Filament comparison
PA-CF ESD vs PPS-CF
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | ESD-safe CF nylonPA | Fibre-reinforced PPSHIGHTEMP |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $129.98/kg median; $129.98–$129.98/kg across 1 dated product listings | $139.98/kg median; $119.98–$174.17/kg across 5 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Carbon-filled polyamide compounded to a static-dissipative resistivity — Polymaker's grade uses a PA612 matrix[1] | Carbon-fibre reinforced PPS — Polymaker's Fiberon grade is nominally 10 wt%[2] |
| Densityg/cm³ | 1.10 (ISO 1183)[1] | 1.29 (Fiberon PPS-CF10) and 1.36 (Fiberon PPS-GF20), ISO 1183[2][3] |
| Typical priceUSD/kg | 1 kg-equivalent spools cluster near 130[4] | 1 kg-equivalent spools span 93–174; the middle of the market is about 140[4][5][6][7] |
| Price range across brandsUSD/kg | 130 at Polymaker's 0.5 kg pricing[4] | 93-174 across brands and formats; Polymaker Fiberon PPS-GF20 93 at 3 kg, IEMAI 3D CF-PPS 131 at 750 g, LEHVOSS Luvocom 3F PPS CF 9938 164 at 2.3 kg, Bambu Lab PPS-CF 174 at 750 g[4][5][6][7] |
| Market availability1–5 | Special order, 1–2 makers worldwide[4] | Available from several mainstream brands[4][5][6] |
| Spool sizes & diameters | 1.75 mm; 0.5 kg spools[4] | 1.75 mm; 0.5 kg spools[4] |
| Typical applications | Electronics jigs and trays that also need nylon toughness and heat resistance[1] | Chemical and automotive parts needing PPS chemistry with structural stiffness[2] |
| Printing Parameters | ||
| Enclosure / chamber requirement1–5 | Enclosure required (passive)[8] | Enclosure required (passive) — Polymaker states its Fiberon PPS-CF10 needs no heated chamber, unlike the unfilled sulfones and PAEKs[2] |
| Bed surface & adhesion aid | PEI sheet with a glue stick, or a dedicated adhesive such as Magigoo[9][8] | Not documented |
| Bed-adhesion difficulty1–5 | Needs a specific surface plus adhesive[9] | Not documented |
| Stringing / oozing tendency1–5 | Moderate — retraction tuning needed[8] | Not documented |
| Overall printing difficulty1–5 | Expert / industrial hardware only[8][10] | Expert / industrial hardware only[2] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Hardened steel required — Polymaker measures brass nozzle life at about 9 h on PA612-ESD and recommends hardened steel or ruby[1] | Hardened steel required[2] |
| Abrasiveness1–5 | Highly abrasive — carbon-filled nylon composite; Polymaker puts brass nozzle life at roughly 9 h on PA612-ESD[1] | Highly abrasive — standard CF composite[2] |
| Nozzle clog risk1–5 | High — jams from moisture, heat creep or particles[10] | High — jams from moisture, heat creep or particles; Polymaker specifies hardened steel or ruby nozzles for carbon-filled PPS and Prusa lists composites as a higher clogging risk[11][12] |
| Heat-creep / jam sensitivity1–5 | Moderate — good heatbreak cooling needed[9] | Not documented |
| Hotend requirement | May require an all-metal hot end (Simplify3D)[9] | Not documented |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | High (0.8–2 %) — the PA612 matrix sits between PA6 and PA12[13][14] | Low (0.1–0.3 %) — 0.225 % equilibrium for Fiberon PPS-CF10 and 0.11 % for PPS-GF20[2][3] |
| Equilibrium moisture content at ~50 % RH% | Not documented | 0.225 equilibrium (Fiberon PPS-CF10); 0.11 (PPS-GF20)[2][3] |
| Effect of moisture on strength | Polymaker publishes dry and wet printed blocks for PA612-ESD itself: at 4.64 % moisture tensile falls 84.3 → 73.6 MPa and modulus 4294 → 3731 MPa[1][14] | No dry-versus-conditioned figures are published; equilibrium uptake is 0.225 % and Polymaker specifies a 100 °C, 10 h dry[2] |
| Storage requirement | Sealed below 20 % RH with desiccant[10] | Not documented |
| Hydrolysis at melt temperature | Polymaker specifies an 80–100 °C dry and storage below 20 % RH; no molecular-weight loss figure is published, and the wet data it does publish is conditioning rather than melt hydrolysis[15][16] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 84.3 ± 2.3 printed XY dry (annealed 100 °C/16 h), 73.6 ± 2.3 conditioned to 4.64 % moisture, ISO 527[1] | 59.4 ± 1.3 (PPS-CF10) and 64.1 ± 2.1 (PPS-GF20) printed XY, ISO 527[2][3] |
| Young's modulusMPa | 4293.7 ± 116.4 printed XY dry and 3730.8 ± 156.2 conditioned, ISO 527[1] | 5446.7 ± 149.0 (PPS-CF10) and 4552.0 ± 54.6 (PPS-GF20) printed XY, ISO 527[2][3] |
| Elongation at break% | 3.0 ± 0.1 printed XY dry and 4.2 ± 0.4 conditioned, ISO 527[1] | 1.4 ± 0.1 (PPS-CF10) and 2.0 ± 0.2 (PPS-GF20) printed XY, ISO 527 — the lowest elongation in the dataset[2][3] |
| Charpy impact, notchedkJ/m² | 5.9 ± 0.4 printed XY dry and 4.9 ± 0.3 conditioned, ISO 179 notched[1] | 5.3 ± 0.2 printed XY for PPS-CF10 and 7.3 ± 0.2 for PPS-GF20, ISO 179 notched[2][3] |
| Other impact data | Charpy unnotched 24.1 ± 2.4 printed XY and 4.5 ± 0.2 printed Z (ISO 179)[1] | Not documented |
| Layer adhesion / Z tensileMPa | 21.5 ± 2.7 printed Z dry — only a quarter of XY, the most anisotropic nylon composite here; 19.2 ± 1.6 conditioned[1] | 32.0 ± 5.1 (PPS-CF10) and 22.9 ± 0.8 (PPS-GF20) printed Z, ISO 527[2][3] |
| Brittleness1–5 | Brittle — snaps with little warning; elongation 3.0 % in XY and 1.4 % in Z[1] | Very brittle — cracks or shatters easily; elongation at break 1.4 %[2] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Rockwell M88 / R117 on extruded PA66-GF30 stock (ASTM D785); no figure is published for a conductive carbon-filled nylon filament[17] | Rockwell 105 (and R124) on extruded unfilled PPS stock (ASTM D785); no figure is published for a fibre-filled PPS filament[18] |
| Creep resistance / sustained load1–5 | Good. Ensinger rates its PA66-CF30 compound for sustained static and dynamic load at 110 °C continuous service; the PA612 matrix here still takes up 4.64 % moisture at conditioning, which softens it[19][1] | Excellent — holds load for years. Ensinger lists high creep resistance for unfilled PPS stock and Spectrum states creep resistance is unchanged under continuous load at high temperature; the fibre raises heat deflection to 252 °C at 0.45 MPa[18][20][2] |
| Fatigue / repeated-flex resistance1–5 | Good. Ensinger states carbon-filled PA66 compounds have improved fatigue strength in tension, flexure and compression[19] | Not documented |
| Elasticity / flexibility1–5 | Rigid[1] | Rigid[2] |
| Z strength as % of XY% | 26 (printed Z against XY tensile)[1] | 54 (PPS-CF10) and 36 (PPS-GF20), printed[2][3] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 157.0 (ISO 75, 0.45 MPa)[1] | 252.5 (PPS-CF10) and 236.3 (PPS-GF20), printed, ISO 75 at 0.45 MPa[2][3] |
| HDT at 1.8 MPa°C | 125.4 (ISO 75, 1.8 MPa)[1] | 133 (PPS-CF10) and 125.8 (PPS-GF20), printed, ISO 75 at 1.8 MPa[2][3] |
| Glass transition (Tg)°C | 41.8 (DSC)[1] | 97.7 (PPS-CF10) and 95.0 (PPS-GF20), DSC[2][3] |
| Melting point / Vicat°C | 187.3 melting (DSC); Vicat 190.0 (ISO 306)[1] | 279.7 (PPS-CF10) and 279.6 (PPS-GF20) melting, DSC; Vicat 267.5 and 272.5 (ISO 306)[2][3] |
| Continuous service temperature°C | Not documented | 170 long-term service on extruded PPS stock, converted from 338 °F; no figure published for the carbon-filled grade[18] |
| Flammability / UL 94 | Flammable; no UL 94 rating published for the grades surveyed[15] | Not documented |
| Environment & Chemical | ||
| UV resistance1–5 | Months outdoors before embrittlement — unstabilised polyamide yellows under UV[8] | Not documented |
| Chemical resistance | Withstands oils, fuels and alkalis[8] | Outstanding — PPS resists essentially all solvents below 200 °C[11] |
| Food contact | Not food-contact certified as filament[8] | Not documented |
| Biodegradability / compostability | Not biodegradable[8] | Not documented |
| Recyclability | Not accepted in household plastic collection[8] | Not documented |
| Electrical & ESD properties | Static-dissipative — the reason the grade exists; Polymaker's insulating nylon composites sit above 10¹² ohm by contrast[1][13] | Surface resistivity above 10¹² ohm — insulating (ANSI/ESD S11.11)[2][3] |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised[21] | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[21] |
| VOC emission rateµg/min | Up to 180 caprolactam, the dominant VOC from nylon and the largest single-VOC rate in the study[21] | Not documented |
| Ultrafine-particle emission rateparticles/min | ≈2 × 10⁸ median for nylon — low for particles despite the highest VOC mass measured[21] | Not documented |
| Hazardous species emitted | Caprolactam, at up to 180 µg/min from nylon filament[21] | Not documented |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[21] | Ventilated room or enclosure recommended[21] |
| Dust & fibre handling hazard | Fibre is bound in the matrix; sanding dust should not be inhaled[15] | Fibre is bound in the matrix; sanding dust should not be inhaled[2] |
| Post-Processing | ||
| Sanding & machining | Sands poorly — gums rather than powders[9] | Not documented |
| Gluing & solvent welding | Cyanoacrylate; no common solvent welds polyamide[9] | Not documented |
| Vapour / chemical smoothing | No practical vapour smoothing[9] | Not documented |
| Solvents & Solubility | ||
| Soluble in | Formic acid, phenol, m-cresol and hexafluoroisopropanol dissolve the matrix at 23 °C, leaving the fibre; laboratory reagents.[22] | None — PPS does not dissolve in any known solvent below 200 °C.[23][24] |
| Softened or crazed by | Zinc chloride solutions stress-crack the nylon matrix, alcoholic calcium chloride dissolves it, mineral acids attack it.[22] | Nothing at 23 °C; Ensinger rates it only conditionally resistant to benzene, dichloromethane, toluene and pyridine.[24] |
| Solvent welding & smoothing agent | None — nylon's only solvents (formic acid, phenol, HFIP) degrade the part, and the fibre blocks surface flow anyway.[22] | None — no solvent welds or smooths PPS.[23] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- Fiberon PA612-ESD Technical Data Sheet V1.0 Polymaker · 2025-06 · tds
- Fiberon PPS-CF10 Technical Data Sheet V1.1 Polymaker · 2025-07 · tds
- Fiberon PPS-GF20 Technical Data Sheet V1.1 Polymaker · 2025-07 · tds
- Polymaker product catalogue Polymaker · 2026-08 · vendor
- Bambu Lab PPS-CF Black, spool (750 g) 3DJAKE · 2026-08 · vendor
- 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
- IEMAI 3D CF-PPS 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
- Nylon — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- PPS — material basics Polymaker Wiki · 2026-08 · doc
- Composite materials filled with carbon, kevlar or glass Prusa Knowledge Base · 2026-08 · doc
- Fiberon PA612-CF15 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
- Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
- Fiberon PA6-CF20 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
- PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
- TECAMID 66 GF30 black (PA66-GF30) — stock shape properties Ensinger · 2026-08 · tds
- TECATRON natural (PPS) — stock shape properties Ensinger · 2026-08 · tds
- TECACOMP PA66 CF30 black — injection-moulding compound Ensinger · 2026-08 · tds
- Spectrum PPS AM230 Technical Data Sheet Spectrum Filaments · 2022-04 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
- PPS (Polyphenylene sulfide) — Knowledge Base Prusa Research · 2026-08 · doc
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds