Filament comparison
PPSU vs TPE SEBS
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | PPSUHIGHTEMP | TPE (SEBS)FLEX |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $337.40/kg median; $223.00–$732.56/kg across 4 dated product listings | $98.25/kg median; $76.50–$120.00/kg across 2 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Polyphenylsulfone — an amorphous high-temperature sulfone polymer[1] | Styrene-ethylene-butadiene-styrene thermoplastic elastomer — a styrenic rubber, not a polyurethane[2] |
| Densityg/cm³ | 1.28 (ISO 1183, 3DXTech; ASTM D792, Stratasys PPSF)[1][3] | 1.044 printed part density (BASF Ultrafuse TPS 90A, ISO 1183-1) — the lightest elastomer here[2] |
| Typical priceUSD/kg | 1 kg-equivalent spools span 223–733; the middle of the market is about 425[4][5][6][7] | 1 kg-equivalent spools cluster near 77[8] |
| Price range across brandsUSD/kg | 223-733 across brands; IEMAI 3D 223 at 1 kg, 3DXTech ThermaX PPSU 250 at 500 g, 3D4Makers 425 at 750 g, Kimya PPSU-S 733 at 500 g[4][5][6][7] | 77 for the Recreus 600 g spool; Proto-pasta only lists a 50 g coil, which prices at 120[8][9] |
| Market availability1–5 | Niche, a handful of specialist brands[4][5][6] | Niche, a handful of specialist brands[2][9][8] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 200 g to 750 g spools[4][5][6] | 1.75 and 2.85 mm; 0.05 and 0.6 kg spools[2][8] |
| Typical applications | Steam-sterilisable medical and dental tooling, and aircraft interior parts[1] | Soft-touch overmoulds and skin-contact parts where a non-polyurethane elastomer is wanted[2] |
| Printing Parameters | ||
| Nozzle temperature°C | Not documented | 260–280 (BASF Ultrafuse TPS 90A) — far hotter than any TPU here[2] |
| Bed temperature°C | 130–150 (3DXTech)[1] | 70–90 (BASF Ultrafuse TPS 90A)[2] |
| Enclosure / chamber requirement1–5 | Actively heated chamber required[10][11] | Open frame is fine[2] |
| Bed surface & adhesion aid | Not documented | PEI sheet or painter's tape; Polymaker warns TPU can over-stick and advises a glue stick as a release agent[12][13] |
| Maximum volumetric flow (mm³/s; see test conditions)mm³/s | Not documented | 0.8–2.4 at the 10–30 mm/s BASF specifies on a 0.4 mm nozzle at 0.2 mm layer — the slowest material in this group[2] |
| Warping tendency1–5 | Severe — heated chamber needed[10] | Not documented |
| Overall printing difficulty1–5 | Expert / industrial hardware only[10][11] | Advanced — enclosure, hardware upgrades, tuning[2] |
| Extruder requirement | Not documented | Nozzle 0.4 mm or larger; BASF caps print speed at 10–30 mm/s[2] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Brass fine indefinitely for unfilled grades, but brass softens near these nozzle temperatures — hardened or plated hot ends are the norm[10] | Brass fine indefinitely[14] |
| Abrasiveness1–5 | Non-abrasive when unfilled[1] | Non-abrasive[14] |
| Nozzle clog risk1–5 | Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[15] | Moderate — needs dry filament and a clean nozzle; BASF caps print speed at 10–30 mm/s and Simplify3D warns that raised feed rates on flexibles most likely end in a jam[12][2] |
| Hotend requirement | Not documented | No special hot-end required, but a direct-drive extruder is (Simplify3D)[12] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Not documented | Negligible (<0.1 % EMC) — BASF states drying is not necessary, unique among the elastomers here[2] |
| Equilibrium moisture content at ~50 % RH% | 0.37 in 24 h and 1.1 at saturation on extruded stock (ASTM D570)[16] | Not documented |
| Drying temperature & time | Not documented | None — BASF states Ultrafuse TPS 90A arrives in a printable condition and drying is not necessary[2] |
| Symptoms when wet | Not documented | Bubbling and popping at the nozzle, stringing and a rough surface[17] |
| Effect of moisture on strength | No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[15] | Not applicable — the SEBS chemistry has no amide or ester linkages to take up water, and BASF specifies no drying at all[2] |
| Storage requirement | Not documented | Sealed with desiccant; often kept in a dryer during the print[17] |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 55 (printed XY, ISO 527, 3DXTech) and 55 (printed on side long edge, ASTM D638, Stratasys PPSF); 79 at yield on extruded stock[1][3][16] | Not documented |
| Young's modulusMPa | 2100 (printed, ASTM D638, Stratasys PPSF) and 2310 (printed XY, ISO 527, 3DXTech); 2344 on extruded stock[1][3][16] | Not documented |
| Elongation at break% | 3 (printed, ISO 527 and ASTM D638) against 60 on extruded stock — printing costs PPSU almost all of its ductility[1][3][16] | Not documented |
| Flexural strengthMPa | 110 (printed, ISO 178 and ASTM D790, 3DXTech and Stratasys PPSF agree); 91 on extruded stock[1][3][16] | Not documented |
| Flexural modulusMPa | 2200 (printed, ASTM D790, Stratasys PPSF) and 2215 (printed XY, ISO 178, 3DXTech)[1][3] | Not documented |
| Other impact data | Izod notched 58.7 J/m and unnotched 165.5 J/m (printed, ASTM D256 Method A, Stratasys PPSF); 160 J/m notched on extruded stock[3][16] | Not documented |
| Brittleness1–5 | Brittle — snaps with little warning[1] | Very ductile — bends far before failing[2] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Rockwell M86 on printed PPSF (ASTM D785, Stratasys); M96 on extruded PPSU stock (and an unlabelled 123)[3][16] | 89 Shore A and 29 Shore D (BASF Ultrafuse TPS 90A, ISO 7619-1)[2] |
| Creep resistance / sustained load1–5 | Good. Printed PPSF holds 189 °C heat deflection at 1.8 MPa (ASTM D648) and extruded stock is rated 149 °C long-term service, but Ensinger does not claim the creep resistance it claims for PSU and PPS[3][16] | Poor — no SEBS creep test; a printed 95A TPU bar crept from 74.5 to 82.7 mm over 5 days at 1.25 kg[18] |
| Fatigue / repeated-flex resistance1–5 | Not documented | Excellent — living hinges viable[13] |
| Elasticity / flexibility1–5 | Rigid[1] | Rubbery / highly elastic[2] |
| Wear resistance & friction | Not documented | Abrasion 111 mm³ (ISO 4649) — the poorest abrasion resistance in this group, well behind TPU[2] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 190 (printed XY, ISO 75 at 0.45 MPa, 3DXTech)[1] | Not documented |
| HDT at 1.8 MPa°C | 189 (printed, ASTM D648 at 264 psi, Stratasys PPSF); 207 on extruded stock, converted from 405 °F[3][16] | Not documented |
| Glass transition (Tg)°C | 230 (DSC) — the highest glass transition in the dataset[1] | Not documented |
| Melting point / Vicat°C | Not documented | 242–249 melting (BASF Ultrafuse TPS 90A, ISO 11357-3)[2] |
| Continuous service temperature°C | 149 long-term service on extruded PPSU stock, converted from 300 °F[16] | Not documented |
| Thermal expansion (CTE)µm/m·K | 55.0 (printed PPSF, ASTM D696; source states 5.5e-5 mm/mm/°C) and 55.8 on extruded stock (ASTM D696, from 3.1e-5 in/in/°F)[3][16] | Not documented |
| Flammability / UL 94 | UL 94 V-0 at 1.5 mm, rated on the base resin[1] | Not documented |
| Environment & Chemical | ||
| UV resistance1–5 | Not documented | Good — years with some colour shift; Polymaker lists UV exposure among the conditions TPU withstands[13] |
| Chemical resistance | Withstands repeated steam autoclaving, the usual reason to choose PPSU over PSU; Stratasys also lists PPSF as passing 24 h stress-crack exposure to antifreeze, petrol, motor oil, power-steering, transmission and washer fluid at 23 °C and 100 °C[1][3] | Withstands industrial solvents and UV exposure (Polymaker)[13] |
| Water / humidity resistance in service1–5 | Not documented | Excellent — essentially unaffected[2] |
| Food contact | Not documented | Not food safe without specific certification (Polymaker)[13] |
| Biodegradability / compostability | Not documented | Not biodegradable[13] |
| Recyclability | Not documented | Not accepted in household plastic collection[13] |
| Electrical & ESD properties | Volume resistivity 5e13 to 1.5e14 ohm-cm and dielectric strength 80-290 V/mil on printed PPSF (ASTM D257, D149)[3] | Not documented |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[19] | Low hazard — minimal VOC and particle emission; TPU was not among the nine filaments in the chamber study[19] |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[19] | Open a window / occasional ventilation[19] |
| Post-Processing | ||
| Sanding & machining | Not documented | Difficult to sand or smooth; Polymaker limits post-processing to trimming or tumbling[13] |
| Gluing & solvent welding | Not documented | Cyanoacrylate bonds TPU; no common solvent welds it[13] |
| Vapour / chemical smoothing | Not documented | No practical vapour smoothing[13] |
| Support material pairing | Not documented | Polymaker warns TPU supports are often very difficult to remove[13] |
| Solvents & Solubility | ||
| Soluble in | Dichloromethane dissolves it at 23 °C at every stress level; acetone solvates and softens unstressed PPSU (Solvay ESCR).[20] | Toluene dissolves SEBS at room temperature — Kraton quotes solution viscosity at 25 % mass in toluene, 25 °C.[21] |
| Softened or crazed by | MEK ruptures stressed parts and toluene crazes them above 13.8 MPa; glass-filled grades survive where unfilled craze.[20] | Soaking in hydrocarbon solvents and oils deteriorates it; short exposures are tolerated. Resists water, acids and bases.[21] |
| Solvent welding & smoothing agent | Dichloromethane cements PPSU and NMP softens residual resin; both are laboratory reagents, not workshop stock.[20] | Toluene will weld it, though the joint stays soft; no workshop-safe agent, and vapour smoothing is not practical.[21] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- ThermaX PPSU Technical Data Sheet v3 3DXTech · 2026-08 · tds
- Ultrafuse TPS 90A Technical Data Sheet (Version 1.1, SEBS) BASF Forward AM · 2020-12 · tds
- PPSF (polyphenylsulfone) — FDM Data Sheet Stratasys · 2018-06 · tds
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- Kimya PPSU-S Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
- 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
- IEMAI 3D PPSU 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- Recreus product catalogue Recreus · 2026-08 · vendor
- Proto-pasta product catalogue Proto-pasta · 2026-08 · vendor
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- Flexible (TPE/TPU) — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- TPU — material basics Polymaker Wiki · 2026-08 · doc
- Extrudr Product Catalogue (DURAPRO PA12 data block) Extrudr · 2025-03 · tds
- THERMAX PPSU — product page (print recommendations) 3DXTech · 2026-08 · doc
- TECASON P black (PPSU) — stock shape properties Ensinger · 2026-08 · tds
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- BambuLab TPU 95A HF vs Qidi TPU 95A HF — results spreadsheet My Tech Fun (Igor Gaspar) · 2024-02 · test
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Radel PPSU, Veradel PESU, Acudel modified PPSU Design Guide — environmental stress cracking tables Solvay Specialty Polymers · 2026-08 · tds
- KRATON polymers Grade Range — chemical resistance and toluene solution data Kraton Corporation · 2025-07 · tds