3D Printing Info

Filament comparison

PEKK vs PVA

Compare printing settings, strength, heat resistance, dated prices and sources.

PEKK guidePVA (soluble support) guide

2 selected · all documented properties

Open these two in the interactive comparisonMore PEKK comparisonsMore PVA comparisons
PEKK vs PVA — documented properties and sources
PropertyPEKKHIGHTEMPPVA (soluble support)SUPPORT
Market snapshot
Listing priceUSD/kg; dated snapshots$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings$65.98/kg median; $42.00–$96.00/kg across 5 dated product listings
Identity & Market
Base polymer / chemistryPolyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[1][2]Polyvinyl alcohol — a water-soluble support polymer[3][4]
Densityg/cm³1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[2][1]0.6–0.9 (3DXTech AquaTek, ISO 1183) and 1.13 (Polymaker PolyDissolve S1)[3][4]
Typical priceUSD/kg1 kg-equivalent spools cluster near 550[5][6][7]1 kg-equivalent spools span 42–96; the middle of the market is about 66[5][8][9][10]
Price range across brandsUSD/kg333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[5][6][7][11][12]42–96 across brands; IEMAI 3D E-WATER 42, YXPOLYER 55, Reli3D 66 at 500 g, Polymaker PolyDissolve S1 67 at 750 g, 3DXTech AquaTek 96 at 750 g in 1.75 mm[5][8][9][13][10]
Market availability1–5Niche, a handful of specialist brands[5][6][7]Stocked by most mainstream brands[5][8][9][13][10]
Spool sizes & diameters1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[5][6][2]1.75 and 2.85 mm; 0.5 and 0.75 kg spools[5][8]
Typical applicationsAerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[1][2]Dissolvable support for PLA, TPU, PVB and PETG — Polymaker names those four for PolyDissolve S1[4]
Printing Parameters
Nozzle temperature°CNot documented215–225 (Polymaker PolyDissolve S1)[4]
Bed temperature°C140 (3DXTech CarbonX PEKK-A CF15)[1]25–60 (Polymaker PolyDissolve S1)[4]
Enclosure / chamber requirement1–5Actively heated chamber required[14][15]Open frame is fine[4]
Part cooling fanNot documentedPart cooling fan required (Simplify3D)[16]
Bed surface & adhesion aidNot documentedPEI sheet or painter's tape[16]
Maximum volumetric flow (mm³/s; see test conditions)mm³/sNot documented4–12 at Polymaker's 50–150 mm/s on a 0.4 mm nozzle at 0.2 mm layer[4]
Bed-adhesion difficulty1–5Not documentedSticks to most surfaces[16]
Stringing / oozing tendency1–5Not documentedModerate — retraction tuning needed[16]
Overall printing difficulty1–5Expert / industrial hardware only[14][15]Intermediate — dry filament and a tuned profile; PVA is unusable once it has taken up moisture[17][4]
Extruder requirementNot documentedA second extruder or a tool changer; PVA is a support material, not a model material[4]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[1][2]Brass fine indefinitely[4]
Abrasiveness1–5Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[1][2]Non-abrasive[4]
Nozzle clog risk1–5Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[18]Very high — frequent jams without careful setup; wet PVA foams and carbonises in the nozzle[17]
Heat-creep / jam sensitivity1–5Not documentedHigh — all-metal hotend and strong cooling needed; Simplify3D warns PVA clogs if the nozzle is left hot while not extruding[16]
Hotend requirementNot documentedNo special hot-end required, but the nozzle must not be parked hot[16]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Not documentedVery high (>2 %) — Polymaker measures 10.21 % equilibrium water absorption, by far the highest in the dataset[4]
Equilibrium moisture content at ~50 % RH%Not documented10.21 equilibrium water absorption (Polymaker PolyDissolve S1)[4]
Symptoms when wetNot documentedBubbling and popping at the nozzle, stringing and a rough surface; with PVA this progresses to clogging[17]
Effect of moisture on strengthNo dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[18]Polymaker groups PVA with nylon as the most moisture-prone class and says it often has to stay in a dryer while printing; there is no published dry-versus-conditioned strength comparison because PVA is not a structural material[17]
Storage requirementNot documentedSealed with desiccant at all times; PVA takes up water faster than any other filament here[17][4]
Mechanical Properties
Tensile strength (XY)MPa86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]Not documented
Young's modulusMPa2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]Not documented
Elongation at break%6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[2][1]Not documented
Flexural strengthMPa136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]Not documented
Flexural modulusMPa3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]Not documented
Other impact dataIzod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[2]Not documented
Layer adhesion / Z tensileMPa50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[2][19]Not documented
Brittleness1–5Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[2][1]Not documented
Creep resistance / sustained load1–5Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[2]Poor — deforms under load at room temperature; PVA is not used structurally[3]
Fatigue / repeated-flex resistance1–5Not documentedPoor — fails after a few cycles[3]
Elasticity / flexibility1–5Rigid[1]Not documented
Z strength as % of XY%56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[2][19]Not documented
Wear resistance & frictionNot documented3DXTech marks tensile strength, modulus and elongation as not applicable for its PVA support grade — it is not characterised as a structural material[3]
Thermal Properties
HDT at 0.45 MPa°C158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[2][1]Not documented
HDT at 1.8 MPa°C156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[2]Not documented
Glass transition (Tg)°C156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[2][1]60 (3DXTech AquaTek, DSC)[3]
Melting point / Vicat°C300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[2][1]Not documented
Continuous service temperature°CNot documentedBounded by a glass transition of 60 °C[3]
Thermal expansion (CTE)µm/m·K36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[2][19]Not documented
Flammability / UL 94Not documentedFlammable; no UL 94 rating published[3]
Environment & Chemical
UV resistance1–5Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[2]Degrades within weeks outdoors, and dissolves in rain long before UV matters[4]
Chemical resistanceNot documentedDissolves in water; unusable in any wet or humid service environment[4][16]
Water / humidity resistance in service1–5Not documentedDissolves or disintegrates — by design[4][3]
Food contactNot documentedNot offered as a food-contact material[3]
Biodegradability / compostabilityNot documentedPVA is water-soluble and biodegrades in wastewater treatment, but Simplify3D notes disposal should follow local guidance[16]
RecyclabilityNot documentedDissolved PVA goes to drain rather than to recycling[16]
Electrical & ESD propertiesUnfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[2][1][19]Surface resistance above 10^13 ohm/sq (ASTM D257, 3DXTech AquaTek PVA)[3]
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[20]Low hazard — minimal VOC and particle emission; none of these materials was in the chamber study[20]
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[20]Open a window / occasional ventilation[20]
Dust & fibre handling hazardCarbon fibre is bound in the matrix; sanding dust should not be inhaled[1]Not documented
Post-Processing
Sanding & machiningNot documentedNot sanded — it is dissolved away rather than finished[16]
Gluing & solvent weldingNot documentedNot applicable — PVA is a sacrificial support[16]
Vapour / chemical smoothingNot documentedWater is the solvent; no vapour smoothing is used[4]
Support material pairingNot documentedThis is the support material; Polymaker pairs PolyDissolve S1 with PLA, TPU, PVB and PETG[4]
Solvents & Solubility
Soluble inConcentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[21][22]Water — tap water works cold, warm moving water is faster; 6–12 h typical, changing the water every few hours.[23][24]
Softened or crazed byConcentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[21]Nothing else: polyvinyl alcohol resists organic solvents, so an IPA or acetone rinse leaves the support intact.[25]
Solvent welding & smoothing agentNone — no solvent softens a polyaryletherketone.[21]None — water dissolves PVA rather than welding it, and no solvent gives it a smoothed surface.[23]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  2. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  3. AquaTek PVA Water Soluble Support Technical Data Sheet v1.0 3DXTech · 2026-08 · tds
  4. PolyDissolve S1 Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
  5. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  6. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  7. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  8. Polymaker product catalogue Polymaker · 2026-08 · vendor
  9. YXPOLYER PVA 1 kg — product page YXPOLYER · 2026-08 · vendor
  10. IEMAI 3D E-WATER water-soluble support filament — store page IEMAI 3D · 2026-08 · vendor
  11. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  12. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  13. Reli3D PVA Filament 1.75 mm 500 g Natural — Amazon listing Amazon.com · 2026-08 · vendor
  14. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  15. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  16. PVA — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  17. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  18. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  19. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  20. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  21. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  22. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
  23. PolyDissolve S1 — Polymaker Wiki Polymaker · 2026-08 · doc
  24. 3DXTech AquaTek PVA product page 3DXTech · 2026-08 · vendor
  25. Polyvinyl alcohol — KURARAY POVAL application guide Kuraray · 2026-08 · tds