Filament comparison
PA12-GF vs PEKK
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | Glass-fibre PA12 (PA12-GF)PA | PEKKHIGHTEMP |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $130.67/kg median; $46.00–$140.18/kg across 3 dated product listings | $525.00/kg median; $332.50–$771.12/kg across 6 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | PA12 reinforced with chopped glass fibre — 3DXTech's grade is nominally 30 wt%[1] | Polyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[2][3] |
| Densityg/cm³ | 1.23 (ISO 1183)[1] | 1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[3][2] |
| Typical priceUSD/kg | 1 kg-equivalent spools span 46–140; the middle of the market is about 88[4][5][6] | 1 kg-equivalent spools cluster near 550[4][7][8] |
| Price range across brandsUSD/kg | 46–140 across brands; IEMAI 3D 46, 3DXTech 131 at 750 g and 130 at 2 kg, PrimaCreator NylonPower Glass Fiber 140 at 500 g[4][5][6] | 333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[4][7][8][9][10] |
| Market availability1–5 | Available from several mainstream brands[4][5] | Niche, a handful of specialist brands[4][7][8] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 0.5, 0.75 and 2 kg spools[4][6] | 1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[4][7][3] |
| Typical applications | Stiff, humidity-stable structural parts — the glass gives the modulus, the PA12 matrix limits the moisture drift[1][11] | Aerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[2][3] |
| Printing Parameters | ||
| Bed temperature°C | Not documented | 140 (3DXTech CarbonX PEKK-A CF15)[2] |
| Enclosure / chamber requirement1–5 | Enclosure required (passive)[12] | Actively heated chamber required[13][14] |
| Bed surface & adhesion aid | PEI sheet with a glue stick, or a dedicated adhesive such as Magigoo[15][12] | Not documented |
| Bed-adhesion difficulty1–5 | Needs a specific surface plus adhesive[15] | Not documented |
| Stringing / oozing tendency1–5 | Moderate — retraction tuning needed[12] | Not documented |
| Overall printing difficulty1–5 | Advanced — enclosure, hardware upgrades, tuning[12] | Expert / industrial hardware only[13][14] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Hardened steel required — no nozzle-life figure is published for a PA12-GF30 grade; Polymaker measures about 9 h of brass nozzle life on its comparable fibre-filled nylons[16] | Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[2][3] |
| Abrasiveness1–5 | Highly abrasive — standard GF composite[16] | Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[2][3] |
| Nozzle clog risk1–5 | High — jams from moisture, heat creep or particles[17] | Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[18] |
| Heat-creep / jam sensitivity1–5 | Moderate — good heatbreak cooling needed[15] | Not documented |
| Hotend requirement | May require an all-metal hot end (Simplify3D)[15] | Not documented |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | High (0.8–2 %) — the PA12 matrix takes up far less than PA6, on the evidence of Polymaker's 1.5 % for PA12-CF10 against 3.33 % for PA6-GF25[19][20] | Not documented |
| Effect of moisture on strength | Polymaker's PA12 grades change little between wet and dry, unlike PA6; the CoPA dry-to-wet blocks show the PA6-type response[11][21] | No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[18] |
| Storage requirement | Sealed below 20 % RH with desiccant[17] | Not documented |
| Hydrolysis at melt temperature | Polymaker specifies an 80–100 °C dry and storage below 20 % RH; no molecular-weight loss figure is published, and the wet data it does publish is conditioning rather than melt hydrolysis[16][21] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 82 at break (printed XY, ISO 527)[1] | 86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[3][2] |
| Young's modulusMPa | 7800 (printed XY, ISO 527)[1] | 2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[3][2] |
| Elongation at break% | 4.5 at break (printed XY, ISO 527) — nearly double the 2.4 % of Polymaker's PA6-GF25[1][20] | 6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[3][2] |
| Flexural strengthMPa | 94 (printed XY, ISO 178)[1] | 136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[3][2] |
| Flexural modulusMPa | 7550 (printed XY, ISO 178)[1] | 3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[3][2] |
| Other impact data | Not documented | Izod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[3] |
| Layer adhesion / Z tensileMPa | Not documented | 50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[3][22] |
| Brittleness1–5 | Moderate[1] | Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[3][2] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Rockwell M88 / R117 on extruded PA66-GF30 stock (ASTM D785); no figure is published for a glass-fibre PA12 filament[23] | Not documented |
| Creep resistance / sustained load1–5 | Good. Ensinger lists high creep resistance for extruded PA66-GF30 stock, and the PA12 matrix absorbs far less water than PA6, so a PA12-GF part holds load better in a humid environment[23][12] | Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[3] |
| Fatigue / repeated-flex resistance1–5 | Good. Ensinger lists high fatigue strength as a headline property of extruded PA66-GF30 stock[23] | Not documented |
| Elasticity / flexibility1–5 | Rigid[1] | Rigid[2] |
| Z strength as % of XY% | Not documented | 56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[3][22] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | Not documented | 158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[3][2] |
| HDT at 1.8 MPa°C | Not documented | 156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[3] |
| Glass transition (Tg)°C | Not documented | 156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[3][2] |
| Melting point / Vicat°C | Not documented | 300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[3][2] |
| Thermal expansion (CTE)µm/m·K | 48.6 on extruded PA66-GF30 stock (ASTM D696; source states 2.7e-5 in/in/°F) — no figure is published for a glass-fibre PA12 filament[23] | 36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[3][22] |
| Flammability / UL 94 | Flammable; no UL 94 rating published for the grades surveyed[16] | Not documented |
| Environment & Chemical | ||
| UV resistance1–5 | Months outdoors before embrittlement — unstabilised polyamide yellows under UV[12] | Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[3] |
| Chemical resistance | Withstands oils, fuels and alkalis[12] | Not documented |
| Water / humidity resistance in service1–5 | Good — minor absorption relative to PA6-based composites[11] | Not documented |
| Food contact | Not food-contact certified as filament[12] | Not documented |
| Biodegradability / compostability | Not biodegradable[12] | Not documented |
| Recyclability | Not accepted in household plastic collection[12] | Not documented |
| Electrical & ESD properties | Surface resistance above 10¹³ ohm/sq — insulating (ASTM D257)[1] | Unfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[3][2][22] |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised[24] | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[24] |
| VOC emission rateµg/min | Up to 180 caprolactam, the dominant VOC from nylon and the largest single-VOC rate in the study[24] | Not documented |
| Ultrafine-particle emission rateparticles/min | ≈2 × 10⁸ median for nylon — low for particles despite the highest VOC mass measured[24] | Not documented |
| Hazardous species emitted | Caprolactam, at up to 180 µg/min from nylon filament[24] | Not documented |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[24] | Ventilated room or enclosure recommended[24] |
| Dust & fibre handling hazard | Glass fibre is bound in the matrix; avoid inhaling sanding dust[1] | Carbon fibre is bound in the matrix; sanding dust should not be inhaled[2] |
| Post-Processing | ||
| Sanding & machining | Sands poorly — gums rather than powders[15] | Not documented |
| Gluing & solvent welding | Cyanoacrylate; no common solvent welds polyamide[15] | Not documented |
| Vapour / chemical smoothing | No practical vapour smoothing[15] | Not documented |
| Solvents & Solubility | ||
| Soluble in | Formic acid, phenol, m-cresol and hexafluoroisopropanol dissolve the matrix at 23 °C, leaving the fibre; laboratory reagents.[25] | Concentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[26][27] |
| Softened or crazed by | Zinc chloride solutions stress-crack the nylon matrix, alcoholic calcium chloride dissolves it, mineral acids attack it.[25] | Concentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[26] |
| Solvent welding & smoothing agent | None — nylon's only solvents (formic acid, phenol, HFIP) degrade the part, and the fibre blocks surface flow anyway.[25] | None — no solvent softens a polyaryletherketone.[26] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- FibreX PA12-GF30 Technical Data Sheet v1.0 3DXTech · 2026-08 · tds
- CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
- Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- IEMAI 3D GF-PA12 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- PrimaCreator SELECT NylonPower Glass Fiber product page PrimaCreator · 2026-08 · vendor
- 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
- Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
- Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
- IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
- PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- Nylon — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- Fiberon PA6-CF20 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
- Fiberon PA12-CF10 Technical Data Sheet V1.1 Polymaker · 2025-02 · tds
- Fiberon PA6-GF25 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
- PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
- Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
- TECAMID 66 GF30 black (PA66-GF30) — stock shape properties Ensinger · 2026-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
- The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper