3D Printing Info

Filament comparison

PEKK vs PP-CF

Compare printing settings, strength, heat resistance, dated prices and sources.

PEKK guideCarbon-fibre PP (PP-CF) guide

2 selected · all documented properties

Open these two in the interactive comparisonMore PEKK comparisonsMore PP-CF comparisons
PEKK vs PP-CF — documented properties and sources
PropertyPEKKHIGHTEMPCarbon-fibre PP (PP-CF)POLYOLEFIN
Market snapshot
Listing priceUSD/kg; dated snapshots$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings$107.68/kg median; $57.13–$120.00/kg across 3 dated product listings
Identity & Market
Base polymer / chemistryPolyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[1][2]Polypropylene reinforced with chopped carbon fibre[3][4]
Densityg/cm³1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[2][1]0.91 (Prusament PP Carbon Fiber, ISO 1183)[3]
Typical priceUSD/kg1 kg-equivalent spools cluster near 550[5][6][7]1 kg-equivalent spools span 57–138; the middle of the market is about 108[8][5][9]
Price range across brandsUSD/kg333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[5][6][7][10][11]57–138 across brands; Reli3D 57 at 700 g on Amazon, Prusament 108 direct from Prusa and 138 at Printed Solid, 3DXTech CarbonX PP+CF 120[8][12][5][9]
Market availability1–5Niche, a handful of specialist brands[5][6][7]Available from several mainstream brands[5][12]
Spool sizes & diameters1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[5][6][2]1.75 mm; 0.65 kg spools[12][5]
Typical applicationsAerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[1][2]Lightweight chemical-resistant parts, automotive clips and ducting that must survive above 150 °C[13]
Diameter tolerance± mmNot documented±0.04 (Prusament)[3]
Printing Parameters
Nozzle temperature°CNot documented270 ± 10 (Prusament)[3]
Bed temperature°C140 (3DXTech CarbonX PEKK-A CF15)[1]85 ± 10 (Prusament)[3]
Enclosure / chamber requirement1–5Actively heated chamber required[14][15]Enclosure recommended — Simplify3D lists an enclosure as a hardware requirement and Polymaker advises one below 70 °C ambient to stop warping and cracking[16][17]
Part cooling fanNot documentedOff — Prusa runs 0 % except 100 % on bridges[3]
Maximum volumetric flow (mm³/s; see test conditions)mm³/sNot documented3.2 at Prusa's 40 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[3][18]
Warping tendency1–5Not documentedHigh — enclosure needed for reliable large parts; Prusa recommends a brim[3]
Bed-adhesion difficulty1–5Not documentedVery difficult — special plates or slurry required[3]
Overall printing difficulty1–5Expert / industrial hardware only[14][15]Advanced — enclosure, hardware upgrades, tuning; hardened nozzle mandatory[3]
Extruder requirementNot documentedPrusa states a hardened nozzle is necessary and recommends a brim[3]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[1][2]Hardened steel required — Prusa states plainly that a hardened nozzle is necessary[3]
Abrasiveness1–5Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[1][2]Highly abrasive — standard CF composite[3]
Nozzle clog risk1–5Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[19]Moderate — needs dry filament and a clean nozzle; 3DXTech specifies a hardened 0.4 mm minimum nozzle and 0.25 mm layers or higher, and Prusa lists composites as a higher clogging risk[4][20]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Not documentedNegligible (<0.1 % EMC) — Prusa measures 0.03 % in 24 h and 0.04 % in 7 days on its PP composite, the lowest figures it publishes for any filament[3]
Equilibrium moisture content at ~50 % RH%Not documented0.03 after 24 h and 0.04 after 7 days at 24 °C / 22 % RH (Prusa Polymers)[3]
Effect of moisture on strengthNo dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[19]Not applicable in practice at 0.04 % equilibrium uptake[3]
Storage requirementNot documentedNo special storage needed[3]
Mechanical Properties
Tensile strength (XY)MPa86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]21 ± 0.4 filament tensile yield (Prusament, ISO 527)[3]
Young's modulusMPa2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[2][1]Not documented
Elongation at break%6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[2][1]Not documented
Flexural strengthMPa136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]Not documented
Flexural modulusMPa3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[2][1]Not documented
Charpy impact, notchedkJ/m²Not documented14.5 ± 0.3 printed horizontal and 10.5 ± 0.8 printed vertical XZ (ISO 179-1, notched)[3]
Other impact dataIzod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[2]Not documented
Layer adhesion / Z tensileMPa50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[2][21]Not documented
Brittleness1–5Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[2][1]Tough — absorbs impact, yields before breaking[3]
Hardness (scale-specific)Shore A / Shore D / RockwellNot documentedRockwell R102 (and M95) on extruded unfilled PP stock (ASTM D785); no figure is published for a carbon-fibre PP filament[22]
Creep resistance / sustained load1–5Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[2]Not documented
Fatigue / repeated-flex resistance1–5Not documentedGood[23]
Elasticity / flexibility1–5Rigid[1]Slightly flexible in thin sections[3]
Z strength as % of XY%56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[2][21]Not documented
Thermal Properties
HDT at 0.45 MPa°C158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[2][1]158 (ISO 75, 0.45 MPa) — far above unfilled PP and above most engineering filaments[3]
HDT at 1.8 MPa°C156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[2]115 (ISO 75, 1.8 MPa)[3]
Glass transition (Tg)°C156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[2][1]Not documented
Melting point / Vicat°C300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[2][1]Not documented
Thermal expansion (CTE)µm/m·K36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[2][21]Not documented
Environment & Chemical
UV resistance1–5Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[2]Not documented
Chemical resistanceNot documentedExcellent against acids, alkalis and most solvents[17]
Water / humidity resistance in service1–5Not documentedExcellent — essentially unaffected[3]
Electrical & ESD propertiesUnfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[2][1][21]Not documented
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[24]Low hazard — minimal VOC and particle emission. Inferred: no polyolefin was among the nine filaments in the Azimi chamber study, so this is a family-level judgement rather than a measurement[24]
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[24]Open a window / occasional ventilation. Inferred — no polyolefin was measured in the chamber study[24]
Dust & fibre handling hazardCarbon fibre is bound in the matrix; sanding dust should not be inhaled[1]Carbon fibre is bound in the matrix; sanding dust should not be inhaled[3]
Solvents & Solubility
Soluble inConcentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[25][26]None at room temperature; chloroform dissolves the matrix at 60 °C and xylene at about 118 °C, leaving the fibre.[27][28]
Softened or crazed byConcentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[25]Xylene, decalin, CCl4 and chlorobenzene are heavily absorbed at 20 °C; oleum, chlorosulphonic acid and bromine destroy it.[27]
Solvent welding & smoothing agentNone — no solvent softens a polyaryletherketone.[25]None — nothing softens PP at room temperature, so joints have to be welded thermally rather than chemically.[27]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  2. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  3. Prusament PP Carbon Fiber Technical Datasheet v1.0 Prusa Polymers · 2024-11 · tds
  4. CarbonX PP+CF — product page 3DXTech · 2026-08 · vendor
  5. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  6. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  7. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  8. Prusament PP Carbon Fiber Black 650g — product page Prusa Research · 2026-08 · vendor
  9. Reli3D Carbon Fiber PP Filament 1.75 mm 700 g Black — Amazon listing Amazon.com · 2026-08 · vendor
  10. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  11. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  12. Printed Solid product catalogue Printed Solid · 2026-08 · vendor
  13. Prusament PP Carbon Fiber — material page Prusa Polymers · 2026-08 · doc
  14. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  15. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  16. Polypropylene — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  17. PP — material basics Polymaker Wiki · 2026-08 · doc
  18. Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
  19. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  20. Composite materials filled with carbon, kevlar or glass Prusa Knowledge Base · 2026-08 · doc
  21. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  22. TECAFINE PP natural — stock shape properties Ensinger · 2026-08 · tds
  23. Centaur PP Technical Data Sheet Formfutura · 2026-08 · tds
  24. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  25. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  26. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
  27. Pro-fax and Moplen polypropylene — Chemical Resistance Guide (20, 60 and 100 °C) LyondellBasell · 2026-08 · tds
  28. US 5,278,282 Polymer recycling by selective dissolution — xylene dissolution temperatures Nauman & Lynch, Rensselaer Polytechnic Institute · 1994-01 · paper