Filament comparison
PA12-GF vs PPSU
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | Glass-fibre PA12 (PA12-GF)PA | PPSUHIGHTEMP |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $130.67/kg median; $46.00–$140.18/kg across 3 dated product listings | $337.40/kg median; $223.00–$732.56/kg across 4 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | PA12 reinforced with chopped glass fibre — 3DXTech's grade is nominally 30 wt%[1] | Polyphenylsulfone — an amorphous high-temperature sulfone polymer[2] |
| Densityg/cm³ | 1.23 (ISO 1183)[1] | 1.28 (ISO 1183, 3DXTech; ASTM D792, Stratasys PPSF)[2][3] |
| Typical priceUSD/kg | 1 kg-equivalent spools span 46–140; the middle of the market is about 88[4][5][6] | 1 kg-equivalent spools span 223–733; the middle of the market is about 425[4][7][8][9] |
| Price range across brandsUSD/kg | 46–140 across brands; IEMAI 3D 46, 3DXTech 131 at 750 g and 130 at 2 kg, PrimaCreator NylonPower Glass Fiber 140 at 500 g[4][5][6] | 223-733 across brands; IEMAI 3D 223 at 1 kg, 3DXTech ThermaX PPSU 250 at 500 g, 3D4Makers 425 at 750 g, Kimya PPSU-S 733 at 500 g[4][7][8][9] |
| Market availability1–5 | Available from several mainstream brands[4][5] | Niche, a handful of specialist brands[4][7][8] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 0.5, 0.75 and 2 kg spools[4][6] | 1.75 and 2.85 mm; 200 g to 750 g spools[4][7][8] |
| Typical applications | Stiff, humidity-stable structural parts — the glass gives the modulus, the PA12 matrix limits the moisture drift[1][10] | Steam-sterilisable medical and dental tooling, and aircraft interior parts[2] |
| Printing Parameters | ||
| Bed temperature°C | Not documented | 130–150 (3DXTech)[2] |
| Enclosure / chamber requirement1–5 | Enclosure required (passive)[11] | Actively heated chamber required[12][13] |
| Bed surface & adhesion aid | PEI sheet with a glue stick, or a dedicated adhesive such as Magigoo[14][11] | Not documented |
| Warping tendency1–5 | Not documented | Severe — heated chamber needed[12] |
| Bed-adhesion difficulty1–5 | Needs a specific surface plus adhesive[14] | Not documented |
| Stringing / oozing tendency1–5 | Moderate — retraction tuning needed[11] | Not documented |
| Overall printing difficulty1–5 | Advanced — enclosure, hardware upgrades, tuning[11] | Expert / industrial hardware only[12][13] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Hardened steel required — no nozzle-life figure is published for a PA12-GF30 grade; Polymaker measures about 9 h of brass nozzle life on its comparable fibre-filled nylons[15] | Brass fine indefinitely for unfilled grades, but brass softens near these nozzle temperatures — hardened or plated hot ends are the norm[12] |
| Abrasiveness1–5 | Highly abrasive — standard GF composite[15] | Non-abrasive when unfilled[2] |
| Nozzle clog risk1–5 | High — jams from moisture, heat creep or particles[16] | Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[17] |
| Heat-creep / jam sensitivity1–5 | Moderate — good heatbreak cooling needed[14] | Not documented |
| Hotend requirement | May require an all-metal hot end (Simplify3D)[14] | Not documented |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | High (0.8–2 %) — the PA12 matrix takes up far less than PA6, on the evidence of Polymaker's 1.5 % for PA12-CF10 against 3.33 % for PA6-GF25[18][19] | Not documented |
| Equilibrium moisture content at ~50 % RH% | Not documented | 0.37 in 24 h and 1.1 at saturation on extruded stock (ASTM D570)[20] |
| Effect of moisture on strength | Polymaker's PA12 grades change little between wet and dry, unlike PA6; the CoPA dry-to-wet blocks show the PA6-type response[10][21] | No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[17] |
| Storage requirement | Sealed below 20 % RH with desiccant[16] | Not documented |
| Hydrolysis at melt temperature | Polymaker specifies an 80–100 °C dry and storage below 20 % RH; no molecular-weight loss figure is published, and the wet data it does publish is conditioning rather than melt hydrolysis[15][21] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 82 at break (printed XY, ISO 527)[1] | 55 (printed XY, ISO 527, 3DXTech) and 55 (printed on side long edge, ASTM D638, Stratasys PPSF); 79 at yield on extruded stock[2][3][20] |
| Young's modulusMPa | 7800 (printed XY, ISO 527)[1] | 2100 (printed, ASTM D638, Stratasys PPSF) and 2310 (printed XY, ISO 527, 3DXTech); 2344 on extruded stock[2][3][20] |
| Elongation at break% | 4.5 at break (printed XY, ISO 527) — nearly double the 2.4 % of Polymaker's PA6-GF25[1][19] | 3 (printed, ISO 527 and ASTM D638) against 60 on extruded stock — printing costs PPSU almost all of its ductility[2][3][20] |
| Flexural strengthMPa | 94 (printed XY, ISO 178)[1] | 110 (printed, ISO 178 and ASTM D790, 3DXTech and Stratasys PPSF agree); 91 on extruded stock[2][3][20] |
| Flexural modulusMPa | 7550 (printed XY, ISO 178)[1] | 2200 (printed, ASTM D790, Stratasys PPSF) and 2215 (printed XY, ISO 178, 3DXTech)[2][3] |
| Other impact data | Not documented | Izod notched 58.7 J/m and unnotched 165.5 J/m (printed, ASTM D256 Method A, Stratasys PPSF); 160 J/m notched on extruded stock[3][20] |
| Brittleness1–5 | Moderate[1] | Brittle — snaps with little warning[2] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Rockwell M88 / R117 on extruded PA66-GF30 stock (ASTM D785); no figure is published for a glass-fibre PA12 filament[22] | Rockwell M86 on printed PPSF (ASTM D785, Stratasys); M96 on extruded PPSU stock (and an unlabelled 123)[3][20] |
| Creep resistance / sustained load1–5 | Good. Ensinger lists high creep resistance for extruded PA66-GF30 stock, and the PA12 matrix absorbs far less water than PA6, so a PA12-GF part holds load better in a humid environment[22][11] | Good. Printed PPSF holds 189 °C heat deflection at 1.8 MPa (ASTM D648) and extruded stock is rated 149 °C long-term service, but Ensinger does not claim the creep resistance it claims for PSU and PPS[3][20] |
| Fatigue / repeated-flex resistance1–5 | Good. Ensinger lists high fatigue strength as a headline property of extruded PA66-GF30 stock[22] | Not documented |
| Elasticity / flexibility1–5 | Rigid[1] | Rigid[2] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | Not documented | 190 (printed XY, ISO 75 at 0.45 MPa, 3DXTech)[2] |
| HDT at 1.8 MPa°C | Not documented | 189 (printed, ASTM D648 at 264 psi, Stratasys PPSF); 207 on extruded stock, converted from 405 °F[3][20] |
| Glass transition (Tg)°C | Not documented | 230 (DSC) — the highest glass transition in the dataset[2] |
| Continuous service temperature°C | Not documented | 149 long-term service on extruded PPSU stock, converted from 300 °F[20] |
| Thermal expansion (CTE)µm/m·K | 48.6 on extruded PA66-GF30 stock (ASTM D696; source states 2.7e-5 in/in/°F) — no figure is published for a glass-fibre PA12 filament[22] | 55.0 (printed PPSF, ASTM D696; source states 5.5e-5 mm/mm/°C) and 55.8 on extruded stock (ASTM D696, from 3.1e-5 in/in/°F)[3][20] |
| Flammability / UL 94 | Flammable; no UL 94 rating published for the grades surveyed[15] | UL 94 V-0 at 1.5 mm, rated on the base resin[2] |
| Environment & Chemical | ||
| UV resistance1–5 | Months outdoors before embrittlement — unstabilised polyamide yellows under UV[11] | Not documented |
| Chemical resistance | Withstands oils, fuels and alkalis[11] | Withstands repeated steam autoclaving, the usual reason to choose PPSU over PSU; Stratasys also lists PPSF as passing 24 h stress-crack exposure to antifreeze, petrol, motor oil, power-steering, transmission and washer fluid at 23 °C and 100 °C[2][3] |
| Water / humidity resistance in service1–5 | Good — minor absorption relative to PA6-based composites[10] | Not documented |
| Food contact | Not food-contact certified as filament[11] | Not documented |
| Biodegradability / compostability | Not biodegradable[11] | Not documented |
| Recyclability | Not accepted in household plastic collection[11] | Not documented |
| Electrical & ESD properties | Surface resistance above 10¹³ ohm/sq — insulating (ASTM D257)[1] | Volume resistivity 5e13 to 1.5e14 ohm-cm and dielectric strength 80-290 V/mil on printed PPSF (ASTM D257, D149)[3] |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised[23] | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[23] |
| VOC emission rateµg/min | Up to 180 caprolactam, the dominant VOC from nylon and the largest single-VOC rate in the study[23] | Not documented |
| Ultrafine-particle emission rateparticles/min | ≈2 × 10⁸ median for nylon — low for particles despite the highest VOC mass measured[23] | Not documented |
| Hazardous species emitted | Caprolactam, at up to 180 µg/min from nylon filament[23] | Not documented |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[23] | Ventilated room or enclosure recommended[23] |
| Dust & fibre handling hazard | Glass fibre is bound in the matrix; avoid inhaling sanding dust[1] | Not documented |
| Post-Processing | ||
| Sanding & machining | Sands poorly — gums rather than powders[14] | Not documented |
| Gluing & solvent welding | Cyanoacrylate; no common solvent welds polyamide[14] | Not documented |
| Vapour / chemical smoothing | No practical vapour smoothing[14] | Not documented |
| Solvents & Solubility | ||
| Soluble in | Formic acid, phenol, m-cresol and hexafluoroisopropanol dissolve the matrix at 23 °C, leaving the fibre; laboratory reagents.[24] | Dichloromethane dissolves it at 23 °C at every stress level; acetone solvates and softens unstressed PPSU (Solvay ESCR).[25] |
| Softened or crazed by | Zinc chloride solutions stress-crack the nylon matrix, alcoholic calcium chloride dissolves it, mineral acids attack it.[24] | MEK ruptures stressed parts and toluene crazes them above 13.8 MPa; glass-filled grades survive where unfilled craze.[25] |
| Solvent welding & smoothing agent | None — nylon's only solvents (formic acid, phenol, HFIP) degrade the part, and the fibre blocks surface flow anyway.[24] | Dichloromethane cements PPSU and NMP softens residual resin; both are laboratory reagents, not workshop stock.[25] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- FibreX PA12-GF30 Technical Data Sheet v1.0 3DXTech · 2026-08 · tds
- ThermaX PPSU Technical Data Sheet v3 3DXTech · 2026-08 · tds
- PPSF (polyphenylsulfone) — FDM Data Sheet Stratasys · 2018-06 · tds
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- IEMAI 3D GF-PA12 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- PrimaCreator SELECT NylonPower Glass Fiber product page PrimaCreator · 2026-08 · vendor
- Kimya PPSU-S Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
- 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
- IEMAI 3D PPSU 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
- PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- Nylon — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- Fiberon PA6-CF20 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- THERMAX PPSU — product page (print recommendations) 3DXTech · 2026-08 · doc
- Fiberon PA12-CF10 Technical Data Sheet V1.1 Polymaker · 2025-02 · tds
- Fiberon PA6-GF25 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
- TECASON P black (PPSU) — stock shape properties Ensinger · 2026-08 · tds
- PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
- TECAMID 66 GF30 black (PA66-GF30) — stock shape properties Ensinger · 2026-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
- Radel PPSU, Veradel PESU, Acudel modified PPSU Design Guide — environmental stress cracking tables Solvay Specialty Polymers · 2026-08 · tds