3D Printing Info

Filament comparison

PA-CF ESD vs PEKK

Compare printing settings, strength, heat resistance, dated prices and sources.

ESD-safe CF nylon guidePEKK guide

2 selected · all documented properties

Open these two in the interactive comparisonMore PA-CF ESD comparisonsMore PEKK comparisons
PA-CF ESD vs PEKK — documented properties and sources
PropertyESD-safe CF nylonPAPEKKHIGHTEMP
Market snapshot
Listing priceUSD/kg; dated snapshots$129.98/kg median; $129.98–$129.98/kg across 1 dated product listings$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings
Identity & Market
Base polymer / chemistryCarbon-filled polyamide compounded to a static-dissipative resistivity — Polymaker's grade uses a PA612 matrix[1]Polyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[2][3]
Densityg/cm³1.10 (ISO 1183)[1]1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[3][2]
Typical priceUSD/kg1 kg-equivalent spools cluster near 130[4]1 kg-equivalent spools cluster near 550[5][6][7]
Price range across brandsUSD/kg130 at Polymaker's 0.5 kg pricing[4]333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[5][6][7][8][9]
Market availability1–5Special order, 1–2 makers worldwide[4]Niche, a handful of specialist brands[5][6][7]
Spool sizes & diameters1.75 mm; 0.5 kg spools[4]1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[5][6][3]
Typical applicationsElectronics jigs and trays that also need nylon toughness and heat resistance[1]Aerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[2][3]
Printing Parameters
Bed temperature°CNot documented140 (3DXTech CarbonX PEKK-A CF15)[2]
Enclosure / chamber requirement1–5Enclosure required (passive)[10]Actively heated chamber required[11][12]
Bed surface & adhesion aidPEI sheet with a glue stick, or a dedicated adhesive such as Magigoo[13][10]Not documented
Bed-adhesion difficulty1–5Needs a specific surface plus adhesive[13]Not documented
Stringing / oozing tendency1–5Moderate — retraction tuning needed[10]Not documented
Overall printing difficulty1–5Expert / industrial hardware only[10][14]Expert / industrial hardware only[11][12]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required — Polymaker measures brass nozzle life at about 9 h on PA612-ESD and recommends hardened steel or ruby[1]Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[2][3]
Abrasiveness1–5Highly abrasive — carbon-filled nylon composite; Polymaker puts brass nozzle life at roughly 9 h on PA612-ESD[1]Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[2][3]
Nozzle clog risk1–5High — jams from moisture, heat creep or particles[14]Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[15]
Heat-creep / jam sensitivity1–5Moderate — good heatbreak cooling needed[13]Not documented
Hotend requirementMay require an all-metal hot end (Simplify3D)[13]Not documented
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5High (0.8–2 %) — the PA612 matrix sits between PA6 and PA12[16][17]Not documented
Effect of moisture on strengthPolymaker publishes dry and wet printed blocks for PA612-ESD itself: at 4.64 % moisture tensile falls 84.3 → 73.6 MPa and modulus 4294 → 3731 MPa[1][17]No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[15]
Storage requirementSealed below 20 % RH with desiccant[14]Not documented
Hydrolysis at melt temperaturePolymaker specifies an 80–100 °C dry and storage below 20 % RH; no molecular-weight loss figure is published, and the wet data it does publish is conditioning rather than melt hydrolysis[18][19]Not documented
Mechanical Properties
Tensile strength (XY)MPa84.3 ± 2.3 printed XY dry (annealed 100 °C/16 h), 73.6 ± 2.3 conditioned to 4.64 % moisture, ISO 527[1]86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[3][2]
Young's modulusMPa4293.7 ± 116.4 printed XY dry and 3730.8 ± 156.2 conditioned, ISO 527[1]2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[3][2]
Elongation at break%3.0 ± 0.1 printed XY dry and 4.2 ± 0.4 conditioned, ISO 527[1]6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[3][2]
Flexural strengthMPaNot documented136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[3][2]
Flexural modulusMPaNot documented3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[3][2]
Charpy impact, notchedkJ/m²5.9 ± 0.4 printed XY dry and 4.9 ± 0.3 conditioned, ISO 179 notched[1]Not documented
Other impact dataCharpy unnotched 24.1 ± 2.4 printed XY and 4.5 ± 0.2 printed Z (ISO 179)[1]Izod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[3]
Layer adhesion / Z tensileMPa21.5 ± 2.7 printed Z dry — only a quarter of XY, the most anisotropic nylon composite here; 19.2 ± 1.6 conditioned[1]50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[3][20]
Brittleness1–5Brittle — snaps with little warning; elongation 3.0 % in XY and 1.4 % in Z[1]Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[3][2]
Hardness (scale-specific)Shore A / Shore D / RockwellRockwell M88 / R117 on extruded PA66-GF30 stock (ASTM D785); no figure is published for a conductive carbon-filled nylon filament[21]Not documented
Creep resistance / sustained load1–5Good. Ensinger rates its PA66-CF30 compound for sustained static and dynamic load at 110 °C continuous service; the PA612 matrix here still takes up 4.64 % moisture at conditioning, which softens it[22][1]Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[3]
Fatigue / repeated-flex resistance1–5Good. Ensinger states carbon-filled PA66 compounds have improved fatigue strength in tension, flexure and compression[22]Not documented
Elasticity / flexibility1–5Rigid[1]Rigid[2]
Z strength as % of XY%26 (printed Z against XY tensile)[1]56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[3][20]
Thermal Properties
HDT at 0.45 MPa°C157.0 (ISO 75, 0.45 MPa)[1]158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[3][2]
HDT at 1.8 MPa°C125.4 (ISO 75, 1.8 MPa)[1]156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[3]
Glass transition (Tg)°C41.8 (DSC)[1]156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[3][2]
Melting point / Vicat°C187.3 melting (DSC); Vicat 190.0 (ISO 306)[1]300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[3][2]
Thermal expansion (CTE)µm/m·KNot documented36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[3][20]
Flammability / UL 94Flammable; no UL 94 rating published for the grades surveyed[18]Not documented
Environment & Chemical
UV resistance1–5Months outdoors before embrittlement — unstabilised polyamide yellows under UV[10]Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[3]
Chemical resistanceWithstands oils, fuels and alkalis[10]Not documented
Food contactNot food-contact certified as filament[10]Not documented
Biodegradability / compostabilityNot biodegradable[10]Not documented
RecyclabilityNot accepted in household plastic collection[10]Not documented
Electrical & ESD propertiesStatic-dissipative — the reason the grade exists; Polymaker's insulating nylon composites sit above 10¹² ohm by contrast[1][16]Unfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[3][2][20]
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised[23]Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[23]
VOC emission rateµg/minUp to 180 caprolactam, the dominant VOC from nylon and the largest single-VOC rate in the study[23]Not documented
Ultrafine-particle emission rateparticles/min≈2 × 10⁸ median for nylon — low for particles despite the highest VOC mass measured[23]Not documented
Hazardous species emittedCaprolactam, at up to 180 µg/min from nylon filament[23]Not documented
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[23]Ventilated room or enclosure recommended[23]
Dust & fibre handling hazardFibre is bound in the matrix; sanding dust should not be inhaled[18]Carbon fibre is bound in the matrix; sanding dust should not be inhaled[2]
Post-Processing
Sanding & machiningSands poorly — gums rather than powders[13]Not documented
Gluing & solvent weldingCyanoacrylate; no common solvent welds polyamide[13]Not documented
Vapour / chemical smoothingNo practical vapour smoothing[13]Not documented
Solvents & Solubility
Soluble inFormic acid, phenol, m-cresol and hexafluoroisopropanol dissolve the matrix at 23 °C, leaving the fibre; laboratory reagents.[24]Concentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[25][26]
Softened or crazed byZinc chloride solutions stress-crack the nylon matrix, alcoholic calcium chloride dissolves it, mineral acids attack it.[24]Concentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[25]
Solvent welding & smoothing agentNone — nylon's only solvents (formic acid, phenol, HFIP) degrade the part, and the fibre blocks surface flow anyway.[24]None — no solvent softens a polyaryletherketone.[25]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. Fiberon PA612-ESD Technical Data Sheet V1.0 Polymaker · 2025-06 · tds
  2. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  3. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  4. Polymaker product catalogue Polymaker · 2026-08 · vendor
  5. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  6. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  7. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  8. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  9. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  10. PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
  11. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  12. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  13. Nylon — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  14. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  15. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  16. Fiberon PA612-CF15 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
  17. Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
  18. Fiberon PA6-CF20 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
  19. PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
  20. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  21. TECAMID 66 GF30 black (PA66-GF30) — stock shape properties Ensinger · 2026-08 · tds
  22. TECACOMP PA66 CF30 black — injection-moulding compound Ensinger · 2026-08 · tds
  23. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  24. Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
  25. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  26. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper