3D Printing Info

Filament comparison

PEEK vs PEKK

Compare printing settings, strength, heat resistance, dated prices and sources.

PEEK guidePEKK guide

2 selected · all documented properties

Open these two in the interactive comparisonMore PEEK comparisonsMore PEKK comparisons
PEEK vs PEKK — documented properties and sources
PropertyPEEKHIGHTEMPPEKKHIGHTEMP
Market snapshot
Listing priceUSD/kg; dated snapshots$531.87/kg median; $296.14–$770.00/kg across 5 dated product listings$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings
Identity & Market
Base polymer / chemistryPolyether ether ketone — a semi-crystalline polyaryletherketone[1]Polyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[2][3]
Densityg/cm³1.30 (ISO 1183)[1][4]1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[3][2]
Typical priceUSD/kg1 kg-equivalent spools span 296–770; the middle of the market is about 532[5][6][7]1 kg-equivalent spools cluster near 550[5][6][8]
Price range across brandsUSD/kg296-770 across brands and spool sizes; 3D4Makers recycled R-PEEK 296 at 750 g, IEMAI 3D 420 at 1 kg, LEHVOSS Luvocom 3F PEEK 9581 532 at 2 kg, 3DXTech ThermaX PEEK 770 at 500 g[5][6][7]333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[5][6][8][9][10]
Market availability1–5Niche, a handful of specialist brands[5][6][4]Niche, a handful of specialist brands[5][6][8]
Spool sizes & diameters1.75 and 2.85 mm; 200 g to 2 kg spools[5][6][4]1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[5][6][3]
Typical applicationsAerospace brackets, semiconductor handling, sterilisable medical tooling and downhole parts[1]Aerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[2][3]
Printing Parameters
Nozzle temperature°C380-400 (3DXTech printed-specimen conditions); Victrex quotes a 340-450 melt range for AM 450 FIL[1][4]Not documented
Bed temperature°C130–140 (3DXTech)[1]140 (3DXTech CarbonX PEKK-A CF15)[2]
Enclosure / chamber requirement1–5Actively heated chamber required[11][12]Actively heated chamber required[11][12]
Recommended chamber temperature°CNot less than 150 for semi-crystalline printing (Victrex AM 450 FIL); bed above 150[4]Not documented
Warping tendency1–5Severe — heated chamber needed[11]Not documented
Bed-adhesion difficulty1–5Very difficult — special plates or slurry required[11]Not documented
Overall printing difficulty1–5Expert / industrial hardware only[11][12]Expert / industrial hardware only[11][12]
Extruder requirementAn all-metal hot end rated above 400 °C and a heated chamber; 3DXTech tests at 0.25 mm layer height on a 0.4 mm nozzle[1][11]Not documented
Hardware Wear & Reliability
Nozzle hardness required1–4Brass fine indefinitely for unfilled grades, but brass softens near these nozzle temperatures — hardened or plated hot ends are the norm[11]Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[2][3]
Abrasiveness1–5Non-abrasive when unfilled[1]Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[2][3]
Nozzle clog risk1–5Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[13]Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[14]
Moisture Behaviour
Equilibrium moisture content at ~50 % RH%0.45 at saturation, 23 °C (ISO 62); 0.55 at 100 °C[4]Not documented
Drying temperature & time120 °C for 5 h, target below 0.020 % moisture (Victrex AM 450 FIL)[4]Not documented
Effect of moisture on strengthNo dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[13]No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[14]
Mechanical Properties
Tensile strength (XY)MPa60-100 (printed XY): Victrex AM 450 FIL 60-80 at yield and 3DXTech 100, both ISO 527; 98 at yield injection-moulded[1][4]86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[3][2]
Young's modulusMPa3000-4000 (printed XY, ISO 527, Victrex AM 450 FIL); 3720 (3DXTech); 4000 injection-moulded[1][4]2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[3][2]
Elongation at break%28 (printed XY, ISO 527) — remarkably ductile for a high-temperature polymer[1]6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[3][2]
Flexural strengthMPa130 (printed XY, ISO 178)[1]136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[3][2]
Flexural modulusMPa2700 (printed XY, ISO 178)[1]3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[3][2]
Charpy impact, notchedkJ/m²6.0 (injection-moulded, ISO 179/1eA); unnotched does not break[4]Not documented
Other impact dataIzod notched 7.0 kJ/m2 injection-moulded (ISO 180/A). Printed anisotropy is extreme: VICTREX AM 200 on a Stratasys F900 gives Izod notched 1380-1530 J/m XZ against 30-62 J/m ZX (ASTM D256)[4][15]Izod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[3]
Layer adhesion / Z tensileMPa20-85 at yield (printed ZX, ISO 527, Victrex AM 450 FIL); the spread is set by chamber temperature and weld quality[4]50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[3][16]
Brittleness1–5Tough — absorbs impact, yields before breaking[1]Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[3][2]
Hardness (scale-specific)Shore A / Shore D / RockwellShore D 84.5 (injection-moulded, ISO 868); Rockwell M100 / R125 on extruded PEEK stock (ASTM D785)[4][17]Not documented
Creep resistance / sustained load1–5Excellent — holds load for years. Victrex rates PEEK for long-term creep; injection-moulded flexural stress at 3.5 % strain falls only from 125 MPa at 23 °C to 85 MPa at 125 °C, and extruded stock is rated to 249 °C continuous[18][4][17]Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[3]
Fatigue / repeated-flex resistance1–5Excellent — living hinges viable. Victrex rates PEEK for long-term fatigue as well as creep[18]Not documented
Elasticity / flexibility1–5Rigid[1]Rigid[2]
Z strength as % of XY%71-84 (VICTREX AM 200 LMPAEK printed on the Stratasys F900 and Fortus 450mc, ZX against XZ tensile yield, ASTM D638); unfilled PEEK's own ZX spread is wider[15]56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[3][16]
Thermal Properties
HDT at 0.45 MPa°C140 (printed XY, ISO 75 at 0.45 MPa, 3DXTech)[1]158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[3][2]
HDT at 1.8 MPa°C152 (unannealed, ISO 75-2/Af, Victrex AM 450 FIL); 160 on extruded stock (ASTM D648 at 264 psi)[4][17]156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[3]
Glass transition (Tg)°C143 (DSC, 3DXTech); Victrex gives onset 143 and midpoint 150 (ISO 11357-2)[1][4]156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[3][2]
Melting point / Vicat°C343 melting (ISO 11357-3, Victrex); VICTREX AM 200 LMPAEK melts at 303[4][15]300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[3][2]
Continuous service temperature°C240 UL 746B relative thermal index, strength (RTI electrical 260, impact 180); Ensinger rates extruded PEEK stock at 249 long term[4][17]Not documented
Thermal expansion (CTE)µm/m·K37.8 (extruded PEEK stock, 23-60 °C, ASTM E831; source states 2.1e-5 in/in/°F), rising to 41.9 at 60-100 °C and 55.8 at 100-150 °C[17]36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[3][16]
Flammability / UL 94UL 94 V-0 at 1.5 mm on the base resin; glow-wire flammability index 960 °C at 2.0 mm (IEC 60695-2-12)[1][4]Not documented
Environment & Chemical
UV resistance1–5Not documentedGood — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[3]
Chemical resistanceOutstanding — resistant to almost all solvents and to steam sterilisation[1]Not documented
Water / humidity resistance in service1–5Excellent — essentially unaffected; 0.45 % water at saturation and resistant to steam sterilisation[4][1]Not documented
Electrical & ESD propertiesNot documentedUnfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[3][2][16]
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[19]Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[19]
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[19]Ventilated room or enclosure recommended[19]
Dust & fibre handling hazardNot documentedCarbon fibre is bound in the matrix; sanding dust should not be inhaled[2]
Solvents & Solubility
Soluble in95–98 wt% sulphuric acid dissolves it — 10 g per 100 mL at 40–70 °C gives a dark red solution. Laboratory route only.[20][21]Concentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[21][20]
Softened or crazed byConcentrated nitric, hydrofluoric, hydrobromic and hydriodic acids attack it; DCM, DMSO and THF swell thin-walled sections.[22][21]Concentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[21]
Solvent welding & smoothing agentNone — no solvent softens PEEK, so parts are joined thermally or mechanically, never chemically.[22][21]None — no solvent softens a polyaryletherketone.[21]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. ThermaX PEEK Technical Data Sheet v3 3DXTech · 2026-08 · tds
  2. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  3. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  4. VICTREX AM 450 FIL — datasheet Victrex · 2025-12 · tds
  5. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  6. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  7. IEMAI 3D PEEK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  8. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  9. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  10. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  11. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  12. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  13. ThermaX PEEK — product page 3DXTech · 2026-08 · vendor
  14. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  15. VICTREX AM 200 — FDM Material Data Sheet Stratasys · 2024-04 · tds
  16. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  17. TECAPEEK natural (PEEK) — stock shape properties Ensinger · 2026-08 · tds
  18. PEEK polymers — product overview Victrex · 2026-08 · doc
  19. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  20. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
  21. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  22. What solvents are not compatible with PEEK? — fluidics technical FAQ IDEX Health & Science · 2026-08 · doc