3D Printing Info

Filament comparison

PEKK vs Breakaway

Compare printing settings, strength, heat resistance, dated prices and sources.

PEKK guideBreak-away support guide

2 selected · all documented properties

Open these two in the interactive comparisonMore PEKK comparisonsMore Breakaway comparisons
PEKK vs Breakaway — documented properties and sources
PropertyPEKKHIGHTEMPBreak-away supportSUPPORT
Market snapshot
Listing priceUSD/kg; dated snapshots$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings$42.49/kg median; $26.00–$79.98/kg across 4 dated product listings
Identity & Market
Base polymer / chemistryPolyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[1][2]Break-away support compounds matched to a specific model material — Polymaker sells separate grades for PLA and for PA12[3][4]
Densityg/cm³1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[2][1]1.22 (PolySupport for PLA) and 1.29 (PolySupport for PA12), ISO 1183[3][4]
Typical priceUSD/kg1 kg-equivalent spools cluster near 550[5][6][7]1 kg-equivalent spools span 26–80; the middle of the market is about 45[8][9][10]
Price range across brandsUSD/kg333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[5][6][7][11][12]26–80 across brands and grades; IEMAI 3D E-REMOVE 26, Polymaker PolySupport for PLA 40 at 750 g, YXPOLYER 45, PolySupport for PA12 80 at 500 g[8][9][10]
Market availability1–5Niche, a handful of specialist brands[5][6][7]Available from several mainstream brands[8][5]
Spool sizes & diameters1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[5][6][2]1.75 and 2.85 mm; 0.5 and 0.75 kg spools[8]
Typical applicationsAerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[1][2]Support that peels off by hand, avoiding the moisture handling and dissolution time that soluble supports demand[3]
Printing Parameters
Nozzle temperature°CNot documented220–230 (PolySupport for PLA)[3]
Bed temperature°C140 (3DXTech CarbonX PEKK-A CF15)[1]25–60 (PolySupport for PLA)[3]
Enclosure / chamber requirement1–5Actively heated chamber required[13][14]Open frame is fine[3]
Maximum volumetric flow (mm³/s; see test conditions)mm³/sNot documented4–12 at Polymaker's 50–150 mm/s on a 0.4 mm nozzle at 0.2 mm layer[3]
Overall printing difficulty1–5Expert / industrial hardware only[13][14]Easy — minor profile tuning[3]
Extruder requirementNot documentedA second extruder or a tool changer[3]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[1][2]Brass fine indefinitely[3]
Abrasiveness1–5Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[1][2]Non-abrasive[3]
Nozzle clog risk1–5Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[15]Moderate — needs dry filament and a clean nozzle; Polymaker specifies a 55 °C dry for the PLA grade and warns brass nozzle life falls to about 9 h on the PA12 grade[3][4]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Not documentedModerate — 0.64 % equilibrium water absorption (PolySupport for PLA)[3]
Equilibrium moisture content at ~50 % RH%Not documented0.64 equilibrium water absorption (Polymaker PolySupport for PLA)[3]
Effect of moisture on strengthNo dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[15]Not a structural material; no dry-versus-conditioned data is published[16]
Mechanical Properties
Tensile strength (XY)MPa86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]Not documented
Young's modulusMPa2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]Not documented
Elongation at break%6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[2][1]Not documented
Flexural strengthMPa136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]Not documented
Flexural modulusMPa3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]Not documented
Other impact dataIzod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[2]Not documented
Layer adhesion / Z tensileMPa50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[2][17]Not documented
Brittleness1–5Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[2][1]Not documented
Creep resistance / sustained load1–5Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[2]Not documented
Elasticity / flexibility1–5Rigid[1]Not documented
Z strength as % of XY%56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[2][17]Not documented
Thermal Properties
HDT at 0.45 MPa°C158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[2][1]43 (ISO 75, 0.45 MPa, PolySupport for PA12). Polymaker's sheet prints a higher figure at the higher load, which is physically inverted; treat both HDT numbers as approximate[4]
HDT at 1.8 MPa°C156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[2]53 (ISO 75, 1.8 MPa, PolySupport for PA12) — printed above the 0.45 MPa figure on Polymaker's own sheet, which cannot be right; treat both as approximate[4]
Glass transition (Tg)°C156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[2][1]Not documented
Melting point / Vicat°C300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[2][1]Vicat 171 (PolySupport for PA12, ISO 306)[4]
Thermal expansion (CTE)µm/m·K36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[2][17]Not documented
Environment & Chemical
UV resistance1–5Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[2]Not documented
Electrical & ESD propertiesUnfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[2][1][17]Surface resistance above 10^13 ohm/sq (ASTM D257, THERMAX HTS2 and MTS1)[18][19]
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[20]Low hazard — minimal VOC and particle emission; none of these materials was in the chamber study[20]
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[20]Open a window / occasional ventilation[20]
Dust & fibre handling hazardCarbon fibre is bound in the matrix; sanding dust should not be inhaled[1]Not documented
Post-Processing
Support material pairingNot documentedThis is the support material. Polymaker publishes an adhesion matrix per model material, from very good to unusable, because break-away supports only work against the polymer they were matched to[3][4]
Solvents & Solubility
Soluble inConcentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[21][22]None — break-away support is removed mechanically; 3DXTech lists no water or solvent route for it.[23]
Softened or crazed byConcentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[21]Not documented
Solvent welding & smoothing agentNone — no solvent softens a polyaryletherketone.[21]None — there is no solvent to weld or smooth with.[23]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  2. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  3. PolySupport Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
  4. PolySupport for PA12 Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
  5. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  6. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  7. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  8. Polymaker product catalogue Polymaker · 2026-08 · vendor
  9. YXPOLYER Breakaway Support Filament 1 kg Black — product page YXPOLYER · 2026-08 · vendor
  10. IEMAI 3D E-REMOVE breakaway support filament — store page IEMAI 3D · 2026-08 · vendor
  11. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  12. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  13. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  14. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  15. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  16. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  17. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  18. THERMAX HTS2 Break Away Support Technical Data Sheet v1.0 3DXTech · 2026-08 · tds
  19. THERMAX MTS1 Break Away Support Technical Data Sheet v1.0 3DXTech · 2026-08 · tds
  20. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  21. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  22. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
  23. THERMAX HTS1 — product page 3DXTech · 2026-08 · vendor