Filament comparison
PA-CF ESD vs PEEK-CF
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | ESD-safe CF nylonPA | Fibre-reinforced PEEKHIGHTEMP |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $129.98/kg median; $129.98–$129.98/kg across 1 dated product listings | $597.50/kg median; $448.00–$695.00/kg across 5 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Carbon-filled polyamide compounded to a static-dissipative resistivity — Polymaker's grade uses a PA612 matrix[1] | Short-fibre reinforced PEEK. 3DXTech's CarbonX grade is nominally 10 wt% carbon and its FibreX grade 20 wt% glass; LEHVOSS Luvocom 3F PEEK CF 9676 is 15 wt% carbon; Ensinger's machining stock runs to 30 wt% carbon[2][3][4][5] |
| Densityg/cm³ | 1.10 (ISO 1183)[1] | 1.39 (ISO 1183)[2] |
| Typical priceUSD/kg | 1 kg-equivalent spools cluster near 130[6] | 1 kg-equivalent spools span 448–972; the middle of the market is about 598[3][4][7] |
| Price range across brandsUSD/kg | 130 at Polymaker's 0.5 kg pricing[6] | 448-972 across formats and filler types; IEMAI 3D CF-PEEK and GF-PEEK 448 at 1 kg, 3DXTech CarbonX PEEK+CF10 598 at 2 kg and FibreX PEEK+GF20 695 at 1 kg, Luvocom 3F PEEK CF 9676 648 at 2 kg[3][4][7][8] |
| Market availability1–5 | Special order, 1–2 makers worldwide[6] | Niche, a handful of specialist brands[3][4] |
| Spool sizes & diameters | 1.75 mm; 0.5 kg spools[6] | 1.75 and 2.85 mm; 200 g to 2 kg spools[3][4] |
| Typical applications | Electronics jigs and trays that also need nylon toughness and heat resistance[1] | Stiff aerospace and oil-and-gas parts where PEEK alone is not rigid enough[2] |
| Printing Parameters | ||
| Enclosure / chamber requirement1–5 | Enclosure required (passive)[9] | Actively heated chamber required[10][11] |
| Bed surface & adhesion aid | PEI sheet with a glue stick, or a dedicated adhesive such as Magigoo[12][9] | Not documented |
| Warping tendency1–5 | Not documented | Moderate — needs adhesion aid or draught shield; the fibre cuts PEEK's crystallisation shrinkage[2] |
| Bed-adhesion difficulty1–5 | Needs a specific surface plus adhesive[12] | Not documented |
| Stringing / oozing tendency1–5 | Moderate — retraction tuning needed[9] | Not documented |
| Overall printing difficulty1–5 | Expert / industrial hardware only[9][13] | Expert / industrial hardware only[10][11] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Hardened steel required — Polymaker measures brass nozzle life at about 9 h on PA612-ESD and recommends hardened steel or ruby[1] | Hardened steel required[2] |
| Abrasiveness1–5 | Highly abrasive — carbon-filled nylon composite; Polymaker puts brass nozzle life at roughly 9 h on PA612-ESD[1] | Highly abrasive — standard CF composite[2] |
| Nozzle clog risk1–5 | High — jams from moisture, heat creep or particles[13] | High — jams from moisture, heat creep or particles; 3DXTech adds a hardened 0.4 mm minimum nozzle and 0.25 mm layers to the mandatory 120 °C pre-dry[14][15] |
| Heat-creep / jam sensitivity1–5 | Moderate — good heatbreak cooling needed[12] | Not documented |
| Hotend requirement | May require an all-metal hot end (Simplify3D)[12] | Not documented |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | High (0.8–2 %) — the PA612 matrix sits between PA6 and PA12[16][17] | Not documented |
| Equilibrium moisture content at ~50 % RH% | Not documented | 0.06 in 24 h on extruded CF30 stock (ASTM D570)[5] |
| Effect of moisture on strength | Polymaker publishes dry and wet printed blocks for PA612-ESD itself: at 4.64 % moisture tensile falls 84.3 → 73.6 MPa and modulus 4294 → 3731 MPa[1][17] | No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[14] |
| Storage requirement | Sealed below 20 % RH with desiccant[13] | Not documented |
| Hydrolysis at melt temperature | Polymaker specifies an 80–100 °C dry and storage below 20 % RH; no molecular-weight loss figure is published, and the wet data it does publish is conditioning rather than melt hydrolysis[18][19] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 84.3 ± 2.3 printed XY dry (annealed 100 °C/16 h), 73.6 ± 2.3 conditioned to 4.64 % moisture, ISO 527[1] | 105 at break (printed XY, ISO 527, CF10); 121 at yield on extruded CF30 stock (ASTM D638)[2][5] |
| Young's modulusMPa | 4293.7 ± 116.4 printed XY dry and 3730.8 ± 156.2 conditioned, ISO 527[1] | 8100 (printed XY, ISO 527, CF10) — more than double unfilled PEEK; 6343 on extruded CF30 stock (ASTM D638)[2][5] |
| Elongation at break% | 3.0 ± 0.1 printed XY dry and 4.2 ± 0.4 conditioned, ISO 527[1] | 3 at break (printed XY, ISO 527), against 28 for unfilled PEEK[2][20] |
| Flexural strengthMPa | Not documented | 136 (printed XY, ISO 178, CF10); 193 on extruded CF30 stock (ASTM D790)[2][5] |
| Flexural modulusMPa | Not documented | 8300 (printed XY, ISO 178, CF10); 7171 on extruded CF30 stock (ASTM D790)[2][5] |
| Charpy impact, notchedkJ/m² | 5.9 ± 0.4 printed XY dry and 4.9 ± 0.3 conditioned, ISO 179 notched[1] | Not documented |
| Other impact data | Charpy unnotched 24.1 ± 2.4 printed XY and 4.5 ± 0.2 printed Z (ISO 179)[1] | Izod notched 61.9 J/m on extruded CF30 stock, converted from 1.16 ft-lb/in (ASTM D256)[5] |
| Layer adhesion / Z tensileMPa | 21.5 ± 2.7 printed Z dry — only a quarter of XY, the most anisotropic nylon composite here; 19.2 ± 1.6 conditioned[1] | Not documented |
| Brittleness1–5 | Brittle — snaps with little warning; elongation 3.0 % in XY and 1.4 % in Z[1] | Brittle — snaps with little warning; elongation falls from 28 % to 3 %[2][20] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Rockwell M88 / R117 on extruded PA66-GF30 stock (ASTM D785); no figure is published for a conductive carbon-filled nylon filament[21] | Rockwell M107 on extruded PEEK-CF30 stock (ASTM D785), against M100 unfilled[5][22] |
| Creep resistance / sustained load1–5 | Good. Ensinger rates its PA66-CF30 compound for sustained static and dynamic load at 110 °C continuous service; the PA612 matrix here still takes up 4.64 % moisture at conditioning, which softens it[23][1] | Excellent — holds load for years. Ensinger rates carbon-fibre PEEK stock as very highly creep resistant and specifies 260 °C continuous service[5] |
| Fatigue / repeated-flex resistance1–5 | Good. Ensinger states carbon-filled PA66 compounds have improved fatigue strength in tension, flexure and compression[23] | Good. Victrex rates PEEK for long-term fatigue as well as creep; the fibre cuts elongation at break from 28 % to 3 %, which limits repeated large-strain flexing[24][2][20] |
| Elasticity / flexibility1–5 | Rigid[1] | Rigid[2] |
| Z strength as % of XY% | 26 (printed Z against XY tensile)[1] | Not documented |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 157.0 (ISO 75, 0.45 MPa)[1] | 265 (printed XY, ISO 75 at 0.45 MPa, CarbonX PEEK+CF10) against 140 for unfilled PEEK[2][20] |
| HDT at 1.8 MPa°C | 125.4 (ISO 75, 1.8 MPa)[1] | 316 on extruded CF30 stock, converted from 600 °F at 264 psi (ASTM D648)[5] |
| Glass transition (Tg)°C | 41.8 (DSC)[1] | 143 (DSC, CarbonX PEEK+CF10) — the fibre does not move the glass transition[2] |
| Melting point / Vicat°C | 187.3 melting (DSC); Vicat 190.0 (ISO 306)[1] | 334 melting on extruded CF30 stock, converted from 633 °F[5] |
| Continuous service temperature°C | Not documented | 260 long-term on extruded CF30 stock, converted from 500 °F; 300 short term[5] |
| Thermal expansion (CTE)µm/m·K | Not documented | 14.4 (extruded PEEK-CF30 stock, ASTM D696; source states 0.80e-5 in/in/°F) — about a third of unfilled PEEK[5][22] |
| Flammability / UL 94 | Flammable; no UL 94 rating published for the grades surveyed[18] | UL 94 V-0 on the base resin; Ensinger lists extruded PEEK-CF30 stock as inherently flame resistant[20][5] |
| Environment & Chemical | ||
| UV resistance1–5 | Months outdoors before embrittlement — unstabilised polyamide yellows under UV[9] | Not documented |
| Chemical resistance | Withstands oils, fuels and alkalis[9] | Not documented |
| Food contact | Not food-contact certified as filament[9] | Not documented |
| Biodegradability / compostability | Not biodegradable[9] | Not documented |
| Recyclability | Not accepted in household plastic collection[9] | Not documented |
| Electrical & ESD properties | Static-dissipative — the reason the grade exists; Polymaker's insulating nylon composites sit above 10¹² ohm by contrast[1][16] | Surface resistance above 10⁹ ohm/sq — not static-dissipative (ASTM D257)[2] |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised[25] | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[25] |
| VOC emission rateµg/min | Up to 180 caprolactam, the dominant VOC from nylon and the largest single-VOC rate in the study[25] | Not documented |
| Ultrafine-particle emission rateparticles/min | ≈2 × 10⁸ median for nylon — low for particles despite the highest VOC mass measured[25] | Not documented |
| Hazardous species emitted | Caprolactam, at up to 180 µg/min from nylon filament[25] | Not documented |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[25] | Ventilated room or enclosure recommended[25] |
| Dust & fibre handling hazard | Fibre is bound in the matrix; sanding dust should not be inhaled[18] | Carbon fibre is bound in the matrix; sanding dust should not be inhaled[2] |
| Post-Processing | ||
| Sanding & machining | Sands poorly — gums rather than powders[12] | Not documented |
| Gluing & solvent welding | Cyanoacrylate; no common solvent welds polyamide[12] | Not documented |
| Vapour / chemical smoothing | No practical vapour smoothing[12] | Not documented |
| Solvents & Solubility | ||
| Soluble in | Formic acid, phenol, m-cresol and hexafluoroisopropanol dissolve the matrix at 23 °C, leaving the fibre; laboratory reagents.[26] | 95–98 wt% sulphuric acid dissolves the matrix at 40–70 °C and leaves the fibre. Nothing else touches PEEK.[27][28] |
| Softened or crazed by | Zinc chloride solutions stress-crack the nylon matrix, alcoholic calcium chloride dissolves it, mineral acids attack it.[26] | Concentrated nitric, hydrofluoric, hydrobromic and hydriodic acids attack it; DCM, DMSO and THF swell thin-walled sections.[29][28] |
| Solvent welding & smoothing agent | None — nylon's only solvents (formic acid, phenol, HFIP) degrade the part, and the fibre blocks surface flow anyway.[26] | None — no solvent softens PEEK, so parts are joined thermally or mechanically, never chemically.[29][28] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- Fiberon PA612-ESD Technical Data Sheet V1.0 Polymaker · 2025-06 · tds
- CarbonX Carbon Fiber PEEK Technical Data Sheet v3 3DXTech · 2026-08 · tds
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
- TECAPEEK CF30 black (PEEK-CF30) — stock shape properties Ensinger · 2026-08 · tds
- Polymaker product catalogue Polymaker · 2026-08 · vendor
- IEMAI 3D CF-PEEK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- IEMAI 3D GF-PEEK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- Nylon — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- CARBONX PEEK+CF10 — product page (print recommendations) 3DXTech · 2026-08 · doc
- Composite materials filled with carbon, kevlar or glass Prusa Knowledge Base · 2026-08 · doc
- Fiberon PA612-CF15 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
- Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
- Fiberon PA6-CF20 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
- PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
- ThermaX PEEK Technical Data Sheet v3 3DXTech · 2026-08 · tds
- TECAMID 66 GF30 black (PA66-GF30) — stock shape properties Ensinger · 2026-08 · tds
- TECAPEEK natural (PEEK) — stock shape properties Ensinger · 2026-08 · tds
- TECACOMP PA66 CF30 black — injection-moulding compound Ensinger · 2026-08 · tds
- PEEK polymers — product overview Victrex · 2026-08 · doc
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
- The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
- What solvents are not compatible with PEEK? — fluidics technical FAQ IDEX Health & Science · 2026-08 · doc