Filament comparison
PA11 vs PEEK-CF
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | PA11 (Nylon 11)PA | Fibre-reinforced PEEKHIGHTEMP |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $194.98/kg median; $194.98–$194.98/kg across 1 dated product listings | $597.50/kg median; $448.00–$695.00/kg across 5 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Polyamide 11, polymerised from castor-oil-derived aminoundecanoic acid — a bio-based nylon[1][2] | Short-fibre reinforced PEEK. 3DXTech's CarbonX grade is nominally 10 wt% carbon and its FibreX grade 20 wt% glass; LEHVOSS Luvocom 3F PEEK CF 9676 is 15 wt% carbon; Ensinger's machining stock runs to 30 wt% carbon[3][4][5][6] |
| Densityg/cm³ | 1.02 (ISO 1183)[1] | 1.39 (ISO 1183)[3] |
| Typical priceUSD/kg | Not documented | 1 kg-equivalent spools span 448–972; the middle of the market is about 598[4][5][7] |
| Price range across brandsUSD/kg | Not documented | 448-972 across formats and filler types; IEMAI 3D CF-PEEK and GF-PEEK 448 at 1 kg, 3DXTech CarbonX PEEK+CF10 598 at 2 kg and FibreX PEEK+GF20 695 at 1 kg, Luvocom 3F PEEK CF 9676 648 at 2 kg[4][5][7][8] |
| Market availability1–5 | Niche, a handful of specialist brands[2] | Niche, a handful of specialist brands[4][5] |
| Spool sizes & diameters | 1.75 mm; 1 kg spools[2] | 1.75 and 2.85 mm; 200 g to 2 kg spools[4][5] |
| Typical applications | Tough, chemically resistant functional parts; Prusa targets it at impact-loaded and vibration-loaded components[2] | Stiff aerospace and oil-and-gas parts where PEEK alone is not rigid enough[3] |
| Diameter tolerance± mm | ±0.02 (Prusament)[1] | Not documented |
| Printing Parameters | ||
| Nozzle temperature°C | 275 ± 10 (Prusament)[1] | Not documented |
| Bed temperature°C | 100 ± 10 (Prusament)[1] | Not documented |
| Enclosure / chamber requirement1–5 | Enclosure required (passive) — Prusament specifies a 55 ± 5 °C chamber[1] | Actively heated chamber required[9][10] |
| Recommended chamber temperature°C | 55 ± 5 (Prusament)[1] | Not documented |
| Bed surface & adhesion aid | PA nylon sheet (Prusament)[1] | Not documented |
| Warping tendency1–5 | Not documented | Moderate — needs adhesion aid or draught shield; the fibre cuts PEEK's crystallisation shrinkage[3] |
| Overall printing difficulty1–5 | Advanced — enclosure, hardware upgrades, tuning[1][11] | Expert / industrial hardware only[9][10] |
| Extruder requirement | Prusa printed its test specimens with a high-flow CHT nozzle[1] | Not documented |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Brass fine indefinitely for unfilled grades[11] | Hardened steel required[3] |
| Abrasiveness1–5 | Non-abrasive when unfilled[11] | Highly abrasive — standard CF composite[3] |
| Nozzle clog risk1–5 | High — jams from moisture, heat creep or particles[12] | High — jams from moisture, heat creep or particles; 3DXTech adds a hardened 0.4 mm minimum nozzle and 0.25 mm layers to the mandatory 120 °C pre-dry[13][14] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | High (0.8–2 %) — Prusa measures 0.46 % after 7 days at 22 % RH, but PA11 sits between PA12 and PA6 in the family[1][12] | Not documented |
| Equilibrium moisture content at ~50 % RH% | 0.26 after 24 h and 0.46 after 7 days (Prusa Polymers method)[1] | 0.06 in 24 h on extruded CF30 stock (ASTM D570)[6] |
| Symptoms when wet | Popping and cracking during extrusion, then hard-to-diagnose defects[15] | Not documented |
| Effect of moisture on strength | Prusa publishes no dry-versus-conditioned columns; the CoPA reference shows the PA-family response — stiffness and strength fall sharply, impact and elongation rise[15][16] | No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[13] |
| Storage requirement | Sealed below 20 % RH with desiccant[12] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 38.3 ± 0.8 printed horizontal and 39.5 ± 0.5 printed vertical at yield, ISO 527-1[1] | 105 at break (printed XY, ISO 527, CF10); 121 at yield on extruded CF30 stock (ASTM D638)[3][6] |
| Young's modulusMPa | 1200 printed, both orientations, ISO 527-1[1] | 8100 (printed XY, ISO 527, CF10) — more than double unfilled PEEK; 6343 on extruded CF30 stock (ASTM D638)[3][6] |
| Elongation at break% | 5.6 ± 0.1 at yield, printed, ISO 527-1[1] | 3 at break (printed XY, ISO 527), against 28 for unfilled PEEK[3][17] |
| Flexural strengthMPa | Not documented | 136 (printed XY, ISO 178, CF10); 193 on extruded CF30 stock (ASTM D790)[3][6] |
| Flexural modulusMPa | 1100 printed horizontal and 1000 printed vertical, ISO 178[1] | 8300 (printed XY, ISO 178, CF10); 7171 on extruded CF30 stock (ASTM D790)[3][6] |
| Charpy impact, notchedkJ/m² | 12.9 ± 2.1 printed horizontal and 11.7 ± 1.2 printed vertical, ISO 179-1 notched[1] | Not documented |
| Other impact data | Not documented | Izod notched 61.9 J/m on extruded CF30 stock, converted from 1.16 ft-lb/in (ASTM D256)[6] |
| Layer adhesion / Z tensileMPa | 32 ± 1 (Prusa Polymers interlayer adhesion test) — the highest interlayer figure Prusa publishes for any of its filaments[1] | Not documented |
| Brittleness1–5 | Tough — absorbs impact, yields before breaking[1] | Brittle — snaps with little warning; elongation falls from 28 % to 3 %[3][17] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | 70 Shore D (Prusa Polymers method)[1] | Rockwell M107 on extruded PEEK-CF30 stock (ASTM D785), against M100 unfilled[6][18] |
| Creep resistance / sustained load1–5 | Not documented | Excellent — holds load for years. Ensinger rates carbon-fibre PEEK stock as very highly creep resistant and specifies 260 °C continuous service[6] |
| Fatigue / repeated-flex resistance1–5 | Excellent — living hinges viable[11] | Good. Victrex rates PEEK for long-term fatigue as well as creep; the fibre cuts elongation at break from 28 % to 3 %, which limits repeated large-strain flexing[19][3][17] |
| Elasticity / flexibility1–5 | Semi-flexible[1] | Rigid[3] |
| Z strength as % of XY% | 84 — Prusa publishes a tensile anisotropy coefficient of 0.84, the ratio of Z to XY tensile strength[1] | Not documented |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 58.7 (ISO 75, 0.45 MPa)[1] | 265 (printed XY, ISO 75 at 0.45 MPa, CarbonX PEEK+CF10) against 140 for unfilled PEEK[3][17] |
| HDT at 1.8 MPa°C | 49.9 (ISO 75, 1.8 MPa)[1] | 316 on extruded CF30 stock, converted from 600 °F at 264 psi (ASTM D648)[6] |
| Glass transition (Tg)°C | Not documented | 143 (DSC, CarbonX PEEK+CF10) — the fibre does not move the glass transition[3] |
| Melting point / Vicat°C | Not documented | 334 melting on extruded CF30 stock, converted from 633 °F[6] |
| Continuous service temperature°C | Not documented | 260 long-term on extruded CF30 stock, converted from 500 °F; 300 short term[6] |
| Thermal expansion (CTE)µm/m·K | Not documented | 14.4 (extruded PEEK-CF30 stock, ASTM D696; source states 0.80e-5 in/in/°F) — about a third of unfilled PEEK[6][18] |
| Flammability / UL 94 | Not documented | UL 94 V-0 on the base resin; Ensinger lists extruded PEEK-CF30 stock as inherently flame resistant[17][6] |
| Environment & Chemical | ||
| Water / humidity resistance in service1–5 | Absorbs water, properties shift[15] | Not documented |
| Biodegradability / compostability | Bio-based — the monomer comes from castor oil[2] | Not documented |
| Electrical & ESD properties | Not documented | Surface resistance above 10⁹ ohm/sq — not static-dissipative (ASTM D257)[3] |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised[20] | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[20] |
| VOC emission rateµg/min | Up to 180 caprolactam, the dominant VOC from nylon; total VOC reached nearly 200 µg/min, the highest of the nine filaments tested[20] | Not documented |
| Ultrafine-particle emission rateparticles/min | ≈2 × 10⁸ median — low for ultrafine particles despite the highest VOC mass of any filament tested[20] | Not documented |
| Hazardous species emitted | Caprolactam, at up to 180 µg/min from nylon filament — the largest single-VOC emission rate measured in the study[20] | Not documented |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[20] | Ventilated room or enclosure recommended[20] |
| Dust & fibre handling hazard | Not documented | Carbon fibre is bound in the matrix; sanding dust should not be inhaled[3] |
| Solvents & Solubility | ||
| Soluble in | Dissolved at 23 °C by formic acid, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — all laboratory reagents.[21][22] | 95–98 wt% sulphuric acid dissolves the matrix at 40–70 °C and leaves the fibre. Nothing else touches PEEK.[23][22] |
| Softened or crazed by | Mineral acids, oxidants, halogens and zinc chloride solutions attack the amide bond; ordinary solvents do not (BASF, PA6/66).[21] | Concentrated nitric, hydrofluoric, hydrobromic and hydriodic acids attack it; DCM, DMSO and THF swell thin-walled sections.[24][22] |
| Solvent welding & smoothing agent | None — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[21] | None — no solvent softens PEEK, so parts are joined thermally or mechanically, never chemically.[24][22] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- Prusament PA11 Technical Datasheet v1.0 Prusa Polymers · 2026-07 · tds
- Prusament PA11 — material page Prusa Polymers · 2026-08 · doc
- CarbonX Carbon Fiber PEEK Technical Data Sheet v3 3DXTech · 2026-08 · tds
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
- TECAPEEK CF30 black (PEEK-CF30) — stock shape properties Ensinger · 2026-08 · tds
- IEMAI 3D CF-PEEK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- IEMAI 3D GF-PEEK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- CARBONX PEEK+CF10 — product page (print recommendations) 3DXTech · 2026-08 · doc
- Composite materials filled with carbon, kevlar or glass Prusa Knowledge Base · 2026-08 · doc
- Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
- PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
- ThermaX PEEK Technical Data Sheet v3 3DXTech · 2026-08 · tds
- TECAPEEK natural (PEEK) — stock shape properties Ensinger · 2026-08 · tds
- PEEK polymers — product overview Victrex · 2026-08 · doc
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
- The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
- What solvents are not compatible with PEEK? — fluidics technical FAQ IDEX Health & Science · 2026-08 · doc