Filament comparison
PE vs PEKK
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | Polyethylene (PE)POLYOLEFIN | PEKKHIGHTEMP |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $87.72/kg median; $87.72–$87.72/kg across 1 dated product listings | $525.00/kg median; $332.50–$771.12/kg across 6 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Polyethylene — the simplest polyolefin, non-polar and highly crystalline. The one retailed filament grade, Spectrum HDPE, uses what Spectrum calls Low Warp technology and is denser and stiffer than plain HDPE[1][2] | Polyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[3][4] |
| Densityg/cm³ | 1.10 (Spectrum HDPE filament, ISO 1183) against 0.95 for extruded HDPE stock — the filament is a modified formulation[1][2] | 1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[4][3] |
| Typical priceUSD/kg | 1 kg-equivalent spools cluster near 88[5] | 1 kg-equivalent spools cluster near 550[6][7][8] |
| Price range across brandsUSD/kg | 87.72 — Spectrum's 500 g spools at 3DJAKE are the only PE filament listing found[5] | 333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[6][7][8][9][10] |
| Market availability1–5 | Niche, a handful of specialist brands — Spectrum HDPE in six colours is the only PE filament in the 3DJAKE and igo3d product sitemaps, at MatterHackers or at Printed Solid, but it is a normal stocked item rather than a special order[11][12][13][5] | Niche, a handful of specialist brands[6][7][8] |
| Spool sizes & diameters | 1.75 mm; 500 g spools in six colours[5][11] | 1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[6][7][4] |
| Typical applications | Chemically resistant containers, packaging prototypes and consumer goods where HDPE is the production material[1] | Aerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[3][4] |
| Printing Parameters | ||
| Nozzle temperature°C | 240-290 (Spectrum HDPE)[1] | Not documented |
| Bed temperature°C | 80-100 (Spectrum HDPE)[1] | 140 (3DXTech CarbonX PEKK-A CF15)[3] |
| Enclosure / chamber requirement1–5 | Enclosure recommended — Spectrum recommends a closed chamber for larger prints[1] | Actively heated chamber required[14][15] |
| Part cooling fan | 0-50 % part cooling (Spectrum HDPE)[1] | Not documented |
| Bed surface & adhesion aid | Spectrum states no adhesive is necessary for its low-warp HDPE, depending on geometry[1] | Not documented |
| Warping tendency1–5 | Moderate — needs adhesion aid or draught shield. Spectrum's low-warp grade is sold as printable on desktop machines, which is not true of plain polyethylene[1] | Not documented |
| Bed-adhesion difficulty1–5 | Needs the right surface or a thin adhesive; Spectrum states no adhesive is necessary but recommends a closed chamber for large parts[1] | Not documented |
| Overall printing difficulty1–5 | Intermediate — dry filament and a tuned profile; Spectrum sells the grade as desktop-printable with no dry box and no hardened nozzle[1] | Expert / industrial hardware only[14][15] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Brass fine indefinitely — Spectrum states a ruby or hardened nozzle is not required[1] | Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[3][4] |
| Abrasiveness1–5 | Non-abrasive[1] | Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[3][4] |
| Nozzle clog risk1–5 | Low — Spectrum lists no drybox and no ruby or hardened nozzle for HDPE, and very low moisture absorption[1] | Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[16] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Negligible (<0.1 % EMC) — Spectrum lists very low moisture absorption and no dry box[1] | Not documented |
| Drying temperature & time | No drying step published; Spectrum lists a dry box as not required[1] | Not documented |
| Effect of moisture on strength | Not applicable in practice — Spectrum lists very low moisture absorption and no drybox requirement for HDPE[1] | No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[16] |
| Storage requirement | Store dry at 18-25 °C out of sunlight; Spectrum quotes a 24-month shelf life[1] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 29 at break (Spectrum HDPE, ISO 527; specimen type not stated) against 25.5 at yield on extruded HDPE stock (ASTM D638, from 3700 psi)[1][2] | 86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[4][3] |
| Young's modulusMPa | 3500 (Spectrum HDPE, ISO 527) against 965 on extruded HDPE stock (ASTM D638, from 140,000 psi) — the filament grade is nearly four times stiffer than plain polyethylene[1][2] | 2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[4][3] |
| Elongation at break% | 18 at break (Spectrum HDPE, ISO 527) against above 100 on extruded stock (ASTM D638)[1][2] | 6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[4][3] |
| Flexural strengthMPa | 27.6 on extruded HDPE stock (ASTM D790; converted from 4000 psi)[2] | 136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[4][3] |
| Flexural modulusMPa | 3200 (Spectrum HDPE, ISO 178) against 965 on extruded stock (ASTM D790, from 140,000 psi)[1][2] | 3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[4][3] |
| Other impact data | Charpy 10 kJ/m2 (Spectrum HDPE, ISO 179-1; notch condition not stated); Izod 104 J/m on extruded stock, converted from 1.94 ft-lb/in (ASTM D256)[1][2] | Izod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[4] |
| Layer adhesion / Z tensileMPa | Not documented | 50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[4][17] |
| Brittleness1–5 | Tough — absorbs impact, yields before breaking; 18 % elongation at break on the filament and above 100 % on extruded stock[1][2] | Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[4][3] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Shore D 67 and Rockwell R54 on extruded HDPE stock (ASTM D2240, D785); Spectrum quotes Rockwell 80 HRM for its filament (ISO 2039-2)[2][1] | Not documented |
| Creep resistance / sustained load1–5 | Not documented | Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[4] |
| Fatigue / repeated-flex resistance1–5 | Good — Spectrum lists outstanding abrasion and crack resistance for its HDPE, but no repeated-flex or fatigue test data was found for any PE filament[1] | Not documented |
| Elasticity / flexibility1–5 | Slightly flexible in thin sections — Spectrum's low-warp grade has a 3.5 GPa tensile modulus; plain extruded HDPE at 965 MPa is genuinely semi-flexible[1][2] | Rigid[3] |
| Z strength as % of XY% | Not documented | 56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[4][17] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 75 on extruded HDPE stock (ASTM D648 at 66 psi; converted from 167 °F)[2] | 158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[4][3] |
| HDT at 1.8 MPa°C | Not documented | 156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[4] |
| Glass transition (Tg)°C | Not documented | 156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[4][3] |
| Melting point / Vicat°C | Not documented | 300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[4][3] |
| Continuous service temperature°C | 110 stated as heat resistance by Spectrum with no test standard given; extruded stock is rated 120 long-term maximum (converted from 248 °F) and brittle below -76[1][2] | Not documented |
| Thermal expansion (CTE)µm/m·K | 117 (extruded HDPE stock, ASTM D696; source states 6.5e-5 in/in/°F)[2] | 36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[4][17] |
| Environment & Chemical | ||
| UV resistance1–5 | Moderate — a season or two. Spectrum describes its HDPE as UV-stable and weather-resistant but publishes no exposure data[1] | Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[4] |
| Chemical resistance | Excellent chemical resistance to acids, bases, oils and solvents (Spectrum); Ensinger lists broad chemical compatibility for HDPE stock[1][2] | Not documented |
| Water / humidity resistance in service1–5 | Excellent — essentially unaffected; Ensinger lists low moisture absorption for HDPE stock and Spectrum very low absorption for the filament[1][2] | Not documented |
| Recyclability | Spectrum states the filament is fully recyclable; HDPE is resin code 2[1] | Not documented |
| Electrical & ESD properties | Not documented | Unfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[4][3][17] |
| Health & Safety | ||
| Fume toxicity1–5 | Not documented | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[18] |
| Ventilation / filtration requirement1–5 | Not documented | Ventilated room or enclosure recommended[18] |
| Dust & fibre handling hazard | Not documented | Carbon fibre is bound in the matrix; sanding dust should not be inhaled[3] |
| Post-Processing | ||
| Sanding & machining | Easy to machine — Ensinger lists machinability as a headline property of HDPE stock[2] | Not documented |
| Dimensional accuracy & detail | Spectrum lists a shiny surface finish and no adhesive requirement; shrinkage remains the limit on large flat parts[1] | Not documented |
| Solvents & Solubility | ||
| Soluble in | None at room temperature; xylene dissolves HDPE at about 105 °C and LDPE at 75 °C. Hot decalin does the same.[19][20] | Concentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[21][22] |
| Softened or crazed by | Toluene, xylene, styrene, chloroform, dichloromethane, MEK and trichloroethylene are all unsatisfactory at 21 °C.[20] | Concentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[21] |
| Solvent welding & smoothing agent | None — polyethylene has no room-temperature solvent, so joints are made by heat welding.[20][19] | None — no solvent softens a polyaryletherketone.[21] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- Spectrum HDPE Technical Data Sheet Spectrum Filaments · 2025-10 · tds
- TECAFINE HDPE natural — stock shape properties Ensinger · 2026-08 · tds
- CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
- Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
- Spectrum HDPE Traffic Black, 1.75 mm / 500 g 3DJAKE · 2026-08 · vendor
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
- Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
- Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
- IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- 3DJAKE product catalogue 3DJAKE · 2026-08 · vendor
- igo3d product sitemap (17452 product URLs) igo3d · 2026-08 · vendor
- Printed Solid product catalogue Printed Solid · 2026-08 · vendor
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
- Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- US 5,278,282 Polymer recycling by selective dissolution — xylene dissolution temperatures Nauman & Lynch, Rensselaer Polytechnic Institute · 1994-01 · paper
- HDPE Chemical Resistance Guide (21 °C and 60 °C) INEOS Olefins & Polymers USA · 2026-08 · tds
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
- The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper