3D Printing Info

Filament comparison

ASA vs PPSU

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

ASA vs PPSU — documented properties and sources
PropertyASAASAPPSUHIGHTEMP
Market snapshot
Listing priceUSD/kg; dated snapshots$28.98/kg median; $17.99–$50.00/kg across 14 dated product listings$337.40/kg median; $223.00–$732.56/kg across 4 dated product listings
Identity & Market
Base polymer / chemistryAcrylonitrile styrene acrylate — ABS with the butadiene rubber phase replaced by an acrylate rubber that has no UV-vulnerable double bonds[1][2]Polyphenylsulfone — an amorphous high-temperature sulfone polymer[3]
Densityg/cm³1.05 (Bambu Lab) to 1.13 (PolyLite ASA), ISO 1183; Prusament 1.07[4][5][2]1.28 (ISO 1183, 3DXTech; ASTM D792, Stratasys PPSF)[3][6]
Typical priceUSD/kg1 kg spools cluster near 30[7][8][9]1 kg-equivalent spools span 223–733; the middle of the market is about 425[10][11][12][13]
Price range across brandsUSD/kg18–50 across brands; IEMAI 18, SUNLU 18, Ambrosia 23, Polymaker 26, Bambu Lab 30, YXPOLYER 30, Prusament 41, 3DXTech 50[14][8][7][15][9][10][16][17][18]223-733 across brands; IEMAI 3D 223 at 1 kg, 3DXTech ThermaX PPSU 250 at 500 g, 3D4Makers 425 at 750 g, Kimya PPSU-S 733 at 500 g[10][11][12][13]
Market availability1–5Stocked by most mainstream brands[7][8][10][9]Niche, a handful of specialist brands[10][11][12]
Spool sizes & diameters1.75 and 2.85 mm; 0.8, 1, 4 and 10 kg spools[10][9][7]1.75 and 2.85 mm; 200 g to 750 g spools[10][11][12]
Typical applicationsOutdoor fittings, signage, automotive exterior trim and anything that has to hold colour and strength in sunlight[19][1]Steam-sterilisable medical and dental tooling, and aircraft interior parts[3]
Diameter tolerance± mm±0.04 (Prusament)[2]Not documented
Printing Parameters
Nozzle temperature°C230–270 across brands; Prusament 260 ± 10, Bambu Lab 240–270, PolyLite 230–260[4][5][2]Not documented
Bed temperature°C75–110; Prusament 110 ± 5, Bambu Lab 80–100, PolyLite 75–95[4][5][2]130–150 (3DXTech)[3]
Enclosure / chamber requirement1–5Enclosure recommended — Polymaker calls a chamber needed at ambient temperature, Bambu Lab requires an enclosed printer and rules out its P1P and A-series machines[5][20]Actively heated chamber required[21][22]
Recommended chamber temperature°C45–60 (Bambu Lab)[4]Not documented
Part cooling fanLow — Prusament 30 % within a 0–50 % range, Bambu Lab 0–80 %, PolyLite off[2][4][5]Not documented
Bed surface & adhesion aidSatin, smooth PEI or powder-coated sheet with a glue stick; Prusa advises a 3 mm or taller brim on large parts[2][20]Not documented
Maximum volumetric flow (mm³/s; see test conditions)mm³/s10–16 (PrusaSlicer guidance for ABS/ASA)[23]Not documented
Warping tendency1–5High — enclosure needed for reliable large parts; Prusa recommends a tall brim and Bambu Lab attributes cracking to cooling stress exceeding interlayer adhesion[2][20]Severe — heated chamber needed[21]
Bed-adhesion difficulty1–5Needs a specific surface plus adhesive[2][20]Not documented
Stringing / oozing tendency1–5Slight[5]Not documented
Overall printing difficulty1–5Intermediate — dry filament and a tuned profile[20][2]Expert / industrial hardware only[21][22]
Hardware Wear & Reliability
Nozzle hardness required1–4Brass fine indefinitely[20]Brass fine indefinitely for unfilled grades, but brass softens near these nozzle temperatures — hardened or plated hot ends are the norm[21]
Abrasiveness1–5Non-abrasive[20]Non-abrasive when unfilled[3]
Nozzle clog risk1–5Low — no special hot-end required and clogging is not among the listed drawbacks; Prusa lists no drybox and no hardened nozzle[24][25]Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[26]
Heat-creep / jam sensitivity1–5Slightly sensitive[24]Not documented
Hotend requirementNo special hot-end required[24]Not documented
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Moderate — 0.45 % saturated at 25 °C / 55 % RH (Bambu Lab) and 0.40 % equilibrium (Polymaker); Prusa measures only 0.17 % after 7 days at 22 % RH[4][5][2]Not documented
Equilibrium moisture content at ~50 % RH%0.45 saturated at 25 °C / 55 % RH (Bambu Lab); 0.40 equilibrium (Polymaker); 0.17 after 7 days at 24 °C / 22 % RH (Prusa)[4][5][2]0.37 in 24 h and 1.1 at saturation on extruded stock (ASTM D570)[27]
Drying temperature & time80 °C for 8 h (Bambu Lab); 70 °C for 7 h (Polymaker)[4][5]Not documented
Symptoms when wetBubbling and popping at the nozzle, stringing, rough surface and weak layers[28]Not documented
Effect of moisture on strengthNo dry-versus-conditioned figures are published for ASA; Polymaker groups the styrenics as moderate-sensitivity and the loss shows as poor layer adhesion rather than a stated strength delta[28]No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[26]
Storage requirementSealed with desiccant; Polymaker rates the styrenics moderate-sensitivity[28]Not documented
Mechanical Properties
Tensile strength (XY)MPa37 ± 3 (Bambu Lab) to 43.8 (PolyLite) printed XY, ISO 527; Prusament 42 ± 1 at yield; Formfutura quotes 47.5 at yield[4][5][2][29]55 (printed XY, ISO 527, 3DXTech) and 55 (printed on side long edge, ASTM D638, Stratasys PPSF); 79 at yield on extruded stock[3][6][27]
Young's modulusMPa2379 (PolyLite) to 2450 (Bambu Lab) printed XY, ISO 527; Prusament 1600, Formfutura 2020[4][5][2][29]2100 (printed, ASTM D638, Stratasys PPSF) and 2310 (printed XY, ISO 527, 3DXTech); 2344 on extruded stock[3][6][27]
Elongation at break%6.7 (PolyLite) to 9.2 (Bambu Lab) at break, printed XY, ISO 527; Formfutura quotes 15 at break, Prusament 3.4 at yield[4][5][29][2]3 (printed, ISO 527 and ASTM D638) against 60 on extruded stock — printing costs PPSU almost all of its ductility[3][6][27]
Flexural strengthMPa64 ± 1 printed horizontal (Prusament, ISO 178); Bambu Lab 65 ± 5, PolyLite 73.4[2][4][5]110 (printed, ISO 178 and ASTM D790, 3DXTech and Stratasys PPSF agree); 91 on extruded stock[3][6][27]
Flexural modulusMPa1920 ± 130 (Bambu Lab) to 3206 (PolyLite) printed XY, ISO 178; Prusament 2000[4][5][2]2200 (printed, ASTM D790, Stratasys PPSF) and 2215 (printed XY, ISO 178, 3DXTech)[3][6]
Charpy impact, notchedkJ/m²10.3 (PolyLite) to 19.6 (Bambu Lab) printed XY, ISO 179, notched; Prusament 12 ± 1, Formfutura 18[5][4][2][29]Not documented
Other impact dataCharpy unnotched 25 ± 3 printed horizontal and 38 ± 11 printed vertical (Prusament, ISO 179-1); Bambu Lab 41.0 ± 2.3 printed XY[2][4]Izod notched 58.7 J/m and unnotched 165.5 J/m (printed, ASTM D256 Method A, Stratasys PPSF); 160 J/m notched on extruded stock[6][27]
Layer adhesion / Z tensileMPa11 ± 1 (Prusa interlayer adhesion test); 31 ± 4 (Bambu Lab) and 32 (PolyLite) printed Z tensile, ISO 527[2][4][5]Not documented
Brittleness1–5Tough — absorbs impact, yields before breaking[4][2]Brittle — snaps with little warning[3]
Hardness (scale-specific)Shore A / Shore D / Rockwell78 Shore D (Prusa Polymers method)[2]Rockwell M86 on printed PPSF (ASTM D785, Stratasys); M96 on extruded PPSU stock (and an unlabelled 123)[6][27]
Creep resistance / sustained load1–5Moderate — no printed-ASA creep test found; Tg of 98 °C keeps room-temperature service far below softening, unlike PLA[5][2]Good. Printed PPSF holds 189 °C heat deflection at 1.8 MPa (ASTM D648) and extruded stock is rated 149 °C long-term service, but Ensinger does not claim the creep resistance it claims for PSU and PPS[6][27]
Fatigue / repeated-flex resistance1–5Moderate — fatigue limit at 25 % of tensile strength (8 MPa) on printed specimens, the best of the four polymers in that study[30]Not documented
Elasticity / flexibility1–5Rigid[4]Rigid[3]
Z strength as % of XY%84 (Bambu Lab, printed Z against XY tensile); 73 for PolyLite ASA[4][5]Not documented
Thermal Properties
HDT at 0.45 MPa°C93 (Prusament) to 103 (PolyLite), ISO 75 at 0.45 MPa; Bambu Lab 100[2][5][4]190 (printed XY, ISO 75 at 0.45 MPa, 3DXTech)[3]
HDT at 1.8 MPa°C86 (Prusament) to 100 (PolyLite), ISO 75 at 1.8 MPa; Bambu Lab 92[2][5][4]189 (printed, ASTM D648 at 264 psi, Stratasys PPSF); 207 on extruded stock, converted from 405 °F[6][27]
Glass transition (Tg)°C98 (PolyLite, DSC)[5]230 (DSC) — the highest glass transition in the dataset[3]
Melting point / Vicat°CAmorphous — no melting point; Vicat 105 (PolyLite, ISO 306)[5]Not documented
Continuous service temperature°C93 — Prusa publishes this as the temperature resistance of Prusament ASA[31]149 long-term service on extruded PPSU stock, converted from 300 °F[27]
Thermal expansion (CTE)µm/m·K69 ± 17 in XY and 115 ± 24 in the build direction (printed, TMA, 40–70 °C)[32]55.0 (printed PPSF, ASTM D696; source states 5.5e-5 mm/mm/°C) and 55.8 on extruded stock (ASTM D696, from 3.1e-5 in/in/°F)[6][27]
Flammability / UL 94Flammable; no UL 94 rating published for standard ASA[4]UL 94 V-0 at 1.5 mm, rated on the base resin[3]
Environment & Chemical
UV resistance1–5Excellent — designed for permanent outdoor use. After 1000 h of QUV exposure to ASTM G154 Stratasys measured yield strength falling only from 30.5 to 30.3 MPa and stress at break by 3.0 %[19]Not documented
Outdoor durability1000 h QUV per ASTM G154, cycling 8 h at 60 °C and 4 h at 50 °C with condensation: yield 30.5 → 30.3 MPa, stress at break 30.5 → 29.5 MPa, elongation 2.8 → 2.3 %, modulus 1.82 → 1.95 GPa[19]Not documented
Chemical resistanceGood against weak acids, weak alkalis, oils and grease; dissolved by acetone[5]Withstands repeated steam autoclaving, the usual reason to choose PPSU over PSU; Stratasys also lists PPSF as passing 24 h stress-crack exposure to antifreeze, petrol, motor oil, power-steering, transmission and washer fluid at 23 °C and 100 °C[3][6]
Water / humidity resistance in service1–5Good — minor absorption[4]Not documented
Food contactNot food safe[1]Not documented
Biodegradability / compostabilityNot biodegradable[1]Not documented
RecyclabilityNot accepted in household plastic collection[1]Not documented
Electrical & ESD propertiesNot documentedVolume resistivity 5e13 to 1.5e14 ohm-cm and dielectric strength 80-290 V/mil on printed PPSF (ASTM D257, D149)[6]
Health & Safety
Fume toxicity1–5High — hazardous VOC such as styrene; enclosure and filtration needed[33][20]Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[33]
VOC emission rateµg/min12–113 styrene, the range measured across the styrenic filaments tested; ASA itself was not among them[33]Not documented
Ultrafine-particle emission rateparticles/min2 × 10¹⁰ to 9 × 10¹⁰ median for ABS, the closest styrenic tested; ASA itself was not measured[33]Not documented
Hazardous species emittedStyrene. Bambu Lab states ABS and ASA release harmful gases such as styrene at printing temperature, which can be toxic and cause dizziness or nausea. Azimi et al. measured styrene from every styrenic filament tested but did not test ASA itself[20][33]Not documented
Ventilation / filtration requirement1–5Enclosure with carbon and HEPA filtration[33][20]Ventilated room or enclosure recommended[33]
Post-Processing
Sanding & machiningSands well and takes filler before painting[1]Not documented
Gluing & solvent weldingSolvent-welds with acetone[5]Not documented
Vapour / chemical smoothingAcetone vapour smoothing works — ASA dissolves in acetone[5]Not documented
Support material pairingHIPS breaks away or dissolves in d-limonene; Bambu Lab sells a dedicated Support for ABS that also serves ASA[20]Not documented
Dimensional accuracy & detailWarping and cooling-stress cracking are the accuracy limits; Stratasys notes the matte finish as a deliberate aesthetic advantage[20][19]Not documented
Solvents & Solubility
Soluble inAcetone dissolves it (Polymaker); MEK, THF, ethyl acetate and the chlorinated solvents dissolve the styrenic backbone.[34][5]Dichloromethane dissolves it at 23 °C at every stress level; acetone solvates and softens unstressed PPSU (Solvay ESCR).[35]
Softened or crazed byLimonene attacks some grades — Prusa reports Prusament ASA Orange flaking apart as layer adhesion fails.[36]MEK ruptures stressed parts and toluene crazes them above 13.8 MPa; glass-filled grades survive where unfilled craze.[35]
Solvent welding & smoothing agentAcetone vapour, ~20 min at 80 °C over 5 mm of liquid (15–40 min across brands); layer adhesion up, tensile slightly down.[37]Dichloromethane cements PPSU and NMP softens residual resin; both are laboratory reagents, not workshop stock.[35]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. ASA — material basics Polymaker Wiki · 2026-08 · doc
  2. Prusament ASA Technical Datasheet v1.1 Prusa Polymers · 2024-05 · tds
  3. ThermaX PPSU Technical Data Sheet v3 3DXTech · 2026-08 · tds
  4. Bambu Filament Technical Data Sheet V3.0 — ASA Bambu Lab · 2026-08 · tds
  5. PolyLite ASA Technical Data Sheet Polymaker · 2024-11 · tds
  6. PPSF (polyphenylsulfone) — FDM Data Sheet Stratasys · 2018-06 · tds
  7. ASA — product page Bambu Lab US Store · 2026-08 · vendor
  8. Polymaker product catalogue Polymaker · 2026-08 · vendor
  9. Printed Solid product catalogue Printed Solid · 2026-08 · vendor
  10. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  11. Kimya PPSU-S Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  12. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  13. IEMAI 3D PPSU 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  14. Filastruder product catalogue Filastruder · 2026-08 · vendor
  15. ZYLtech ASA-GF Glass Fiber filament — product page ZYLtech · 2026-08 · vendor
  16. IEMAI ASA 3D Printing Filament product page IEMAI 3D · 2026-08 · vendor
  17. SUNLU ASA 3D Printer Filament 1 kg SUNLU · 2026-08 · vendor
  18. YXPOLYER ASA Purple product page YXPOLYER · 2026-08 · vendor
  19. ASA — FDM Material Data Sheet (includes 1000 h QUV exposure results) Stratasys · 2026-08 · tds
  20. ABS / ASA / PC Usage Guide Bambu Lab Wiki · 2026-08 · doc
  21. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  22. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  23. Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
  24. ASA — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  25. Filament Material Guide Prusa Knowledge Base · 2026-08 · doc
  26. THERMAX PPSU — product page (print recommendations) 3DXTech · 2026-08 · doc
  27. TECASON P black (PPSU) — stock shape properties Ensinger · 2026-08 · tds
  28. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  29. ApolloX Technical Data Sheet Formfutura · 2026-08 · tds
  30. Mechanical, Fatigue, and Thermal Characterization of ASA, Nylon 12, PC and PC-ABS Manufactured by Fused Filament Fabrication (FFF) Polymers 18(2):302 · 2026-01 · paper
  31. Prusament ASA — material page Prusa Polymers · 2026-08 · doc
  32. Basalt Fiber Composites with Reduced Thermal Expansion for Additive Manufacturing Polymers 14(15):3216 · 2022-08 · paper
  33. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  34. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  35. Radel PPSU, Veradel PESU, Acudel modified PPSU Design Guide — environmental stress cracking tables Solvay Specialty Polymers · 2026-08 · tds
  36. HIPS — Knowledge Base Prusa Research · 2026-08 · doc
  37. Improve your 3D prints with chemical smoothing Prusa Research · 2026-08 · doc