3D Printing Info

Filament comparison

PEKK vs PP

Compare printing settings, strength, heat resistance, dated prices and sources.

PEKK guidePolypropylene (PP) guide

2 selected · all documented properties

Open these two in the interactive comparisonMore PEKK comparisonsMore PP comparisons
PEKK vs PP — documented properties and sources
PropertyPEKKHIGHTEMPPolypropylene (PP)POLYOLEFIN
Market snapshot
Listing priceUSD/kg; dated snapshots$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings$46.56/kg median; $31.99–$53.00/kg across 4 dated product listings
Identity & Market
Base polymer / chemistryPolyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[1][2]Polypropylene — a semi-crystalline polyolefin with no polar groups, so it neither absorbs water nor bonds to most bed surfaces[3][4]
Densityg/cm³1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[2][1]0.91 (Prusa PP composite, ISO 1183) — the lightest common filament[5]
Typical priceUSD/kg1 kg-equivalent spools cluster near 550[6][7][8]1 kg-equivalent spools span 27–53; the middle of the market is about 44[9][10][11][12]
Price range across brandsUSD/kg333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[6][7][8][13][14]27–53 across brands; Reli3D 32 on Amazon, SUNLU 44 at 0.8 kg, Fiberlogy 49 at 750 g, IEMAI 3D 53, and the 3DJake PP listing spans 27–49[9][15][10][11][12]
Market availability1–5Niche, a handful of specialist brands[6][7][8]Available from several mainstream brands[15][10][9]
Spool sizes & diameters1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[6][7][2]1.75 and 2.85 mm; 0.75 kg spools are common[10]
Typical applicationsAerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[1][2]Living hinges, chemical-resistant containers, automotive clips and packaging prototypes[3]
Printing Parameters
Nozzle temperature°CNot documented210–230 (Braskem-type PE/PP window); Formfutura's Centaur PP melts at 205 ± 15 °C[3]
Bed temperature°C140 (3DXTech CarbonX PEKK-A CF15)[1]Not documented
Enclosure / chamber requirement1–5Actively heated chamber required[16][17]Enclosure recommended — Simplify3D lists an enclosure as a hardware requirement and Polymaker advises one below 70 °C ambient to stop warping and cracking[18][4]
Part cooling fanNot documentedPart cooling fan required (Simplify3D)[18]
Bed surface & adhesion aidNot documentedPacking tape, a polypropylene sheet, or a PP-specific adhesive such as Magigoo PP — ordinary PLA and ABS adhesives do not hold it[18][4]
Warping tendency1–5Not documentedHigh — enclosure needed for reliable large parts; PP's crystallinity drives shrinkage and Prusa recommends a brim on its PP grades[5][19]
Bed-adhesion difficulty1–5Not documentedVery difficult — special plates or slurry required. PP bonds to almost nothing; a polypropylene-specific tape or adhesive is the normal answer[5][4]
Stringing / oozing tendency1–5Not documentedSlight — Polymaker advises 1–2 mm retraction at 20–30 mm/s[4]
Overall printing difficulty1–5Expert / industrial hardware only[16][17]Advanced — enclosure, hardware upgrades, tuning; bed adhesion is the whole problem[4][5]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[1][2]Brass fine indefinitely for unfilled grades — Simplify3D states no special hotend is required[18]
Abrasiveness1–5Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[1][2]Non-abrasive when unfilled[18]
Nozzle clog risk1–5Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[20]Low — Simplify3D lists no special hotend requirement for PP and clogging is not among its listed drawbacks[21][18]
Heat-creep / jam sensitivity1–5Not documentedSlightly sensitive[18]
Hotend requirementNot documentedNo special hot-end required (Simplify3D)[18]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Not documentedNegligible (<0.1 % EMC) — Prusa measures 0.03 % in 24 h and 0.04 % in 7 days on its PP composite, the lowest figures it publishes for any filament[5]
Equilibrium moisture content at ~50 % RH%Not documented0.03 after 24 h and 0.04 after 7 days at 24 °C / 22 % RH (Prusa Polymers, measured on its PP composite)[5]
Drying temperature & timeNot documentedNo drying step is published for PP; uptake is below the level that affects printing[5]
Symptoms when wetNot documentedBubbling and popping at the nozzle; Polymaker still advises a 70 °C dry for 4–6 h despite the low uptake[4]
Effect of moisture on strengthNo dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[20]Not applicable in practice — with equilibrium uptake at 0.04 %, there is no moisture-driven strength loss to measure. Polymaker's sensitivity tiers put polyolefins below even PLA[5][21]
Storage requirementNot documentedNo special storage needed[5]
Mechanical Properties
Tensile strength (XY)MPa86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]12 at yield (Formfutura Centaur PP, ASTM D638)[3]
Young's modulusMPa2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]724 on extruded PP stock (ASTM D638; converted from 105,000 psi)[22]
Elongation at break%6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[2][1]Above 600 at break (Formfutura Centaur PP, ASTM D638)[3]
Flexural strengthMPa136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]31.0 on extruded PP stock (ASTM D790; converted from 4500 psi)[22]
Flexural modulusMPa3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]402 flexural modulus (Formfutura Centaur PP, ASTM D790) — an order of magnitude below any rigid filament[3]
Other impact dataIzod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[2]Izod notched 112 J/m on extruded PP stock, converted from 2.1 ft-lb/in (ASTM D256)[22]
Layer adhesion / Z tensileMPa50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[2][23]Not documented
Brittleness1–5Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[2][1]Very ductile — bends far before failing[3]
Hardness (scale-specific)Shore A / Shore D / RockwellNot documentedRockwell R102 (and M95) on extruded PP stock (ASTM D785)[22]
Creep resistance / sustained load1–5Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[2]Below average[3]
Fatigue / repeated-flex resistance1–5Not documentedExcellent — living hinges viable, the classic polypropylene application[3]
Elasticity / flexibility1–5Rigid[1]Semi-flexible[3]
Z strength as % of XY%56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[2][23]Not documented
Thermal Properties
HDT at 0.45 MPa°C158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[2][1]74 on extruded PP stock (ASTM D648 at 66 psi; converted from 165 °F)[22]
HDT at 1.8 MPa°C156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[2]Not documented
Glass transition (Tg)°C156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[2][1]Not documented
Melting point / Vicat°C300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[2][1]205 ± 15 melting (Formfutura Centaur PP)[3]
Continuous service temperature°CNot documentedBounded by a melting point of 205 ± 15 °C and by the 158 °C heat deflection of the carbon-filled grade; no loaded-bar service figure is published for unfilled PP[3][5]
Thermal expansion (CTE)µm/m·K36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[2][23]Not documented
Flammability / UL 94Not documentedFlammable; no UL 94 rating published for the grades surveyed[5]
Environment & Chemical
UV resistance1–5Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[2]Months outdoors before embrittlement — unstabilised polypropylene chalks under UV[4]
Chemical resistanceNot documentedExcellent against acids, alkalis and most solvents — the usual reason to choose PP[4]
Water / humidity resistance in service1–5Not documentedExcellent — essentially unaffected[5]
Food contactNot documentedPolypropylene is a common food-packaging polymer, but no filament here carries a food-contact certification[4]
Biodegradability / compostabilityNot documentedNot biodegradable[4]
RecyclabilityNot documentedMechanically recyclable as resin code 5, but printed waste is not accepted in household collection[4]
Electrical & ESD propertiesUnfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[2][1][23]Not documented
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[24]Low hazard — minimal VOC and particle emission. Inferred: no polyolefin was among the nine filaments in the Azimi chamber study, so this is a family-level judgement rather than a measurement[24]
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[24]Open a window / occasional ventilation. Inferred — no polyolefin was measured in the chamber study[24]
Dust & fibre handling hazardCarbon fibre is bound in the matrix; sanding dust should not be inhaled[1]Not documented
Post-Processing
Sanding & machiningNot documentedSands poorly — the waxy surface loads abrasive paper[18]
Painting & finishingNot documentedPaint and adhesives do not key to untreated PP; flame or plasma treatment is normally needed first[4]
Gluing & solvent weldingNot documentedNothing common bonds untreated PP; flame or plasma treatment is needed before adhesives key[4]
Vapour / chemical smoothingNot documentedNo practical vapour smoothing[18]
Support material pairingNot documentedPrints its own supports; no soluble support is rated for PP[18]
Dimensional accuracy & detailNot documentedShrinkage and warping dominate; the low modulus means parts flex rather than hold tolerance[5]
Solvents & Solubility
Soluble inConcentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[25][26]None at room temperature; chloroform dissolves it at 60 °C and xylene at about 118 °C — the xylene-solubles route.[27][28]
Softened or crazed byConcentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[25]Xylene, decalin, CCl4 and chlorobenzene are heavily absorbed at 20 °C; oleum, chlorosulphonic acid and bromine destroy it.[27]
Solvent welding & smoothing agentNone — no solvent softens a polyaryletherketone.[25]None — nothing softens PP at room temperature, so joints have to be welded thermally rather than chemically.[27]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  2. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  3. Centaur PP Technical Data Sheet Formfutura · 2026-08 · tds
  4. PP — material basics Polymaker Wiki · 2026-08 · doc
  5. Prusament PP Carbon Fiber Technical Datasheet v1.0 Prusa Polymers · 2024-11 · tds
  6. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  7. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  8. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  9. SUNLU product catalogue SUNLU · 2026-08 · vendor
  10. Fiberlogy PP Natural — product page 3DJake International · 2026-08 · vendor
  11. Reli3D Low Warp PP Filament 1.75 mm 1 kg Black — Amazon listing Amazon.com · 2026-08 · vendor
  12. IEMAI 3D PP 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  13. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  14. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  15. PP filament listing 3DJake International · 2026-08 · vendor
  16. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  17. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  18. Polypropylene — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  19. Prusament PP Glass Fiber Technical Datasheet v1.0 Prusa Polymers · 2024-11 · tds
  20. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  21. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  22. TECAFINE PP natural — stock shape properties Ensinger · 2026-08 · tds
  23. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  24. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  25. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  26. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
  27. Pro-fax and Moplen polypropylene — Chemical Resistance Guide (20, 60 and 100 °C) LyondellBasell · 2026-08 · tds
  28. US 5,278,282 Polymer recycling by selective dissolution — xylene dissolution temperatures Nauman & Lynch, Rensselaer Polytechnic Institute · 1994-01 · paper