3D Printing Info

Filament comparison

PPSU vs TPE SEBS

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PPSU vs TPE SEBS — documented properties and sources
PropertyPPSUHIGHTEMPTPE (SEBS)FLEX
Market snapshot
Listing priceUSD/kg; dated snapshots$337.40/kg median; $223.00–$732.56/kg across 4 dated product listings$98.25/kg median; $76.50–$120.00/kg across 2 dated product listings
Identity & Market
Base polymer / chemistryPolyphenylsulfone — an amorphous high-temperature sulfone polymer[1]Styrene-ethylene-butadiene-styrene thermoplastic elastomer — a styrenic rubber, not a polyurethane[2]
Densityg/cm³1.28 (ISO 1183, 3DXTech; ASTM D792, Stratasys PPSF)[1][3]1.044 printed part density (BASF Ultrafuse TPS 90A, ISO 1183-1) — the lightest elastomer here[2]
Typical priceUSD/kg1 kg-equivalent spools span 223–733; the middle of the market is about 425[4][5][6][7]1 kg-equivalent spools cluster near 77[8]
Price range across brandsUSD/kg223-733 across brands; IEMAI 3D 223 at 1 kg, 3DXTech ThermaX PPSU 250 at 500 g, 3D4Makers 425 at 750 g, Kimya PPSU-S 733 at 500 g[4][5][6][7]77 for the Recreus 600 g spool; Proto-pasta only lists a 50 g coil, which prices at 120[8][9]
Market availability1–5Niche, a handful of specialist brands[4][5][6]Niche, a handful of specialist brands[2][9][8]
Spool sizes & diameters1.75 and 2.85 mm; 200 g to 750 g spools[4][5][6]1.75 and 2.85 mm; 0.05 and 0.6 kg spools[2][8]
Typical applicationsSteam-sterilisable medical and dental tooling, and aircraft interior parts[1]Soft-touch overmoulds and skin-contact parts where a non-polyurethane elastomer is wanted[2]
Printing Parameters
Nozzle temperature°CNot documented260–280 (BASF Ultrafuse TPS 90A) — far hotter than any TPU here[2]
Bed temperature°C130–150 (3DXTech)[1]70–90 (BASF Ultrafuse TPS 90A)[2]
Enclosure / chamber requirement1–5Actively heated chamber required[10][11]Open frame is fine[2]
Bed surface & adhesion aidNot documentedPEI sheet or painter's tape; Polymaker warns TPU can over-stick and advises a glue stick as a release agent[12][13]
Maximum volumetric flow (mm³/s; see test conditions)mm³/sNot documented0.8–2.4 at the 10–30 mm/s BASF specifies on a 0.4 mm nozzle at 0.2 mm layer — the slowest material in this group[2]
Warping tendency1–5Severe — heated chamber needed[10]Not documented
Overall printing difficulty1–5Expert / industrial hardware only[10][11]Advanced — enclosure, hardware upgrades, tuning[2]
Extruder requirementNot documentedNozzle 0.4 mm or larger; BASF caps print speed at 10–30 mm/s[2]
Hardware Wear & Reliability
Nozzle hardness required1–4Brass fine indefinitely for unfilled grades, but brass softens near these nozzle temperatures — hardened or plated hot ends are the norm[10]Brass fine indefinitely[14]
Abrasiveness1–5Non-abrasive when unfilled[1]Non-abrasive[14]
Nozzle clog risk1–5Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[15]Moderate — needs dry filament and a clean nozzle; BASF caps print speed at 10–30 mm/s and Simplify3D warns that raised feed rates on flexibles most likely end in a jam[12][2]
Hotend requirementNot documentedNo special hot-end required, but a direct-drive extruder is (Simplify3D)[12]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Not documentedNegligible (<0.1 % EMC) — BASF states drying is not necessary, unique among the elastomers here[2]
Equilibrium moisture content at ~50 % RH%0.37 in 24 h and 1.1 at saturation on extruded stock (ASTM D570)[16]Not documented
Drying temperature & timeNot documentedNone — BASF states Ultrafuse TPS 90A arrives in a printable condition and drying is not necessary[2]
Symptoms when wetNot documentedBubbling and popping at the nozzle, stringing and a rough surface[17]
Effect of moisture on strengthNo dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[15]Not applicable — the SEBS chemistry has no amide or ester linkages to take up water, and BASF specifies no drying at all[2]
Storage requirementNot documentedSealed with desiccant; often kept in a dryer during the print[17]
Mechanical Properties
Tensile strength (XY)MPa55 (printed XY, ISO 527, 3DXTech) and 55 (printed on side long edge, ASTM D638, Stratasys PPSF); 79 at yield on extruded stock[1][3][16]Not documented
Young's modulusMPa2100 (printed, ASTM D638, Stratasys PPSF) and 2310 (printed XY, ISO 527, 3DXTech); 2344 on extruded stock[1][3][16]Not documented
Elongation at break%3 (printed, ISO 527 and ASTM D638) against 60 on extruded stock — printing costs PPSU almost all of its ductility[1][3][16]Not documented
Flexural strengthMPa110 (printed, ISO 178 and ASTM D790, 3DXTech and Stratasys PPSF agree); 91 on extruded stock[1][3][16]Not documented
Flexural modulusMPa2200 (printed, ASTM D790, Stratasys PPSF) and 2215 (printed XY, ISO 178, 3DXTech)[1][3]Not documented
Other impact dataIzod notched 58.7 J/m and unnotched 165.5 J/m (printed, ASTM D256 Method A, Stratasys PPSF); 160 J/m notched on extruded stock[3][16]Not documented
Brittleness1–5Brittle — snaps with little warning[1]Very ductile — bends far before failing[2]
Hardness (scale-specific)Shore A / Shore D / RockwellRockwell M86 on printed PPSF (ASTM D785, Stratasys); M96 on extruded PPSU stock (and an unlabelled 123)[3][16]89 Shore A and 29 Shore D (BASF Ultrafuse TPS 90A, ISO 7619-1)[2]
Creep resistance / sustained load1–5Good. Printed PPSF holds 189 °C heat deflection at 1.8 MPa (ASTM D648) and extruded stock is rated 149 °C long-term service, but Ensinger does not claim the creep resistance it claims for PSU and PPS[3][16]Poor — no SEBS creep test; a printed 95A TPU bar crept from 74.5 to 82.7 mm over 5 days at 1.25 kg[18]
Fatigue / repeated-flex resistance1–5Not documentedExcellent — living hinges viable[13]
Elasticity / flexibility1–5Rigid[1]Rubbery / highly elastic[2]
Wear resistance & frictionNot documentedAbrasion 111 mm³ (ISO 4649) — the poorest abrasion resistance in this group, well behind TPU[2]
Thermal Properties
HDT at 0.45 MPa°C190 (printed XY, ISO 75 at 0.45 MPa, 3DXTech)[1]Not documented
HDT at 1.8 MPa°C189 (printed, ASTM D648 at 264 psi, Stratasys PPSF); 207 on extruded stock, converted from 405 °F[3][16]Not documented
Glass transition (Tg)°C230 (DSC) — the highest glass transition in the dataset[1]Not documented
Melting point / Vicat°CNot documented242–249 melting (BASF Ultrafuse TPS 90A, ISO 11357-3)[2]
Continuous service temperature°C149 long-term service on extruded PPSU stock, converted from 300 °F[16]Not documented
Thermal expansion (CTE)µm/m·K55.0 (printed PPSF, ASTM D696; source states 5.5e-5 mm/mm/°C) and 55.8 on extruded stock (ASTM D696, from 3.1e-5 in/in/°F)[3][16]Not documented
Flammability / UL 94UL 94 V-0 at 1.5 mm, rated on the base resin[1]Not documented
Environment & Chemical
UV resistance1–5Not documentedGood — years with some colour shift; Polymaker lists UV exposure among the conditions TPU withstands[13]
Chemical resistanceWithstands repeated steam autoclaving, the usual reason to choose PPSU over PSU; Stratasys also lists PPSF as passing 24 h stress-crack exposure to antifreeze, petrol, motor oil, power-steering, transmission and washer fluid at 23 °C and 100 °C[1][3]Withstands industrial solvents and UV exposure (Polymaker)[13]
Water / humidity resistance in service1–5Not documentedExcellent — essentially unaffected[2]
Food contactNot documentedNot food safe without specific certification (Polymaker)[13]
Biodegradability / compostabilityNot documentedNot biodegradable[13]
RecyclabilityNot documentedNot accepted in household plastic collection[13]
Electrical & ESD propertiesVolume resistivity 5e13 to 1.5e14 ohm-cm and dielectric strength 80-290 V/mil on printed PPSF (ASTM D257, D149)[3]Not documented
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[19]Low hazard — minimal VOC and particle emission; TPU was not among the nine filaments in the chamber study[19]
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[19]Open a window / occasional ventilation[19]
Post-Processing
Sanding & machiningNot documentedDifficult to sand or smooth; Polymaker limits post-processing to trimming or tumbling[13]
Gluing & solvent weldingNot documentedCyanoacrylate bonds TPU; no common solvent welds it[13]
Vapour / chemical smoothingNot documentedNo practical vapour smoothing[13]
Support material pairingNot documentedPolymaker warns TPU supports are often very difficult to remove[13]
Solvents & Solubility
Soluble inDichloromethane dissolves it at 23 °C at every stress level; acetone solvates and softens unstressed PPSU (Solvay ESCR).[20]Toluene dissolves SEBS at room temperature — Kraton quotes solution viscosity at 25 % mass in toluene, 25 °C.[21]
Softened or crazed byMEK ruptures stressed parts and toluene crazes them above 13.8 MPa; glass-filled grades survive where unfilled craze.[20]Soaking in hydrocarbon solvents and oils deteriorates it; short exposures are tolerated. Resists water, acids and bases.[21]
Solvent welding & smoothing agentDichloromethane cements PPSU and NMP softens residual resin; both are laboratory reagents, not workshop stock.[20]Toluene will weld it, though the joint stays soft; no workshop-safe agent, and vapour smoothing is not practical.[21]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. ThermaX PPSU Technical Data Sheet v3 3DXTech · 2026-08 · tds
  2. Ultrafuse TPS 90A Technical Data Sheet (Version 1.1, SEBS) BASF Forward AM · 2020-12 · tds
  3. PPSF (polyphenylsulfone) — FDM Data Sheet Stratasys · 2018-06 · tds
  4. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  5. Kimya PPSU-S Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  6. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  7. IEMAI 3D PPSU 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  8. Recreus product catalogue Recreus · 2026-08 · vendor
  9. Proto-pasta product catalogue Proto-pasta · 2026-08 · vendor
  10. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  11. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  12. Flexible (TPE/TPU) — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  13. TPU — material basics Polymaker Wiki · 2026-08 · doc
  14. Extrudr Product Catalogue (DURAPRO PA12 data block) Extrudr · 2025-03 · tds
  15. THERMAX PPSU — product page (print recommendations) 3DXTech · 2026-08 · doc
  16. TECASON P black (PPSU) — stock shape properties Ensinger · 2026-08 · tds
  17. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  18. BambuLab TPU 95A HF vs Qidi TPU 95A HF — results spreadsheet My Tech Fun (Igor Gaspar) · 2024-02 · test
  19. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  20. Radel PPSU, Veradel PESU, Acudel modified PPSU Design Guide — environmental stress cracking tables Solvay Specialty Polymers · 2026-08 · tds
  21. KRATON polymers Grade Range — chemical resistance and toluene solution data Kraton Corporation · 2025-07 · tds