3D Printing Info

Filament comparison

PA6 vs PEKK

Compare printing settings, strength, heat resistance, dated prices and sources.

PA6 (Nylon 6) guidePEKK guide

2 selected · all documented properties

Open these two in the interactive comparisonMore PA6 comparisonsMore PEKK comparisons
PA6 vs PEKK — documented properties and sources
PropertyPA6 (Nylon 6)PAPEKKHIGHTEMP
Market snapshot
Listing priceUSD/kg; dated snapshots$104.00/kg median; $38.99–$136.00/kg across 3 dated product listings$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings
Identity & Market
Base polymer / chemistryPolyamide 6, ring-opened from caprolactam — the most hygroscopic of the common nylons[1][2]Polyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[3][4]
Densityg/cm³1.06 (ISO 1183, 3DXTech iOn PA6 alloy)[5]1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[4][3]
Typical priceUSD/kg1 kg-equivalent spools span 39–136; the middle of the market is about 104, though budget unfilled PA6 has now arrived at 39[6][7]1 kg-equivalent spools cluster near 550[6][8][9]
Price range across brandsUSD/kg39–136 across brands; YXPOLYER 39, 3DXTech iOn Nylon 6 Alloy 104, WearX Nylon 6 136. Unfilled PA6 filament stays rare — most PA6 reaches the market glass- or carbon-filled[6][7]333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[6][8][9][10][11]
Market availability1–5Niche, a handful of specialist brands[6]Niche, a handful of specialist brands[6][8][9]
Spool sizes & diameters1.75 and 2.85 mm; 500 g and 750 g spools[6]1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[6][8][4]
Typical applicationsWear parts, bushings and gears where PA6's toughness and abrasion resistance matter more than dimensional stability[1]Aerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[3][4]
Printing Parameters
Nozzle temperature°C220–260 (Polymaker); 225–265 (Simplify3D)[1][12]Not documented
Bed temperature°C70–100 (Polymaker); 70–90 (Simplify3D)[1][12]140 (3DXTech CarbonX PEKK-A CF15)[3]
Enclosure / chamber requirement1–5Enclosure required (passive)[13][1]Actively heated chamber required[14][15]
Part cooling fanPart cooling fan not required (Simplify3D)[12]Not documented
Bed surface & adhesion aidPEI sheet with a glue stick, or a dedicated adhesive such as Magigoo[12][1]Not documented
Bed-adhesion difficulty1–5Needs a specific surface plus adhesive[12][1]Not documented
Stringing / oozing tendency1–5Moderate — retraction tuning needed[1]Not documented
Overall printing difficulty1–5Advanced — enclosure, hardware upgrades, tuning; the filament must be kept dry throughout the print[1][16]Expert / industrial hardware only[14][15]
Hardware Wear & Reliability
Nozzle hardness required1–4Brass fine indefinitely for unfilled grades[1]Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[3][4]
Abrasiveness1–5Non-abrasive when unfilled[1]Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[3][4]
Nozzle clog risk1–5Very high — frequent jams without careful setup; wet nylon pops and cracks in the melt[17][16]Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[18]
Heat-creep / jam sensitivity1–5Moderate — good heatbreak cooling needed[12]Not documented
Hotend requirementMay require an all-metal hot end (Simplify3D)[12]Not documented
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Very high (>2 %) — Polymaker groups nylon with PVA as the most moisture-prone class, and its own PA6-based composites reach 2.35–3.33 % equilibrium[16][19]Not documented
Drying temperature & time100 °C for 8 h (Polymaker CoPA); storage below 20 % RH[13][20]Not documented
Symptoms when wetPopping and cracking during extrusion, then defects that Polymaker describes as very hard to diagnose[17]Not documented
Effect of moisture on strengthMeasured dry against wet on printed specimens at 6.16 % moisture (Polymaker CoPA): tensile 78.0 → 34.3 MPa, Young's modulus 2703 → 724 MPa, flexural strength 109.8 → 22.6 MPa, while notched Charpy rises 6.9 → 27.7 kJ/m² and elongation 12.7 → 13.2 %[13][17]No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[18]
Storage requirementSealed below 20 % RH with desiccant; Polymaker says nylon often needs to stay in a dryer while printing[20][16]Not documented
Hydrolysis at melt temperaturePolymaker requires a 100 °C dry for 8 h and storage below 20 % RH; no molecular-weight loss figure is published, and the published wet data is conditioning rather than melt hydrolysis[13][20]Not documented
Mechanical Properties
Tensile strength (XY)MPa62 at break (printed XY, ISO 527, 3DXTech iOn PA6 alloy); Stratasys FDM Nylon 6 conditioned to 20 °C / 50 % RH gives 67.6 ultimate and 49.3 at yield printed XZ (ASTM D638)[5][21]86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[4][3]
Young's modulusMPa2110 (printed XY, ISO 527, 3DXTech iOn PA6 alloy); Stratasys FDM Nylon 6 conditioned gives 2232 printed XZ and 1817 ZX (ASTM D638)[5][21]2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[4][3]
Elongation at break%9 at break (printed XY, ISO 527, 3DXTech iOn PA6 alloy); Stratasys FDM Nylon 6 conditioned gives 38 printed XZ against 3.2 in ZX (ASTM D638)[5][21]6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[4][3]
Flexural strengthMPa78 (printed XY, ISO 178, 3DXTech iOn PA6 alloy); Stratasys FDM Nylon 6 conditioned gives 97.2 printed XZ and 82 ZX (ASTM D790)[5][21]136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[4][3]
Flexural modulusMPa2200 (printed XY, ISO 178, 3DXTech iOn PA6 alloy); Stratasys FDM Nylon 6 conditioned gives 2196 printed XZ and 1879 ZX (ASTM D790)[5][21]3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[4][3]
Other impact dataIzod notched 106 J/m printed XZ against 43 J/m in ZX; unnotched 2873 against 192 J/m (Stratasys FDM Nylon 6, conditioned 20 °C / 50 % RH, ASTM D256 Method A) — a 15x anisotropy unnotched[21]Izod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[4]
Layer adhesion / Z tensileMPa36.5 ultimate and 28.9 at yield printed ZX (Stratasys FDM Nylon 6, conditioned 20 °C / 50 % RH, ASTM D638)[21]50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[4][22]
Brittleness1–5Tough — absorbs impact, yields before breaking[1]Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[4][3]
Hardness (scale-specific)Shore A / Shore D / RockwellShore D 86 and Rockwell 85 (108) — the source does not name the scales on extruded unfilled PA66 stock (ASTM D2240, D785); no figure is published for a PA6 filament[23]Not documented
Creep resistance / sustained load1–5Moderate[1]Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[4]
Fatigue / repeated-flex resistance1–5Excellent — living hinges viable[1]Not documented
Elasticity / flexibility1–5Semi-flexible[17]Rigid[3]
Z strength as % of XY%54 (Stratasys FDM Nylon 6 conditioned, ZX against XZ ultimate tensile, ASTM D638); 59 on the yield figures[21]56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[4][22]
Wear resistance & friction3DXTech sells a dedicated wear-resistant PA6 grade; abrasion resistance is the usual reason to choose PA6 over PA12[6]Not documented
Thermal Properties
HDT at 0.45 MPa°CNot documented158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[4][3]
HDT at 1.8 MPa°C93 (Stratasys FDM Nylon 6, conditioned, ASTM D648 at 264 psi)[21]156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[4]
Glass transition (Tg)°C105 (DSC, 3DXTech iOn PA6 alloy)[5]156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[4][3]
Melting point / Vicat°CNot documented300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[4][3]
Thermal expansion (CTE)µm/m·K81.0 on extruded unfilled PA66 stock (ASTM D696; source states 4.5e-5 in/in/°F); no figure is published for a PA6 filament, and PA6 and PA66 expand almost identically[23]36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[4][22]
Flammability / UL 94Flammable; no UL 94 rating published for the unfilled filament grades surveyed[5]Not documented
Environment & Chemical
UV resistance1–5Months outdoors before embrittlement — unstabilised polyamide yellows and chalks under UV[1]Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[4]
Chemical resistanceWithstands oils, fuels and alkalis — the usual reason to choose a polyamide[1]Not documented
Water / humidity resistance in service1–5Absorbs water, properties shift — a conditioned part is measurably softer and larger than the same part dry[17][13]Not documented
Food contactPolymaker notes medical-grade variants exist, but standard filament is not food-contact certified[1]Not documented
Biodegradability / compostabilityNot biodegradable[1]Not documented
RecyclabilityMechanically recyclable but not accepted in household plastic collection[1]Not documented
Electrical & ESD propertiesNot documentedUnfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[4][3][22]
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised[2]Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[2]
VOC emission rateµg/minUp to 180 caprolactam, the dominant VOC from nylon; total VOC reached nearly 200 µg/min, the highest of the nine filaments tested[2]Not documented
Ultrafine-particle emission rateparticles/min≈2 × 10⁸ median — low for ultrafine particles despite the highest VOC mass of any filament tested[2]Not documented
Hazardous species emittedCaprolactam, at up to 180 µg/min from nylon filament — the largest single-VOC emission rate measured in the study[2]Not documented
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[2]Ventilated room or enclosure recommended[2]
Dust & fibre handling hazardNot documentedCarbon fibre is bound in the matrix; sanding dust should not be inhaled[3]
Post-Processing
Sanding & machiningSands poorly — the toughness makes it gum rather than powder[12]Not documented
Gluing & solvent weldingCyanoacrylate; no common solvent welds polyamide[12]Not documented
Vapour / chemical smoothingNo practical vapour smoothing[12]Not documented
Support material pairingPVA dissolves cleanly against nylon; Polymaker sells a break-away PolySupport for PA12[12]Not documented
Dimensional accuracy & detailParts grow as they absorb moisture after printing; Polymaker declines to publish a standard dimensional allowance because it depends on geometry and infill[17]Not documented
Solvents & Solubility
Soluble inDissolved at 23 °C by formic acid above ~50 %, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — laboratory reagents.[24]Concentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[25][26]
Softened or crazed byZinc chloride solutions stress-crack it — 10 % marginal, 37 % not resistant; alcoholic calcium chloride dissolves it.[24]Concentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[25]
Solvent welding & smoothing agentNone — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[24]None — no solvent softens a polyaryletherketone.[25]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
  2. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  3. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  4. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  5. iOn PA6-based Nylon Alloy Technical Data Sheet v2.0 3DXTech · 2026-08 · tds
  6. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  7. YXPOLYER PA6 Black 1 kg — product page YXPOLYER · 2026-08 · vendor
  8. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  9. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  10. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  11. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  12. Nylon — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  13. PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
  14. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  15. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  16. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  17. Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
  18. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  19. Fiberon PA612-CF15 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
  20. PolyMide CoPA — Technical Data Sheet page Polymaker Wiki · 2026-08 · tds
  21. FDM Nylon 6 — data sheet (conditioned 20 °C / 50 % RH) Stratasys · 2017-11 · tds
  22. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  23. TECAMID 66 natural (PA66) — stock shape properties Ensinger · 2026-08 · tds
  24. Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
  25. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  26. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper