Filament comparison
PP vs PPS
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | Polypropylene (PP)POLYOLEFIN | PPSHIGHTEMP |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $46.56/kg median; $31.99–$53.00/kg across 4 dated product listings | $116.97/kg median; $84.00–$200.00/kg across 3 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Polypropylene — a semi-crystalline polyolefin with no polar groups, so it neither absorbs water nor bonds to most bed surfaces[1][2] | Polyphenylene sulfide — a semi-crystalline high-temperature polymer[3][4] |
| Densityg/cm³ | 0.91 (Prusa PP composite, ISO 1183) — the lightest common filament[5] | 1.28 (ISO 1183, 3DXTech) and 1.33 (ISO 1183, Spectrum PPS AM230)[3][6] |
| Typical priceUSD/kg | 1 kg-equivalent spools span 27–53; the middle of the market is about 44[7][8][9][10] | 1 kg-equivalent spools span 84–200; the middle of the market is about 117[11][12][13] |
| Price range across brandsUSD/kg | 27–53 across brands; Reli3D 32 on Amazon, SUNLU 44 at 0.8 kg, Fiberlogy 49 at 750 g, IEMAI 3D 53, and the 3DJake PP listing spans 27–49[7][14][8][9][10] | 84-200 across brands and diameters; IEMAI 3D 84 at 1 kg, Spectrum PPS AM230 117 at 750 g, 3DXTech ThermaX PPS 140 at 2.85 mm and 200 at 1.75 mm[11][12][13] |
| Market availability1–5 | Available from several mainstream brands[14][8][7] | Niche, a handful of specialist brands[11][12] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 0.75 kg spools are common[8] | 1.75 and 2.85 mm; 500 g and 750 g spools[11][12] |
| Typical applications | Living hinges, chemical-resistant containers, automotive clips and packaging prototypes[1] | Chemical-plant and under-bonnet parts needing solvent resistance above 200 °C[4] |
| Printing Parameters | ||
| Nozzle temperature°C | 210–230 (Braskem-type PE/PP window); Formfutura's Centaur PP melts at 205 ± 15 °C[1] | 335-345 (3DXTech printed-specimen conditions); 300-330 (Spectrum)[3][6] |
| Bed temperature°C | Not documented | 110-130 (3DXTech); 100-120 (Spectrum)[3][6] |
| Enclosure / chamber requirement1–5 | Enclosure recommended — Simplify3D lists an enclosure as a hardware requirement and Polymaker advises one below 70 °C ambient to stop warping and cracking[15][2] | Actively heated chamber required[16][17] |
| Recommended chamber temperature°C | Not documented | 60-80 actively heated (Spectrum PPS AM230)[6] |
| Part cooling fan | Part cooling fan required (Simplify3D)[15] | Not documented |
| Bed surface & adhesion aid | Packing tape, a polypropylene sheet, or a PP-specific adhesive such as Magigoo PP — ordinary PLA and ABS adhesives do not hold it[15][2] | Adhesive required — Spectrum specifies Magigoo Pro HT[6] |
| Warping tendency1–5 | High — enclosure needed for reliable large parts; PP's crystallinity drives shrinkage and Prusa recommends a brim on its PP grades[5][18] | Not documented |
| Bed-adhesion difficulty1–5 | Very difficult — special plates or slurry required. PP bonds to almost nothing; a polypropylene-specific tape or adhesive is the normal answer[5][2] | Not documented |
| Stringing / oozing tendency1–5 | Slight — Polymaker advises 1–2 mm retraction at 20–30 mm/s[2] | Not documented |
| Overall printing difficulty1–5 | Advanced — enclosure, hardware upgrades, tuning; bed adhesion is the whole problem[2][5] | Expert / industrial hardware only[16][17] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Brass fine indefinitely for unfilled grades — Simplify3D states no special hotend is required[15] | Brass fine indefinitely for unfilled grades, but brass softens near these nozzle temperatures — hardened or plated hot ends are the norm[16] |
| Abrasiveness1–5 | Non-abrasive when unfilled[15] | Non-abrasive when unfilled[3] |
| Nozzle clog risk1–5 | Low — Simplify3D lists no special hotend requirement for PP and clogging is not among its listed drawbacks[19][15] | Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 110 °C pre-dry before every print[20] |
| Heat-creep / jam sensitivity1–5 | Slightly sensitive[15] | Not documented |
| Hotend requirement | No special hot-end required (Simplify3D)[15] | Not documented |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Negligible (<0.1 % EMC) — Prusa measures 0.03 % in 24 h and 0.04 % in 7 days on its PP composite, the lowest figures it publishes for any filament[5] | Negligible (<0.1 % EMC) — Polymaker states minimal water absorption at 0.05 %[4] |
| Equilibrium moisture content at ~50 % RH% | 0.03 after 24 h and 0.04 after 7 days at 24 °C / 22 % RH (Prusa Polymers, measured on its PP composite)[5] | 0.01 in 24 h on extruded stock (ASTM D570) — effectively non-absorbing[21] |
| Drying temperature & time | No drying step is published for PP; uptake is below the level that affects printing[5] | At least 3 h at 90 °C in hot dry air if the filament has taken up moisture (Spectrum)[6] |
| Symptoms when wet | Bubbling and popping at the nozzle; Polymaker still advises a 70 °C dry for 4–6 h despite the low uptake[2] | Not documented |
| Effect of moisture on strength | Not applicable in practice — with equilibrium uptake at 0.04 %, there is no moisture-driven strength loss to measure. Polymaker's sensitivity tiers put polyolefins below even PLA[5][19] | Little to measure — equilibrium uptake is 0.05 %; 3DXTech still specifies a 110 °C, 4 h pre-dry before printing[4][20] |
| Storage requirement | No special storage needed[5] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 12 at yield (Formfutura Centaur PP, ASTM D638)[1] | 50 at break (printed XY, ISO 527, 3DXTech); 65 at break injection-moulded (ISO 527, Spectrum); 94 at yield on extruded stock (ASTM D638)[3][6][21] |
| Young's modulusMPa | 724 on extruded PP stock (ASTM D638; converted from 105,000 psi)[22] | 2650 (printed XY, ISO 527, 3DXTech); 3650 injection-moulded (ISO 527, Spectrum); 5769 on extruded stock (ASTM D638)[3][6][21] |
| Elongation at break% | Above 600 at break (Formfutura Centaur PP, ASTM D638)[1] | 18 at break (printed XY, ISO 527, 3DXTech) against 2.0 injection-moulded (Spectrum) and 2.5 on extruded stock — the suppliers disagree by nearly an order of magnitude[3][6][21] |
| Flexural strengthMPa | 31.0 on extruded PP stock (ASTM D790; converted from 4500 psi)[22] | 52 (printed XY, ISO 178, 3DXTech); 141 on extruded stock (ASTM D790)[3][21] |
| Flexural modulusMPa | 402 flexural modulus (Formfutura Centaur PP, ASTM D790) — an order of magnitude below any rigid filament[1] | 2540 (printed XY, ISO 178)[3] |
| Charpy impact, notchedkJ/m² | Not documented | 1.3 notched injection-moulded (ISO 179-1eA, Spectrum); unnotched 18[6] |
| Other impact data | Izod notched 112 J/m on extruded PP stock, converted from 2.1 ft-lb/in (ASTM D256)[22] | Izod notched 33 J/m on extruded PPS stock, converted from 0.62 ft-lb/in (ASTM D256)[21] |
| Brittleness1–5 | Very ductile — bends far before failing[1] | Moderate[3] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Rockwell R102 (and M95) on extruded PP stock (ASTM D785)[22] | Rockwell 105 (and R124) on extruded PPS stock (ASTM D785)[21] |
| Creep resistance / sustained load1–5 | Below average[1] | Excellent — holds load for years. Ensinger lists high creep resistance as a headline property of extruded PPS stock, and Spectrum states that rigidity, strength and creep resistance are unchanged under continuous load at high temperature[21][6] |
| Fatigue / repeated-flex resistance1–5 | Excellent — living hinges viable, the classic polypropylene application[1] | Not documented |
| Elasticity / flexibility1–5 | Semi-flexible[1] | Rigid[3] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 74 on extruded PP stock (ASTM D648 at 66 psi; converted from 165 °F)[22] | 90 (printed XY, ISO 75 at 0.45 MPa, 3DXTech); 129 injection-moulded (ISO 75, Spectrum); 204 on extruded stock (ASTM D648 at 66 psi)[3][6][21] |
| HDT at 1.8 MPa°C | Not documented | 107 injection-moulded (ISO 75 at 1.81 MPa, Spectrum); 104 on extruded stock (ASTM D648 at 264 psi)[6][21] |
| Melting point / Vicat°C | 205 ± 15 melting (Formfutura Centaur PP)[1] | 283 melting (ISO 11357, 3DXTech) and 280 on extruded stock; Vicat softening 236 at 50 N injection-moulded (ISO 306, Spectrum)[3][6][21] |
| Continuous service temperature°C | Bounded by a melting point of 205 ± 15 °C and by the 158 °C heat deflection of the carbon-filled grade; no loaded-bar service figure is published for unfilled PP[1][5] | 170 long-term service on extruded PPS stock, converted from 338 °F[21] |
| Thermal expansion (CTE)µm/m·K | Not documented | 59.4 (extruded PPS stock, 22-60 °C, ASTM D696; source states 3.3e-5 in/in/°F)[21] |
| Flammability / UL 94 | Flammable; no UL 94 rating published for the grades surveyed[5] | UL 94 V-0 at 1.5 mm, rated on the base resin[3] |
| Environment & Chemical | ||
| UV resistance1–5 | Months outdoors before embrittlement — unstabilised polypropylene chalks under UV[2] | Not documented |
| Chemical resistance | Excellent against acids, alkalis and most solvents — the usual reason to choose PP[2] | Outstanding — PPS resists essentially all solvents below 200 °C[4] |
| Water / humidity resistance in service1–5 | Excellent — essentially unaffected[5] | Excellent — essentially unaffected; extruded stock takes up 0.01 % water in 24 h[21] |
| Food contact | Polypropylene is a common food-packaging polymer, but no filament here carries a food-contact certification[2] | Not documented |
| Biodegradability / compostability | Not biodegradable[2] | Not documented |
| Recyclability | Mechanically recyclable as resin code 5, but printed waste is not accepted in household collection[2] | Not documented |
| Health & Safety | ||
| Fume toxicity1–5 | Low hazard — minimal VOC and particle emission. Inferred: no polyolefin was among the nine filaments in the Azimi chamber study, so this is a family-level judgement rather than a measurement[23] | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[23] |
| Ventilation / filtration requirement1–5 | Open a window / occasional ventilation. Inferred — no polyolefin was measured in the chamber study[23] | Ventilated room or enclosure recommended[23] |
| Post-Processing | ||
| Sanding & machining | Sands poorly — the waxy surface loads abrasive paper[15] | Not documented |
| Painting & finishing | Paint and adhesives do not key to untreated PP; flame or plasma treatment is normally needed first[2] | Not documented |
| Gluing & solvent welding | Nothing common bonds untreated PP; flame or plasma treatment is needed before adhesives key[2] | Not documented |
| Vapour / chemical smoothing | No practical vapour smoothing[15] | Not documented |
| Support material pairing | Prints its own supports; no soluble support is rated for PP[15] | Not documented |
| Dimensional accuracy & detail | Shrinkage and warping dominate; the low modulus means parts flex rather than hold tolerance[5] | Not documented |
| Solvents & Solubility | ||
| Soluble in | None at room temperature; chloroform dissolves it at 60 °C and xylene at about 118 °C — the xylene-solubles route.[24][25] | None — PPS does not dissolve in any known solvent below 200 °C.[26][27] |
| Softened or crazed by | Xylene, decalin, CCl4 and chlorobenzene are heavily absorbed at 20 °C; oleum, chlorosulphonic acid and bromine destroy it.[24] | Nothing at 23 °C; Ensinger rates it only conditionally resistant to benzene, dichloromethane, toluene and pyridine.[27] |
| Solvent welding & smoothing agent | None — nothing softens PP at room temperature, so joints have to be welded thermally rather than chemically.[24] | None — no solvent welds or smooths PPS.[26] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- Centaur PP Technical Data Sheet Formfutura · 2026-08 · tds
- PP — material basics Polymaker Wiki · 2026-08 · doc
- ThermaX PPS Technical Data Sheet v3 3DXTech · 2026-08 · tds
- PPS — material basics Polymaker Wiki · 2026-08 · doc
- Prusament PP Carbon Fiber Technical Datasheet v1.0 Prusa Polymers · 2024-11 · tds
- Spectrum PPS AM230 Technical Data Sheet Spectrum Filaments · 2022-04 · tds
- SUNLU product catalogue SUNLU · 2026-08 · vendor
- Fiberlogy PP Natural — product page 3DJake International · 2026-08 · vendor
- Reli3D Low Warp PP Filament 1.75 mm 1 kg Black — Amazon listing Amazon.com · 2026-08 · vendor
- IEMAI 3D PP 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- Spectrum PPS AM230 Natural, 1.75 mm / 750 g 3DJAKE · 2026-08 · vendor
- IEMAI 3D PPS 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- PP filament listing 3DJake International · 2026-08 · vendor
- Polypropylene — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- Prusament PP Glass Fiber Technical Datasheet v1.0 Prusa Polymers · 2024-11 · tds
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- THERMAX PPS — product page (print recommendations) 3DXTech · 2026-08 · doc
- TECATRON natural (PPS) — stock shape properties Ensinger · 2026-08 · tds
- TECAFINE PP natural — stock shape properties Ensinger · 2026-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Pro-fax and Moplen polypropylene — Chemical Resistance Guide (20, 60 and 100 °C) LyondellBasell · 2026-08 · tds
- US 5,278,282 Polymer recycling by selective dissolution — xylene dissolution temperatures Nauman & Lynch, Rensselaer Polytechnic Institute · 1994-01 · paper
- PPS (Polyphenylene sulfide) — Knowledge Base Prusa Research · 2026-08 · doc
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds