3D Printing Info

Filament comparison

PA6/66 vs PEBA

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PA6/66 vs PEBA — documented properties and sources
PropertyPA66 (Nylon 66)PAPEBA (polyether block amide)FLEX
Market snapshot
Listing priceUSD/kg; dated snapshotsNot documented$60.99/kg median; $60.99–$60.99/kg across 1 dated product listings
Identity & Market
Base polymer / chemistryPolyamide 66, condensed from hexamethylenediamine and adipic acid; melts around 40 °C above PA6[1]Polyether block amide: rigid polyamide and flexible polyether blocks.[2]
Densityg/cm³1.14 (extruded unfilled PA66 stock)[3]1.01 g/cm³ (GB/T 1033; eSUN manufacturer data)[2]
Market availability1–5Special order, 1–2 makers worldwide — no unfilled PA66 filament appeared in any catalogue searched, and the 3DXTech nylon range offers PA6, PA12 and a 6/66 copolymer but no straight PA66[4][5]Not documented
Spool sizes & diametersNot documented1.75 mm diameter, 1 kg spool.[6]
Typical applicationsNot documentedManufacturer applications include footwear, sports equipment and cushioning.[2]
Printing Parameters
Nozzle temperature°CNot documented230–260 °C; 240 °C recommended.[2]
Bed temperature°CNot documented60–90 °C[2]
Enclosure / chamber requirement1–5Enclosure required (passive)[1]Not documented
Part cooling fanNot documented10–50% fan recommended; mechanical-test specimens used 50–100%.[2]
Bed surface & adhesion aidNot documentedPEI build plate[2]
Maximum volumetric flow (mm³/s; see test conditions)mm³/sNot documented9 mm³/s maximum in eSUN spiral-vase test; mechanical specimens used 2 mm³/s. Linear recommendation 25–110 mm/s is a separate quantity.[2]
Overall printing difficulty1–5Advanced — enclosure, hardware upgrades, tuning[1]Not documented
Hardware Wear & Reliability
Nozzle clog risk1–5Very high — frequent jams without careful setup[7][8]Not documented
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Very high (>2 %)[8]Not documented
Equilibrium moisture content at ~50 % RH%8.5 at saturation on extruded PA66 stock (ASTM D570) — the highest uptake of any polymer in this dataset[3]Not documented
Drying temperature & timeNot documented70–75 °C for 6–8 h; re-dry after receiving or extended exposure.[2]
Effect of moisture on strengthMeasured dry against wet on printed specimens at 6.16 % moisture (Polymaker CoPA): tensile 78.0 → 34.3 MPa, Young's modulus 2703 → 724 MPa, flexural strength 109.8 → 22.6 MPa, while notched Charpy rises 6.9 → 27.7 kJ/m² and elongation 12.7 → 13.2 %[9][7]Not documented
Mechanical Properties
Tensile strength (XY)MPa82.7 at yield and 84.8 at break on extruded PA66 stock (ASTM D638; converted from 12,000 and 12,300 psi) — no printed figure exists because no unfilled PA66 filament was found[3]>16.5 MPa printed XY, GB/T 1040; manufacturer lower bound, not an exact measurement.[2]
Young's modulusMPa2413 on extruded PA66 stock (ASTM D638; converted from 350,000 psi)[3]Not documented
Elongation at break%50 at break on extruded PA66 stock (ASTM D638)[3]>520% printed XY, GB/T 1040; manufacturer lower bound.[2]
Flexural strengthMPa113.8 on extruded PA66 stock (ASTM D790; converted from 16,500 psi)[3]Not documented
Flexural modulusMPa3034 on extruded PA66 stock (ASTM D790; converted from 440,000 psi)[3]Not documented
Other impact dataIzod 53 J/m on extruded PA66 stock, converted from 1.0 ft-lb/in (ASTM D256)[3]Not documented
Layer adhesion / Z tensileMPaNot documented7.5 MPa printed Z, GB/T 1040 (manufacturer test)[2]
Hardness (scale-specific)Shore A / Shore D / RockwellShore D 86 and Rockwell 85 (108) — the source does not name the scales on extruded PA66 stock (ASTM D2240, D785)[3]90 Shore A nominal grade designation; do not compare numerically with Shore D or Rockwell.[6]
Fatigue / repeated-flex resistance1–5Excellent — living hinges viable[1]Not documented
Elasticity / flexibility1–5Semi-flexible[7]Not documented
Wear resistance & frictionWear factor 200e-10 in3*min/(ft*lb*h) on extruded PA66 stock (ASTM D3702); Ensinger lists very good slide and wear properties[3]Not documented
Thermal Properties
HDT at 0.45 MPa°C232 on extruded PA66 stock (ASTM D648 at 66 psi; converted from 450 °F)[3]Not documented
HDT at 1.8 MPa°C90 on extruded PA66 stock (ASTM D648 at 264 psi; converted from 194 °F) — the gap to the 0.45 MPa figure is the widest in the dataset[3]Not documented
Melting point / Vicat°C255 melting on extruded PA66 stock (ASTM D2133; converted from 491 °F)[3]110 °C Vicat softening (GB/T 1633, 120 °C/h, 10 N); not HDT or a continuous-use rating.[2]
Continuous service temperature°C85 long term and 149 short term on extruded PA66 stock (converted from 185 °F and 300 °F)[3]Not documented
Thermal expansion (CTE)µm/m·K81.0 (extruded PA66 stock, ASTM D696; source states 4.5e-5 in/in/°F)[3]Not documented
Flammability / UL 94UL 94 V-2 on extruded PA66 stock[3]Not documented
Environment & Chemical
Electrical & ESD propertiesVolume resistance 1e15 ohm-cm and dielectric constant 4 on extruded PA66 stock (ASTM D257, D150)[3]Not documented
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised[10]Not documented
VOC emission rateµg/minUp to 180 caprolactam, the dominant VOC from nylon; total VOC reached nearly 200 µg/min, the highest of the nine filaments tested[10]Not documented
Ultrafine-particle emission rateparticles/min≈2 × 10⁸ median — low for ultrafine particles despite the highest VOC mass of any filament tested[10]Not documented
Hazardous species emittedCaprolactam, at up to 180 µg/min from nylon filament — the largest single-VOC emission rate measured in the study[10]Not documented
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[10]Not documented
Solvents & Solubility
Soluble inDissolved at 23 °C by formic acid above ~80 %, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — laboratory reagents.[11]Not documented
Softened or crazed byZinc chloride solutions stress-crack it — 10 % marginal, 37 % not resistant; alcoholic calcium chloride dissolves it.[11]Not documented
Solvent welding & smoothing agentNone — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[11]Not documented

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
  2. eSUN PEBA-90A Technical Data Sheet v1.0 (Aug 2025), checked 2026-10-17 eSUN · 2025-08 · tds
  3. TECAMID 66 natural (PA66) — stock shape properties Ensinger · 2026-08 · tds
  4. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  5. Polymaker product catalogue Polymaker · 2026-08 · vendor
  6. eSUN PEBA-90A official product page: 1 kg price and product identity eSUN · 2026-10-17 · vendor
  7. Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
  8. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  9. PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
  10. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  11. Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds