3D Printing Info

Filament comparison

PA12-GF vs PPSU

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PA12-GF vs PPSU — documented properties and sources
PropertyGlass-fibre PA12 (PA12-GF)PAPPSUHIGHTEMP
Market snapshot
Listing priceUSD/kg; dated snapshots$130.67/kg median; $46.00–$140.18/kg across 3 dated product listings$337.40/kg median; $223.00–$732.56/kg across 4 dated product listings
Identity & Market
Base polymer / chemistryPA12 reinforced with chopped glass fibre — 3DXTech's grade is nominally 30 wt%[1]Polyphenylsulfone — an amorphous high-temperature sulfone polymer[2]
Densityg/cm³1.23 (ISO 1183)[1]1.28 (ISO 1183, 3DXTech; ASTM D792, Stratasys PPSF)[2][3]
Typical priceUSD/kg1 kg-equivalent spools span 46–140; the middle of the market is about 88[4][5][6]1 kg-equivalent spools span 223–733; the middle of the market is about 425[4][7][8][9]
Price range across brandsUSD/kg46–140 across brands; IEMAI 3D 46, 3DXTech 131 at 750 g and 130 at 2 kg, PrimaCreator NylonPower Glass Fiber 140 at 500 g[4][5][6]223-733 across brands; IEMAI 3D 223 at 1 kg, 3DXTech ThermaX PPSU 250 at 500 g, 3D4Makers 425 at 750 g, Kimya PPSU-S 733 at 500 g[4][7][8][9]
Market availability1–5Available from several mainstream brands[4][5]Niche, a handful of specialist brands[4][7][8]
Spool sizes & diameters1.75 and 2.85 mm; 0.5, 0.75 and 2 kg spools[4][6]1.75 and 2.85 mm; 200 g to 750 g spools[4][7][8]
Typical applicationsStiff, humidity-stable structural parts — the glass gives the modulus, the PA12 matrix limits the moisture drift[1][10]Steam-sterilisable medical and dental tooling, and aircraft interior parts[2]
Printing Parameters
Bed temperature°CNot documented130–150 (3DXTech)[2]
Enclosure / chamber requirement1–5Enclosure required (passive)[11]Actively heated chamber required[12][13]
Bed surface & adhesion aidPEI sheet with a glue stick, or a dedicated adhesive such as Magigoo[14][11]Not documented
Warping tendency1–5Not documentedSevere — heated chamber needed[12]
Bed-adhesion difficulty1–5Needs a specific surface plus adhesive[14]Not documented
Stringing / oozing tendency1–5Moderate — retraction tuning needed[11]Not documented
Overall printing difficulty1–5Advanced — enclosure, hardware upgrades, tuning[11]Expert / industrial hardware only[12][13]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required — no nozzle-life figure is published for a PA12-GF30 grade; Polymaker measures about 9 h of brass nozzle life on its comparable fibre-filled nylons[15]Brass fine indefinitely for unfilled grades, but brass softens near these nozzle temperatures — hardened or plated hot ends are the norm[12]
Abrasiveness1–5Highly abrasive — standard GF composite[15]Non-abrasive when unfilled[2]
Nozzle clog risk1–5High — jams from moisture, heat creep or particles[16]Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[17]
Heat-creep / jam sensitivity1–5Moderate — good heatbreak cooling needed[14]Not documented
Hotend requirementMay require an all-metal hot end (Simplify3D)[14]Not documented
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5High (0.8–2 %) — the PA12 matrix takes up far less than PA6, on the evidence of Polymaker's 1.5 % for PA12-CF10 against 3.33 % for PA6-GF25[18][19]Not documented
Equilibrium moisture content at ~50 % RH%Not documented0.37 in 24 h and 1.1 at saturation on extruded stock (ASTM D570)[20]
Effect of moisture on strengthPolymaker's PA12 grades change little between wet and dry, unlike PA6; the CoPA dry-to-wet blocks show the PA6-type response[10][21]No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[17]
Storage requirementSealed below 20 % RH with desiccant[16]Not documented
Hydrolysis at melt temperaturePolymaker specifies an 80–100 °C dry and storage below 20 % RH; no molecular-weight loss figure is published, and the wet data it does publish is conditioning rather than melt hydrolysis[15][21]Not documented
Mechanical Properties
Tensile strength (XY)MPa82 at break (printed XY, ISO 527)[1]55 (printed XY, ISO 527, 3DXTech) and 55 (printed on side long edge, ASTM D638, Stratasys PPSF); 79 at yield on extruded stock[2][3][20]
Young's modulusMPa7800 (printed XY, ISO 527)[1]2100 (printed, ASTM D638, Stratasys PPSF) and 2310 (printed XY, ISO 527, 3DXTech); 2344 on extruded stock[2][3][20]
Elongation at break%4.5 at break (printed XY, ISO 527) — nearly double the 2.4 % of Polymaker's PA6-GF25[1][19]3 (printed, ISO 527 and ASTM D638) against 60 on extruded stock — printing costs PPSU almost all of its ductility[2][3][20]
Flexural strengthMPa94 (printed XY, ISO 178)[1]110 (printed, ISO 178 and ASTM D790, 3DXTech and Stratasys PPSF agree); 91 on extruded stock[2][3][20]
Flexural modulusMPa7550 (printed XY, ISO 178)[1]2200 (printed, ASTM D790, Stratasys PPSF) and 2215 (printed XY, ISO 178, 3DXTech)[2][3]
Other impact dataNot documentedIzod notched 58.7 J/m and unnotched 165.5 J/m (printed, ASTM D256 Method A, Stratasys PPSF); 160 J/m notched on extruded stock[3][20]
Brittleness1–5Moderate[1]Brittle — snaps with little warning[2]
Hardness (scale-specific)Shore A / Shore D / RockwellRockwell M88 / R117 on extruded PA66-GF30 stock (ASTM D785); no figure is published for a glass-fibre PA12 filament[22]Rockwell M86 on printed PPSF (ASTM D785, Stratasys); M96 on extruded PPSU stock (and an unlabelled 123)[3][20]
Creep resistance / sustained load1–5Good. Ensinger lists high creep resistance for extruded PA66-GF30 stock, and the PA12 matrix absorbs far less water than PA6, so a PA12-GF part holds load better in a humid environment[22][11]Good. Printed PPSF holds 189 °C heat deflection at 1.8 MPa (ASTM D648) and extruded stock is rated 149 °C long-term service, but Ensinger does not claim the creep resistance it claims for PSU and PPS[3][20]
Fatigue / repeated-flex resistance1–5Good. Ensinger lists high fatigue strength as a headline property of extruded PA66-GF30 stock[22]Not documented
Elasticity / flexibility1–5Rigid[1]Rigid[2]
Thermal Properties
HDT at 0.45 MPa°CNot documented190 (printed XY, ISO 75 at 0.45 MPa, 3DXTech)[2]
HDT at 1.8 MPa°CNot documented189 (printed, ASTM D648 at 264 psi, Stratasys PPSF); 207 on extruded stock, converted from 405 °F[3][20]
Glass transition (Tg)°CNot documented230 (DSC) — the highest glass transition in the dataset[2]
Continuous service temperature°CNot documented149 long-term service on extruded PPSU stock, converted from 300 °F[20]
Thermal expansion (CTE)µm/m·K48.6 on extruded PA66-GF30 stock (ASTM D696; source states 2.7e-5 in/in/°F) — no figure is published for a glass-fibre PA12 filament[22]55.0 (printed PPSF, ASTM D696; source states 5.5e-5 mm/mm/°C) and 55.8 on extruded stock (ASTM D696, from 3.1e-5 in/in/°F)[3][20]
Flammability / UL 94Flammable; no UL 94 rating published for the grades surveyed[15]UL 94 V-0 at 1.5 mm, rated on the base resin[2]
Environment & Chemical
UV resistance1–5Months outdoors before embrittlement — unstabilised polyamide yellows under UV[11]Not documented
Chemical resistanceWithstands oils, fuels and alkalis[11]Withstands repeated steam autoclaving, the usual reason to choose PPSU over PSU; Stratasys also lists PPSF as passing 24 h stress-crack exposure to antifreeze, petrol, motor oil, power-steering, transmission and washer fluid at 23 °C and 100 °C[2][3]
Water / humidity resistance in service1–5Good — minor absorption relative to PA6-based composites[10]Not documented
Food contactNot food-contact certified as filament[11]Not documented
Biodegradability / compostabilityNot biodegradable[11]Not documented
RecyclabilityNot accepted in household plastic collection[11]Not documented
Electrical & ESD propertiesSurface resistance above 10¹³ ohm/sq — insulating (ASTM D257)[1]Volume resistivity 5e13 to 1.5e14 ohm-cm and dielectric strength 80-290 V/mil on printed PPSF (ASTM D257, D149)[3]
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised[23]Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[23]
VOC emission rateµg/minUp to 180 caprolactam, the dominant VOC from nylon and the largest single-VOC rate in the study[23]Not documented
Ultrafine-particle emission rateparticles/min≈2 × 10⁸ median for nylon — low for particles despite the highest VOC mass measured[23]Not documented
Hazardous species emittedCaprolactam, at up to 180 µg/min from nylon filament[23]Not documented
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[23]Ventilated room or enclosure recommended[23]
Dust & fibre handling hazardGlass fibre is bound in the matrix; avoid inhaling sanding dust[1]Not documented
Post-Processing
Sanding & machiningSands poorly — gums rather than powders[14]Not documented
Gluing & solvent weldingCyanoacrylate; no common solvent welds polyamide[14]Not documented
Vapour / chemical smoothingNo practical vapour smoothing[14]Not documented
Solvents & Solubility
Soluble inFormic acid, phenol, m-cresol and hexafluoroisopropanol dissolve the matrix at 23 °C, leaving the fibre; laboratory reagents.[24]Dichloromethane dissolves it at 23 °C at every stress level; acetone solvates and softens unstressed PPSU (Solvay ESCR).[25]
Softened or crazed byZinc chloride solutions stress-crack the nylon matrix, alcoholic calcium chloride dissolves it, mineral acids attack it.[24]MEK ruptures stressed parts and toluene crazes them above 13.8 MPa; glass-filled grades survive where unfilled craze.[25]
Solvent welding & smoothing agentNone — nylon's only solvents (formic acid, phenol, HFIP) degrade the part, and the fibre blocks surface flow anyway.[24]Dichloromethane cements PPSU and NMP softens residual resin; both are laboratory reagents, not workshop stock.[25]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. FibreX PA12-GF30 Technical Data Sheet v1.0 3DXTech · 2026-08 · tds
  2. ThermaX PPSU Technical Data Sheet v3 3DXTech · 2026-08 · tds
  3. PPSF (polyphenylsulfone) — FDM Data Sheet Stratasys · 2018-06 · tds
  4. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  5. IEMAI 3D GF-PA12 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  6. PrimaCreator SELECT NylonPower Glass Fiber product page PrimaCreator · 2026-08 · vendor
  7. Kimya PPSU-S Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  8. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  9. IEMAI 3D PPSU 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  10. Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
  11. PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
  12. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  13. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  14. Nylon — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  15. Fiberon PA6-CF20 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
  16. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  17. THERMAX PPSU — product page (print recommendations) 3DXTech · 2026-08 · doc
  18. Fiberon PA12-CF10 Technical Data Sheet V1.1 Polymaker · 2025-02 · tds
  19. Fiberon PA6-GF25 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
  20. TECASON P black (PPSU) — stock shape properties Ensinger · 2026-08 · tds
  21. PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
  22. TECAMID 66 GF30 black (PA66-GF30) — stock shape properties Ensinger · 2026-08 · tds
  23. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  24. Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
  25. Radel PPSU, Veradel PESU, Acudel modified PPSU Design Guide — environmental stress cracking tables Solvay Specialty Polymers · 2026-08 · tds