Filament comparison
PA12-GF vs PPS
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | Glass-fibre PA12 (PA12-GF)PA | PPSHIGHTEMP |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $130.67/kg median; $46.00–$140.18/kg across 3 dated product listings | $116.97/kg median; $84.00–$200.00/kg across 3 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | PA12 reinforced with chopped glass fibre — 3DXTech's grade is nominally 30 wt%[1] | Polyphenylene sulfide — a semi-crystalline high-temperature polymer[2][3] |
| Densityg/cm³ | 1.23 (ISO 1183)[1] | 1.28 (ISO 1183, 3DXTech) and 1.33 (ISO 1183, Spectrum PPS AM230)[2][4] |
| Typical priceUSD/kg | 1 kg-equivalent spools span 46–140; the middle of the market is about 88[5][6][7] | 1 kg-equivalent spools span 84–200; the middle of the market is about 117[5][8][9] |
| Price range across brandsUSD/kg | 46–140 across brands; IEMAI 3D 46, 3DXTech 131 at 750 g and 130 at 2 kg, PrimaCreator NylonPower Glass Fiber 140 at 500 g[5][6][7] | 84-200 across brands and diameters; IEMAI 3D 84 at 1 kg, Spectrum PPS AM230 117 at 750 g, 3DXTech ThermaX PPS 140 at 2.85 mm and 200 at 1.75 mm[5][8][9] |
| Market availability1–5 | Available from several mainstream brands[5][6] | Niche, a handful of specialist brands[5][8] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 0.5, 0.75 and 2 kg spools[5][7] | 1.75 and 2.85 mm; 500 g and 750 g spools[5][8] |
| Typical applications | Stiff, humidity-stable structural parts — the glass gives the modulus, the PA12 matrix limits the moisture drift[1][10] | Chemical-plant and under-bonnet parts needing solvent resistance above 200 °C[3] |
| Printing Parameters | ||
| Nozzle temperature°C | Not documented | 335-345 (3DXTech printed-specimen conditions); 300-330 (Spectrum)[2][4] |
| Bed temperature°C | Not documented | 110-130 (3DXTech); 100-120 (Spectrum)[2][4] |
| Enclosure / chamber requirement1–5 | Enclosure required (passive)[11] | Actively heated chamber required[12][13] |
| Recommended chamber temperature°C | Not documented | 60-80 actively heated (Spectrum PPS AM230)[4] |
| Bed surface & adhesion aid | PEI sheet with a glue stick, or a dedicated adhesive such as Magigoo[14][11] | Adhesive required — Spectrum specifies Magigoo Pro HT[4] |
| Bed-adhesion difficulty1–5 | Needs a specific surface plus adhesive[14] | Not documented |
| Stringing / oozing tendency1–5 | Moderate — retraction tuning needed[11] | Not documented |
| Overall printing difficulty1–5 | Advanced — enclosure, hardware upgrades, tuning[11] | Expert / industrial hardware only[12][13] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Hardened steel required — no nozzle-life figure is published for a PA12-GF30 grade; Polymaker measures about 9 h of brass nozzle life on its comparable fibre-filled nylons[15] | Brass fine indefinitely for unfilled grades, but brass softens near these nozzle temperatures — hardened or plated hot ends are the norm[12] |
| Abrasiveness1–5 | Highly abrasive — standard GF composite[15] | Non-abrasive when unfilled[2] |
| Nozzle clog risk1–5 | High — jams from moisture, heat creep or particles[16] | Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 110 °C pre-dry before every print[17] |
| Heat-creep / jam sensitivity1–5 | Moderate — good heatbreak cooling needed[14] | Not documented |
| Hotend requirement | May require an all-metal hot end (Simplify3D)[14] | Not documented |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | High (0.8–2 %) — the PA12 matrix takes up far less than PA6, on the evidence of Polymaker's 1.5 % for PA12-CF10 against 3.33 % for PA6-GF25[18][19] | Negligible (<0.1 % EMC) — Polymaker states minimal water absorption at 0.05 %[3] |
| Equilibrium moisture content at ~50 % RH% | Not documented | 0.01 in 24 h on extruded stock (ASTM D570) — effectively non-absorbing[20] |
| Drying temperature & time | Not documented | At least 3 h at 90 °C in hot dry air if the filament has taken up moisture (Spectrum)[4] |
| Effect of moisture on strength | Polymaker's PA12 grades change little between wet and dry, unlike PA6; the CoPA dry-to-wet blocks show the PA6-type response[10][21] | Little to measure — equilibrium uptake is 0.05 %; 3DXTech still specifies a 110 °C, 4 h pre-dry before printing[3][17] |
| Storage requirement | Sealed below 20 % RH with desiccant[16] | Not documented |
| Hydrolysis at melt temperature | Polymaker specifies an 80–100 °C dry and storage below 20 % RH; no molecular-weight loss figure is published, and the wet data it does publish is conditioning rather than melt hydrolysis[15][21] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 82 at break (printed XY, ISO 527)[1] | 50 at break (printed XY, ISO 527, 3DXTech); 65 at break injection-moulded (ISO 527, Spectrum); 94 at yield on extruded stock (ASTM D638)[2][4][20] |
| Young's modulusMPa | 7800 (printed XY, ISO 527)[1] | 2650 (printed XY, ISO 527, 3DXTech); 3650 injection-moulded (ISO 527, Spectrum); 5769 on extruded stock (ASTM D638)[2][4][20] |
| Elongation at break% | 4.5 at break (printed XY, ISO 527) — nearly double the 2.4 % of Polymaker's PA6-GF25[1][19] | 18 at break (printed XY, ISO 527, 3DXTech) against 2.0 injection-moulded (Spectrum) and 2.5 on extruded stock — the suppliers disagree by nearly an order of magnitude[2][4][20] |
| Flexural strengthMPa | 94 (printed XY, ISO 178)[1] | 52 (printed XY, ISO 178, 3DXTech); 141 on extruded stock (ASTM D790)[2][20] |
| Flexural modulusMPa | 7550 (printed XY, ISO 178)[1] | 2540 (printed XY, ISO 178)[2] |
| Charpy impact, notchedkJ/m² | Not documented | 1.3 notched injection-moulded (ISO 179-1eA, Spectrum); unnotched 18[4] |
| Other impact data | Not documented | Izod notched 33 J/m on extruded PPS stock, converted from 0.62 ft-lb/in (ASTM D256)[20] |
| Brittleness1–5 | Moderate[1] | Moderate[2] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Rockwell M88 / R117 on extruded PA66-GF30 stock (ASTM D785); no figure is published for a glass-fibre PA12 filament[22] | Rockwell 105 (and R124) on extruded PPS stock (ASTM D785)[20] |
| Creep resistance / sustained load1–5 | Good. Ensinger lists high creep resistance for extruded PA66-GF30 stock, and the PA12 matrix absorbs far less water than PA6, so a PA12-GF part holds load better in a humid environment[22][11] | Excellent — holds load for years. Ensinger lists high creep resistance as a headline property of extruded PPS stock, and Spectrum states that rigidity, strength and creep resistance are unchanged under continuous load at high temperature[20][4] |
| Fatigue / repeated-flex resistance1–5 | Good. Ensinger lists high fatigue strength as a headline property of extruded PA66-GF30 stock[22] | Not documented |
| Elasticity / flexibility1–5 | Rigid[1] | Rigid[2] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | Not documented | 90 (printed XY, ISO 75 at 0.45 MPa, 3DXTech); 129 injection-moulded (ISO 75, Spectrum); 204 on extruded stock (ASTM D648 at 66 psi)[2][4][20] |
| HDT at 1.8 MPa°C | Not documented | 107 injection-moulded (ISO 75 at 1.81 MPa, Spectrum); 104 on extruded stock (ASTM D648 at 264 psi)[4][20] |
| Melting point / Vicat°C | Not documented | 283 melting (ISO 11357, 3DXTech) and 280 on extruded stock; Vicat softening 236 at 50 N injection-moulded (ISO 306, Spectrum)[2][4][20] |
| Continuous service temperature°C | Not documented | 170 long-term service on extruded PPS stock, converted from 338 °F[20] |
| Thermal expansion (CTE)µm/m·K | 48.6 on extruded PA66-GF30 stock (ASTM D696; source states 2.7e-5 in/in/°F) — no figure is published for a glass-fibre PA12 filament[22] | 59.4 (extruded PPS stock, 22-60 °C, ASTM D696; source states 3.3e-5 in/in/°F)[20] |
| Flammability / UL 94 | Flammable; no UL 94 rating published for the grades surveyed[15] | UL 94 V-0 at 1.5 mm, rated on the base resin[2] |
| Environment & Chemical | ||
| UV resistance1–5 | Months outdoors before embrittlement — unstabilised polyamide yellows under UV[11] | Not documented |
| Chemical resistance | Withstands oils, fuels and alkalis[11] | Outstanding — PPS resists essentially all solvents below 200 °C[3] |
| Water / humidity resistance in service1–5 | Good — minor absorption relative to PA6-based composites[10] | Excellent — essentially unaffected; extruded stock takes up 0.01 % water in 24 h[20] |
| Food contact | Not food-contact certified as filament[11] | Not documented |
| Biodegradability / compostability | Not biodegradable[11] | Not documented |
| Recyclability | Not accepted in household plastic collection[11] | Not documented |
| Electrical & ESD properties | Surface resistance above 10¹³ ohm/sq — insulating (ASTM D257)[1] | Not documented |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised[23] | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[23] |
| VOC emission rateµg/min | Up to 180 caprolactam, the dominant VOC from nylon and the largest single-VOC rate in the study[23] | Not documented |
| Ultrafine-particle emission rateparticles/min | ≈2 × 10⁸ median for nylon — low for particles despite the highest VOC mass measured[23] | Not documented |
| Hazardous species emitted | Caprolactam, at up to 180 µg/min from nylon filament[23] | Not documented |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[23] | Ventilated room or enclosure recommended[23] |
| Dust & fibre handling hazard | Glass fibre is bound in the matrix; avoid inhaling sanding dust[1] | Not documented |
| Post-Processing | ||
| Sanding & machining | Sands poorly — gums rather than powders[14] | Not documented |
| Gluing & solvent welding | Cyanoacrylate; no common solvent welds polyamide[14] | Not documented |
| Vapour / chemical smoothing | No practical vapour smoothing[14] | Not documented |
| Solvents & Solubility | ||
| Soluble in | Formic acid, phenol, m-cresol and hexafluoroisopropanol dissolve the matrix at 23 °C, leaving the fibre; laboratory reagents.[24] | None — PPS does not dissolve in any known solvent below 200 °C.[25][26] |
| Softened or crazed by | Zinc chloride solutions stress-crack the nylon matrix, alcoholic calcium chloride dissolves it, mineral acids attack it.[24] | Nothing at 23 °C; Ensinger rates it only conditionally resistant to benzene, dichloromethane, toluene and pyridine.[26] |
| Solvent welding & smoothing agent | None — nylon's only solvents (formic acid, phenol, HFIP) degrade the part, and the fibre blocks surface flow anyway.[24] | None — no solvent welds or smooths PPS.[25] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- FibreX PA12-GF30 Technical Data Sheet v1.0 3DXTech · 2026-08 · tds
- ThermaX PPS Technical Data Sheet v3 3DXTech · 2026-08 · tds
- PPS — material basics Polymaker Wiki · 2026-08 · doc
- Spectrum PPS AM230 Technical Data Sheet Spectrum Filaments · 2022-04 · tds
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- IEMAI 3D GF-PA12 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- PrimaCreator SELECT NylonPower Glass Fiber product page PrimaCreator · 2026-08 · vendor
- Spectrum PPS AM230 Natural, 1.75 mm / 750 g 3DJAKE · 2026-08 · vendor
- IEMAI 3D PPS 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
- PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- Nylon — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- Fiberon PA6-CF20 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- THERMAX PPS — product page (print recommendations) 3DXTech · 2026-08 · doc
- Fiberon PA12-CF10 Technical Data Sheet V1.1 Polymaker · 2025-02 · tds
- Fiberon PA6-GF25 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
- TECATRON natural (PPS) — stock shape properties Ensinger · 2026-08 · tds
- PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
- TECAMID 66 GF30 black (PA66-GF30) — stock shape properties Ensinger · 2026-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
- PPS (Polyphenylene sulfide) — Knowledge Base Prusa Research · 2026-08 · doc
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds