3D Printing Info

Filament comparison

PA12-CF vs PEKK

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PA12-CF vs PEKK — documented properties and sources
PropertyCarbon-fibre PA12 (PA12-CF)PAPEKKHIGHTEMP
Market snapshot
Listing priceUSD/kg; dated snapshots$109.98/kg median; $52.00–$180.00/kg across 4 dated product listings$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings
Identity & Market
Base polymer / chemistryPA12 reinforced with chopped carbon fibre — Polymaker's grade is 10 wt%[1][2]Polyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[3][4]
Densityg/cm³1.06 (Polymaker Fiberon) and 1.16 (3DXTech), ISO 1183[1][2]1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[4][3]
Typical priceUSD/kg1 kg-equivalent spools span 52–180; the middle of the market is about 110[5][6][7]1 kg-equivalent spools cluster near 550[6][8][9]
Price range across brandsUSD/kg52–180 across brands; IEMAI 3D 52, YXPOLYER 80 at 500 g, Polymaker Fiberon 140, 3DXTech CarbonX 180[5][6][10][7]333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[6][8][9][11][12]
Market availability1–5Available from several mainstream brands[5][6]Niche, a handful of specialist brands[6][8][9]
Spool sizes & diameters1.75 mm; 0.5, 0.75 and 2 kg spools[5][6]1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[6][8][4]
Typical applicationsStiff parts that must stay dimensionally stable in changing humidity — Polymaker sells this grade specifically on low moisture sensitivity[13][1]Aerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[3][4]
Printing Parameters
Nozzle temperature°C260–290 (Extrudr DURAPRO PA12 CF)[14]Not documented
Bed temperature°C110 (Extrudr DURAPRO PA12 CF)[14]140 (3DXTech CarbonX PEKK-A CF15)[3]
Enclosure / chamber requirement1–5Enclosure required (passive)[15][1]Actively heated chamber required[16][17]
Bed surface & adhesion aidPEI sheet with a glue stick, or a dedicated adhesive such as Magigoo[18][15]Not documented
Maximum volumetric flow (mm³/s; see test conditions)mm³/s12 at Extrudr's 150 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[14][19]Not documented
Bed-adhesion difficulty1–5Needs a specific surface plus adhesive[18]Not documented
Stringing / oozing tendency1–5Moderate — retraction tuning needed[15]Not documented
Overall printing difficulty1–5Advanced — enclosure, hardware upgrades, tuning[15]Expert / industrial hardware only[16][17]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required — Polymaker measures brass nozzle life at about 9 h on PA12-CF10 and recommends hardened steel or ruby[1]Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[3][4]
Abrasiveness1–5Highly abrasive — standard CF composite; Polymaker puts brass nozzle life at roughly 9 h on PA12-CF10[1]Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[3][4]
Nozzle clog risk1–5High — jams from moisture, heat creep or particles[20]Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[21]
Heat-creep / jam sensitivity1–5Moderate — good heatbreak cooling needed[18]Not documented
Hotend requirementMay require an all-metal hot end (Simplify3D)[18]Not documented
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5High (0.8–2 %) — 1.5 % equilibrium, the lowest of Polymaker's nylon composites and less than half its PA6-GF25[1][22]Not documented
Equilibrium moisture content at ~50 % RH%1.5 equilibrium water absorption (Polymaker Fiberon PA12-CF10)[1]Not documented
Drying temperature & time80–100 °C; storage below 20 % RH[20][1]Not documented
Effect of moisture on strengthPolymaker's own dry/wet blocks for PA12-CF10 change little: at 2.92 % moisture tensile falls 77.4 → 71.7 MPa and modulus 3311 → 3132 MPa, against a halving for its PA6 grades[1][13]No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[21]
Storage requirementSealed below 20 % RH with desiccant[20]Not documented
Hydrolysis at melt temperaturePolymaker specifies an 80–100 °C dry and storage below 20 % RH; no molecular-weight loss figure is published, and the wet data it does publish is conditioning rather than melt hydrolysis[23][24]Not documented
Mechanical Properties
Tensile strength (XY)MPa77.4 ± 1.1 printed XY dry (Polymaker Fiberon), 71.7 ± 0.7 conditioned to 2.92 % moisture, ISO 527; 3DXTech quotes 72 at break. Stratasys FDM Nylon 12CF spans 76.5-124 at break printed XZ across five machine and tip combinations (ASTM D638)[1][2][25]86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[4][3]
Young's modulusMPa3311 ± 135 printed XY dry and 3132 ± 124 conditioned, ISO 527 (Polymaker Fiberon); 3DXTech quotes 8000. Stratasys FDM Nylon 12CF spans 7910-15400 printed XZ against 2130-3000 in ZX (ASTM D638)[1][2][25]2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[4][3]
Elongation at break%4.2 ± 0.4 printed XY dry and 5.3 ± 0.3 conditioned, ISO 527 (Polymaker Fiberon); 3DXTech quotes 2.1 at break[1][2]6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[4][3]
Flexural strengthMPa90 (printed XY, 3DXTech, ISO 178). Stratasys FDM Nylon 12CF spans 152-200 printed XZ against 61-73 in ZX (ASTM D790)[2][25]136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[4][3]
Flexural modulusMPa7900 (printed XY, 3DXTech, ISO 178)[2]3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[4][3]
Charpy impact, notchedkJ/m²9.9 ± 0.7 printed XY dry and 10.2 ± 0.8 conditioned, ISO 179 notched (Polymaker Fiberon)[1]Not documented
Other impact dataIzod notched 102-138 J/m printed XZ against 22.4-45.5 J/m in ZX (Stratasys FDM Nylon 12CF, ASTM D256)[25]Izod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[4]
Layer adhesion / Z tensileMPa52.2 ± 0.8 printed Z dry (Polymaker Fiberon) — 67 % of XY, unusually isotropic for a filled nylon; 42.1 ± 1.8 conditioned. Stratasys FDM Nylon 12CF gives 32.7-38.4 at break printed ZX (ASTM D638)[1][25]50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[4][26]
Brittleness1–5Moderate[1]Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[4][3]
Hardness (scale-specific)Shore A / Shore D / RockwellRockwell M88 / R117 on extruded PA66-GF30 stock (ASTM D785); no figure is published for a carbon-fibre PA12 filament[27]Not documented
Creep resistance / sustained load1–5Good. Ensinger rates its PA66-CF30 compound for sustained static and dynamic load at 110 °C continuous service; the PA12 matrix takes up 1.5 % equilibrium moisture against PA6's several per cent, so a PA12-CF part drifts less in service[28][1]Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[4]
Fatigue / repeated-flex resistance1–5Good. Stratasys sells unfilled FDM Nylon 12 specifically for repetitive-flex parts on the strength of its fatigue properties, and Ensinger reports improved fatigue strength for carbon-filled nylon compounds[28]Not documented
Elasticity / flexibility1–5Rigid[1]Rigid[3]
Z strength as % of XY%31-50 (Stratasys FDM Nylon 12CF, ZX against XZ tensile at break, ASTM D638, five machine and tip combinations) against 67 (Polymaker Fiberon PA12-CF10, printed Z against XY)[1][25]56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[4][26]
Thermal Properties
HDT at 0.45 MPa°C131 (ISO 75, 0.45 MPa, Polymaker Fiberon). Stratasys FDM Nylon 12CF gives 160 printed XY and 168 ZX, and 175 with unidirectional toolpaths (ASTM D648 at 66 psi)[1][25]158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[4][3]
HDT at 1.8 MPa°C105 (ISO 75, 1.8 MPa, Polymaker Fiberon). Stratasys FDM Nylon 12CF gives 130 printed XY and 154 ZX (ASTM D648 at 264 psi)[1][25]156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[4]
Glass transition (Tg)°C55 (DSC, Polymaker Fiberon)[1]156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[4][3]
Melting point / Vicat°C171 melting (DSC); Vicat 170.2 (ISO 306)[1]300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[4][3]
Thermal expansion (CTE)µm/m·KStratasys FDM Nylon 12CF gives 116 on XY-built and 37 on ZX-built specimens over -50 to 20 °C, rising to 181 (XY) and 46 (ZX) above the 37.5 °C glass transition (ASTM E831); Extrudr quotes 100 for DURAPRO PA12 CF (ISO 11359-2)[14][25]36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[4][26]
Flammability / UL 94Flammable; no UL 94 rating published for the grades surveyed[23]Not documented
Environment & Chemical
UV resistance1–5Months outdoors before embrittlement — unstabilised polyamide yellows under UV[15]Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[4]
Chemical resistanceWithstands oils, fuels and alkalis[15]Not documented
Water / humidity resistance in service1–5Good — minor absorption; the most humidity-stable nylon composite here[13][1]Not documented
Food contactNot food-contact certified as filament[15]Not documented
Biodegradability / compostabilityNot biodegradable[15]Not documented
RecyclabilityNot accepted in household plastic collection[15]Not documented
Electrical & ESD propertiesSurface resistivity above 10¹² ohm — insulating (Polymaker Fiberon, ANSI/ESD S11.11)[1]Unfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[4][3][26]
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised[29]Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[29]
VOC emission rateµg/minUp to 180 caprolactam, the dominant VOC from nylon and the largest single-VOC rate in the study[29]Not documented
Ultrafine-particle emission rateparticles/min≈2 × 10⁸ median for nylon — low for particles despite the highest VOC mass measured[29]Not documented
Hazardous species emittedCaprolactam, at up to 180 µg/min from nylon filament[29]Not documented
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[29]Ventilated room or enclosure recommended[29]
Dust & fibre handling hazardFibre is bound in the matrix; sanding dust should not be inhaled[23]Carbon fibre is bound in the matrix; sanding dust should not be inhaled[3]
Post-Processing
Sanding & machiningSands poorly — gums rather than powders[18]Not documented
Gluing & solvent weldingCyanoacrylate; no common solvent welds polyamide[18]Not documented
Vapour / chemical smoothingNo practical vapour smoothing[18]Not documented
Dimensional accuracy & detailPolymaker's own conditioning test found PA12-CF10 was the only nylon that did not grow past its original size after moisture conditioning[13]Not documented
Solvents & Solubility
Soluble inFormic acid, phenol, m-cresol and hexafluoroisopropanol dissolve the matrix at 23 °C, leaving the fibre; laboratory reagents.[30]Concentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[31][32]
Softened or crazed byZinc chloride solutions stress-crack the nylon matrix, alcoholic calcium chloride dissolves it, mineral acids attack it.[30]Concentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[31]
Solvent welding & smoothing agentNone — nylon's only solvents (formic acid, phenol, HFIP) degrade the part, and the fibre blocks surface flow anyway.[30]None — no solvent softens a polyaryletherketone.[31]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. Fiberon PA12-CF10 Technical Data Sheet V1.1 Polymaker · 2025-02 · tds
  2. CarbonX CF PA12 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  3. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  4. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  5. Polymaker product catalogue Polymaker · 2026-08 · vendor
  6. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  7. IEMAI 3D CF-PA12 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  8. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  9. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  10. YXPOLYER PA12 CF 500 g — product page YXPOLYER · 2026-08 · vendor
  11. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  12. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  13. Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
  14. Extrudr Product Catalogue (DURAPRO PA12 data block) Extrudr · 2025-03 · tds
  15. PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
  16. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  17. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  18. Nylon — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  19. Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
  20. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  21. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  22. Fiberon PA6-GF25 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
  23. Fiberon PA6-CF20 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
  24. PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
  25. FDM Nylon 12CF — Material Data Sheet Stratasys · 2025-09 · tds
  26. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  27. TECAMID 66 GF30 black (PA66-GF30) — stock shape properties Ensinger · 2026-08 · tds
  28. TECACOMP PA66 CF30 black — injection-moulding compound Ensinger · 2026-08 · tds
  29. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  30. Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
  31. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  32. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper