3D Printing Info

Filament comparison

PEEK-CF vs PP

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PEEK-CF vs PP — documented properties and sources
PropertyFibre-reinforced PEEKHIGHTEMPPolypropylene (PP)POLYOLEFIN
Market snapshot
Listing priceUSD/kg; dated snapshots$597.50/kg median; $448.00–$695.00/kg across 5 dated product listings$46.56/kg median; $31.99–$53.00/kg across 4 dated product listings
Identity & Market
Base polymer / chemistryShort-fibre reinforced PEEK. 3DXTech's CarbonX grade is nominally 10 wt% carbon and its FibreX grade 20 wt% glass; LEHVOSS Luvocom 3F PEEK CF 9676 is 15 wt% carbon; Ensinger's machining stock runs to 30 wt% carbon[1][2][3][4]Polypropylene — a semi-crystalline polyolefin with no polar groups, so it neither absorbs water nor bonds to most bed surfaces[5][6]
Densityg/cm³1.39 (ISO 1183)[1]0.91 (Prusa PP composite, ISO 1183) — the lightest common filament[7]
Typical priceUSD/kg1 kg-equivalent spools span 448–972; the middle of the market is about 598[2][3][8]1 kg-equivalent spools span 27–53; the middle of the market is about 44[9][10][11][12]
Price range across brandsUSD/kg448-972 across formats and filler types; IEMAI 3D CF-PEEK and GF-PEEK 448 at 1 kg, 3DXTech CarbonX PEEK+CF10 598 at 2 kg and FibreX PEEK+GF20 695 at 1 kg, Luvocom 3F PEEK CF 9676 648 at 2 kg[2][3][8][13]27–53 across brands; Reli3D 32 on Amazon, SUNLU 44 at 0.8 kg, Fiberlogy 49 at 750 g, IEMAI 3D 53, and the 3DJake PP listing spans 27–49[9][14][10][11][12]
Market availability1–5Niche, a handful of specialist brands[2][3]Available from several mainstream brands[14][10][9]
Spool sizes & diameters1.75 and 2.85 mm; 200 g to 2 kg spools[2][3]1.75 and 2.85 mm; 0.75 kg spools are common[10]
Typical applicationsStiff aerospace and oil-and-gas parts where PEEK alone is not rigid enough[1]Living hinges, chemical-resistant containers, automotive clips and packaging prototypes[5]
Printing Parameters
Nozzle temperature°CNot documented210–230 (Braskem-type PE/PP window); Formfutura's Centaur PP melts at 205 ± 15 °C[5]
Enclosure / chamber requirement1–5Actively heated chamber required[15][16]Enclosure recommended — Simplify3D lists an enclosure as a hardware requirement and Polymaker advises one below 70 °C ambient to stop warping and cracking[17][6]
Part cooling fanNot documentedPart cooling fan required (Simplify3D)[17]
Bed surface & adhesion aidNot documentedPacking tape, a polypropylene sheet, or a PP-specific adhesive such as Magigoo PP — ordinary PLA and ABS adhesives do not hold it[17][6]
Warping tendency1–5Moderate — needs adhesion aid or draught shield; the fibre cuts PEEK's crystallisation shrinkage[1]High — enclosure needed for reliable large parts; PP's crystallinity drives shrinkage and Prusa recommends a brim on its PP grades[7][18]
Bed-adhesion difficulty1–5Not documentedVery difficult — special plates or slurry required. PP bonds to almost nothing; a polypropylene-specific tape or adhesive is the normal answer[7][6]
Stringing / oozing tendency1–5Not documentedSlight — Polymaker advises 1–2 mm retraction at 20–30 mm/s[6]
Overall printing difficulty1–5Expert / industrial hardware only[15][16]Advanced — enclosure, hardware upgrades, tuning; bed adhesion is the whole problem[6][7]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required[1]Brass fine indefinitely for unfilled grades — Simplify3D states no special hotend is required[17]
Abrasiveness1–5Highly abrasive — standard CF composite[1]Non-abrasive when unfilled[17]
Nozzle clog risk1–5High — jams from moisture, heat creep or particles; 3DXTech adds a hardened 0.4 mm minimum nozzle and 0.25 mm layers to the mandatory 120 °C pre-dry[19][20]Low — Simplify3D lists no special hotend requirement for PP and clogging is not among its listed drawbacks[21][17]
Heat-creep / jam sensitivity1–5Not documentedSlightly sensitive[17]
Hotend requirementNot documentedNo special hot-end required (Simplify3D)[17]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Not documentedNegligible (<0.1 % EMC) — Prusa measures 0.03 % in 24 h and 0.04 % in 7 days on its PP composite, the lowest figures it publishes for any filament[7]
Equilibrium moisture content at ~50 % RH%0.06 in 24 h on extruded CF30 stock (ASTM D570)[4]0.03 after 24 h and 0.04 after 7 days at 24 °C / 22 % RH (Prusa Polymers, measured on its PP composite)[7]
Drying temperature & timeNot documentedNo drying step is published for PP; uptake is below the level that affects printing[7]
Symptoms when wetNot documentedBubbling and popping at the nozzle; Polymaker still advises a 70 °C dry for 4–6 h despite the low uptake[6]
Effect of moisture on strengthNo dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[19]Not applicable in practice — with equilibrium uptake at 0.04 %, there is no moisture-driven strength loss to measure. Polymaker's sensitivity tiers put polyolefins below even PLA[7][21]
Storage requirementNot documentedNo special storage needed[7]
Mechanical Properties
Tensile strength (XY)MPa105 at break (printed XY, ISO 527, CF10); 121 at yield on extruded CF30 stock (ASTM D638)[1][4]12 at yield (Formfutura Centaur PP, ASTM D638)[5]
Young's modulusMPa8100 (printed XY, ISO 527, CF10) — more than double unfilled PEEK; 6343 on extruded CF30 stock (ASTM D638)[1][4]724 on extruded PP stock (ASTM D638; converted from 105,000 psi)[22]
Elongation at break%3 at break (printed XY, ISO 527), against 28 for unfilled PEEK[1][23]Above 600 at break (Formfutura Centaur PP, ASTM D638)[5]
Flexural strengthMPa136 (printed XY, ISO 178, CF10); 193 on extruded CF30 stock (ASTM D790)[1][4]31.0 on extruded PP stock (ASTM D790; converted from 4500 psi)[22]
Flexural modulusMPa8300 (printed XY, ISO 178, CF10); 7171 on extruded CF30 stock (ASTM D790)[1][4]402 flexural modulus (Formfutura Centaur PP, ASTM D790) — an order of magnitude below any rigid filament[5]
Other impact dataIzod notched 61.9 J/m on extruded CF30 stock, converted from 1.16 ft-lb/in (ASTM D256)[4]Izod notched 112 J/m on extruded PP stock, converted from 2.1 ft-lb/in (ASTM D256)[22]
Brittleness1–5Brittle — snaps with little warning; elongation falls from 28 % to 3 %[1][23]Very ductile — bends far before failing[5]
Hardness (scale-specific)Shore A / Shore D / RockwellRockwell M107 on extruded PEEK-CF30 stock (ASTM D785), against M100 unfilled[4][24]Rockwell R102 (and M95) on extruded PP stock (ASTM D785)[22]
Creep resistance / sustained load1–5Excellent — holds load for years. Ensinger rates carbon-fibre PEEK stock as very highly creep resistant and specifies 260 °C continuous service[4]Below average[5]
Fatigue / repeated-flex resistance1–5Good. Victrex rates PEEK for long-term fatigue as well as creep; the fibre cuts elongation at break from 28 % to 3 %, which limits repeated large-strain flexing[25][1][23]Excellent — living hinges viable, the classic polypropylene application[5]
Elasticity / flexibility1–5Rigid[1]Semi-flexible[5]
Thermal Properties
HDT at 0.45 MPa°C265 (printed XY, ISO 75 at 0.45 MPa, CarbonX PEEK+CF10) against 140 for unfilled PEEK[1][23]74 on extruded PP stock (ASTM D648 at 66 psi; converted from 165 °F)[22]
HDT at 1.8 MPa°C316 on extruded CF30 stock, converted from 600 °F at 264 psi (ASTM D648)[4]Not documented
Glass transition (Tg)°C143 (DSC, CarbonX PEEK+CF10) — the fibre does not move the glass transition[1]Not documented
Melting point / Vicat°C334 melting on extruded CF30 stock, converted from 633 °F[4]205 ± 15 melting (Formfutura Centaur PP)[5]
Continuous service temperature°C260 long-term on extruded CF30 stock, converted from 500 °F; 300 short term[4]Bounded by a melting point of 205 ± 15 °C and by the 158 °C heat deflection of the carbon-filled grade; no loaded-bar service figure is published for unfilled PP[5][7]
Thermal expansion (CTE)µm/m·K14.4 (extruded PEEK-CF30 stock, ASTM D696; source states 0.80e-5 in/in/°F) — about a third of unfilled PEEK[4][24]Not documented
Flammability / UL 94UL 94 V-0 on the base resin; Ensinger lists extruded PEEK-CF30 stock as inherently flame resistant[23][4]Flammable; no UL 94 rating published for the grades surveyed[7]
Environment & Chemical
UV resistance1–5Not documentedMonths outdoors before embrittlement — unstabilised polypropylene chalks under UV[6]
Chemical resistanceNot documentedExcellent against acids, alkalis and most solvents — the usual reason to choose PP[6]
Water / humidity resistance in service1–5Not documentedExcellent — essentially unaffected[7]
Food contactNot documentedPolypropylene is a common food-packaging polymer, but no filament here carries a food-contact certification[6]
Biodegradability / compostabilityNot documentedNot biodegradable[6]
RecyclabilityNot documentedMechanically recyclable as resin code 5, but printed waste is not accepted in household collection[6]
Electrical & ESD propertiesSurface resistance above 10⁹ ohm/sq — not static-dissipative (ASTM D257)[1]Not documented
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[26]Low hazard — minimal VOC and particle emission. Inferred: no polyolefin was among the nine filaments in the Azimi chamber study, so this is a family-level judgement rather than a measurement[26]
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[26]Open a window / occasional ventilation. Inferred — no polyolefin was measured in the chamber study[26]
Dust & fibre handling hazardCarbon fibre is bound in the matrix; sanding dust should not be inhaled[1]Not documented
Post-Processing
Sanding & machiningNot documentedSands poorly — the waxy surface loads abrasive paper[17]
Painting & finishingNot documentedPaint and adhesives do not key to untreated PP; flame or plasma treatment is normally needed first[6]
Gluing & solvent weldingNot documentedNothing common bonds untreated PP; flame or plasma treatment is needed before adhesives key[6]
Vapour / chemical smoothingNot documentedNo practical vapour smoothing[17]
Support material pairingNot documentedPrints its own supports; no soluble support is rated for PP[17]
Dimensional accuracy & detailNot documentedShrinkage and warping dominate; the low modulus means parts flex rather than hold tolerance[7]
Solvents & Solubility
Soluble in95–98 wt% sulphuric acid dissolves the matrix at 40–70 °C and leaves the fibre. Nothing else touches PEEK.[27][28]None at room temperature; chloroform dissolves it at 60 °C and xylene at about 118 °C — the xylene-solubles route.[29][30]
Softened or crazed byConcentrated nitric, hydrofluoric, hydrobromic and hydriodic acids attack it; DCM, DMSO and THF swell thin-walled sections.[31][28]Xylene, decalin, CCl4 and chlorobenzene are heavily absorbed at 20 °C; oleum, chlorosulphonic acid and bromine destroy it.[29]
Solvent welding & smoothing agentNone — no solvent softens PEEK, so parts are joined thermally or mechanically, never chemically.[31][28]None — nothing softens PP at room temperature, so joints have to be welded thermally rather than chemically.[29]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. CarbonX Carbon Fiber PEEK Technical Data Sheet v3 3DXTech · 2026-08 · tds
  2. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  3. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  4. TECAPEEK CF30 black (PEEK-CF30) — stock shape properties Ensinger · 2026-08 · tds
  5. Centaur PP Technical Data Sheet Formfutura · 2026-08 · tds
  6. PP — material basics Polymaker Wiki · 2026-08 · doc
  7. Prusament PP Carbon Fiber Technical Datasheet v1.0 Prusa Polymers · 2024-11 · tds
  8. IEMAI 3D CF-PEEK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  9. SUNLU product catalogue SUNLU · 2026-08 · vendor
  10. Fiberlogy PP Natural — product page 3DJake International · 2026-08 · vendor
  11. Reli3D Low Warp PP Filament 1.75 mm 1 kg Black — Amazon listing Amazon.com · 2026-08 · vendor
  12. IEMAI 3D PP 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  13. IEMAI 3D GF-PEEK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  14. PP filament listing 3DJake International · 2026-08 · vendor
  15. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  16. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  17. Polypropylene — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  18. Prusament PP Glass Fiber Technical Datasheet v1.0 Prusa Polymers · 2024-11 · tds
  19. CARBONX PEEK+CF10 — product page (print recommendations) 3DXTech · 2026-08 · doc
  20. Composite materials filled with carbon, kevlar or glass Prusa Knowledge Base · 2026-08 · doc
  21. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  22. TECAFINE PP natural — stock shape properties Ensinger · 2026-08 · tds
  23. ThermaX PEEK Technical Data Sheet v3 3DXTech · 2026-08 · tds
  24. TECAPEEK natural (PEEK) — stock shape properties Ensinger · 2026-08 · tds
  25. PEEK polymers — product overview Victrex · 2026-08 · doc
  26. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  27. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
  28. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  29. Pro-fax and Moplen polypropylene — Chemical Resistance Guide (20, 60 and 100 °C) LyondellBasell · 2026-08 · tds
  30. US 5,278,282 Polymer recycling by selective dissolution — xylene dissolution temperatures Nauman & Lynch, Rensselaer Polytechnic Institute · 1994-01 · paper
  31. What solvents are not compatible with PEEK? — fluidics technical FAQ IDEX Health & Science · 2026-08 · doc