3D Printing Info

Filament comparison

PA11 vs PEKK

Compare printing settings, strength, heat resistance, dated prices and sources.

PA11 (Nylon 11) guidePEKK guide

2 selected · all documented properties

Open these two in the interactive comparisonMore PA11 comparisonsMore PEKK comparisons
PA11 vs PEKK — documented properties and sources
PropertyPA11 (Nylon 11)PAPEKKHIGHTEMP
Market snapshot
Listing priceUSD/kg; dated snapshots$194.98/kg median; $194.98–$194.98/kg across 1 dated product listings$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings
Identity & Market
Base polymer / chemistryPolyamide 11, polymerised from castor-oil-derived aminoundecanoic acid — a bio-based nylon[1][2]Polyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[3][4]
Densityg/cm³1.02 (ISO 1183)[1]1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[4][3]
Typical priceUSD/kgNot documented1 kg-equivalent spools cluster near 550[5][6][7]
Price range across brandsUSD/kgNot documented333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[5][6][7][8][9]
Market availability1–5Niche, a handful of specialist brands[2]Niche, a handful of specialist brands[5][6][7]
Spool sizes & diameters1.75 mm; 1 kg spools[2]1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[5][6][4]
Typical applicationsTough, chemically resistant functional parts; Prusa targets it at impact-loaded and vibration-loaded components[2]Aerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[3][4]
Diameter tolerance± mm±0.02 (Prusament)[1]Not documented
Printing Parameters
Nozzle temperature°C275 ± 10 (Prusament)[1]Not documented
Bed temperature°C100 ± 10 (Prusament)[1]140 (3DXTech CarbonX PEKK-A CF15)[3]
Enclosure / chamber requirement1–5Enclosure required (passive) — Prusament specifies a 55 ± 5 °C chamber[1]Actively heated chamber required[10][11]
Recommended chamber temperature°C55 ± 5 (Prusament)[1]Not documented
Bed surface & adhesion aidPA nylon sheet (Prusament)[1]Not documented
Overall printing difficulty1–5Advanced — enclosure, hardware upgrades, tuning[1][12]Expert / industrial hardware only[10][11]
Extruder requirementPrusa printed its test specimens with a high-flow CHT nozzle[1]Not documented
Hardware Wear & Reliability
Nozzle hardness required1–4Brass fine indefinitely for unfilled grades[12]Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[3][4]
Abrasiveness1–5Non-abrasive when unfilled[12]Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[3][4]
Nozzle clog risk1–5High — jams from moisture, heat creep or particles[13]Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[14]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5High (0.8–2 %) — Prusa measures 0.46 % after 7 days at 22 % RH, but PA11 sits between PA12 and PA6 in the family[1][13]Not documented
Equilibrium moisture content at ~50 % RH%0.26 after 24 h and 0.46 after 7 days (Prusa Polymers method)[1]Not documented
Symptoms when wetPopping and cracking during extrusion, then hard-to-diagnose defects[15]Not documented
Effect of moisture on strengthPrusa publishes no dry-versus-conditioned columns; the CoPA reference shows the PA-family response — stiffness and strength fall sharply, impact and elongation rise[15][16]No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[14]
Storage requirementSealed below 20 % RH with desiccant[13]Not documented
Mechanical Properties
Tensile strength (XY)MPa38.3 ± 0.8 printed horizontal and 39.5 ± 0.5 printed vertical at yield, ISO 527-1[1]86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[4][3]
Young's modulusMPa1200 printed, both orientations, ISO 527-1[1]2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[4][3]
Elongation at break%5.6 ± 0.1 at yield, printed, ISO 527-1[1]6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[4][3]
Flexural strengthMPaNot documented136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[4][3]
Flexural modulusMPa1100 printed horizontal and 1000 printed vertical, ISO 178[1]3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[4][3]
Charpy impact, notchedkJ/m²12.9 ± 2.1 printed horizontal and 11.7 ± 1.2 printed vertical, ISO 179-1 notched[1]Not documented
Other impact dataNot documentedIzod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[4]
Layer adhesion / Z tensileMPa32 ± 1 (Prusa Polymers interlayer adhesion test) — the highest interlayer figure Prusa publishes for any of its filaments[1]50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[4][17]
Brittleness1–5Tough — absorbs impact, yields before breaking[1]Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[4][3]
Hardness (scale-specific)Shore A / Shore D / Rockwell70 Shore D (Prusa Polymers method)[1]Not documented
Creep resistance / sustained load1–5Not documentedExcellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[4]
Fatigue / repeated-flex resistance1–5Excellent — living hinges viable[12]Not documented
Elasticity / flexibility1–5Semi-flexible[1]Rigid[3]
Z strength as % of XY%84 — Prusa publishes a tensile anisotropy coefficient of 0.84, the ratio of Z to XY tensile strength[1]56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[4][17]
Thermal Properties
HDT at 0.45 MPa°C58.7 (ISO 75, 0.45 MPa)[1]158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[4][3]
HDT at 1.8 MPa°C49.9 (ISO 75, 1.8 MPa)[1]156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[4]
Glass transition (Tg)°CNot documented156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[4][3]
Melting point / Vicat°CNot documented300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[4][3]
Thermal expansion (CTE)µm/m·KNot documented36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[4][17]
Environment & Chemical
UV resistance1–5Not documentedGood — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[4]
Water / humidity resistance in service1–5Absorbs water, properties shift[15]Not documented
Biodegradability / compostabilityBio-based — the monomer comes from castor oil[2]Not documented
Electrical & ESD propertiesNot documentedUnfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[4][3][17]
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised[18]Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[18]
VOC emission rateµg/minUp to 180 caprolactam, the dominant VOC from nylon; total VOC reached nearly 200 µg/min, the highest of the nine filaments tested[18]Not documented
Ultrafine-particle emission rateparticles/min≈2 × 10⁸ median — low for ultrafine particles despite the highest VOC mass of any filament tested[18]Not documented
Hazardous species emittedCaprolactam, at up to 180 µg/min from nylon filament — the largest single-VOC emission rate measured in the study[18]Not documented
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[18]Ventilated room or enclosure recommended[18]
Dust & fibre handling hazardNot documentedCarbon fibre is bound in the matrix; sanding dust should not be inhaled[3]
Solvents & Solubility
Soluble inDissolved at 23 °C by formic acid, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — all laboratory reagents.[19][20]Concentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[20][21]
Softened or crazed byMineral acids, oxidants, halogens and zinc chloride solutions attack the amide bond; ordinary solvents do not (BASF, PA6/66).[19]Concentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[20]
Solvent welding & smoothing agentNone — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[19]None — no solvent softens a polyaryletherketone.[20]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. Prusament PA11 Technical Datasheet v1.0 Prusa Polymers · 2026-07 · tds
  2. Prusament PA11 — material page Prusa Polymers · 2026-08 · doc
  3. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  4. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  5. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  6. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  7. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  8. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  9. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  10. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  11. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  12. PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
  13. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  14. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  15. Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
  16. PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
  17. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  18. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  19. Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
  20. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  21. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper