3D Printing Info

Filament comparison

PLA+ vs PVDF

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PLA+ vs PVDF — documented properties and sources
PropertyPLA+ / Tough PLAPLAPVDFENGINEERING
Market snapshot
Listing priceUSD/kg; dated snapshots$16.49/kg median; $10.45–$39.99/kg across 10 dated product listings$250.67/kg median; $250.67–$250.67/kg across 1 dated product listings
Identity & Market
Base polymer / chemistryPLA compounded with impact modifiers; suppliers publish the base as polylactic acid only[1][2]Polyvinylidene fluoride — a semi-crystalline fluoropolymer[3][4]
Densityg/cm³1.17–1.24 (Polymaker); 1.21 (Bambu Lab, ISO 1183)[1][2]1.71 (ISO 1183) — the densest unfilled filament in the dataset[3]
Typical priceUSD/kgMainstream 1 kg spools cluster near 16[5][6]1 kg-equivalent spools cluster near 251[7]
Price range across brandsUSD/kg10–40 across brands; budget house brands 10–17, Sakata 3D HR-870 26, Polymaker and Fiberlogy 36–40[8][6][9][10][11]251 at 3DXTech's 750 g pricing — the most expensive material in the whole dataset[7]
Market availability1–5Stocked by most mainstream brands[8][5][6][9][10]Special order, 1–2 makers worldwide[7][12]
Spool sizes & diameters1.75 and 2.85 mm; 0.75, 0.85, 1 and 1.1 kg spools[9][10][8]1.75 and 2.85 mm; 750 g spools[7]
Typical applicationsFunctional parts and enclosures that need impact tolerance but not heat resistance[1][2]Chemical-plant fittings, semiconductor handling and parts needing outstanding UV and chemical resistance[3]
Diameter tolerance± mm±0.03 (Bambu Lab)[13]Not documented
Printing Parameters
Nozzle temperature°C190–230 (Polymaker); Bambu Lab Tough+ needs 220–250[1][2]Not documented
Bed temperature°C25–60 (Polymaker); 35–65 (Bambu Lab Tough+)[1][2]70–110 (3DXTech FluorX)[3]
Enclosure / chamber requirement1–5Open frame is fine[1][2]Enclosure required (passive)[3]
Part cooling fanFan on[1][2]Not documented
Bed surface & adhesion aidTextured or smooth PEI; Bambu Lab recommends glue stick or liquid glue for Tough+[1][2]Not documented
Warping tendency1–5None[1]High — enclosure needed for reliable large parts[3]
Bed-adhesion difficulty1–5Sticks to anything[14]Not documented
Stringing / oozing tendency1–5Slight — 1–3 mm retraction handles it[1][14]Not documented
Overall printing difficulty1–5Easy — minor profile tuning; Tough+ wants a hotter nozzle than plain PLA[1][2]Expert / industrial hardware only[3][4]
Hardware Wear & Reliability
Nozzle hardness required1–4Brass fine indefinitely[15]Brass fine indefinitely for unfilled grades[3]
Abrasiveness1–5Non-abrasive[16][15]Non-abrasive when unfilled[3]
Nozzle clog risk1–5Very low[15]Low — 3DXTech lists no special nozzle concerns, no minimum layer height and states drying is not required[12]
Heat-creep / jam sensitivity1–5Moderate — good heatbreak cooling needed; softens below 60 °C like plain PLA[17]Not documented
Hotend requirementNo special hot-end required[14]Not documented
Other hardware wearNot documentedHydrogen fluoride released on overheating is extremely corrosive and will attack hotend and enclosure metalwork as well as people[4]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Low — 0.27 % saturated at 25 °C / 55 % RH[2]Negligible (<0.1 % EMC) — fluoropolymers are essentially non-hygroscopic[3]
Equilibrium moisture content at ~50 % RH%0.27 saturated at 25 °C / 55 % RH (Bambu Lab Tough+)[2]Not documented
Drying temperature & time55 °C for 6–8 h; 65–75 °C for 12 h on a Bambu Lab X1 heatbed[1][2]Not documented
Symptoms when wetBubbling and popping at the nozzle, stringing, rough surface and weak layers[18]Not documented
Effect of moisture on strengthPolymaker rates PLA low-sensitivity and publishes no dry-versus-conditioned figures for the modified grades; the loss shows as poor layer adhesion rather than a strength number[18]Not applicable in practice — 3DXTech states drying is not required for PVDF, so there is no moisture-driven strength loss to measure[12]
Storage requirementSealed with desiccant below 20 % RH; shelf life at ambient is long[2][14]Not documented
Mechanical Properties
Tensile strength (XY)MPa35–43 (printed XY, ISO 527); 53 on My Tech Fun 4×4 mm bars for Bambu Lab Tough[1][2][19][20]51 at break (printed XY, ISO 527)[3]
Young's modulusMPa1860–2150 (printed XY, ISO 527) — below plain PLA at 2300–3427[1][2][21][22]2450 (printed XY, ISO 527)[3]
Elongation at break%5.1–5.7 (printed XY, ISO 527)[1][2]25 at break (printed XY, ISO 527)[3]
Flexural strengthMPa62–65 (printed XY, ISO 178) — below plain PLA at 76–87[1][2][23][22]50 (printed XY, ISO 178)[3]
Flexural modulusMPa2140–2393 (printed XY, ISO 178)[1][2]1800 (printed XY, ISO 178)[3]
Charpy impact, notchedkJ/m²38.9–72.3 (printed XY, ISO 179, notched) — 5–9× plain PLA[1][2]Not documented
Other impact dataCharpy unnotched 80.6 printed XY (Bambu Lab Tough+); CNC Kitchen measured ~20 vs 5 kJ/m² for PolyLite PLA[2][19]Izod 133 J/m on extruded PVDF stock, converted from 2.49 ft-lb/in (ASTM D256)[24]
Layer adhesion / Z tensileMPa20.9–32.4 printed Z (ISO 527); 33.0 on My Tech Fun layer-adhesion bars vs 27.6 for PLA Basic[1][2][20]Not documented
Brittleness1–5Tough — absorbs impact, yields before breaking[1][2][19]Tough — absorbs impact, yields before breaking[3]
Hardness (scale-specific)Shore A / Shore D / Rockwell78.8 Shore D measured on printed bars (My Tech Fun), against 75.3 for the same maker's plain PLA[25]Rockwell M79 on extruded PVDF stock (ASTM D785)[24]
Creep resistance / sustained load1–5Poor — 12 mm bar sagged to 20.2 mm over 5 days at 1.25 kg, the same as plain PLA[20][26]Not documented
Fatigue / repeated-flex resistance1–5Below average — impact modifiers raise absorbed energy 5–9×; plain PLA ran 38 000–49 000 cycles at 30 % of tensile strength[27][2][19]Not documented
Elasticity / flexibility1–5Rigid[1]Slightly flexible in thin sections[3]
Z strength as % of XY%60 (Bambu Lab Tough+) to 78 (PolyMax PLA), printed[1][2]Not documented
Thermal Properties
HDT at 0.45 MPa°C55 (PolyMax) to 61 (Tough+), ISO 75 at 0.45 MPa[1][2]149 on extruded PVDF stock (ASTM D648 at 66 psi; converted from 300 °F)[24]
HDT at 1.8 MPa°C52 (PolyMax) to 58 (Tough+), ISO 75 at 1.8 MPa[1][2]113 on extruded PVDF stock (ASTM D648 at 264 psi; converted from 235 °F)[24]
Glass transition (Tg)°C61 (DSC)[1][2]Not documented
Melting point / Vicat°C149–151 peak melt (DSC); Vicat 62 (ISO 306)[1][2]170 melting (ISO 11357)[3]
Continuous service temperature°C48–57 — loaded bars begin to move at this temperature: 48 for Polymaker PLA Pro, 50 for Sunlu PLA+, 52 for Bambu Lab Tough, 57 for PolyTerra PLA+[20][28][25][26]149 long term and short term on extruded PVDF stock (converted from 300 °F)[24]
Thermal expansion (CTE)µm/m·K96–99 for plain printed PLA (fibre Bragg grating, 25–50 °C); no grade-specific measurement published[29]127.8 (extruded PVDF stock, ASTM D696; source states 7.1e-5 in/in/°F) — the highest thermal expansion of any engineering polymer in this dataset[24]
Flammability / UL 94Flammable; no UL 94 rating published by the major brands[2][1]UL 94 V-0 on extruded PVDF stock; Ensinger lists inherent flame resistance[24]
Environment & Chemical
UV resistance1–5Degrades within weeks outdoors[17][30]Excellent — designed for permanent outdoor use; Ensinger lists good UV and weather resistance and high gamma radiation resistance for PVDF stock[3][24]
Chemical resistanceGood against weak acids, oils and grease; poor against strong acids and alkalis[1][2]Outstanding — resistant to most acids, solvents and oxidising agents, which is the reason to use it[3]
Water / humidity resistance in service1–5Not documentedExcellent — essentially unaffected[3]
Food contactBase resin is food-contact grade, but printed layer grooves harbour bacteria; Prusa advises against food use[17]Not documented
Biodegradability / compostabilityIndustrially compostable only — needs sustained 55 °C; not home compostable[31][17]Not documented
RecyclabilityMechanically recyclable; not accepted in household plastic collection[31]Not documented
Health & Safety
Fume toxicity1–5Low hazard — minimal VOC and particle emission[32]Very high — toxic decomposition products; local exhaust mandatory. Above 315 °C thermal decomposition yields hydrofluoric acid, hydrogen cyanide and carbon monoxide[4]
Hazardous species emittedNot documentedAbove 315 °C: hydrofluoric acid, hydrogen cyanide, phenols, carbon monoxide, carbon dioxide and dense smoke. HF is extremely corrosive, its skin burns may not be immediately visible or painful, and exposure can be fatal by skin absorption, inhalation or ingestion[4]
Ventilation / filtration requirement1–5None needed in a normal room[32]Local exhaust to outside / fume hood — the SDS states local exhaust is preferred[4]
Dust & fibre handling hazardNot documentedMolten polymer causes thermal burns and must not be pulled off the skin. If HF is detected during a decomposition event, cut the heat but keep the extraction running, ventilate, and clear non-essential people from the area[4]
Post-Processing
Sanding & machiningWet sanding — dry sanding heats the surface by friction and smears it[30][17]Not documented
Gluing & solvent weldingCyanoacrylate for most joints; some grades partially dissolve and bond with acetone[17][33]Not documented
Vapour / chemical smoothingNo practical vapour smoothing — only chloroform, hot benzene or THF, which are laboratory-only[17]Not documented
Support material pairingPolySupport and PolyDissolve S1 (Polymaker); Support for PLA (Bambu Lab)[1][2]Not documented
Dimensional accuracy & detail55° overhangs and 30 mm bridges (Bambu Lab Tough+)[2]The processing window sits well below the 315 °C decomposition threshold, so nozzle temperature must be controlled rather than raised to chase flow[3][4]
Solvents & Solubility
Soluble inChloroform: 10 % w/v in 2–4 h at 23 °C, every grade and morphology; THF and DMF only at 65 °C. Laboratory reagents.[34]THF, MEK, DMF, DMAc, NMP, DMSO and trimethyl phosphate dissolve 5–10 wt% at ambient — Arkema's active solvents, all lab reagents.[35]
Softened or crazed byAcetone, ethyl acetate and toluene plasticise it but dissolve <1 % even at 65 °C; submersion in acetone crazes and destroys parts.[34][36]Acetone, MIBK, cyclohexanone, butyl acetate and glycol ethers swell it; alkalis above pH 12 attack the homopolymer.[35][37]
Solvent welding & smoothing agentChloroform vapour smooths and welds PLA at the cost of tensile strength; acetone does not smooth it at all.[38][36]None for the workshop — the active solvents (NMP, DMAc, DMF) are laboratory reagents used for casting membranes, not joints.[35]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. PolyMax PLA Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
  2. Bambu Filament Technical Data Sheet V3.0 — PLA Tough+ Bambu Lab · 2026-08 · tds
  3. FluorX PVDF Technical Data Sheet v3 3DXTech · 2026-08 · tds
  4. FluorX PVDF Safety Data Sheet v1.1 3DXTech · 2026-08 · msds
  5. eSUN PLA+ 1.75mm 1KG eSUN Official Store · 2026-08 · vendor
  6. Overture PLA+ 1.75mm Overture3D · 2026-08 · vendor
  7. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  8. JAYO PLA+ 1.1KG Reusable Spool 1.75mm JAYO Official Store · 2026-08 · vendor
  9. Polymaker PolyMax PLA 0.75kg Polymaker Shop · 2026-08 · vendor
  10. Fiberlogy Impact PLA 850g 3DJake International · 2026-08 · vendor
  11. PLA HR-870 NATURAL Sakata 3D Filaments · 2026-08 · vendor
  12. FluorX PVDF — product page 3DXTech · 2026-08 · vendor
  13. PLA Basic — product page Bambu Lab US Store · 2026-08 · vendor
  14. PLA — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  15. Filament Material Guide Prusa Knowledge Base · 2026-08 · doc
  16. Prusament PLA — material page Prusa Polymers · 2026-08 · doc
  17. PLA — material guide Prusa Knowledge Base · 2026-08 · doc
  18. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  19. The difference of PLA and PLA+ tested! (feat. Polymaker) CNC Kitchen · 2020-08 · test
  20. BambuLab PLA Basic vs PLA Tough vs PLA-CF — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  21. Prusament PLA Technical Datasheet v1.1 Prusa Polymers · 2022-02 · tds
  22. PolyLite PLA Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
  23. Bambu Filament Technical Data Sheet V3.0 — PLA Basic Bambu Lab · 2026-08 · tds
  24. TECAFLON PVDF natural — stock shape properties Ensinger · 2026-08 · tds
  25. Carbon Fiber PLA vs META-PLA vs PLA+ vs PLA by Sunlu — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  26. PolyTerra PLA vs PLA+ — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  27. Mechanical Properties of Additively Manufactured Polymeric Materials — PLA and PETG — For Biomechanical Applications Polymers 16(13):1868 · 2024-06 · paper
  28. Polymaker PLA Pro vs PLA-CF — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
  29. Characterization of Thermal Expansion Coefficient of 3D Printing Polymeric Materials Using Fiber Bragg Grating Sensors Materials 17(18):4668 · 2024-09 · paper
  30. Prusament PLA Technical Data Sheet v1.0 Prusa Polymers · 2018-09 · tds
  31. Filamentive PLA (recycled) — product page Filamentive · 2026-08 · vendor
  32. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  33. Prusament rPLA Corn Pigment 1kg — product page Prusa Research · 2026-08 · vendor
  34. Solubility Study of Ingeo Biopolymer Grades in Common Organic Solvents (NWPD003) NatureWorks · 2019-10 · tds
  35. Kynar PVDF — Design properties: solubility and irradiation (active and latent solvents) Arkema · 2026-08 · tds
  36. Improve your 3D prints with chemical smoothing Prusa Research · 2026-08 · doc
  37. Kynar PVDF resin — chemical and fuel resistance Arkema · 2026-08 · tds
  38. Effect of vapour smoothing in trichloromethane on 3D printed PLA — surface, mechanical and chemical structure Pitale, Keche & Chopra, Engineering Research Express 6(4) 045579 · 2024-12 · paper