Filament comparison
PEI 1010 vs PVDF
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | PEI (ULTEM 1010)HIGHTEMP | PVDFENGINEERING |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $281.22/kg median; $195.00–$698.00/kg across 6 dated product listings | $250.67/kg median; $250.67–$250.67/kg across 1 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Polyetherimide, ULTEM 1010 grade — the higher-temperature, food- and medical-contact PEI[1][2] | Polyvinylidene fluoride — a semi-crystalline fluoropolymer[3][4] |
| Densityg/cm³ | 1.27 (ISO 1183, 3DXTech and Prusament); 1.29 specific gravity on moulded plaques (ASTM D792, Stratasys)[1][2][5] | 1.71 (ISO 1183) — the densest unfilled filament in the dataset[3] |
| Typical priceUSD/kg | 1 kg-equivalent spools span 195–698; the middle of the market is about 270[6][7][8][9][10] | 1 kg-equivalent spools cluster near 251[6] |
| Price range across brandsUSD/kg | 195-698 across brands and grades; 3DXTech ThermaX PEI 1010 195 at 2 kg, IEMAI 3D 223 at 1 kg, 3D4Makers 270 at 2 kg, Prusament 292 at 500 g, Kimya 347 at 500 g, 3DXTech ESD-PEI 1010 698 at 500 g[6][7][8][9][10] | 251 at 3DXTech's 750 g pricing — the most expensive material in the whole dataset[6] |
| Market availability1–5 | Niche, a handful of specialist brands[6][7][8][9] | Special order, 1–2 makers worldwide[6][11] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[6][9][5] | 1.75 and 2.85 mm; 750 g spools[6] |
| Typical applications | Autoclavable tooling, food-contact fixtures and parts that must hold load near 200 °C[2] | Chemical-plant fittings, semiconductor handling and parts needing outstanding UV and chemical resistance[3] |
| Printing Parameters | ||
| Nozzle temperature°C | 410 ± 10 (Prusament) — the hottest nozzle in the dataset[2] | Not documented |
| Bed temperature°C | 140–160 (Prusament); 130–140 (3DXTech)[2][1] | 70–110 (3DXTech FluorX)[3] |
| Enclosure / chamber requirement1–5 | Actively heated chamber required — Prusa specifies 90 °C[2] | Enclosure required (passive)[3] |
| Recommended chamber temperature°C | 90 (Prusament)[2] | Not documented |
| Bed surface & adhesion aid | PA nylon sheet or powder-coated sheet with high-temperature glue (Prusament)[2] | Not documented |
| Warping tendency1–5 | Severe — heated chamber needed[2] | High — enclosure needed for reliable large parts[3] |
| Overall printing difficulty1–5 | Expert / industrial hardware only[2][12] | Expert / industrial hardware only[3][4] |
| Extruder requirement | A hot end rated to 420 °C, a heated chamber and a high-temperature bed; Prusa dries the filament at 150 °C for 6–8 h before printing[2] | Not documented |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Brass fine indefinitely for unfilled grades, but brass softens near these nozzle temperatures — hardened or plated hot ends are the norm[2] | Brass fine indefinitely for unfilled grades[3] |
| Abrasiveness1–5 | Non-abrasive when unfilled[1] | Non-abrasive when unfilled[3] |
| Nozzle clog risk1–5 | Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 150 °C pre-dry before every print[13] | Low — 3DXTech lists no special nozzle concerns, no minimum layer height and states drying is not required[11] |
| Other hardware wear | Not documented | Hydrogen fluoride released on overheating is extremely corrosive and will attack hotend and enclosure metalwork as well as people[4] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Not documented | Negligible (<0.1 % EMC) — fluoropolymers are essentially non-hygroscopic[3] |
| Equilibrium moisture content at ~50 % RH% | 0.4 in 24 h and 0.7 in 7 days at 24 °C and 22 % RH (Prusament)[2] | Not documented |
| Drying temperature & time | 150 °C for 6–8 h (Prusament) — the hottest drying schedule in the dataset[2] | Not documented |
| Effect of moisture on strength | No dry-versus-conditioned figures are published; 3DXTech mandates a 150 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[13] | Not applicable in practice — 3DXTech states drying is not required for PVDF, so there is no moisture-driven strength loss to measure[11] |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 79-95 printed in plane: Stratasys 79.2 (F900 T14) to 91.6 (F3300 N500) at break in XZ, ASTM D638; Prusament 95 +/- 3.5 at yield printed horizontal, ISO 527-1; 3DXTech quotes 56 (ISO 527)[5][2][1] | 51 at break (printed XY, ISO 527)[3] |
| Young's modulusMPa | 2300-3040 printed in plane: Prusament 2300 +/- 100 horizontal (ISO 527-1), Stratasys 2920-3040 in XZ (ASTM D638); 3DXTech quotes 2500[5][2][1] | 2450 (printed XY, ISO 527)[3] |
| Elongation at break% | 4.0-4.1 at break in XZ (ASTM D638, Stratasys); Prusament gives 6.6 +/- 0.7 at yield printed horizontal (ISO 527-1); 3DXTech quotes 3[5][2][1] | 25 at break (printed XY, ISO 527)[3] |
| Flexural strengthMPa | 128 at 5 % strain (F900 T14) and 144 at break (F3300) printed XZ, ASTM D790; Prusament 98 +/- 6.5 horizontal and 138 +/- 5.3 vertical (ISO 178); 3DXTech quotes 110[5][2][1] | 50 (printed XY, ISO 178)[3] |
| Flexural modulusMPa | 2910-3260 printed XZ (ASTM D790, Stratasys); Prusament 2300 horizontal and 2700 vertical (ISO 178); 3DXTech quotes 2510[5][2][1] | 1800 (printed XY, ISO 178)[3] |
| Charpy impact, notchedkJ/m² | 3.4 ± 0.9 printed horizontal and 3.6 ± 0.4 printed vertical, ISO 179-1 notched (Prusament)[2] | Not documented |
| Other impact data | Izod notched 26.6-36.3 J/m XZ against 21.7-27.2 J/m ZX; unnotched 260-406 J/m XZ against 68-116 J/m ZX (printed, ASTM D256/D4812, Stratasys). Charpy unnotched 19.7 +/- 4.3 horizontal and 39 +/- 10 vertical (Prusament, ISO 179-1)[5][2] | Izod 133 J/m on extruded PVDF stock, converted from 2.49 ft-lb/in (ASTM D256)[14] |
| Layer adhesion / Z tensileMPa | 28-37 at break (printed ZX, ASTM D638, Stratasys F900 and F3300) against 72 +/- 5 at yield printed vertical (ISO 527-1, Prusament on the Pro HT90 with a 0.6 mm nozzle and 90 °C chamber) — a fourfold spread driven by chamber temperature and bead size[5][2] | Not documented |
| Brittleness1–5 | Brittle — snaps with little warning; notched Charpy only 3.4 kJ/m²[2] | Tough — absorbs impact, yields before breaking[3] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Shore D 83.5 (Prusa Polymers method); Rockwell M110 / R126 on extruded PEI stock (ASTM D785)[2][15] | Rockwell M79 on extruded PVDF stock (ASTM D785)[14] |
| Creep resistance / sustained load1–5 | Excellent — holds load for years. Printed coupons hold 215 °C heat deflection at 1.8 MPa (ASTM D648) and extruded PEI stock is rated 170 °C long-term service[5][15] | Not documented |
| Elasticity / flexibility1–5 | Rigid[2] | Slightly flexible in thin sections[3] |
| Z strength as % of XY% | 36-40 (Stratasys ZX against XZ tensile at break, ASTM D638) against 76 (Prusament vertical against horizontal tensile yield, ISO 527-1)[5][2] | Not documented |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 207 (Prusament, ISO 75 at 0.45 MPa) to 217 (printed XY 216.9 and XZ 217.1, ASTM D648 Method B at 66 psi, Stratasys); 3DXTech quotes 208[2][5][1] | 149 on extruded PVDF stock (ASTM D648 at 66 psi; converted from 300 °F)[14] |
| HDT at 1.8 MPa°C | 194 (Prusament, ISO 75 at 1.8 MPa) to 215 (printed XY 215.1 and XZ 214.5, ASTM D648 Method B at 264 psi, Stratasys) — the highest heat deflection in the dataset[2][5] | 113 on extruded PVDF stock (ASTM D648 at 264 psi; converted from 235 °F)[14] |
| Glass transition (Tg)°C | 209 (moulded plaque, ASTM D7426 inflection point, Stratasys); 217 (DSC, 3DXTech)[5][1] | Not documented |
| Melting point / Vicat°C | Not documented | 170 melting (ISO 11357)[3] |
| Continuous service temperature°C | 170 long-term service on extruded PEI stock, converted from 338 °F; 200 short term[15] | 149 long term and short term on extruded PVDF stock (converted from 300 °F)[14] |
| Thermal expansion (CTE)µm/m·K | 36.1 (printed XY, -50 to 60 °C, ASTM E831), falling to 29.8 over 60-205 °C; ZX gives 32.5 over -50 to 110 °C and 16.2 over 110-165 °C[5] | 127.8 (extruded PVDF stock, ASTM D696; source states 7.1e-5 in/in/°F) — the highest thermal expansion of any engineering polymer in this dataset[14] |
| Flammability / UL 94 | UL 94 V-0 at 1.5 mm, rated on the base resin[1] | UL 94 V-0 on extruded PVDF stock; Ensinger lists inherent flame resistance[14] |
| Environment & Chemical | ||
| UV resistance1–5 | Not documented | Excellent — designed for permanent outdoor use; Ensinger lists good UV and weather resistance and high gamma radiation resistance for PVDF stock[3][14] |
| Chemical resistance | Not documented | Outstanding — resistant to most acids, solvents and oxidising agents, which is the reason to use it[3] |
| Water / humidity resistance in service1–5 | Not documented | Excellent — essentially unaffected[3] |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[16] | Very high — toxic decomposition products; local exhaust mandatory. Above 315 °C thermal decomposition yields hydrofluoric acid, hydrogen cyanide and carbon monoxide[4] |
| Hazardous species emitted | Not documented | Above 315 °C: hydrofluoric acid, hydrogen cyanide, phenols, carbon monoxide, carbon dioxide and dense smoke. HF is extremely corrosive, its skin burns may not be immediately visible or painful, and exposure can be fatal by skin absorption, inhalation or ingestion[4] |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[16] | Local exhaust to outside / fume hood — the SDS states local exhaust is preferred[4] |
| Dust & fibre handling hazard | Not documented | Molten polymer causes thermal burns and must not be pulled off the skin. If HF is detected during a decomposition event, cut the heat but keep the extraction running, ventilate, and clear non-essential people from the area[4] |
| Post-Processing | ||
| Dimensional accuracy & detail | Not documented | The processing window sits well below the 315 °C decomposition threshold, so nozzle temperature must be controlled rather than raised to chase flow[3][4] |
| Solvents & Solubility | ||
| Soluble in | Chlorinated hydrocarbons — dichloromethane and chloroform — are solvents for polyetherimide. Laboratory reagents.[17][18] | THF, MEK, DMF, DMAc, NMP, DMSO and trimethyl phosphate dissolve 5–10 wt% at ambient — Arkema's active solvents, all lab reagents.[19] |
| Softened or crazed by | Acetone, MEK, benzene, toluene and butyl acetate craze or stress-crack it; alcohols, fuels and dilute acids do not.[18][17] | Acetone, MIBK, cyclohexanone, butyl acetate and glycol ethers swell it; alkalis above pH 12 attack the homopolymer.[19][20] |
| Solvent welding & smoothing agent | Dichloromethane is the only welding route, and it is a controlled carcinogen rather than a workshop material.[17][18] | None for the workshop — the active solvents (NMP, DMAc, DMF) are laboratory reagents used for casting membranes, not joints.[19] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- ThermaX PEI 1010 Technical Data Sheet v4 3DXTech · 2026-08 · tds
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- FluorX PVDF Technical Data Sheet v3 3DXTech · 2026-08 · tds
- FluorX PVDF Safety Data Sheet v1.1 3DXTech · 2026-08 · msds
- ULTEM 1010 Resin — FDM Material Data Sheet Stratasys · 2026-06 · tds
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- Kimya PEI-1010 Amber Yellow 1.75 mm 500 g igo3d · 2026-08 · vendor
- Prusa Prusament PEI 1010 Natural (NFC), 1.75 mm / 500 g 3DJAKE · 2026-08 · vendor
- 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
- IEMAI 3D PEI 1010 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- FluorX PVDF — product page 3DXTech · 2026-08 · vendor
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- THERMAX PEI 1010 — product page (print recommendations) 3DXTech · 2026-08 · doc
- TECAFLON PVDF natural — stock shape properties Ensinger · 2026-08 · tds
- TECAPEI natural (PEI) — stock shape properties Ensinger · 2026-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Radel PPSU, Veradel PESU, Acudel modified PPSU Design Guide — environmental stress cracking tables Solvay Specialty Polymers · 2026-08 · tds
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
- Kynar PVDF — Design properties: solubility and irradiation (active and latent solvents) Arkema · 2026-08 · tds
- Kynar PVDF resin — chemical and fuel resistance Arkema · 2026-08 · tds