3D Printing Info

Filament comparison

PA12 vs PPS-CF

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PA12 vs PPS-CF — documented properties and sources
PropertyPA12 (Nylon 12)PAFibre-reinforced PPSHIGHTEMP
Market snapshot
Listing priceUSD/kg; dated snapshots$64.33/kg median; $36.00–$170.67/kg across 3 dated product listings$139.98/kg median; $119.98–$174.17/kg across 5 dated product listings
Identity & Market
Base polymer / chemistryPolyamide 12 — the longest-chain common nylon, with the fewest amide groups per unit mass and so the least moisture uptake[1][2]Carbon-fibre reinforced PPS — Polymaker's Fiberon grade is nominally 10 wt%[3]
Densityg/cm³1.01 specific gravity (Stratasys FDM Nylon 12, ASTM D792)[4]1.29 (Fiberon PPS-CF10) and 1.36 (Fiberon PPS-GF20), ISO 1183[3][5]
Typical priceUSD/kg1 kg-equivalent spools span 36–171; the middle of the market is about 64[6][7]1 kg-equivalent spools span 93–174; the middle of the market is about 140[8][9][10][11]
Price range across brandsUSD/kg36–171 across brands; IEMAI 3D 36, Fiberlogy 64 at 3DJake, 3DXTech AmideX Nylon 12 171[6][12][7]93-174 across brands and formats; Polymaker Fiberon PPS-GF20 93 at 3 kg, IEMAI 3D CF-PPS 131 at 750 g, LEHVOSS Luvocom 3F PPS CF 9938 164 at 2.3 kg, Bambu Lab PPS-CF 174 at 750 g[8][9][10][11]
Market availability1–5Available from several mainstream brands[6][12]Available from several mainstream brands[8][9][10]
Spool sizes & diameters1.75 and 2.85 mm; 750 g and 1 kg spools[12][6]1.75 mm; 0.5 kg spools[8]
Typical applicationsDimensionally stable functional parts, ducting and living hinges where PA6 would move too much with humidity[1][13]Chemical and automotive parts needing PPS chemistry with structural stiffness[3]
Printing Parameters
Nozzle temperature°C260–290 (Extrudr DURAPRO PA12)[14]Not documented
Bed temperature°C110 (Extrudr DURAPRO PA12)[14]Not documented
Enclosure / chamber requirement1–5Enclosure required (passive)[1]Enclosure required (passive) — Polymaker states its Fiberon PPS-CF10 needs no heated chamber, unlike the unfilled sulfones and PAEKs[3]
Part cooling fanPart cooling fan not required (Simplify3D)[15]Not documented
Bed surface & adhesion aidPEI sheet with a glue stick, or a dedicated adhesive such as Magigoo[15][1]Not documented
Maximum volumetric flow (mm³/s; see test conditions)mm³/s12 at Extrudr's 150 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[14][16]Not documented
Bed-adhesion difficulty1–5Needs a specific surface plus adhesive[15][1]Not documented
Stringing / oozing tendency1–5Moderate — retraction tuning needed[1]Not documented
Overall printing difficulty1–5Advanced — enclosure, hardware upgrades, tuning[1]Expert / industrial hardware only[3]
Hardware Wear & Reliability
Nozzle hardness required1–4Brass fine indefinitely for unfilled grades[1]Hardened steel required[3]
Abrasiveness1–5Non-abrasive when unfilled[1]Highly abrasive — standard CF composite[3]
Nozzle clog risk1–5High — jams from moisture, heat creep or particles[13][17]High — jams from moisture, heat creep or particles; Polymaker specifies hardened steel or ruby nozzles for carbon-filled PPS and Prusa lists composites as a higher clogging risk[18][19]
Heat-creep / jam sensitivity1–5Moderate — good heatbreak cooling needed[15]Not documented
Hotend requirementMay require an all-metal hot end (Simplify3D)[15]Not documented
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5High (0.8–2 %) — Polymaker's PA12-CF10 reaches 1.5 % equilibrium against 3.33 % for its PA6-GF25, and Polymaker developed the PA12 grade specifically for lower moisture sensitivity[2][13]Low (0.1–0.3 %) — 0.225 % equilibrium for Fiberon PPS-CF10 and 0.11 % for PPS-GF20[3][5]
Equilibrium moisture content at ~50 % RH%Not documented0.225 equilibrium (Fiberon PPS-CF10); 0.11 (PPS-GF20)[3][5]
Drying temperature & time60–80 °C for 8–12 h (Extrudr DURAPRO PA12); 100 °C for 8 h (Polymaker CoPA)[14][20]Not documented
Symptoms when wetPopping and cracking during extrusion, then hard-to-diagnose defects[13]Not documented
Effect of moisture on strengthPolymaker states its PA12 grade changes little between wet and dry, unlike its PA6-based materials; the CoPA dry-to-wet reference shows what the PA6-type response looks like[13][20]No dry-versus-conditioned figures are published; equilibrium uptake is 0.225 % and Polymaker specifies a 100 °C, 10 h dry[3]
Storage requirementSealed below 20 % RH with desiccant[17]Not documented
Hydrolysis at melt temperaturePolymaker requires a 100 °C dry for 8 h and storage below 20 % RH; no molecular-weight loss figure is published, and the published wet data is conditioning rather than melt hydrolysis[20][21]Not documented
Mechanical Properties
Tensile strength (XY)MPa49.3 at yield and 33.4 at break printed XZ (Stratasys FDM Nylon 12, ASTM D638)[4]59.4 ± 1.3 (PPS-CF10) and 64.1 ± 2.1 (PPS-GF20) printed XY, ISO 527[3][5]
Young's modulusMPa1510 printed XZ and 1250 ZX (Stratasys FDM Nylon 12, ASTM D638)[4]5446.7 ± 149.0 (PPS-CF10) and 4552.0 ± 54.6 (PPS-GF20) printed XY, ISO 527[3][5]
Elongation at break%30 at break printed XZ against 6.5 in ZX (Stratasys FDM Nylon 12, ASTM D638)[4]1.4 ± 0.1 (PPS-CF10) and 2.0 ± 0.2 (PPS-GF20) printed XY, ISO 527 — the lowest elongation in the dataset[3][5]
Charpy impact, notchedkJ/m²11 at +23 °C and 6.0 at -30 °C (Extrudr DuraPro PA12, ISO 179/1eA); unnotched does not break[14]5.3 ± 0.2 printed XY for PPS-CF10 and 7.3 ± 0.2 for PPS-GF20, ISO 179 notched[3][5]
Other impact dataIzod notched 138 J/m printed XZ against 71.0 J/m in ZX (Stratasys FDM Nylon 12, ASTM D256)[4]Not documented
Layer adhesion / Z tensileMPa41.8 at yield and 41.2 at break printed ZX (Stratasys FDM Nylon 12, ASTM D638) — higher than the XZ break figure, because XZ specimens draw and neck first[4]32.0 ± 5.1 (PPS-CF10) and 22.9 ± 0.8 (PPS-GF20) printed Z, ISO 527[3][5]
Brittleness1–5Tough — absorbs impact, yields before breaking[1]Very brittle — cracks or shatters easily; elongation at break 1.4 %[3]
Hardness (scale-specific)Shore A / Shore D / RockwellNot documentedRockwell 105 (and R124) on extruded unfilled PPS stock (ASTM D785); no figure is published for a fibre-filled PPS filament[22]
Creep resistance / sustained load1–5Moderate — the long-chain polyamides hold load better than PLA but below PC[1]Excellent — holds load for years. Ensinger lists high creep resistance for unfilled PPS stock and Spectrum states creep resistance is unchanged under continuous load at high temperature; the fibre raises heat deflection to 252 °C at 0.45 MPa[22][23][3]
Fatigue / repeated-flex resistance1–5Excellent — living hinges viable. Stratasys sells FDM Nylon 12 specifically for repetitive-flex parts such as snap-fit clips and press-fit inserts on the strength of its fatigue properties[1][4]Not documented
Elasticity / flexibility1–5Semi-flexible[13]Rigid[3]
Z strength as % of XY%85 (Stratasys FDM Nylon 12, ZX against XZ tensile yield, ASTM D638) — one of the least anisotropic unfilled filaments measured[4]54 (PPS-CF10) and 36 (PPS-GF20), printed[3][5]
Thermal Properties
HDT at 0.45 MPa°C94.7 printed XY and 91.9 in XZ/ZX (Stratasys FDM Nylon 12, ASTM D648 at 66 psi)[4]252.5 (PPS-CF10) and 236.3 (PPS-GF20), printed, ISO 75 at 0.45 MPa[3][5]
HDT at 1.8 MPa°C84.3 printed XY and 75.3 in XZ/ZX (Stratasys FDM Nylon 12, ASTM D648 at 264 psi)[4]133 (PPS-CF10) and 125.8 (PPS-GF20), printed, ISO 75 at 1.8 MPa[3][5]
Glass transition (Tg)°C34.0 (Stratasys FDM Nylon 12, ASTM D7426 inflection point)[4]97.7 (PPS-CF10) and 95.0 (PPS-GF20), DSC[3][5]
Melting point / Vicat°CVicat A 142 (Extrudr DURAPRO PA12, ISO 306)[14]279.7 (PPS-CF10) and 279.6 (PPS-GF20) melting, DSC; Vicat 267.5 and 272.5 (ISO 306)[3][5]
Continuous service temperature°CBounded by a Vicat softening point of 142 °C (Extrudr DURAPRO PA12); no loaded-bar service figure is published[14]170 long-term service on extruded PPS stock, converted from 338 °F; no figure published for the carbon-filled grade[22]
Thermal expansion (CTE)µm/m·K84-103 printed (Stratasys FDM Nylon 12, ASTM E831: 84.4 in XY and 85.6 in XZ/ZX over -50 to 10 °C, 89.1 over 10-45 °C, 98.2 over 45-70 °C); Extrudr quotes 100 for DURAPRO PA12 (ISO 11359-2)[14][4]Not documented
Flammability / UL 94Flammable; no UL 94 rating published for the unfilled grades surveyed[14]Not documented
Environment & Chemical
UV resistance1–5Months outdoors before embrittlement[1]Not documented
Chemical resistanceWithstands oils, fuels and alkalis[1]Outstanding — PPS resists essentially all solvents below 200 °C[18]
Water / humidity resistance in service1–5Good — minor absorption; the least moisture-sensitive of the common nylons[13]Not documented
Food contactNot food-contact certified as filament[1]Not documented
Biodegradability / compostabilityNot biodegradable[1]Not documented
RecyclabilityMechanically recyclable but not accepted in household plastic collection[1]Not documented
Electrical & ESD propertiesNot documentedSurface resistivity above 10¹² ohm — insulating (ANSI/ESD S11.11)[3][5]
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised[24]Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[24]
VOC emission rateµg/minUp to 180 caprolactam, the dominant VOC from nylon; total VOC reached nearly 200 µg/min, the highest of the nine filaments tested[24]Not documented
Ultrafine-particle emission rateparticles/min≈2 × 10⁸ median — low for ultrafine particles despite the highest VOC mass of any filament tested[24]Not documented
Hazardous species emittedCaprolactam, at up to 180 µg/min from nylon filament — the largest single-VOC emission rate measured in the study[24]Not documented
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[24]Ventilated room or enclosure recommended[24]
Dust & fibre handling hazardNot documentedFibre is bound in the matrix; sanding dust should not be inhaled[3]
Post-Processing
Sanding & machiningSands poorly — gums rather than powders[15]Not documented
Gluing & solvent weldingCyanoacrylate; no common solvent welds polyamide[15]Not documented
Vapour / chemical smoothingNo practical vapour smoothing[15]Not documented
Support material pairingPolymaker sells a break-away PolySupport matched to PA12[15]Not documented
Dimensional accuracy & detailHolds dimensions better than PA6 after conditioning — Polymaker singles its PA12 grade out on exactly this point[13]Not documented
Solvents & Solubility
Soluble inDissolved at 23 °C by formic acid, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — all laboratory reagents.[25][26]None — PPS does not dissolve in any known solvent below 200 °C.[27][26]
Softened or crazed byNot resistant to 10 % formic acid, phenol, chloroform or dichloromethane (Ensinger); zinc chloride stress-cracks nylon.[26][25]Nothing at 23 °C; Ensinger rates it only conditionally resistant to benzene, dichloromethane, toluene and pyridine.[26]
Solvent welding & smoothing agentNone — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[25]None — no solvent welds or smooths PPS.[27]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
  2. Fiberon PA612-CF15 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
  3. Fiberon PPS-CF10 Technical Data Sheet V1.1 Polymaker · 2025-07 · tds
  4. FDM Nylon 12 — Material Data Sheet Stratasys · 2021-09 · tds
  5. Fiberon PPS-GF20 Technical Data Sheet V1.1 Polymaker · 2025-07 · tds
  6. Nylon PA12 — product listing 3DJake International · 2026-08 · vendor
  7. IEMAI 3D PA12 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  8. Polymaker product catalogue Polymaker · 2026-08 · vendor
  9. Bambu Lab PPS-CF Black, spool (750 g) 3DJAKE · 2026-08 · vendor
  10. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  11. IEMAI 3D CF-PPS 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  12. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  13. Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
  14. Extrudr Product Catalogue (DURAPRO PA12 data block) Extrudr · 2025-03 · tds
  15. Nylon — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  16. Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
  17. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  18. PPS — material basics Polymaker Wiki · 2026-08 · doc
  19. Composite materials filled with carbon, kevlar or glass Prusa Knowledge Base · 2026-08 · doc
  20. PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
  21. PolyMide CoPA — Technical Data Sheet page Polymaker Wiki · 2026-08 · tds
  22. TECATRON natural (PPS) — stock shape properties Ensinger · 2026-08 · tds
  23. Spectrum PPS AM230 Technical Data Sheet Spectrum Filaments · 2022-04 · tds
  24. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  25. Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
  26. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  27. PPS (Polyphenylene sulfide) — Knowledge Base Prusa Research · 2026-08 · doc