Filament comparison
PA6/66 vs PETG-GF
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | PA66 (Nylon 66)PA | Glass-fibre polyester (PETG-GF / PET-GF)PETG |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | Not documented | $27.38/kg median; $18.99–$29.99/kg across 3 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Polyamide 66, condensed from hexamethylenediamine and adipic acid; melts around 40 °C above PA6[1] | Glass-fibre reinforced polyester. Polymaker's Fiberon PET-GF15 uses a PET rather than a PETG matrix and carries 15 wt% glass fibre[2] |
| Densityg/cm³ | 1.14 (extruded unfilled PA66 stock)[3] | 1.43 (Fiberon PET-GF15, ISO 1183)[2] |
| Typical priceUSD/kg | Not documented | 1 kg spools cluster near 25[4][5] |
| Price range across brandsUSD/kg | Not documented | 19–30 across brands; ELEGOO 19, Polymaker Fiberon 30[4][5] |
| Market availability1–5 | Special order, 1–2 makers worldwide — no unfilled PA66 filament appeared in any catalogue searched, and the 3DXTech nylon range offers PA6, PA12 and a 6/66 copolymer but no straight PA66[6][5] | Niche, a handful of specialist brands[4][5] |
| Spool sizes & diameters | Not documented | 1.75 mm; 0.5 and 1 kg spools[5] |
| Typical applications | Not documented | Stiff, dimensionally stable fixtures; the Fiberon grade is designed to be annealed for heat resistance[2] |
| Printing Parameters | ||
| Enclosure / chamber requirement1–5 | Enclosure required (passive)[1] | Not documented |
| Bed surface & adhesion aid | Not documented | Textured PEI, satin or powder-coated sheets; on smooth PEI a glue stick acts as a release agent[7][8] |
| Bed-adhesion difficulty1–5 | Not documented | Needs the right surface or a thin adhesive — the problem is releasing the part, not sticking it[7][8] |
| Stringing / oozing tendency1–5 | Not documented | Moderate — retraction tuning needed; Polymaker names stringing as PETG's common quirk[8] |
| Overall printing difficulty1–5 | Advanced — enclosure, hardware upgrades, tuning[1] | Not documented |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Not documented | Hardened steel required[2] |
| Abrasiveness1–5 | Not documented | Highly abrasive — standard GF composite[2] |
| Nozzle clog risk1–5 | Very high — frequent jams without careful setup[9][10] | Moderate — needs dry filament and a clean nozzle; Prusa lists higher risk of nozzle clogging for glass-filled composites[11] |
| Heat-creep / jam sensitivity1–5 | Not documented | Slightly sensitive[12] |
| Hotend requirement | Not documented | No special hot-end required[12] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Very high (>2 %)[10] | Moderate (0.3–0.8 %) — the PETG matrix reaches 0.40 % saturated at 25 °C / 55 % RH; no glass-filled grade publishes its own figure[7] |
| Equilibrium moisture content at ~50 % RH% | 8.5 at saturation on extruded PA66 stock (ASTM D570) — the highest uptake of any polymer in this dataset[3] | Not documented |
| Symptoms when wet | Not documented | Bubbling and popping at the nozzle, stringing and a rough surface[10] |
| Effect of moisture on strength | Measured dry against wet on printed specimens at 6.16 % moisture (Polymaker CoPA): tensile 78.0 → 34.3 MPa, Young's modulus 2703 → 724 MPa, flexural strength 109.8 → 22.6 MPa, while notched Charpy rises 6.9 → 27.7 kJ/m² and elongation 12.7 → 13.2 %[13][9] | Polymaker groups PETG with nylon, PVA and TPU as highly hygroscopic; no dry-versus-conditioned strength figures are published for this grade and the loss shows as bubbling and poor layer adhesion[10] |
| Storage requirement | Not documented | Sealed with desiccant; Polymaker groups PETG with the highly hygroscopic materials[10][8] |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 82.7 at yield and 84.8 at break on extruded PA66 stock (ASTM D638; converted from 12,000 and 12,300 psi) — no printed figure exists because no unfilled PA66 filament was found[3] | 59.9 ± 0.8 printed XY, ISO 527 (Fiberon PET-GF15)[2] |
| Young's modulusMPa | 2413 on extruded PA66 stock (ASTM D638; converted from 350,000 psi)[3] | 4144 ± 133 printed XY, ISO 527 (Fiberon PET-GF15)[2] |
| Elongation at break% | 50 at break on extruded PA66 stock (ASTM D638)[3] | 4.0 ± 0.5 printed XY, ISO 527 (Fiberon PET-GF15)[2] |
| Flexural strengthMPa | 113.8 on extruded PA66 stock (ASTM D790; converted from 16,500 psi)[3] | 104.2 ± 2.4 printed XY, ISO 178 (Fiberon PET-GF15)[2] |
| Flexural modulusMPa | 3034 on extruded PA66 stock (ASTM D790; converted from 440,000 psi)[3] | 3705 ± 85 printed XY, ISO 178 (Fiberon PET-GF15)[2] |
| Charpy impact, notchedkJ/m² | Not documented | 8.7 ± 0.6 printed XY, ISO 179, notched (Fiberon PET-GF15)[2] |
| Other impact data | Izod 53 J/m on extruded PA66 stock, converted from 1.0 ft-lb/in (ASTM D256)[3] | Charpy unnotched 27.2 ± 2.0 printed XY (Fiberon PET-GF15, ISO 179)[2] |
| Layer adhesion / Z tensileMPa | Not documented | 48.2 ± 0.3 printed Z, ISO 527 (Fiberon PET-GF15)[2] |
| Brittleness1–5 | Not documented | Brittle — snaps with little warning; elongation 4.0 % in XY and 2.6 % in Z[2] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Shore D 86 and Rockwell 85 (108) — the source does not name the scales on extruded PA66 stock (ASTM D2240, D785)[3] | Not documented |
| Creep resistance / sustained load1–5 | Not documented | Below average — no GF-grade creep test; the CF grades sagged to 14.8–16.7 mm over 5 days at 1.25 kg against 17.1–20.4 mm unfilled[14][15][16] |
| Fatigue / repeated-flex resistance1–5 | Excellent — living hinges viable[1] | Below average — no GF-grade S-N curve; elongation at break falls to 4.0 % in XY against 5.2–9.3 % unfilled[2][17] |
| Elasticity / flexibility1–5 | Semi-flexible[9] | Rigid[2] |
| Z strength as % of XY% | Not documented | 80 (Fiberon PET-GF15, printed Z against XY tensile)[2] |
| Wear resistance & friction | Wear factor 200e-10 in3*min/(ft*lb*h) on extruded PA66 stock (ASTM D3702); Ensinger lists very good slide and wear properties[3] | Not documented |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 232 on extruded PA66 stock (ASTM D648 at 66 psi; converted from 450 °F)[3] | 81.6 as printed, 133.7 after annealing (ISO 75, 0.45 MPa)[2] |
| HDT at 1.8 MPa°C | 90 on extruded PA66 stock (ASTM D648 at 264 psi; converted from 194 °F) — the gap to the 0.45 MPa figure is the widest in the dataset[3] | 71.8 as printed, 87.3 after annealing (ISO 75, 1.8 MPa)[2] |
| Glass transition (Tg)°C | Not documented | 59.5 (DSC)[2] |
| Melting point / Vicat°C | 255 melting on extruded PA66 stock (ASTM D2133; converted from 491 °F)[3] | 231.6 melting (DSC); Vicat 232.6 (ISO 306)[2] |
| Continuous service temperature°C | 85 long term and 149 short term on extruded PA66 stock (converted from 185 °F and 300 °F)[3] | Not documented |
| Annealing response | Not documented | Annealing lifts HDT at 0.45 MPa from 81.6 to 133.7 °C[2] |
| Thermal expansion (CTE)µm/m·K | 81.0 (extruded PA66 stock, ASTM D696; source states 4.5e-5 in/in/°F)[3] | 20 along the print bead and 63–74 in the build direction at 30 °C (30 wt% GF, large-format printed, TMA)[18] |
| Flammability / UL 94 | UL 94 V-2 on extruded PA66 stock[3] | UL 94 HB at 1.5 mm (Fiberon PET-GF15)[2] |
| Environment & Chemical | ||
| Chemical resistance | Not documented | Withstands acids, alkalis, oils and UV exposure[8] |
| Food contact | Not documented | Not certified for food contact as filament[8] |
| Biodegradability / compostability | Not documented | Not biodegradable[8] |
| Recyclability | Not documented | Not accepted in household plastic collection[8] |
| Electrical & ESD properties | Volume resistance 1e15 ohm-cm and dielectric constant 4 on extruded PA66 stock (ASTM D257, D150)[3] | Surface resistivity above 10¹² ohm — insulating (Fiberon PET-GF15, ANSI/ESD S11.11)[2] |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised[19] | Moderate — measurable VOCs and UFPs, ventilation advised[19] |
| VOC emission rateµg/min | Up to 180 caprolactam, the dominant VOC from nylon; total VOC reached nearly 200 µg/min, the highest of the nine filaments tested[19] | Not documented |
| Ultrafine-particle emission rateparticles/min | ≈2 × 10⁸ median — low for ultrafine particles despite the highest VOC mass of any filament tested[19] | Not documented |
| Hazardous species emitted | Caprolactam, at up to 180 µg/min from nylon filament — the largest single-VOC emission rate measured in the study[19] | Not documented |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[19] | Open a window / occasional ventilation[19] |
| Dust & fibre handling hazard | Not documented | Glass fibre is bound in the matrix; avoid inhaling sanding dust[2] |
| Post-Processing | ||
| Sanding & machining | Not documented | Sands poorly — the material is tough and gums rather than powders[12] |
| Gluing & solvent welding | Not documented | Cyanoacrylate; no common solvent welds PETG cleanly[12] |
| Vapour / chemical smoothing | Not documented | No practical vapour smoothing[12] |
| Support material pairing | Not documented | Prints its own supports; Polymaker rates PolyDissolve S1 for PETG[12] |
| Solvents & Solubility | ||
| Soluble in | Dissolved at 23 °C by formic acid above ~80 %, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — laboratory reagents.[20] | No common workshop solvent; dichloromethane — a carcinogen — dissolves the matrix surface, 1,2-dichloroethane destroys it in a week.[21][22] |
| Softened or crazed by | Zinc chloride solutions stress-crack it — 10 % marginal, 37 % not resistant; alcoholic calcium chloride dissolves it.[20] | Acetone (+16 % weight over 1 year at 23 °C), ethyl acetate, toluene and DMF swell and soften it; methanol crazes it.[21] |
| Solvent welding & smoothing agent | None — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[20] | Dichloromethane reaches only the resin, so the fibre is left standing proud of the surface. Controlled carcinogen.[22] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
- Fiberon PET-GF15 Technical Data Sheet V1.0 Polymaker · 2026-08 · tds
- TECAMID 66 natural (PA66) — stock shape properties Ensinger · 2026-08 · tds
- ELEGOO product catalogue ELEGOO · 2026-08 · vendor
- Polymaker product catalogue Polymaker · 2026-08 · vendor
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- Prusament PETG Technical Datasheet v1.1 Prusa Polymers · 2022-02 · tds
- PETG — material basics Polymaker Wiki · 2026-08 · doc
- Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- Composite materials filled with carbon, kevlar or glass Prusa Knowledge Base · 2026-08 · doc
- PET and PETG — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
- Extrudr PETG vs PCTG vs XPETG-CF — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
- Prusament PETG-CF vs PETG V0 vs PETG — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
- BambuLab PETG Basic vs Translucent vs PETG-CF — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
- Mechanical Properties of Additively Manufactured Polymeric Materials — PLA and PETG — For Biomechanical Applications Polymers 16(13):1868 · 2024-06 · paper
- Effects of Fiber Orientation on the Coefficient of Thermal Expansion of Fiber-Filled Polymer Systems in Large Format Polymer Extrusion-Based Additive Manufacturing Materials 15(8):2764 · 2022-04 · paper
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
- Eastman Spectar copolyester — Chemical resistance (unstressed bars, 1 year at 23 °C) Eastman Chemical Company · 2026-08 · tds
- Improve your 3D prints with chemical smoothing Prusa Research · 2026-08 · doc