3D Printing Info

Filament comparison

PP vs PPSU

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PP vs PPSU — documented properties and sources
PropertyPolypropylene (PP)POLYOLEFINPPSUHIGHTEMP
Market snapshot
Listing priceUSD/kg; dated snapshots$46.56/kg median; $31.99–$53.00/kg across 4 dated product listings$337.40/kg median; $223.00–$732.56/kg across 4 dated product listings
Identity & Market
Base polymer / chemistryPolypropylene — a semi-crystalline polyolefin with no polar groups, so it neither absorbs water nor bonds to most bed surfaces[1][2]Polyphenylsulfone — an amorphous high-temperature sulfone polymer[3]
Densityg/cm³0.91 (Prusa PP composite, ISO 1183) — the lightest common filament[4]1.28 (ISO 1183, 3DXTech; ASTM D792, Stratasys PPSF)[3][5]
Typical priceUSD/kg1 kg-equivalent spools span 27–53; the middle of the market is about 44[6][7][8][9]1 kg-equivalent spools span 223–733; the middle of the market is about 425[10][11][12][13]
Price range across brandsUSD/kg27–53 across brands; Reli3D 32 on Amazon, SUNLU 44 at 0.8 kg, Fiberlogy 49 at 750 g, IEMAI 3D 53, and the 3DJake PP listing spans 27–49[6][14][7][8][9]223-733 across brands; IEMAI 3D 223 at 1 kg, 3DXTech ThermaX PPSU 250 at 500 g, 3D4Makers 425 at 750 g, Kimya PPSU-S 733 at 500 g[10][11][12][13]
Market availability1–5Available from several mainstream brands[14][7][6]Niche, a handful of specialist brands[10][11][12]
Spool sizes & diameters1.75 and 2.85 mm; 0.75 kg spools are common[7]1.75 and 2.85 mm; 200 g to 750 g spools[10][11][12]
Typical applicationsLiving hinges, chemical-resistant containers, automotive clips and packaging prototypes[1]Steam-sterilisable medical and dental tooling, and aircraft interior parts[3]
Printing Parameters
Nozzle temperature°C210–230 (Braskem-type PE/PP window); Formfutura's Centaur PP melts at 205 ± 15 °C[1]Not documented
Bed temperature°CNot documented130–150 (3DXTech)[3]
Enclosure / chamber requirement1–5Enclosure recommended — Simplify3D lists an enclosure as a hardware requirement and Polymaker advises one below 70 °C ambient to stop warping and cracking[15][2]Actively heated chamber required[16][17]
Part cooling fanPart cooling fan required (Simplify3D)[15]Not documented
Bed surface & adhesion aidPacking tape, a polypropylene sheet, or a PP-specific adhesive such as Magigoo PP — ordinary PLA and ABS adhesives do not hold it[15][2]Not documented
Warping tendency1–5High — enclosure needed for reliable large parts; PP's crystallinity drives shrinkage and Prusa recommends a brim on its PP grades[4][18]Severe — heated chamber needed[16]
Bed-adhesion difficulty1–5Very difficult — special plates or slurry required. PP bonds to almost nothing; a polypropylene-specific tape or adhesive is the normal answer[4][2]Not documented
Stringing / oozing tendency1–5Slight — Polymaker advises 1–2 mm retraction at 20–30 mm/s[2]Not documented
Overall printing difficulty1–5Advanced — enclosure, hardware upgrades, tuning; bed adhesion is the whole problem[2][4]Expert / industrial hardware only[16][17]
Hardware Wear & Reliability
Nozzle hardness required1–4Brass fine indefinitely for unfilled grades — Simplify3D states no special hotend is required[15]Brass fine indefinitely for unfilled grades, but brass softens near these nozzle temperatures — hardened or plated hot ends are the norm[16]
Abrasiveness1–5Non-abrasive when unfilled[15]Non-abrasive when unfilled[3]
Nozzle clog risk1–5Low — Simplify3D lists no special hotend requirement for PP and clogging is not among its listed drawbacks[19][15]Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[20]
Heat-creep / jam sensitivity1–5Slightly sensitive[15]Not documented
Hotend requirementNo special hot-end required (Simplify3D)[15]Not documented
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Negligible (<0.1 % EMC) — Prusa measures 0.03 % in 24 h and 0.04 % in 7 days on its PP composite, the lowest figures it publishes for any filament[4]Not documented
Equilibrium moisture content at ~50 % RH%0.03 after 24 h and 0.04 after 7 days at 24 °C / 22 % RH (Prusa Polymers, measured on its PP composite)[4]0.37 in 24 h and 1.1 at saturation on extruded stock (ASTM D570)[21]
Drying temperature & timeNo drying step is published for PP; uptake is below the level that affects printing[4]Not documented
Symptoms when wetBubbling and popping at the nozzle; Polymaker still advises a 70 °C dry for 4–6 h despite the low uptake[2]Not documented
Effect of moisture on strengthNot applicable in practice — with equilibrium uptake at 0.04 %, there is no moisture-driven strength loss to measure. Polymaker's sensitivity tiers put polyolefins below even PLA[4][19]No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[20]
Storage requirementNo special storage needed[4]Not documented
Mechanical Properties
Tensile strength (XY)MPa12 at yield (Formfutura Centaur PP, ASTM D638)[1]55 (printed XY, ISO 527, 3DXTech) and 55 (printed on side long edge, ASTM D638, Stratasys PPSF); 79 at yield on extruded stock[3][5][21]
Young's modulusMPa724 on extruded PP stock (ASTM D638; converted from 105,000 psi)[22]2100 (printed, ASTM D638, Stratasys PPSF) and 2310 (printed XY, ISO 527, 3DXTech); 2344 on extruded stock[3][5][21]
Elongation at break%Above 600 at break (Formfutura Centaur PP, ASTM D638)[1]3 (printed, ISO 527 and ASTM D638) against 60 on extruded stock — printing costs PPSU almost all of its ductility[3][5][21]
Flexural strengthMPa31.0 on extruded PP stock (ASTM D790; converted from 4500 psi)[22]110 (printed, ISO 178 and ASTM D790, 3DXTech and Stratasys PPSF agree); 91 on extruded stock[3][5][21]
Flexural modulusMPa402 flexural modulus (Formfutura Centaur PP, ASTM D790) — an order of magnitude below any rigid filament[1]2200 (printed, ASTM D790, Stratasys PPSF) and 2215 (printed XY, ISO 178, 3DXTech)[3][5]
Other impact dataIzod notched 112 J/m on extruded PP stock, converted from 2.1 ft-lb/in (ASTM D256)[22]Izod notched 58.7 J/m and unnotched 165.5 J/m (printed, ASTM D256 Method A, Stratasys PPSF); 160 J/m notched on extruded stock[5][21]
Brittleness1–5Very ductile — bends far before failing[1]Brittle — snaps with little warning[3]
Hardness (scale-specific)Shore A / Shore D / RockwellRockwell R102 (and M95) on extruded PP stock (ASTM D785)[22]Rockwell M86 on printed PPSF (ASTM D785, Stratasys); M96 on extruded PPSU stock (and an unlabelled 123)[5][21]
Creep resistance / sustained load1–5Below average[1]Good. Printed PPSF holds 189 °C heat deflection at 1.8 MPa (ASTM D648) and extruded stock is rated 149 °C long-term service, but Ensinger does not claim the creep resistance it claims for PSU and PPS[5][21]
Fatigue / repeated-flex resistance1–5Excellent — living hinges viable, the classic polypropylene application[1]Not documented
Elasticity / flexibility1–5Semi-flexible[1]Rigid[3]
Thermal Properties
HDT at 0.45 MPa°C74 on extruded PP stock (ASTM D648 at 66 psi; converted from 165 °F)[22]190 (printed XY, ISO 75 at 0.45 MPa, 3DXTech)[3]
HDT at 1.8 MPa°CNot documented189 (printed, ASTM D648 at 264 psi, Stratasys PPSF); 207 on extruded stock, converted from 405 °F[5][21]
Glass transition (Tg)°CNot documented230 (DSC) — the highest glass transition in the dataset[3]
Melting point / Vicat°C205 ± 15 melting (Formfutura Centaur PP)[1]Not documented
Continuous service temperature°CBounded by a melting point of 205 ± 15 °C and by the 158 °C heat deflection of the carbon-filled grade; no loaded-bar service figure is published for unfilled PP[1][4]149 long-term service on extruded PPSU stock, converted from 300 °F[21]
Thermal expansion (CTE)µm/m·KNot documented55.0 (printed PPSF, ASTM D696; source states 5.5e-5 mm/mm/°C) and 55.8 on extruded stock (ASTM D696, from 3.1e-5 in/in/°F)[5][21]
Flammability / UL 94Flammable; no UL 94 rating published for the grades surveyed[4]UL 94 V-0 at 1.5 mm, rated on the base resin[3]
Environment & Chemical
UV resistance1–5Months outdoors before embrittlement — unstabilised polypropylene chalks under UV[2]Not documented
Chemical resistanceExcellent against acids, alkalis and most solvents — the usual reason to choose PP[2]Withstands repeated steam autoclaving, the usual reason to choose PPSU over PSU; Stratasys also lists PPSF as passing 24 h stress-crack exposure to antifreeze, petrol, motor oil, power-steering, transmission and washer fluid at 23 °C and 100 °C[3][5]
Water / humidity resistance in service1–5Excellent — essentially unaffected[4]Not documented
Food contactPolypropylene is a common food-packaging polymer, but no filament here carries a food-contact certification[2]Not documented
Biodegradability / compostabilityNot biodegradable[2]Not documented
RecyclabilityMechanically recyclable as resin code 5, but printed waste is not accepted in household collection[2]Not documented
Electrical & ESD propertiesNot documentedVolume resistivity 5e13 to 1.5e14 ohm-cm and dielectric strength 80-290 V/mil on printed PPSF (ASTM D257, D149)[5]
Health & Safety
Fume toxicity1–5Low hazard — minimal VOC and particle emission. Inferred: no polyolefin was among the nine filaments in the Azimi chamber study, so this is a family-level judgement rather than a measurement[23]Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[23]
Ventilation / filtration requirement1–5Open a window / occasional ventilation. Inferred — no polyolefin was measured in the chamber study[23]Ventilated room or enclosure recommended[23]
Post-Processing
Sanding & machiningSands poorly — the waxy surface loads abrasive paper[15]Not documented
Painting & finishingPaint and adhesives do not key to untreated PP; flame or plasma treatment is normally needed first[2]Not documented
Gluing & solvent weldingNothing common bonds untreated PP; flame or plasma treatment is needed before adhesives key[2]Not documented
Vapour / chemical smoothingNo practical vapour smoothing[15]Not documented
Support material pairingPrints its own supports; no soluble support is rated for PP[15]Not documented
Dimensional accuracy & detailShrinkage and warping dominate; the low modulus means parts flex rather than hold tolerance[4]Not documented
Solvents & Solubility
Soluble inNone at room temperature; chloroform dissolves it at 60 °C and xylene at about 118 °C — the xylene-solubles route.[24][25]Dichloromethane dissolves it at 23 °C at every stress level; acetone solvates and softens unstressed PPSU (Solvay ESCR).[26]
Softened or crazed byXylene, decalin, CCl4 and chlorobenzene are heavily absorbed at 20 °C; oleum, chlorosulphonic acid and bromine destroy it.[24]MEK ruptures stressed parts and toluene crazes them above 13.8 MPa; glass-filled grades survive where unfilled craze.[26]
Solvent welding & smoothing agentNone — nothing softens PP at room temperature, so joints have to be welded thermally rather than chemically.[24]Dichloromethane cements PPSU and NMP softens residual resin; both are laboratory reagents, not workshop stock.[26]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. Centaur PP Technical Data Sheet Formfutura · 2026-08 · tds
  2. PP — material basics Polymaker Wiki · 2026-08 · doc
  3. ThermaX PPSU Technical Data Sheet v3 3DXTech · 2026-08 · tds
  4. Prusament PP Carbon Fiber Technical Datasheet v1.0 Prusa Polymers · 2024-11 · tds
  5. PPSF (polyphenylsulfone) — FDM Data Sheet Stratasys · 2018-06 · tds
  6. SUNLU product catalogue SUNLU · 2026-08 · vendor
  7. Fiberlogy PP Natural — product page 3DJake International · 2026-08 · vendor
  8. Reli3D Low Warp PP Filament 1.75 mm 1 kg Black — Amazon listing Amazon.com · 2026-08 · vendor
  9. IEMAI 3D PP 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  10. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  11. Kimya PPSU-S Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  12. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  13. IEMAI 3D PPSU 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  14. PP filament listing 3DJake International · 2026-08 · vendor
  15. Polypropylene — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  16. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  17. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  18. Prusament PP Glass Fiber Technical Datasheet v1.0 Prusa Polymers · 2024-11 · tds
  19. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  20. THERMAX PPSU — product page (print recommendations) 3DXTech · 2026-08 · doc
  21. TECASON P black (PPSU) — stock shape properties Ensinger · 2026-08 · tds
  22. TECAFINE PP natural — stock shape properties Ensinger · 2026-08 · tds
  23. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  24. Pro-fax and Moplen polypropylene — Chemical Resistance Guide (20, 60 and 100 °C) LyondellBasell · 2026-08 · tds
  25. US 5,278,282 Polymer recycling by selective dissolution — xylene dissolution temperatures Nauman & Lynch, Rensselaer Polytechnic Institute · 1994-01 · paper
  26. Radel PPSU, Veradel PESU, Acudel modified PPSU Design Guide — environmental stress cracking tables Solvay Specialty Polymers · 2026-08 · tds