Filament comparison
PLA-PHA vs PPS
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | PLA/PHA blendPLA | PPSHIGHTEMP |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $76.40/kg median; $76.40–$76.40/kg across 1 dated product listings | $116.97/kg median; $84.00–$200.00/kg across 3 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | PLA blended with polyhydroxyalkanoate, a bacterially fermented bio-polyester[1] | Polyphenylene sulfide — a semi-crystalline high-temperature polymer[2][3] |
| Densityg/cm³ | 1.2 (ISO 1183)[1] | 1.28 (ISO 1183, 3DXTech) and 1.33 (ISO 1183, Spectrum PPS AM230)[2][4] |
| Typical priceUSD/kg | Not documented | 1 kg-equivalent spools span 84–200; the middle of the market is about 117[5][6][7] |
| Price range across brandsUSD/kg | Not documented | 84-200 across brands and diameters; IEMAI 3D 84 at 1 kg, Spectrum PPS AM230 117 at 750 g, 3DXTech ThermaX PPS 140 at 2.85 mm and 200 at 1.75 mm[5][6][7] |
| Market availability1–5 | Niche, a handful of specialist brands[1][8] | Niche, a handful of specialist brands[5][6] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 750 g and 2200 g spools[1] | 1.75 and 2.85 mm; 500 g and 750 g spools[5][6] |
| Typical applications | General-purpose printing where PLA's brittleness is the limiting factor[1] | Chemical-plant and under-bonnet parts needing solvent resistance above 200 °C[3] |
| Printing Parameters | ||
| Nozzle temperature°C | 195–220 (colorFabb)[1] | 335-345 (3DXTech printed-specimen conditions); 300-330 (Spectrum)[2][4] |
| Bed temperature°C | 50–60 (colorFabb)[1] | 110-130 (3DXTech); 100-120 (Spectrum)[2][4] |
| Enclosure / chamber requirement1–5 | Open frame is fine[1] | Actively heated chamber required[9][10] |
| Recommended chamber temperature°C | Not documented | 60-80 actively heated (Spectrum PPS AM230)[4] |
| Part cooling fan | 0–100 %; colorFabb states the blend runs on both heated and unheated beds[1][11] | Not documented |
| Bed surface & adhesion aid | Not documented | Adhesive required — Spectrum specifies Magigoo Pro HT[4] |
| Maximum volumetric flow (mm³/s; see test conditions)mm³/s | 3.2–8 at colorFabb's 40–100 mm/s, on a 0.4 mm nozzle at 0.2 mm layer[11][12] | Not documented |
| Overall printing difficulty1–5 | Beginner — prints on any machine out of the box[1] | Expert / industrial hardware only[9][10] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Brass fine indefinitely[1] | Brass fine indefinitely for unfilled grades, but brass softens near these nozzle temperatures — hardened or plated hot ends are the norm[9] |
| Abrasiveness1–5 | Non-abrasive[1] | Non-abrasive when unfilled[2] |
| Nozzle clog risk1–5 | Very low — unfilled PLA blend; Prusa lists no drybox and no hardened nozzle for PLA[13] | Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 110 °C pre-dry before every print[14] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Moderate — the PLA matrix takes up 0.40–0.51 % saturated; colorFabb publishes no figure for the blend[15][16] | Negligible (<0.1 % EMC) — Polymaker states minimal water absorption at 0.05 %[3] |
| Equilibrium moisture content at ~50 % RH% | Not documented | 0.01 in 24 h on extruded stock (ASTM D570) — effectively non-absorbing[17] |
| Drying temperature & time | Not documented | At least 3 h at 90 °C in hot dry air if the filament has taken up moisture (Spectrum)[4] |
| Effect of moisture on strength | Polymaker rates PLA low-sensitivity and publishes no dry-versus-conditioned figures for this grade; absorbed water flashes to steam and shows as bubbling and poor layer adhesion[18] | Little to measure — equilibrium uptake is 0.05 %; 3DXTech still specifies a 110 °C, 4 h pre-dry before printing[3][14] |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 62–64 (ISO 527-1A, colorFabb; two grades quoted)[1] | 50 at break (printed XY, ISO 527, 3DXTech); 65 at break injection-moulded (ISO 527, Spectrum); 94 at yield on extruded stock (ASTM D638)[2][4][17] |
| Young's modulusMPa | 2960–3070 (ISO 527-1A, colorFabb)[1] | 2650 (printed XY, ISO 527, 3DXTech); 3650 injection-moulded (ISO 527, Spectrum); 5769 on extruded stock (ASTM D638)[2][4][17] |
| Elongation at break% | 4 and 11 (ISO 527-1A, colorFabb; two grades quoted)[1] | 18 at break (printed XY, ISO 527, 3DXTech) against 2.0 injection-moulded (Spectrum) and 2.5 on extruded stock — the suppliers disagree by nearly an order of magnitude[2][4][17] |
| Flexural strengthMPa | Not documented | 52 (printed XY, ISO 178, 3DXTech); 141 on extruded stock (ASTM D790)[2][17] |
| Flexural modulusMPa | 2500–3300 flexural modulus (ISO 178, colorFabb)[1] | 2540 (printed XY, ISO 178)[2] |
| Charpy impact, notchedkJ/m² | 2.8–3.7 (ISO 179, notched, colorFabb)[1] | 1.3 notched injection-moulded (ISO 179-1eA, Spectrum); unnotched 18[4] |
| Other impact data | Not documented | Izod notched 33 J/m on extruded PPS stock, converted from 0.62 ft-lb/in (ASTM D256)[17] |
| Brittleness1–5 | Moderate — colorFabb positions the blend as tougher and less brittle than its generic PLA grades[1] | Moderate[2] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Not documented | Rockwell 105 (and R124) on extruded PPS stock (ASTM D785)[17] |
| Creep resistance / sustained load1–5 | Poor — no PLA/PHA creep test; plain printed PLA sagged from 12 to 16.2–21.8 mm over 5 days at 1.25 kg[19][20][21] | Excellent — holds load for years. Ensinger lists high creep resistance as a headline property of extruded PPS stock, and Spectrum states that rigidity, strength and creep resistance are unchanged under continuous load at high temperature[17][4] |
| Fatigue / repeated-flex resistance1–5 | Below average — no S-N curve for the blend; colorFabb positions it as tougher and less brittle than its generic PLA, which ran 38 000–49 000 cycles at 30 % of tensile strength[22][1] | Not documented |
| Elasticity / flexibility1–5 | Rigid[1] | Rigid[2] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | Not documented | 90 (printed XY, ISO 75 at 0.45 MPa, 3DXTech); 129 injection-moulded (ISO 75, Spectrum); 204 on extruded stock (ASTM D648 at 66 psi)[2][4][17] |
| HDT at 1.8 MPa°C | Not documented | 107 injection-moulded (ISO 75 at 1.81 MPa, Spectrum); 104 on extruded stock (ASTM D648 at 264 psi)[4][17] |
| Melting point / Vicat°C | Above 155 melting (ISO 3146-C)[1] | 283 melting (ISO 11357, 3DXTech) and 280 on extruded stock; Vicat softening 236 at 50 N injection-moulded (ISO 306, Spectrum)[2][4][17] |
| Continuous service temperature°C | Not documented | 170 long-term service on extruded PPS stock, converted from 338 °F[17] |
| Thermal expansion (CTE)µm/m·K | Not documented | 59.4 (extruded PPS stock, 22-60 °C, ASTM D696; source states 3.3e-5 in/in/°F)[17] |
| Flammability / UL 94 | Not documented | UL 94 V-0 at 1.5 mm, rated on the base resin[2] |
| Environment & Chemical | ||
| UV resistance1–5 | Degrades within weeks outdoors[23] | Not documented |
| Chemical resistance | Not documented | Outstanding — PPS resists essentially all solvents below 200 °C[3] |
| Water / humidity resistance in service1–5 | Not documented | Excellent — essentially unaffected; extruded stock takes up 0.01 % water in 24 h[17] |
| Biodegradability / compostability | colorFabb states the PHA component is 100 % biodegradable[1] | Not documented |
| Health & Safety | ||
| Fume toxicity1–5 | Low hazard — minimal VOC and particle emission[24] | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[24] |
| Ventilation / filtration requirement1–5 | None needed in a normal room[24] | Ventilated room or enclosure recommended[24] |
| Solvents & Solubility | ||
| Soluble in | Chloroform dissolves the PLA phase (10 % w/v, 2–4 h at 23 °C); THF and DMF need 65 °C. Laboratory reagents.[25] | None — PPS does not dissolve in any known solvent below 200 °C.[26][27] |
| Softened or crazed by | Acetone, ethyl acetate and toluene plasticise it but dissolve <1 % even at 65 °C; submersion in acetone crazes and destroys parts.[25][28] | Nothing at 23 °C; Ensinger rates it only conditionally resistant to benzene, dichloromethane, toluene and pyridine.[27] |
| Solvent welding & smoothing agent | Chloroform vapour smooths and welds PLA at the cost of tensile strength; acetone does not smooth it at all.[29][28] | None — no solvent welds or smooths PPS.[26] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- PLA/PHA technical data sheet colorFabb · 2026-08 · tds
- ThermaX PPS Technical Data Sheet v3 3DXTech · 2026-08 · tds
- PPS — material basics Polymaker Wiki · 2026-08 · doc
- Spectrum PPS AM230 Technical Data Sheet Spectrum Filaments · 2022-04 · tds
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- Spectrum PPS AM230 Natural, 1.75 mm / 750 g 3DJAKE · 2026-08 · vendor
- IEMAI 3D PPS 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- woodFill technical data sheet colorFabb · 2026-08 · tds
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- glowFill technical data sheet colorFabb · 2026-08 · tds
- Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
- Filament Material Guide Prusa Knowledge Base · 2026-08 · doc
- THERMAX PPS — product page (print recommendations) 3DXTech · 2026-08 · doc
- Bambu Filament Technical Data Sheet V3.0 — PLA Basic Bambu Lab · 2026-08 · tds
- PolyLite PLA Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
- TECATRON natural (PPS) — stock shape properties Ensinger · 2026-08 · tds
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- BambuLab PLA Basic vs PLA Tough vs PLA-CF — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
- Polymaker PLA Pro vs PLA-CF — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
- Carbon Fiber PLA vs META-PLA vs PLA+ vs PLA by Sunlu — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
- Mechanical Properties of Additively Manufactured Polymeric Materials — PLA and PETG — For Biomechanical Applications Polymers 16(13):1868 · 2024-06 · paper
- PLA — material guide Prusa Knowledge Base · 2026-08 · doc
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Solubility Study of Ingeo Biopolymer Grades in Common Organic Solvents (NWPD003) NatureWorks · 2019-10 · tds
- PPS (Polyphenylene sulfide) — Knowledge Base Prusa Research · 2026-08 · doc
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
- Improve your 3D prints with chemical smoothing Prusa Research · 2026-08 · doc
- Effect of vapour smoothing in trichloromethane on 3D printed PLA — surface, mechanical and chemical structure Pitale, Keche & Chopra, Engineering Research Express 6(4) 045579 · 2024-12 · paper