed, 2.3 annealed, printed XY, ISO 527 (Polymaker); eSUN quotes 7.99[3][4]
Flexural strengthMPa109.8 ± 1.3 printed XY dry and 22.6 ± 0.5 wet, ISO 178 (Polymaker CoPA)[1]86.4 printed XY, ISO 178 (Polymaker)[3]
Flexural modulusMPa2510 ± 25 printed XY dry and 636 ± 11 wet, ISO 178 (Polymaker CoPA)[1]3685 printed XY, ISO 178 (Polymaker); eSUN quotes 4415 flexural modulus by GB/T 9341[3][4]
Charpy impact, notchedkJ/m²6.9 ± 1.4 printed XY dry and 27.7 ± 1.2 wet, ISO 179 notched (Polymaker CoPA) — impact quadruples when conditioned[1]5.31 ± 0.46 as printed and 4.92 ± 0.50 annealed (printed XY, ISO 179, notched); Z 4.28 ± 0.18[3]
Other impact dataNot documentedIzod 10.16 kJ/m² (eSUN, GB/T 1843)[4]
Layer adhesion / Z tensileMPa45.8 ± 1.5 printed Z dry, falling to 13.7 ± 1.2 wet, ISO 527 (Polymaker CoPA)[1]23.7 as printed, 22.5 annealed, printed Z, ISO 527 (Polymaker)[3]
Brittleness1–5Tough — absorbs impact, yields before breaking[1]Very brittle — elongation at break 2.77 % in XY and 0.85 % in Z[3]
Hardness (scale-specific)Shore A / Shore D / RockwellShore D 86 and Rockwell 85 (108) — the source does not name the scales on extruded unfilled PA66 stock (ASTM D2240, D785)[20]Not documented
Creep resistance / sustained load1–5Not documentedPoor — no GF-grade creep test; plain printed PLA sagged from 12 to 16.2–21.8 mm over 5 days at 1.25 kg[21][22][23]
Fatigue / repeated-flex resistance1–5Excellent — living hinges viable[14]Poor — no grade-specific S-N curve; plain printed PLA ran 38 000–49 000 cycles at 30 % of tensile strength and elongation at break falls to 2.77 % in XY and 0.85 % in Z[24][3]
Elasticity / flexibility1–5Semi-flexible[15]Rigid[3]
Z strength as % of XY%59 dry (45.8 Z against 78.0 XY) and 40 wet, printed[1]47 as printed (23.7 Z against 50.1 XY), printed[3]
Wear resistance & frictionNot documentedeSUN describes high wear resistance and positions the grade for wear parts[4]
Thermal Properties
HDT at 0.45 MPa°C111 (ISO 75, 0.45 MPa, Polymaker CoPA)[1]75.5 as printed, 114.7 after annealing (ISO 75, 0.45 MPa) — the point of the material[3]
HDT at 1.8 MPa°C70 (ISO 75, 1.8 MPa, Polymaker CoPA)[1]59.7 as printed, 84 after annealing (ISO 75, 1.8 MPa)[3]
Glass transition (Tg)°C66 (DSC, Polymaker CoPA)[1]59.8 (DSC)[3]
Melting point / Vicat°C189 melting (DSC); Vicat 180, crystallisation 148, decomposition 370 (Polymaker CoPA)[1]174.9 peak melt (DSC); Vicat 148.9 as printed, 148.3 annealed[3]
Annealing response80 °C for 6 h (Polymaker CoPA)[1]Annealing lifts HDT at 0.45 MPa from 75.5 to 114.7 °C and modulus from 3794 to 4207 MPa[3]
Thermal expansion (CTE)µm/m·K81.0 on extruded unfilled PA66 stock (ASTM D696; source states 4.5e-5 in/in/°F) — the same chemistry as a PA6/66 copolymer[20]Not documented
Environment & Chemical
UV resistance1–5Not documentedDegrades within weeks outdoors[25]
Water / humidity resistance in service1–5Absorbs water, properties shift — 6.16 % uptake cost 56 % of tensile strength and 73 % of modulus[1]Not documented
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised[26]Low hazard — minimal VOC and particle emission[26]
VOC emission rateµg/minUp to 180 caprolactam, the dominant VOC from nylon; total VOC reached nearly 200 µg/min, the highest of the nine filaments tested[26]Not documented
Ultrafine-particle emission rateparticles/min≈2 × 10⁸ median — low for ultrafine particles despite the highest VOC mass of any filament tested[26]Not documented
Hazardous species emittedCaprolactam, at up to 180 µg/min from nylon filament — the largest single-VOC emission rate measured in the study[26]Not documented
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[26]None needed in a normal room[26]
Dust & fibre handling hazardNot documentedGlass fibre is bound in the matrix; avoid inhaling sanding dust[27]
Post-Processing
Support material pairingCoPA can support itself, but Polymaker warns the support bonds permanently if it absorbs moisture before removal[1]Not documented
Dimensional accuracy & detailNot documentedNear-zero shrinkage — 0.05 % in X-Y and Z (Polymaker)[3]
Solvents & Solubility
Soluble inDissolved at 23 °C by formic acid above ~50 %, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — laboratory reagents.[28]Chloroform dissolves the PLA matrix (10 % w/v, 2–4 h at 23 °C) and leaves the filler as loose sludge; laboratory reagent.[29]
Softened or crazed byZinc chloride solutions stress-crack it — 10 % marginal, 37 % not resistant; alcoholic calcium chloride dissolves it.[28]Acetone, ethyl acetate and toluene plasticise the matrix but dissolve <1 % even at 65 °C; acetone submersion crazes parts.[29][30]
Solvent welding & smoothing agentNone — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[28]Chloroform vapour attacks only the resin fraction, so the filler is left standing proud; no workshop-safe agent exists.[31][30]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
  2. AmideX Nylon 6-66 — product page 3DXTech · 2026-08 · vendor
  3. Polymaker HT-PLA-GF Technical Data Sheet V1.1 Polymaker · 2026-08 · tds
  4. eSUN ePLA-GF Technical Data Sheet V1.0 (Nov 2023) eSUN (copy hosted on 3d.nice-cdn.com) · 2023-11 · tds
  5. Bambu Filament Technical Data Sheet V1.0 — PLA Galaxy Bambu Lab · 2026-08 · tds
  6. Polymaker product catalogue Polymaker · 2026-08 · vendor
  7. add:north Adura product page add:north · 2026-08 · vendor
  8. PrimaCreator SELECT NylonPower PA6/66 product page PrimaCreator · 2026-08 · vendor
  9. Polymaker HT-PLA-GF — product page Polymaker Shop · 2026-08 · vendor
  10. Proto-pasta product catalogue Proto-pasta · 2026-08 · vendor
  11. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  12. Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
  13. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  14. PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
  15. Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
  16. Composite materials filled with carbon, kevlar or glass Prusa Knowledge Base · 2026-08 · doc
  17. Bambu Filament Technical Data Sheet V3.0 — PLA Basic Bambu Lab · 2026-08 · tds
  18. PolyLite PLA Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
  19. PolyMide CoPA — Technical Data Sheet page Polymaker Wiki · 2026-08 · tds
  20. TECAMID 66 natural (PA66) — stock shape properties Ensinger · 2026-08 · tds
  21. BambuLab PLA Basic vs PLA Tough vs PLA-CF — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  22. Polymaker PLA Pro vs PLA-CF — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  23. Carbon Fiber PLA vs META-PLA vs PLA+ vs PLA by Sunlu — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  24. Mechanical Properties of Additively Manufactured Polymeric Materials — PLA and PETG — For Biomechanical Applications Polymers 16(13):1868 · 2024-06 · paper
  25. PLA — material guide Prusa Knowledge Base · 2026-08 · doc
  26. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  27. StoneFil safety data sheet Formfutura · 2026-08 · msds
  28. Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
  29. Solubility Study of Ingeo Biopolymer Grades in Common Organic Solvents (NWPD003) NatureWorks · 2019-10 · tds
  30. Improve your 3D prints with chemical smoothing Prusa Research · 2026-08 · doc
  31. Effect of vapour smoothing in trichloromethane on 3D printed PLA — surface, mechanical and chemical structure Pitale, Keche & Chopra, Engineering Research Express 6(4) 045579 · 2024-12 · paper