3D Printing Info

Filament comparison

PA-CF ESD vs PPSU

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PA-CF ESD vs PPSU — documented properties and sources
PropertyESD-safe CF nylonPAPPSUHIGHTEMP
Market snapshot
Listing priceUSD/kg; dated snapshots$129.98/kg median; $129.98–$129.98/kg across 1 dated product listings$337.40/kg median; $223.00–$732.56/kg across 4 dated product listings
Identity & Market
Base polymer / chemistryCarbon-filled polyamide compounded to a static-dissipative resistivity — Polymaker's grade uses a PA612 matrix[1]Polyphenylsulfone — an amorphous high-temperature sulfone polymer[2]
Densityg/cm³1.10 (ISO 1183)[1]1.28 (ISO 1183, 3DXTech; ASTM D792, Stratasys PPSF)[2][3]
Typical priceUSD/kg1 kg-equivalent spools cluster near 130[4]1 kg-equivalent spools span 223–733; the middle of the market is about 425[5][6][7][8]
Price range across brandsUSD/kg130 at Polymaker's 0.5 kg pricing[4]223-733 across brands; IEMAI 3D 223 at 1 kg, 3DXTech ThermaX PPSU 250 at 500 g, 3D4Makers 425 at 750 g, Kimya PPSU-S 733 at 500 g[5][6][7][8]
Market availability1–5Special order, 1–2 makers worldwide[4]Niche, a handful of specialist brands[5][6][7]
Spool sizes & diameters1.75 mm; 0.5 kg spools[4]1.75 and 2.85 mm; 200 g to 750 g spools[5][6][7]
Typical applicationsElectronics jigs and trays that also need nylon toughness and heat resistance[1]Steam-sterilisable medical and dental tooling, and aircraft interior parts[2]
Printing Parameters
Bed temperature°CNot documented130–150 (3DXTech)[2]
Enclosure / chamber requirement1–5Enclosure required (passive)[9]Actively heated chamber required[10][11]
Bed surface & adhesion aidPEI sheet with a glue stick, or a dedicated adhesive such as Magigoo[12][9]Not documented
Warping tendency1–5Not documentedSevere — heated chamber needed[10]
Bed-adhesion difficulty1–5Needs a specific surface plus adhesive[12]Not documented
Stringing / oozing tendency1–5Moderate — retraction tuning needed[9]Not documented
Overall printing difficulty1–5Expert / industrial hardware only[9][13]Expert / industrial hardware only[10][11]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required — Polymaker measures brass nozzle life at about 9 h on PA612-ESD and recommends hardened steel or ruby[1]Brass fine indefinitely for unfilled grades, but brass softens near these nozzle temperatures — hardened or plated hot ends are the norm[10]
Abrasiveness1–5Highly abrasive — carbon-filled nylon composite; Polymaker puts brass nozzle life at roughly 9 h on PA612-ESD[1]Non-abrasive when unfilled[2]
Nozzle clog risk1–5High — jams from moisture, heat creep or particles[13]Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[14]
Heat-creep / jam sensitivity1–5Moderate — good heatbreak cooling needed[12]Not documented
Hotend requirementMay require an all-metal hot end (Simplify3D)[12]Not documented
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5High (0.8–2 %) — the PA612 matrix sits between PA6 and PA12[15][16]Not documented
Equilibrium moisture content at ~50 % RH%Not documented0.37 in 24 h and 1.1 at saturation on extruded stock (ASTM D570)[17]
Effect of moisture on strengthPolymaker publishes dry and wet printed blocks for PA612-ESD itself: at 4.64 % moisture tensile falls 84.3 → 73.6 MPa and modulus 4294 → 3731 MPa[1][16]No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[14]
Storage requirementSealed below 20 % RH with desiccant[13]Not documented
Hydrolysis at melt temperaturePolymaker specifies an 80–100 °C dry and storage below 20 % RH; no molecular-weight loss figure is published, and the wet data it does publish is conditioning rather than melt hydrolysis[18][19]Not documented
Mechanical Properties
Tensile strength (XY)MPa84.3 ± 2.3 printed XY dry (annealed 100 °C/16 h), 73.6 ± 2.3 conditioned to 4.64 % moisture, ISO 527[1]55 (printed XY, ISO 527, 3DXTech) and 55 (printed on side long edge, ASTM D638, Stratasys PPSF); 79 at yield on extruded stock[2][3][17]
Young's modulusMPa4293.7 ± 116.4 printed XY dry and 3730.8 ± 156.2 conditioned, ISO 527[1]2100 (printed, ASTM D638, Stratasys PPSF) and 2310 (printed XY, ISO 527, 3DXTech); 2344 on extruded stock[2][3][17]
Elongation at break%3.0 ± 0.1 printed XY dry and 4.2 ± 0.4 conditioned, ISO 527[1]3 (printed, ISO 527 and ASTM D638) against 60 on extruded stock — printing costs PPSU almost all of its ductility[2][3][17]
Flexural strengthMPaNot documented110 (printed, ISO 178 and ASTM D790, 3DXTech and Stratasys PPSF agree); 91 on extruded stock[2][3][17]
Flexural modulusMPaNot documented2200 (printed, ASTM D790, Stratasys PPSF) and 2215 (printed XY, ISO 178, 3DXTech)[2][3]
Charpy impact, notchedkJ/m²5.9 ± 0.4 printed XY dry and 4.9 ± 0.3 conditioned, ISO 179 notched[1]Not documented
Other impact dataCharpy unnotched 24.1 ± 2.4 printed XY and 4.5 ± 0.2 printed Z (ISO 179)[1]Izod notched 58.7 J/m and unnotched 165.5 J/m (printed, ASTM D256 Method A, Stratasys PPSF); 160 J/m notched on extruded stock[3][17]
Layer adhesion / Z tensileMPa21.5 ± 2.7 printed Z dry — only a quarter of XY, the most anisotropic nylon composite here; 19.2 ± 1.6 conditioned[1]Not documented
Brittleness1–5Brittle — snaps with little warning; elongation 3.0 % in XY and 1.4 % in Z[1]Brittle — snaps with little warning[2]
Hardness (scale-specific)Shore A / Shore D / RockwellRockwell M88 / R117 on extruded PA66-GF30 stock (ASTM D785); no figure is published for a conductive carbon-filled nylon filament[20]Rockwell M86 on printed PPSF (ASTM D785, Stratasys); M96 on extruded PPSU stock (and an unlabelled 123)[3][17]
Creep resistance / sustained load1–5Good. Ensinger rates its PA66-CF30 compound for sustained static and dynamic load at 110 °C continuous service; the PA612 matrix here still takes up 4.64 % moisture at conditioning, which softens it[21][1]Good. Printed PPSF holds 189 °C heat deflection at 1.8 MPa (ASTM D648) and extruded stock is rated 149 °C long-term service, but Ensinger does not claim the creep resistance it claims for PSU and PPS[3][17]
Fatigue / repeated-flex resistance1–5Good. Ensinger states carbon-filled PA66 compounds have improved fatigue strength in tension, flexure and compression[21]Not documented
Elasticity / flexibility1–5Rigid[1]Rigid[2]
Z strength as % of XY%26 (printed Z against XY tensile)[1]Not documented
Thermal Properties
HDT at 0.45 MPa°C157.0 (ISO 75, 0.45 MPa)[1]190 (printed XY, ISO 75 at 0.45 MPa, 3DXTech)[2]
HDT at 1.8 MPa°C125.4 (ISO 75, 1.8 MPa)[1]189 (printed, ASTM D648 at 264 psi, Stratasys PPSF); 207 on extruded stock, converted from 405 °F[3][17]
Glass transition (Tg)°C41.8 (DSC)[1]230 (DSC) — the highest glass transition in the dataset[2]
Melting point / Vicat°C187.3 melting (DSC); Vicat 190.0 (ISO 306)[1]Not documented
Continuous service temperature°CNot documented149 long-term service on extruded PPSU stock, converted from 300 °F[17]
Thermal expansion (CTE)µm/m·KNot documented55.0 (printed PPSF, ASTM D696; source states 5.5e-5 mm/mm/°C) and 55.8 on extruded stock (ASTM D696, from 3.1e-5 in/in/°F)[3][17]
Flammability / UL 94Flammable; no UL 94 rating published for the grades surveyed[18]UL 94 V-0 at 1.5 mm, rated on the base resin[2]
Environment & Chemical
UV resistance1–5Months outdoors before embrittlement — unstabilised polyamide yellows under UV[9]Not documented
Chemical resistanceWithstands oils, fuels and alkalis[9]Withstands repeated steam autoclaving, the usual reason to choose PPSU over PSU; Stratasys also lists PPSF as passing 24 h stress-crack exposure to antifreeze, petrol, motor oil, power-steering, transmission and washer fluid at 23 °C and 100 °C[2][3]
Food contactNot food-contact certified as filament[9]Not documented
Biodegradability / compostabilityNot biodegradable[9]Not documented
RecyclabilityNot accepted in household plastic collection[9]Not documented
Electrical & ESD propertiesStatic-dissipative — the reason the grade exists; Polymaker's insulating nylon composites sit above 10¹² ohm by contrast[1][15]Volume resistivity 5e13 to 1.5e14 ohm-cm and dielectric strength 80-290 V/mil on printed PPSF (ASTM D257, D149)[3]
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised[22]Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[22]
VOC emission rateµg/minUp to 180 caprolactam, the dominant VOC from nylon and the largest single-VOC rate in the study[22]Not documented
Ultrafine-particle emission rateparticles/min≈2 × 10⁸ median for nylon — low for particles despite the highest VOC mass measured[22]Not documented
Hazardous species emittedCaprolactam, at up to 180 µg/min from nylon filament[22]Not documented
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[22]Ventilated room or enclosure recommended[22]
Dust & fibre handling hazardFibre is bound in the matrix; sanding dust should not be inhaled[18]Not documented
Post-Processing
Sanding & machiningSands poorly — gums rather than powders[12]Not documented
Gluing & solvent weldingCyanoacrylate; no common solvent welds polyamide[12]Not documented
Vapour / chemical smoothingNo practical vapour smoothing[12]Not documented
Solvents & Solubility
Soluble inFormic acid, phenol, m-cresol and hexafluoroisopropanol dissolve the matrix at 23 °C, leaving the fibre; laboratory reagents.[23]Dichloromethane dissolves it at 23 °C at every stress level; acetone solvates and softens unstressed PPSU (Solvay ESCR).[24]
Softened or crazed byZinc chloride solutions stress-crack the nylon matrix, alcoholic calcium chloride dissolves it, mineral acids attack it.[23]MEK ruptures stressed parts and toluene crazes them above 13.8 MPa; glass-filled grades survive where unfilled craze.[24]
Solvent welding & smoothing agentNone — nylon's only solvents (formic acid, phenol, HFIP) degrade the part, and the fibre blocks surface flow anyway.[23]Dichloromethane cements PPSU and NMP softens residual resin; both are laboratory reagents, not workshop stock.[24]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. Fiberon PA612-ESD Technical Data Sheet V1.0 Polymaker · 2025-06 · tds
  2. ThermaX PPSU Technical Data Sheet v3 3DXTech · 2026-08 · tds
  3. PPSF (polyphenylsulfone) — FDM Data Sheet Stratasys · 2018-06 · tds
  4. Polymaker product catalogue Polymaker · 2026-08 · vendor
  5. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  6. Kimya PPSU-S Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  7. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  8. IEMAI 3D PPSU 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  9. PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
  10. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  11. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  12. Nylon — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  13. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  14. THERMAX PPSU — product page (print recommendations) 3DXTech · 2026-08 · doc
  15. Fiberon PA612-CF15 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
  16. Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
  17. TECASON P black (PPSU) — stock shape properties Ensinger · 2026-08 · tds
  18. Fiberon PA6-CF20 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
  19. PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
  20. TECAMID 66 GF30 black (PA66-GF30) — stock shape properties Ensinger · 2026-08 · tds
  21. TECACOMP PA66 CF30 black — injection-moulding compound Ensinger · 2026-08 · tds
  22. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  23. Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
  24. Radel PPSU, Veradel PESU, Acudel modified PPSU Design Guide — environmental stress cracking tables Solvay Specialty Polymers · 2026-08 · tds